Oil Methyl Ester Research Articles

Combustion Analysis on Compression Engine by using Blends of Methyl Ester, Diesel and Turmeric Oil as an Additive

Combustion Analysis on Compression Engine by using Blends of Methyl Ester, Diesel and Turmeric Oil as an Additive

Experimental Investigation on Performance Characteristics o f Diesel Engine Using Various Blended Biodiesels

Objectives: To evaluate the performance characteristics of diesel engines through experimental research with various biodiesel blends. Method: Three types of oils were chosen for this study: waste cooking oil, waste chicken oil, and palm oil. The methyl esters were produced from waste chicken oil (COME), waste cooking oil (WCOME), and palm oil (POME). The test runs were done on a 4.5 kW direct injection, air-cooled, four-stroke, single-cylinder, and constant-speed diesel engine using varied fuel at maximum load. Findings: This study finds performance analysis for a variety of methyl esters and diesel. The Brake Thermal Efficiency (BTE) was found to be: for Diesel (33.36%), POME (30.53%), WCOME (27.5%), COME (25.0%) at rated power (4.5) K.W. The brake thermal efficiency for palm oil methyl esters is similar to the diesel compared to the other methyl esters. Novelty: This research study provides a comparison between the diesel and methyl esters of break thermal efficiency for diesel engines. Keywords: Diesel Engine, Trans esterification, Biodiesels, Performance characteristics

Synthesis, Properties, and Techno-economic Analysis of Highly Stable Biotransformer Oil Derived from Transesterification of Palm Oil Methyl Esters and Ditrimethylolpropane.

Currently, biotransformer oil (BTO) is in high demand due to the increasing level of electrical power consumption and environmental policy. Hence, this research aimed to prepare a highly stable BTO via basic transesterification of palm oil methyl ester (POME) and ditrimethylolpropane (Di-TMP) catalyzed by sodium methoxide (NaOCH3). Under the optimal conditions (POME/Di-TMP molar ratio = 5.0/1.0, NaOCH3 loading = 8 mol % based on the Di-TMP content under 3.5 mbar, and 300 rpm at 160 °C for 2 h), the POME conversion level and POME-Di-TMPTTE selectivity reached 90.3% and 96.6%, respectively. The obtained BTO with a high POME-Di-TMPTTE portion exhibited greater oxidation stability with a higher flash point and breakdown voltage in accordance with the IEC 62770 specification. A techno-economic analysis revealed the possibility of POME-Di-TMPTTE as a commercial BTO for its competitive cost and profit based on the current commercial price of BTO.

Online characterization of primary and secondary emissions of particulate matter and acidic molecules from a modern fleet of city buses

Abstract. The potential impact of transitioning from conventional fossil fuel to a non-fossil-fuel vehicle fleet was investigated by measuring primary emissions via extractive sampling of bus plumes and assessing secondary mass formation using the Gothenburg Potential Aerosol Mass (Go:PAM) reactor from 76 in-use transit buses. Online chemical characterization of gaseous and particulate emissions from these buses was conducted using chemical ionization mass spectrometry (CIMS) with acetate as the reagent ion, coupled with the Filter Inlet for Gases and AEROsols (FIGAERO). Acetate reagent ion chemistry selectively ionizes acidic compounds, including organic and inorganic acids, as well as nitrated and sulfated organics. A significant reduction (48 %–98 %) in fresh particle emissions was observed in buses utilizing compressed natural gas (CNG), biodiesels like rapeseed methyl ester (RME) and hydrotreated vegetable oil (HVO), and hybrid-electric HVO (HVOHEV) compared to diesel (DSL). However, secondary particle formation from photooxidation of emissions was substantial across all the fuel types. The median ratio of particle mass emission factors of aged to fresh emissions increased in the following order: DSL buses at 4.0, HVO buses at 6.7, HVOHEV buses at 10.5, RME buses at 10.8, and CNG buses at 84. Of the compounds that can be identified by CIMS, fresh gaseous emissions from all Euro V/EEV (Enhanced Environmentally friendly Vehicle) buses, regardless of fuel type, were dominated by nitrogen-containing compounds such as nitrous acid (HONO), nitric acid (HNO3), and isocyanic acid (HNCO), alongside small monoacids (C1−C3). Notably, the emission of nitrogen-containing compounds was lower in Euro VI buses equipped with more advanced emission control technologies. Secondary gaseous organic acids correlated strongly with gaseous HNO3 signals (R2=0.85–0.99) in Go:PAM, but their moderate to weak correlations with post-photooxidation secondary particle mass suggest that they are not reliable tracers of secondary organic aerosol formation from bus exhaust. Our study highlights that non-regulated compounds and secondary pollutant formation, not currently addressed in legislation, are crucial considerations in the evaluation of environmental impacts of future fuel and engine technology shifts.

