Oceanic Air Masses Research Articles

Thermal and precipitation variability across four seasons in Poland (1951–2020)

Abstract This paper shows spatial variability of temperature and precipitation conditions across the four seasons in Poland and examines long-term trends in these parameters. The spatial variability of temperature in Poland is caused primarily by the clash of oceanic air masses from the west and continental air masses from the east. The spatial distribution of precipitation depends strongly on the relief and altitude above sea level. The seasons are generally getting warmer. However, average temperatures increase over time at different rates and levels of significance. Except in winter, no statistically significant trends were found in the seasonal precipitation totals. Seasons are periods when certain climatic conditions prevail. Depending on the criteria adopted, different types of seasons can be distinguished, such as meteorological, thermal, and calendar seasons. These are considered in this research. Consequently, different time frames of seasons result in varying values and patterns of meteorological characteristics. In this research, this concept is presented using Poland as an example.

Airmass history, night-time particulate organonitrates, and meteorology impact urban SOA formation rate

With respect to air quality, the San Antonio metropolitan area, with a population of 1.45 million and the second largest city in Texas, has been designated as non-attainment by the United States Environmental Protection Agency in recent years. Despite the operation of multiple stationary air quality monitoring sites by the Texas Commission on Environmental Quality, the in-situ measurements of submicron aerosol and its precursors in the region is limited. To better understand the formation of secondary organic aerosol (SOA) in the San Antonio urban core, we conducted observations of a range of trace gases, volatile organic compounds, submicron aerosol, and meteorological parameters in May 2017. Data from a High-Resolution Time-of-Flight Aerosol Mass Spectrometer (HR-ToF-AMS) show that organic aerosol (OA) was the dominant component of non-refractory submicron particulate matter (average±1σ, 55 ± 32 %, 5.86 ± 3.40 μg m−3), followed by sulfate (33 ± 23 %, 3.52 ± 2.47 μg m−3). Aerosol liquid water contents predicted by ISORROPIA-II greatly increase from Continental to Oceanic airmass history scenarios, while inorganic aerosol pH remains very acidic. Positive matrix factorization (PMF) analysis of the OA mass spectra indicates that two classes of oxygenated OA (less and more-oxidized OOA, LO and MO) together constituted the bulk of OA mass during the study period (MO-OOA: 44 ± 39 %, 2.35 ± 2.07 μg m−3; LO-OOA: 42 ± 34 %, 2.22 ± 1.77 μg m−3), while the fraction of hydrocarbon-like OA was limited (13 ± 21 %, 0.71 ± 1.11 μg m−3). Using in-situ meteorological data and location-specific empirical coefficients, a zero-dimensional model that utilized PMF factors as proxies to calculate the net rate of formation of types of SOA has been developed; similar calculations were used to estimate the formation rate of particulate organonitrates (pON). The results from the model reveal the importance of pON formation in LO-OOA formation overnight and the influence of temperature and photochemistry during the day. The relationships between local atmospheric factors and the net rate of formation of MO-OOA are not statistically significant. These results emphasize how HR-ToF-AMS-PMF factors could be incorporated into chemistry modeling to evaluate quantitatively the rates of formation of SOA and reveal diurnal differences in SOA formation pathways in a major urban area in southern United States.

Contribution of Ship Emission to Volatile Organic Compounds Based on One‐Year Monitoring at a Coastal Site in the Pearl River Delta Region

AbstractShip emission impacts ambient air quality, especially in coastal regions, by emitting air pollutants such as fine particles, nitrogen oxides (NOx), and sulfur dioxide (SO2), yet its contributions to volatile organic compounds (VOCs) and the formation of secondary organic aerosol (SOA) and ozone (O3) are much less constrained with the challenge in distinguish ship emission from land diesel emission. In this study, we conducted a 1‐year online measurement of VOCs with a 1‐hr resolution at a coastal site in south China's Pearl River Delta region, which holds three of the world's top 10 container ports. The results revealed that C10–C12 n‐alkanes, as typical diesel‐related emission tracers, were significantly enhanced and strongly related to oceanic air masses. Receptor modeling revealed two diesel‐related sources of land diesel emission and ship emission, which could be differentiated based on their source profiles, seasonal trends and air mass back trajectories. Ship emissions contributed 6.4%, 5.0%, and 13.6% of total VOC mixing ratios, ozone formation potentials (OFPs), and secondary organic aerosol formation potentials (SOAFPs), while these percentages were 3.4%, 14.7%, and 15.9% for land diesel emission, respectively. In particular, in July, ship emissions could contribute 21.7%, 14.6%, and 31.2% of VOCs, OFPs, and SOAFPs, respectively. Our results highlight the important contribution of diesel‐related emission VOCs in forming O3 and SOA in coastal regions, and ship emission is a non‐negligible source of VOCs, particularly after the strict control of land emission sources.

