Odd-frequency Pairing Research Articles

Odd-frequency pairing of Bogoliubov quasiparticles in superconductor junctions

Odd-frequency pairing of Bogoliubov quasiparticles in superconductor junctions

Odd-frequency superfluidity from a particle-number-conserving perspective

We investigate odd-in-time—or —pairing of fermions in equilibrium systems within the particle-number-conserving framework of Penrose, Onsager, and Yang, where superfluid order is defined by macroscopic eigenvalues of reduced density matrices. We show that odd-frequency pair correlations are synonymous with even fermion-exchange symmetry in a time-dependent correlation function that generalises the two-body reduced density matrix. Macroscopic even-under-fermion-exchange pairing is found to emerge from conventional Penrose-Onsager-Yang condensation in two-body or higher-order reduced density matrices through the symmetry-mixing properties of the Hamiltonian. We identify and characterize a matrix responsible for producing macroscopic even fermion-exchange correlations that coexist with a conventional Cooper-pair condensate, while a matrix is shown to be responsible for creating macroscopic even fermion-exchange correlations from hidden orders such as a multiparticle condensate. The transformer scenario is illustrated using the spin-balanced s-wave superfluid with Zeeman splitting as an example. The generator scenario is demonstrated by the composite-boson condensate arising for itinerant electrons coupled to magnetic excitations. Structural analysis of the transformer and generator matrices is shown to provide general conditions for odd-frequency pairing order to arise in a given system. Our formalism facilitates a fully general derivation of the Meissner effect for odd-frequency superconductors that holds also beyond the regime of validity for mean-field theory. Published by the American Physical Society 2024

Equal contribution of even-frequency and odd-frequency pairing to transport across normal metal–superconductor junctions

Equal contribution of even-frequency and odd-frequency pairing to transport across normal metal–superconductor junctions

Impurity and hybridization effects on the symmetry classification and magnetic response function of a two-band superconductor with interband pairing order

Abstract The effects of hybridization and impurity (magnetic and nonmagnetic) potentials on the pairing symmetries and magnetic response of a two-band superconductor with an equal-time s-wave interband pairing order parameter in the framework of Green’s function technique are investigated theoretically. First, the effects of spin-independent and spin-dependent hybridization on the generation of even- or odd-frequency Cooper pairs which determines the symmetry classification and the response of the superconductor are studied. Next, the impurity effect on creating different symmetry classes and the kernel response function of a two-band superconductor are discussed. By separating the contributions of even- and odd-frequency pairing to the Meissner kernel, it is shown that the competition between these two terms determines the total Meissner effect of the superconductor. For a two-band spin-singlet superconductor, nonmagnetic impurity scatterings do not change transition temperature according to Anderson’s theorem, while both intra- and interband magnetic impurity scattering cause superconducting transition temperature suppression with the rate following the Abrikosov–Gor’kov theory. For spin-triplet pairing, interband magnetic scattering has no impact on pair breaking, whereas intraband magnetic scattering acts as a pair breaker and suppresses the transition temperature in the Born limit. In this case, the odd-frequency superconducting pairs can be induced in the simultaneous presence of both intra- and interband magnetic impurities. Thus, by controlling the concentration of magnetic impurities, it is possible to engineer triplet-pairing odd-frequency superconductors with a total diamagnetic Meissner response which stabilizes the superconducting state. This technique opens up an avenue for designing stable odd-frequency superconductors.

η -pairing on square and triangular lattices

The $\ensuremath{\eta}$-pairing is a type of Cooper pairing state in which the phase of the superconducting order parameter is aligned in a staggered manner, in contrast to the usual BCS superconductors with a spatially uniform phase. In this study, we search for a characteristic $\ensuremath{\eta}$-pairing state in a triangular lattice where a simple staggered alignment of the phase is not possible. As an example, we consider the attractive Hubbard model on both the square and triangular lattices under a strong external Zeeman field. Using the mean-field approximation, we have identified several $\ensuremath{\eta}$-pairing states. Additionally, we have examined the electromagnetic stability of the pairing state by calculating the Meissner kernel. Odd-frequency pairing plays a crucial role in achieving a diamagnetic response if the electrons experience a staggered superconducting phase during the propagation of current.

Extreme enhancement of superconductivity in epitaxial aluminum near the monolayer limit.