Unique fatty acid composition of coriander seed biodiesel

Biodiesel is a renewable and environmentally friendly alternative fuel that can be used in diesel engines without modification. In this study, biodiesel production from coriander seed oil obtained through a two-stage transesterification process using the cold pressing method was carried out in the Konya region. First, the oil's acid value was reduced through acid-catalyzed pretreatment to form coriander seed oil methyl esters, and then biodiesel was produced using standard transesterification with methanol and sodium methoxide catalyst. Coriander (Coriandrum sativum) contains an unusual fatty acid not previously reported as a major component in biodiesel fuels: petroselinic acid (6Z-octadecenoic acid; 68.5% by weight). Coriandrum sativum seed oil methyl ester was evaluated to have properties suitable for diesel engines, complying with EN 14214 and ASTM D6751 standards, with a unique fatty acid composition and excellent oxidative stability.

Effect of Piston Geometry on Performance Characteristics of VCR Engine with and without EGR when Fueled with Blends of Methyl Ester

The growing population and exhaustion of fossil fuels necessitate our search for new sources of energy. The study for this research encompasses an amalgamation of interest in alternative fuels, advanced engine technology such as variable compression ratio VCR, engine component modification, and a methodical approach to testing for assessing the effects on key performance of the engine. A 3.5 kW compression ignition (CI) engine was fueled with blends of behada, chicken fat, and turmeric oil methyl ester. Engine operating parameters, such as the compression ratio (CR), rate of exhaust gas recirculation (EGR), and piston top geometry, are optimized to maximize engine performance. CI engine was modified by changing the piston head (square and tangential groove top) for methyl ester diesel blend operations. In the study, diesel fuel is designated as B00 and methyl ester as B20. The influence of compression ratio (CR16 and CR18) with exhaust gas re-circulation (EGR 0% and EGR 10%) was evaluated. The key performance indicators: brake thermal efficiency (BTE), brake-specific energy consumption (BSEC), brake-specific fuel consumption (BSFC), air-to-fuel ratio (AFR), and exhaust gas temperature (EGT) are investigated. Results indicate that an increase in BTE accompanies an increase in load, suggesting enhanced thermal efficiency with increased power output. The consequence of VCR is also investigated, and it is determined that a higher CR results in a higher BTE due to an increase in compression pressure and temperature, thereby enhancing combustion. Due to the re-combustion of unburned hydrocarbons with the addition of EGR at a 10% rate, BTE increases further. Utilizing a piston geometry with tangential grooves and methyl ester blends also contributes to increased BTE. BSEC increases with increasing load, with an important rise observed when operating at maximum capacity. However,at CR 18, BSEC decreases as a result of enhanced combustion efficiency. EGR has different effects on BSEC depending on the geometry of the piston and the kind of fuel used. Enhanced air-fuel blending and re-combustion of unburned hydrocarbons reduce the BSEC of the engine. The tangential groove top piston operates with 10% EGR. Similar to BSEC, BSFC decreases with increasing CR and improves with the use of a piston with a tangential groove and 10% EGR operation. AFR decreases as the consumption of fuel increases to meet the power demand, and higher CR values result in a lower AFR. EGT rises with load, and CR18 has a lower EGT than CR16 as a result of a higher compressing temperature and pressure. 10% EGR operation reduces EGT by decreasing the concentration of oxygen in the combustible area.

Evaluation of performance, emissions and combustion attributes of diesel engines powered by Palmyra biodiesel blends with distinct injection pressures and EGR rates

The present work explores the viability of Palmyra oil methyl ester (POME) as a renewable biodiesel. Initially, oil is extracted from the Palmyra fruit and the oil is transesterified to produce Palmyra oil methyl ester. Preliminary tests were conducted with blends of Palmyra oil methyl esters. From the test results, it was found that the POME20 blend performed better than other blends and was considered as an optimised blend. Secondly, analysis was carried out with POME20 on the CI engine at three injection pressures (210bar, 230bar and 250bar). POME20 at 230bar was shown to have improved thermal efficiency and reduced emissions of CO, HC and CO2 except NOX emissions. Finally, the tests were repeated for optimal conditions of 230bar injection pressure along with 6% and 12% EGR rates. The experimental results revealed that POME20 operated at 230bar 6% EGR rate observed a drastic reduction of NOX by 32.08% and 57.49% compared to diesel and POME20.

