Oil Refinery Area Research Articles

Tracking air quality trends and vehicle traffic dynamics at urban scale using satellite and ground data before and after the COVID-19 outbreak

The implications of the COVID-19 outbreak are subjected to an increasing number of studies. So far, air quality trends related to the lockdown due to the pandemic have been analysed in large cities or entire regions.In this work, the region studied is the metropolitan area of Cagliari, which is the main city on the island of Sardinia (Italy) and can be representative of a coastal city that includes industrial settlements. The purpose of the study is to evaluate the effect of restrictions related to the COVID-19 outbreak on air quality levels and the traffic dynamics in this type of urban area. Nitrogen Dioxide (NO₂) levels before, during and after COVID-19 lockdown have been investigated using data acquired from the Sentinel-5P/TROPOMI satellite combined with on-site measurements. Both TROPOMI detected and ground-based data have revealed higher levels of NO₂ before and after the lockdown, compared to those during the period of COVID-related restrictions, in particular in the urban area of Cagliari. On the other hand, NO2 registered in the oil refinery area did not show significant differences associated with lockdown. The correlation of TROPOMI NO₂ tropospheric column with ground data (surface NO2) on a monthly mean basis showed different values based on the background and the highest Pearson's coefficient was of about 0.78 near to the city centre, where traffic can be considered a significant source of emission. In addition, a comparison of the air pollution level with the dynamics of vehicle traffic was investigated. The study highlighted a remarkable correlation between the reduction of the number of vehicles and the corresponding tropospheric NO₂ values that decreased on a weekly mean basis.

A Study on the Geochemistry of Groundwater Exhibiting Natural Attenuation of Phenols in the Alluvial Tracts of Oil Refinery Area of Bongaigaon District, Assam

Abstract: Hydrochemical and hydrogeological studies were carried out in the groundwater of Dhaligaon refinery area, Bongaigoan district, Assam. The study revealed that the area is underlain by alluvial deposits of thickness varying from 67 to 142 meters and the groundwater occurs in unconfined alluvial formations. Transmissivity values of the formations range from 2100 to 3800 m2/day. The effluents from the refinery are disposed off into a natural drain, “Tunia nala”, which contaminates the groundwater. The effluents contain constituents like phenol, nitrite, sulphide, iron etc, which subsequently seep into the dug well zone, but the phenol concentrations get naturally attenuated during the contaminant transport to the depths below. The probable reasons leading to natural attenuation of phenol as per in-situ hydrogeological and environmental conditions have been discussed.

Removing of Crude Oil From Polluted Areas Using the Isolated Fungi From Tehran Oil Refinery

ABSTRACTThe pollution of soil and the subsurface environment by crude oil spill and petroleum products spill is a major concern around the world. The aim of this research was to investigate the ability of fungi isolated from Tehran oil refinery area in removing crude oil and to evaluate their enzymatic activities. Plant root samples were collected from the polluted and control areas, and rhizospheral fungi were isolated and determined using the laboratory methods and taxonomic keys. Seven fungal species were isolated and then cultured in potato dextrose agar (PDA) media containing 0–15% (v/v) crude oil. Oil removal was determined after a one-month growth of fungal colonies and then compared with the control media. The results showed that the studied fungi were able to remove crude oil from the media. The highest removal efficiency was observed in Aspergillus sp. Total protein content and enzymatic activity (of peroxidase and catalase) increased with increasing crude oil pollution. The highest enzymatic activity was evaluated in Aspergillus sp. growing in media containing 15% petroleum and the lowest activity was found in non-polluted groups. Results showed that there is a direct correlation between oil-removing potency and enzymatic activity. Aspergillus sp. showed the highest enzyme activity and also the highest petroleum removal efficiency.

