The study of sex diagnosis is essential to reconstruct the biological profile of an unknown individual. Two approaches are often used: morphometric and scopic. This three-dimensional morphometric study aimed to assess sexual dimorphism in temporary dentition.: A total of 200 dental impressions digitized in 3D using the Revopoint® POP2 3D scanner were used for this odontometric analysis. Discriminant statistical analysis (Student's t-test) revealed that boys had higher mean values than girls for all distances measured. A highly significant sexual dimorphism was observed in the temporary second molars. The distance between the mandibular canines was slightly greater in boys, although this difference was not statistically significant. In conclusion, odontometric parameters are a simple, reliable, and inexpensive method of sex determination. The temporary canines and second molars are the most dimorphic.