Enhancing reactivity-controlled compression ignition engine performance: A response surface methodology approach with ammonium hydroxide-waste cooking oil biodiesel optimization

The focus on ammonium hydroxide, biodiesels and their combustion technology has garnered significant attention in pursuing carbon-neutral and carbon-free fuels to address greenhouse gas emissions (GHG) and mitigate global warming. Low-temperature combustion (LTC) has been introduced as an alternative method to conventional compression ignition (CI) combustion. Reactivity controlled compression ignition (RCCI) can be achieved by introducing highly reactive waste cooking oil methyl ester (WCOME) oil directly into the manifold in intervals of 10% energy and injecting low-reactive ammonium hydroxide at 20%–50%. Utilizing the response surface methodology (RSM) approach, it was determined that for optimal operation in RCCI mode, an ideal ammonium hydroxide energy sharing (AHES) of 43% would account for the varying parameters and their effects on emissions and performance. The results of the experiments predicted a brake thermal efficiency (BTHE) of 34.85% and a brake specific energy consumption (BSEC) of 10.69 MJ/kWh. Meanwhile, a notable decrease in exhaust emissions was observed for HC, CO, CO2, NO x and smoke by 41.54%, 38.89%, 48.89%, 51.27% and 65.80% respectively when compared to conventional biodiesel combustion (CBC). The experimental result at maximum load operation with an AHES of 50% indicates that RCCI combustion led to an increase in thermal efficiency from 30.36% to 35.42%, and the in-cylinder pressure and heat release rate dropped from 83.42 bar to 59.64 bar and 78.68 kJ to 60.92 kJ, respectively. There was a significant reduction in HC, CO, CO2, NO x and smoke emissions recorded as 58.76 ppm, 0.11%v, 1.61%v, 442 ppm and 6.64 N, respectively, compared to CBC.

Dissolved gas analysis comparison of electrically stressed methyl ester and mineral oil

Methyl ester is considered one of the alternative substitutes to mineral oil as an insulating liquid. This study investigates the dissolved gas analysis (DGA) of the methyl ester derived from palm oil, under low energy discharge faults. The aims are to understand the gas composition and evaluate the applicability of the well-established fault interpretation methods for mineral oil to the methyl ester. Experimental procedures were conducted based on the International Electrotechnical Commission (IEC) standards. It involved simulating electrical breakdowns in laboratory conditions as per IEC-156 standard and analyzing gas samples using gas chromatography based on IEC-567. Results show that methyl ester oils produce similar types of gases as mineral oils but at higher concentrations. The interpretation of DGA results using fault identification methods such as Duval Triangle, Duval Pentagon, and IEC ratio indicates an overestimation of fault severity in methyl ester oils, and categorizing the faults as high energy discharge. However, the key gas method correctly identifies the discharge in both methyl ester and mineral oils. These findings suggest the need for adjustments in existing DGA methods to account for the higher gas concentrations in methyl ester oils, for effective condition monitoring and maintenance of transformers if it was filled with methyl ester oil.

Synthesis and evaluation of modified cottonseed oil methyl ester as a novel biofuels

Synthesis and evaluation of modified cottonseed oil methyl ester as a novel biofuels