Sulphuric acid and aerosol particle production in the vicinity of an oil refinery

In this paper we introduce in-situ observations of trace gases, aerosol particles and their precursors in the vicinity of an oil refinery and industrial area in Kilpilahti, Southern Finland. We conducted a one-month measurement campaign near the oil refinery during summertime when the sulphur dioxide concentrations at the site are typically the highest. The source areas around the measurement location were divided into three sectors: oil refinery area, industrial area and non-industrial area. The atmospheric concentrations of aerosols and trace gases showed a large temporal variability, when exposed to the different source areas. The median sulphur dioxide concentrations for the oil refinery, industrial and non-industrial area were 1.88 ppbv, 0.75 ppbv and 0.38 ppbv, respectively, and the corresponding sulphuric acid concentrations were 11.5 × 106 molecules/cm3, 4.4 × 106 molecules/cm3 and 1.3 × 106 molecules/cm3. The observed concentrations were similar to what have been measured in urban or industrial sites. The ratio between sulphuric acid and sulphur dioxide was the highest when the air mass was coming from the oil refinery. The correlation between the sulphuric acid and 1–2 nm particle concentrations was significant, but the composition of the particles remained unknown as no neutral sulphuric acid clusters were detected with the mass spectrometer. Only a few new particle formation events were observed during the measurement period, and during these events a large fraction of the particle growth could be explained by sulphuric acid condensation.

Screening for plants and rhizospheral fungi with bioremediation potency of petroleum-polluted soils in a Tehran oil refinery area

The contamination of soils by toxic and/or hazardous organic pollutants, especially with crude oil, is a widespread problem. This study was conducted in a petroleum-contaminated area in a Tehran oil refinery to find petroleum-resistant plants and their rhizospheral fungal strains with bioremediation potency. The plants growing in the oil-polluted area were collected and determined taxonomically. Root samples of the plant species were collected from a polluted area and fungal strains determined by laboratory methods and taxonomical keys. The growth ability of the isolated fungal strains was studied in media containing 1%–15% crude oil. Results showed that seven plant species were of the highest density in the contaminated area: Alhagi persarum, Hordeum marinum, Peganum harmala, Phragmites australis, Prosopis farcta, Salsola kali, and Senecio glaucus. The root-associated fungi were isolated and showed that the fungal variation in the oil-polluted area is higher than that in a non-polluted area. The growth assay of isolated fungal strains showed that all studied fungal strains were able to form colonies at the applied concentrations but Alternaria sp. and Rhizopus sp. were the most resistant ones. Some plants were resistant to oil pollution, which also had positive effects on the fungal strains.

Soil risk assessment of heavy metal contamination near Oil Refinery area, Northeastern India

The present paper aims to maps Cr, Cd, Ni and Pb concentration and assess the hazard in the soils of surrounding agricultural fields affected by oil refinery drainage of Digboi refinery of Tinsukia district, Assam using statistics, geostatistics and GIS techniques. The amounts of Cr, Cd, Ni and Pb were determined from 97 samples collected within the contaminated area. Among the heavy metals studied, the mean concentration of Pb was high. The greatest and the smallest standard deviation were observed in the Ni (44.1) and pH (0.47), respectively. Analysis of the isotropic variogram indicated that the Cr and Cd semivariograms were well described with the circular model, with the distance of spatial dependence being 1240 and 1022 m, respectively, while the Pb and Ni were well describe with Gaussain model, with the distance of spatial dependence being 1930 and 2321 m, respectively. The ordinary kriging maps of Cr, Cd, Ni and Pb showed that high concentrations of heavy metals were located in the low lying area. Indicator kriged probability maps of soil Cr, Cd, Ni and Pb were prepared based on the concentrations to exceed the respective Food and Agriculture Organization maximum permissible limit (MPL) value of 100, 3, 30 and 50 mg kg−1, respectively. It was seen that whole studied area had a higher than 0.99% probability to exceed the MPL value of Pb. About 10% area of the study site was having higher concentration than MPL value of Cd and Ni concentrated at the centre and north-west corner of the study area, respectively.