BCS theory has been widely successful at describing elemental bulk superconductors. Yet, as the length scales of such superconductors approach the atomic limit, dimensionality as well as the environment of the superconductor can lead to drastically different and unpredictable superconducting behavior. Here, we report a threefold enhancement of the superconducting critical temperature and gap size in ultrathin epitaxial Al films on Si(111), when approaching the 2D limit, based on high-resolution scanning tunneling microscopy/spectroscopy (STM/STS) measurements. Using spatially resolved spectroscopy, we characterize the vortex structure in the presence of a strong Zeeman field and find evidence of a paramagnetic Meissner effect originating from odd-frequency pairing contributions. These results illustrate two notable influences of reduced dimensionality on a BCS superconductor and present a platform to study BCS superconductivity in large magnetic fields.

Odd-frequency pairs and anomalous proximity effect in nematic and chiral states of superconducting topological insulators

We investigate emergent odd-frequency pairs and proximity effect in nematic and chiral states of superconducting topological insulators (STIs), such as ${M}_{x}{\mathrm{Bi}}_{2}{\mathrm{Se}}_{3}$ ($M=$ Cu, Sr, Nb). The interplay of pairing symmetry, the orbital degrees of freedom, and strong spin-orbit interaction generates a variety of odd-frequency pairs in the bulk and surface of STIs. The nematic and chiral states are the prototypes of topological superconductors with and without time-reversal symmetry, respectively. We find that the Fermi surface evolution from a closed spheroidal to an open cylindrical shape changes the pairing symmetry from the nematic to chiral state, which causes the evolution of the odd-frequency pairings and surface Andreev bound states (SABSs). In addition, spin polarization of odd-frequency pairs and SABSs stems from the nonunitary pairing in the chiral state. The evolution and spin polarization of odd-frequency pairs and SABSs can be captured by tunnel conductance spectroscopy. Furthermore, we study the anomalous proximity effect in various irreducible representations of STIs. The anomalous proximity effect was originally predicted in spin-triplet superconductor junctions without spin-orbit interaction. Odd-frequency spin-triplet $s$-wave pairs penetrate into diffusive normal (DN) metals and induce a pronounced zero-energy peak of the local density of states in the DN region. Here we demonstrate that contrary to the well-known results, the anomalous proximity effect in STIs is not immune to nonmagnetic impurities. The fragility is attributed to the fact that the proximitized odd-frequency even-parity pairs are admixtures of $s$-wave and non-$s$-wave pairs due to strong spin-orbit interaction inherent to the parent materials.

Quasiparticle Interference as a Direct Experimental Probe of Bulk Odd-Frequency Superconducting Pairing.

We show that quasiparticle interference (QPI) due to omnipresent weak impurities and probed by Fourier transform scanning tunneling microscopy and spectroscopy acts as a direct experimental probe of bulk odd-frequency superconducting pairing. Taking the example of a conventional s-wave superconductor under applied magnetic field, we show that the nature of the QPI peaks can only be characterized by including the odd-frequency pairing correlations generated in this system. In particular, we identify that the defining feature of odd-frequency pairing gives rise to a bias asymmetry in the QPI, present generically in materials with odd-frequency pairing irrespective of its origin.

Solvable 3D Kondo Lattice Exhibiting Pair Density Wave, Odd-Frequency Pairing, and Order Fractionalization.

The Kondo lattice model plays a key role in our understanding of quantum materials, but a lack of small parameters has posed a long-standing problem. We present a three-dimensional S=1/2 Kondo lattice model describing a spin liquid within an electron sea. Strong correlations in the spin liquid are treated exactly, enabling a controlled analytical approach. Like a Peierls or BCS phase, a logarithmically divergent susceptibility leads to an instability into a new phase at arbitrarily small Kondo coupling. Our solution captures a plethora of emergent phenomena, including odd-frequency pairing, pair density wave formation and order fractionalization. The ground-state state is a pair density wave with a fractionalized charge e, S=1/2 order parameter, formed between electrons and Majorana fermions.

Odd-frequency Cooper pair around a magnetic impurity

The Yu-Shiba-Rusinov (YSR) state appears as a bound state of a quasiparticle at a magnetic atom embedded in a superconductor. We discuss why the YSR state has energy below the superconducting gap and why the pair potential changes the sign at the magnetic atom. Although a magnetic atom in a superconductor has been considered as a pair breaker since 1960s, we propose an alternative physical picture to explain these reasons. We show that a magnetic atom converts a spin-singlet s-wave Cooper pair into an odd-frequency pair rather than breaking it. The odd-frequency pairing correlations always coexist with the quasiparticle states below the gap. The YSR state is an example of such a subgap quasiparticle state. The paramagnetic property of an odd-frequency pair explains the sign change of the pair potential at a magnetic atom and the decrease of superconducting transition temperature in the presence of many magnetic impurities.