STUDYING HOW DIESEL ENGINE ADDITIVES USING SILVER OXIDE (Ag2O) NANOPARTICLES AFFECT THE ENVIRONMENT

Abstract: Biodiesel has been defined as an alternative fuel that has the potential to be used instead of diesel fuel for years. In case of complete combustion reaction in engines, the products released do not directly threaten human health. Compared to diesel fuel, biodiesel has worse combustion performance due to some fuel properties. Therefore, incomplete combustion products such as hydrocarbon (HC), carbon monoxide (CO), nitrogen oxide (NOx), smoke emission and complete combustion products such as CO2 are thrown into the atmosphere. In this study, the changes in exhaust emissions of 50 ppm and 75 ppm Ag2O NPs were experimentally examined to improve the adverse combustion performance and emission characteristics of cottonseed oil methyl ester. In experiments, nano additive improved the thermal conductivity, mass dissipation and heat transfer of the test fuels, and resulted in reducing of CO emissions as it provided a higher oxidation rate of hydrocarbon molecules. Due to the improvement in the combustion reaction, CO2 emission increased with product of complete combustion. The increase in CO2 emissions was 3.17% and 3.97% for CAg-50 and CAg-75 fuels, respectively, when compared to C0 fuel at 40 Nm load. The NPs additive increased the lower calorific value of the fuel and cylinder temperature. This situation caused increase of NOx emissions by 3.69% and 7.47% CAg-50 and CAg-75 fuels 40 Nm load. Adding of NPs in base fuel reduced to viscosity and density provided better atomization. So a reduction in smoke emission was obtained with NPs addition by 35.09% and 47.32% in CAg-50 and CAg-75 fuels, respectively, compared to C0 fuel at 10 Nm load, while 7.45% and 19.43% at 40 Nm load.

Photocatalytic and eco-emission applications of green synthesized ZnO-CB nanoparticles

Herein, we report the synthesis of ZnO nanoparticles (ZnO-CB NPs) by employing the solution combustion method using an aqueous extract of brinjal calyxes as fuel. Characterization techniques, such as X-ray diffraction (XRD), Fourier transform Infrared spectroscopy (FTIR), UV–visible spectroscopy, and Scanning electron microscopy (SEM), were used to investigate the structural, optical, and morphological properties of synthesized nanoparticles, respectively. Highly porous hexagonal crystalline ZnO-CB NPs with less than 7 nm particle size were obtained. The photocatalytic performance of synthesized material is measured with Malachite green (MG), Basic brown 1 (BB1), and Acid orange 36 (AO36) as benchmark dyes. It showed that the synthesized material worked effectively under pH 10 with UV light irradiation. The synthesized ZnO-CB NP shows good removal effectiveness of the MG, BB1, and AO36 dyes with 99.3 %, 99.6 %, and 99.5 %, respectively, which can be promising photocatalysts for ecological applications such as wastewater remediation. Further, the synthesized ZnO-CB NP was used as blends in the methyl ester of Millettia pinnata oil (MPME), which is blended 20 % with commercial diesel (MPME20). The synthesized ZnO-CB NP was added to the MPME20 in varying amounts to ascertain its effects on the quality of emissions of various greenhouse gases such as hydrocarbons, COx, and NOx. Moreover, brake thermal efficiency (BTHE) and brake-specific fuel consumption (BSFC) were studied for the blends. The blend MPME20 with 25 mg of ZnO-CB NP, i.e., MPME20-25 mg, ZnO-CB, displays the best performance and reduced emissions.

Experimental and simulation study of American saffron seed oil blended with diesel

In a variety of industries, including transportation, agriculture, and manufacturing, diesel engines are often employed. Due of rising prices and environmental concerns, researchers examined whether biodiesels might replace diesel. The current study looks into American Saffron Oil's feasibility as a feedstock for biodiesel production. The transesterification technique is used to extract American saffron oil methyl este(ASOME), which is then examined for its physical and chemical properties in accordance with ASTM standards. Diesel fuel and American Saffron Oil methyl ester are mixed on a volume basis to create a variety of fuel blends, including B20, B40, and B60. The test results showed that the 20 % ASOME mix had better performance and reduced emissions. Also, utilizing DIESEL-RK simulation software, diesel engine tests are conducted for the B20, B40, and B60 under identical operating circumstances. Moreover, diesel engine testing for the B20, B40, and B60 are carried out using DIESEL-RK simulation software under comparable operating circumstances. Results of simulation software tests show improved engine performance and reduced pollutants. When experimental data is compared to DIESEL-RK modeling software, it is found that brake thermal efficiency increased by 5.7 % and emissions of hydrocarbon and carbon monoxide decreased by 2.5 % and 14.3 %, respectively.