STUDI KANDUNGAN MINYAK DAN STRUKTUR KOMUNITAS MAKROZOOBENTHOS DI PERAIRAN SEKITAR BUANGAN LIMBAH CAIR KILANG MINYAK PERTAMINA UP II DUMAI

Study on the effects of oil content on the macrozoobenthic community in thecoastal waters receiving oil refinery effluents has been conducted. Samples ofwater and sediment were collected in August 2006 from three stations in oilrefinery and one control station in far distance from the oil refinery area. Waterquality parameters measured in the present study were still in the tolerable levelfor the aquatic biota. Oil content in the stations close to the oil refinery (10.17 -12.17 ppm and 11.17 - 15.42 ppm) was higher than the control station (6.92 and6.17 ppm) at high and low tide respectively. The abundance of macrozoobenthicat the control station (333.23 id/m2) was higher that the oil refinery (151.50 -281.25 ind/m2). Simple linear regression showed that macrozoobenthic abundancewas negatively correlated with oil content in the water column (Y = 431.92 -17.81 X; r = 0.64) and it was positively correlated with total organic matter in thesediment (V = -174.55 + 27.23X: r = 0.69). This study showed that the oil refineryand its related activities have significant contribution to the elevated oil contentand the decreasing water quality which finally affect the macrozoobenthiccommunity structure in the surrounding aquatic environments.

Evaluation of Carcinogenic Risk Due to Accidental Ingestion of PAHs in Contaminated Soils

AbstractPolycyclic aromatic hydrocarbons (PAHs) are types of hazardous contaminants, which their ingestion could cause severe consequences on human health. Leakages from storage tanks, underground pipelines, and evaporation ponds are the main sources of soil and groundwater contaminations at the Tehran Oil Refinery area (TOR site), located in south of Tehran, Iran. In this study, soil samples were collected from different locations at and adjacent to a polluted stream in the south of the refinery. The samples were analyzed for two hazardous PAH compounds, namely benzo[a]anthracene and acenaphthene. The clean up levels due to the accidental ingestion of contaminated soils at the site were also investigated in accordance to the U.S.EPA guidelines. Comparing the soil analysis results indicated that the benzo[a]anthracene concentrations in the samples varied from 53 to 299 mg/kg, which were higher than the clean up level of 1.17 mg/kg. Thus, soil remediation is required for this contaminant. The acenaphthene analysis results denoted that the average concentration of this contaminant was below the clean up level of 116.67 mg/kg, indicating that no treatment for this contaminant is necessary at the TOR site. Also, because the slope of the ground extends to the south of the stream, which stimulates the migration of the contaminants in this direction due to advection and dispersion mechanisms, the average of benzo[a]anthracene concentrations in south samples was higher than north samples (i.e., Cavg(S) = 160 ppm, Cavg(N) = 113 ppm). Various treatment techniques such as thermal desorption, soil vapor extraction (SVE), and solidification/stabilization (S/S) were investigated for this site. Due to moderate to high plasticity and relatively low permeability of the soil and low volatility of benzo[a]anthracene, however S/S method is recommended as a practical approach for the remediation of the soil at the site.

Variations of sulfur isotope ratios in a single lichen thallus: A potential historical archive for sulfur pollution

Utilizing the analytical capability to measure S isotope ratios of small quantities of S in biological material without any chemical pretreatment, the variation of δ 34S within a lichen thallus was investigated using old and young segments of fruticose lichen thalli ( Alectoria sarmentosa) from an oil refinery area in Come-By-Chance and two coastal areas, Newfoundland, Canada. Old segments of lichen samples from the oil refinery area showed significantly higher δ 34S values (1.0–2.5‰) than their corresponding young segments. Lichen samples from two coastal areas showed no noticeable differences in δ 34S values between old and young segments. These results demonstrate that lichen thalli record temporal changes in the isotopic composition of atmospheric S and hence constitute a historical archive of atmospheric S pollution.