Odd-frequency pairing and time-reversal symmetry breaking for repulsive interactions

We study the pairing of fermions by an interaction consisting of a Hubbard repulsion, mimicking a screened Coulomb potential, and a dynamical phonon-mediated attraction. For such interaction, the gap equation allows even- and odd-frequency solutions ${\mathrm{\ensuremath{\Delta}}}_{e}$ and ${\mathrm{\ensuremath{\Delta}}}_{o}$. We show that odd-frequency pairing does not develop within the Eliashberg approximation due to over-critical pair breaking from the self-energy. When vertex corrections are included, the pairing interaction gets stronger, and ${\mathrm{\ensuremath{\Delta}}}_{o}$ can develop. We argue that even in this case keeping the self-energy is still a must as it cancels out the thermal piece in the gap equation. We further argue that ${\mathrm{\ensuremath{\Delta}}}_{o}$ is not affected by Hubbard repulsion and for strong repulsion is comparable to a reduced ${\mathrm{\ensuremath{\Delta}}}_{e}$. The resulting superconducting state is a superposition ${\mathrm{\ensuremath{\Delta}}}_{e}\ifmmode\pm\else\textpm\fi{}i{\mathrm{\ensuremath{\Delta}}}_{o}$, which spontaneously breaks the time-reversal symmetry, despite that the pairing symmetry is an ordinary $s$ wave.

Odd frequency pairing in a quantum critical metal

We analyze a possibility for odd-frequency pairing near a quantum critical point(QCP) in a metal. We consider a model with dynamical pairing interaction $V(\Omega_n)\sim 1/|\Omega_n|^\gamma$ (the $\gamma$-model). This interaction gives rise to a non-Fermi liquid in the normal state and is attractive for pairing. The two trends compete with each other. We search for odd-frequency solutions for the pairing gap $\Delta (\omega_m)= -\Delta(\omega_m)$. We show that for $\gamma <1$, odd-frequency superconductivity looses the competition with a non-Fermi liquid and does not develop. We show that the pairing does develop in the extended model in which interaction in the pairing channel is larger than the one in the particle-hole channel. For $\gamma >1$, we argue that the original model is at the boundary towards odd-frequency pairing and analyze in detail how superconductivity is triggered by a small external perturbation. In addition, we show that for $\gamma >2$, the system gets frozen at the critical point towards pairing in a finite range in the parameter space. This give rise to highly unconventional phase diagrams with flat regions.

Strongly correlated superconductivity with long-range spatial fluctuations

We review recent studies for superconductivity using diagrammatic extensions of dynamical mean field theory. These approaches take into account simultaneously both, the local correlation effect and spatial long-range fluctuations, which are essential to describe unconventional superconductivity in a quasi-two-dimensional plane. The results reproduce and predict the experimental phase diagrams of strongly correlated system such as cuprates and nickelates. Further studies reveal that the dynamical screening effect of the pairing interaction vertex has dramatic consequences for the transition temperature and may even support exotic mechanisms like odd-frequency pairing. We also discuss the dimensionality of layered materials and how to interpret the numerical results in two dimensions.

Fluctuation-induced odd-frequency spin-triplet pairing in a disordered electron liquid

We consider a two-dimensional disordered conductor in the regime when the superconducting phase is destroyed by the magnetic field. We analyze a combination of fluctuations of different origin which results in an effective interaction amplitude suitable for a spontaneous s-wave odd-frequency pairing instability. We observe that the end point of the superconductivity is a quantum critical point separating the conventional superconducting phase from a state with the odd-frequency spin-triplet pairing instability. We speculate that this could shed light on a rather mysterious insulating state observed in strongly disordered superconducting films in a broad region of the magnetic fields.

Odd-frequency pairing in a nonunitary p -wave superconductor with multiple Majorana fermions

Odd-frequency Cooper pairs are gathering attention for the convenience of investigating the edge state of topological superconductors including Majorana fermions. Although a spinless $p$-wave superconductor has only one Majorana fermion in a topological phase, the system with magnetic fields can reach the topological phases with multiple Majorana fermions. To distinguish these multiple Majorana fermion phases, we correlate the energy spectrum with the odd-frequency pair amplitude as increasing the system size. The system size dependence tells us three pieces of information: the parity of the number of the Majorana fermions at the edge, the number of low-energy modes corresponding to the Majorana fermions with different localization lengths, and the fingerprints of the Majorana fermions. Also, we present the spatial dependence of the odd-frequency $\mathrm{f}$ vector that is created from odd-frequency pair amplitude and the spin structure of odd-frequency Cooper pairs. We find that the odd-frequency $\mathrm{f}$ vector is fixed in the same direction in any topological phase. Also, we show that the spin state of odd-frequency Cooper pairs tends to be oriented toward the direction of the magnetic fields. Our results highlight that the odd-frequency Cooper pairs can be a good indicator for the detection of the multiple Majorana fermions and the distinction among the topological phases.