Performance of jack fruit methyl ester and pine oil blends with coconut shell nanoadditive biodiesel for automobile applications

Performance of jack fruit methyl ester and pine oil blends with coconut shell nanoadditive biodiesel for automobile applications

Numerical investigation of combustion characteristics of extended coherent flame model 3 zones (ECFM‐3Z) in diesel engines running with biodiesel

AbstractThis research investigates the application of Extended Coherent Flame Model‐3 Zones (ECFM‐3Z) to assess the performance and emissions of rapeseed oil methyl ester (ROME). Experimental tests were carried out using a Lombardini 3 LD 350 model single‐cylinder diesel engine, at 1600–3000 rpm with 200 rpm speed increments, under full load conditions. For numerical analysis, STAR‐CD/ESICE software was employed. Methyl Oleate (C19H36O2) was predicted as the surrogate biodiesel based on Gas Chromatography (GC) analysis and average mass calculation. Notably, the numerical analysis revealed a remarkable similarity in brake power between the experimental and computational investigations. In the range of 2400–3000 rpm, the biodiesel's performance exhibited a maximum deviation of 5%, primarily attributed to pumping, thermal, and friction losses. In terms of emissions, carbon dioxide (CO2) emissions were consistent with the findings of the experimental study, with a maximum disparity of 10%. However, carbon monoxide (CO) emissions ranged from 57% to 65% lower than those observed in the experimental study, while nitrogen oxide (NOx) emissions exhibited a reduction of 63% to 84%. In contrast, oxygen (O2) emissions were notably higher, ranging from 93% to 117% compared to the experimental study, and exhaust temperatures were elevated by 33% to 49% in comparison to the experimental results.

Effect of palm oil methyl ester on coconut oil as a viable bio‐lubricant alternative to traditional mineral‐based oils

AbstractVegetable oils are promoted as a base oil for automobile lubricants due to increased concerns about the environmental damage caused by synthetic and mineral oils‐derived lubricants. Coconut oil exhibits excellent tribological properties but poor cold flow properties. This work investigates the effect of the addition of palm oil methyl ester (POME), obtained from the transesterification of palm oil, on coconut oil by blending it in three proportions with varying volumes and evaluating for lubricant properties namely tribological properties, rheological properties, thermal properties, chemical properties and corrosion and oxidative stabilities. Fatty acid composition are evaluated for the base oil and the blends. The findings show that the addition of POME improves the base oil's pour point and reduces friction and wear. The corrosion test shows only slight tarnishing of copper strips, while the HOOT and chemical tests indicate appreciable resistance to oxidation. Therefore, this blended mixture has the potential to be a viable bio‐lubricant alternative to traditional mineral‐based oils.

Thermodynamic and exhaust emission studies of CI engine powered by neem oil methyl ester blends doped with nickel oxide nano additives

AbstractAssessment of alternate fuel is categorized on thermophysical aspects and performance—emission derived due to its combustion. Data derived from such analysis is short as the energy expenditure to available chemical exergy of fuel is rarely studied. The study of energy derived from fuel energy gives a detailed picture of fuel efficiency and broadens the field of fuel search criteria. The current article aims to find the thermodynamic effects in terms of energy and exergy utilization of neem biodiesel blends and nickel oxide nano additive dosed neem biodiesel blends. Neem biodiesel was transesterified using standard procedures and analyzed using gas chromatography and mass spectroscopy. Later, neem biodiesel was blended with diesel in three volumetric proportions, that is, NB25, NB50, NB75, and pure Neem Oil Methyl ester was investigated as an engine fuel, and later synthesized nickel oxide nano additives of 25 mg/L was added to all the above fuels and further studied for energy, exergy utilization on a TV‐1 VCR engine test rig under varying engine CR. Nickel oxide additives were manufactured using homogenous addition method and were thoroughly studied for formation and presence of constituents using XRD, FE‐SEM, and EDS methods. The usage of nano additives does prove reduction in exergy destruction and entropy generation for NB25 base blend with 25 mg/L NiO leading to a reduction of 8.2% and 9.7% when compared to base blends. Also, the emission found for hydrocarbon, and carbon monoxide for all base fuel blends reduced by an average of 16.8% and 7.35%.

Effect of Silica and Alumina Nanoparticles Addition on the Dielectric and Rheological Properties of Shea Oil Methyl Ester

Study’s Excerpt/Novelty This study introduces a novel green nanofluid by incorporating shea methyl ester (SME) with surface-modified Al2O3 and SiO2 nanoparticles, addressing the environmental concerns associated with mineral-based transformer oils. The research highlights that SiO2 nanoparticles significantly enhance the dielectric properties of the base oil while minimally impacting its viscosity, suggesting improved insulation performance. This innovative approach offers a sustainable alternative with superior electrical characteristics, potentially transforming the application of transformer oils in the industry. Full Abstract The increasing environmental and utility concerns of mineral-based transformer oils have impelled research into alternative insulation liquids. This study developed a green nanofluid using a two-step approach, incorporating shea methyl ester (SME) derived from shea butter oil and surface-modified Al2O3 and SiO2 nanoparticles. The dynamic viscosity at 25 °C and dielectric properties of the developed nanofluid were investigated in the frequency range of 0.1–15 kHz. Adding nanoparticles into the SME noticeably increased the oil's viscosity, with SiO2 nanoparticles having the least effect on the base liquid's viscosity. The addition of 0.6 wt% of Al2O3 nanoparticles increased the dielectric loss of the SME at all frequencies (0.1–15 kHz), while the addition of 0.6 wt% SiO2 filler nanoparticles reduced the loss of the base oil at frequencies beyond 4 kHz indicative of an improved electrical property. Adding Al2O3 and SiO2 to the base SME oil obtained higher relative permittivity values. This study successfully developed an SME and single nanoparticle-based nanofluid, incorporating a 0.6 wt% weight fraction of surface-modified Al2O3 and SiO2 nanoparticles. The addition of these nanoparticles increased the dynamic viscosity of the base methyl ester oil, with approximately 43% and 36% increases, respectively. The nanofluid developed by incorporating SiO2 nanoparticles showed promising dielectric performance for its application as an insulation liquid.

Enhancing Combustion Efficiency: Utilizing Graphene Oxide Nanofluids as Fuel Additives with Tomato Oil Methyl Ester in CI Engines

The research aims to conduct a thorough examination of the combustion, injection, performance, and emission characteristics of a diesel engine below different engine loads, as well as the synthesis of graphene oxide (GO) nano fuels and their utilization in combination with Tomato Oil methyl ester (TOME) and diesel fuel blend. The (GO), plays a vital role in the pre-mixed combustion phase of diesel engines. Addition of GO nano fuels enhances the high-pressure combustion stage, resulting in increased maximum pressure and heat release rate (HRR). TOME (B20GO75) and TOME (B20GO100) exhibit comparable HRR to diesel due to improved fuel characteristics and quicker ignition delay duration. While TOME (B20) shows a slight decrease in (BTE) compared to diesel, the addition of GO improves BTE, with TOME (B20GO50) displaying the highest BTE at full load, indicating enhanced combustion efficiency. Moreover, GO addition leads to a reduction in carbon monoxide (CO) and hydrocarbon (HC) emissions, with emissions decreasing as the dosage of GO increases. However, NOx emissions initially decrease with TOME (B20) compared to diesel but increase with higher GO dosages. Smoke emissions increase with TOME (B20) but decrease with higher GO dosages. Overall, the incorporation of GO nano fuels into TOME biodiesel fuel blends demonstrates potential for improving engine performance and reducing emissions.

Impact of multi-walled carbon nanotubes (MWCNTs) on hybrid biodiesel blends for cleaner combustion in CI engines

This study investigates the influence of multi-walled carbon nanotubes (MWCNTs) and hybrid biodiesel blends on the performance, combustion, and emission characteristics of a compression ignition engine. The hybrid biodiesel comprises waste frying oil methyl ester (WFOME), sesame oil methyl ester (SOME), and ultra-low sulfur diesel (ULSD) blended at 20 %:80 % by volume (B20). MWCNTs were added into B20 at 25 ppm and 50 ppm concentrations (B20-25MWCNT and B20-50MWCNT). Experimental analysis was conducted under varying engine loads and injection pressures, complemented by CFD simulations. Results demonstrate that the addition of MWCNTs significantly enhances B20 blend performance, with B20-50MWCNT exhibiting a 25 % increase in brake thermal efficiency and a 17 % reduction in brake specific fuel consumption compared to neat B20. Additionally, the incorporation of MWCNTs resulted in notable reductions in harmful emissions. NOx emissions for the B20 + 50MWCNT blend were reduced by up to 36 % compared to diesel and 43 % compared to B20. Smoke opacity and particulate emissions also showed significant decreases, highlighting the cleaner combustion facilitated by the presence of MWCNTs. The CFD simulations provided detailed insights into the combustion process, validating the experimental findings and elucidating the mechanisms behind the observed improvements. The enhanced fuel atomization, better fuel-air mixing, and catalytic properties of MWCNTs were identified as key factors contributing to the superior performance and reduced emissions.