Exceptional odd-frequency pairing in non-Hermitian superconducting systems

We first show the realization of exceptional points in a non-Hermitian superconducting system based on a conventional superconductor and then demonstrate that, surprisingly, the system hosts odd-frequency pairing, solely generated by the non-Hermiticity. While there is a coexistence of even- and odd-frequency pairs under general conditions, we find that the even-frequency term vanishes at the exceptional degeneracies, leaving only odd-frequency pairing. This exceptional odd-frequency pairing is directly given by the imaginary part of the eigenvalues at the exceptional points and can be measured from the spectral function. Our results thus put forward non-Hermitian systems as a powerful platform to realize odd-frequency superconducting pairing.

Temperature and doping dependence of the singlet and triplet pair susceptibilities in the one-band Hubbard model based on the dynamical mean-field theory

The superconductivity in the one-band Hubbard model on a Bethe lattice is investigated on the basis of the dynamical mean-field theory (DMFT) in which the irreducible vertex function has no k-dependence and then only the s-wave superconductivities with the spin-singlet even-frequency and the spin-triplet odd-frequency pairings are possibly realized. We calculate the pair susceptibility by solving the Bethe-Salpeter equation with the use of the linearized DMFT and find that the spin-singlet pair susceptibility is suppressed by the on-site Coulomb interaction U especially for the region near the Mott transition. On the other hand, the spin-triplet pair susceptibility is apparently enhanced by U in the strong correlation regime at very low temperatures where the effective interaction for the triplet pairing is considered to be attractive and then the triplet superconductivity is expected to be realized.

Direct detection of odd-frequency superconductivity via time- and angle-resolved photoelectron fluctuation spectroscopy

We propose a measurement scheme to directly detect odd-frequency superconductivity via time- and angle-resolved photoelectron fluctuation spectroscopy. The scheme includes two consecutive, non-overlapping probe pulses applied to a superconducting sample. The photoemitted electrons are collected in a momentum-resolved fashion. Correlations between signals with opposite momenta are analyzed. Remarkably, these correlations are directly proportional to the absolute square of the time-ordered anomalous Green's function of the superconductor. This setup allows for the direct detection of the "hidden order parameter" of odd-frequency pairing. We illustrate this general scheme by analyzing the signal for the prototypical case of a two-band superconductor.

Unconventional Meissner screening induced by chiral molecules in a conventional superconductor

The coupling of a superconductor to a different material often results in a system with unconventional superconducting properties. A conventional superconductor is a perfect diamagnet expelling magnetic fields out of its volume, a phenomenon known as Meissner effect. Here, we show that the simple adsorption of a monolayer of chiral molecules, which are non-magnetic in solution, onto the surface of a conventional superconductor can markedly change its diamagnetic Meissner response. By measuring the internal magnetic field profile in superconducting Nb thin films under an applied transverse field by low-energy muon spin rotation spectroscopy, we demonstrate that the local field profile inside Nb is considerably modified upon molecular adsorption in a way that also depends on the applied field direction. The modification is not limited to the chiral molecules/Nb interface, but it is long ranged and occurs over a length scale comparable to the superconducting coherence length. Zero-field muon spin spectroscopy measurements in combination with our theoretical analysis show that odd-frequency spin-triplet states induced by the chiral molecules are responsible for the modification of the Meissner response observed inside Nb. These results indicate that a chiral molecules/superconductor system supports odd-frequency spin-triplet pairs due to the molecules acting as a spin active layer and therefore they imply that such system can be used as a simpler alternative to superconductor/ferromagnet or superconductor/topological insulator hybrids for the generation and manipulation of unconventional spin-triplet superconducting states.

Spin injection and spin relaxation in odd-frequency superconductors

The spin transport inside an odd-frequency spin-triplet superconductor differs from that of a conventional superconductor due to its distinct symmetry properties. We study spin transport inside an emergent odd-frequency superconductor by replacing the spin-singlet gap matrix in the Usadel equation with a matrix representing spin-triplet pairing that is odd under inversion of energy. We show that the peculiar nature of the density of states allows for an even larger spin injection than in the normal-state. Moreover, when the odd-frequency pairing inherits its temperature dependence from a conventional superconductor through the proximity effect, the density of states can transition from gapless to gapped as the temperature decreases. At the transition point, the spin accumulation inside the odd-frequency superconductor is peaked and larger than in the normal-state. While the spin-flip scattering time is known to decrease below the superconducting transition temperature in conventional superconductors, we find that the same is true for the spin-orbit scattering time in odd-frequency superconductors. This renormalization is particularly large for energies close to the gap edge, if such a gap is present.