Ocean air masses from the East Asian monsoon dominate the land‐surface atmospheric water cycles in the coastal areas of Liaodong Bay, Northeast China

AbstractLong‐term atmospheric water vapour hydrogen (δ2H), oxygen (δ18O) and deuterium excess (d‐excess) can provide unique insights into the land‐atmosphere coupling processes. The in‐situ measurements of atmospheric water vapour δ2H, δ18O and d‐excess were conducted above a reed wetland of Liaodong Bay (2019–2020). We found significant inter‐annual variations in atmospheric water vapour isotopes between the two growing (May–September) seasons. The δ2H, δ18O and d‐excess of atmospheric water vapour exhibited different seasonal and diurnal cycles concerning the vertical measurement heights, especially in 2019. The isotopic differences of atmospheric water vapour among vertical measurement heights were more evident in the daytime. Rainfall events directly impacted the diurnal patterns of water vapour isotopes, and the influences depended on rainfall intensities. However, only weak correlations existed between water vapour isotopes and local meteorological factors (R2 = 0.01–0.16, p < 0.001), such as water vapour concentration (w), Relative Humidity (RH) and surface air temperature (Ta). Based on the back‐air trajectory analyses, the spatial–temporal dynamics of atmospheric water vapour isotopes are highly synchronized with monsoon activities. Different water vapour sources influence the water vapour isotope in this region and the higher d‐excess value is related to the intense convection brought by the monsoon. High‐resolution measurements of atmospheric water vapour isotopes will improve our understanding of the hydrological cycles in coastal areas.

Aircraft observations of aerosols and BC in autumn over Guangxi Province, China: Diurnal variation, vertical distribution and source appointment

To understand the vertical distribution characteristics of aerosols and black carbon (BC) in southwest China, 12 sorties were conducted from October 10 to November 3, 2020, and the vertical profiles of aerosols and BC at different times in Nanning, Guangxi Province, in autumn were obtained. The contents of aerosols (Na <100 cm−3) and BC (MBC <0.11 μg∙m−3) at 2000–6000 m were small and did not change with height. The vertical profiles of Na and MBC below 2000 m were affected by the boundary layer (PBL), and the vertical profiles had obvious diurnal variations. Aerosols and BC in the residual layer (RL) entered PBL at 10:00–12:00, resulting in increased the values of Na (1971 cm−3) and MBC (2.93 μg∙m−3) in PBL. Under intense turbulent activity in PBL from 13:00 to 15:00, Na and MBC changed little with height. At 17:00, PBL height dropped, aerosols and BC remained in RL. From 18:00 to 22:00, the PBL height decreased, and the aerosols and BC were trapped below 200 m. BC below 2000 m was mainly from fossil fuel combustion. Between 2000 m and 6000 m, MBCff > MBCbb at 12:00–17:00, and MBCbb was similar to MBCff at 10:00, 18:00 and 22:00. The air masses passing over Southeast Asian countries and Guangdong Province brought more BC to Guangxi Province. Air masses from different sources had different effects on aerosols in Guangxi Province. Below 3000 m, the value of Na under the influence of land air mass was greater than that under the influence of ocean air mass. Above 3000 m, different sources of air mass mainly affected the aerosol number concentration spectrum. Under the influence of ocean air mass, the number and concentration of aerosol with particle size of 0.11 μm and 0.24 μm had increased in Guangxi Province.

Air-water exchange and risk assessment of phthalic acid esters during the early phase of COVID-19 pandemic in tropical riverine catchments of India

Given the increased load of waste plastic in the solid waste stream after the outbreak of the COVID-19 pandemic, we investigated the fate of selected plastic additives along open burning dumps, industrial and residential transects in tropical riverine catchments of India. Polyurethane foam disk passive air samples, surface water and community stored water (CSW) samples were collected along the Adyar River (AR), Cooum River (CR) and canals in Chennai and Daman Ganga River (DG) in Vapi. Among the quantified phthalic acid esters (PAEs), a widely used plastic additive, di(2-ethylhexyl) phthalate (DEHP), was ubiquitous across all the transects. More open drains and leaching of littered single-use plastic items can be the reason for significantly higher (p < 0.05) levels of PAEs in CR over other rivers with a dominance of di-n-butyl phthalate (DnBP). Prevalence of open burning of dumped plastic waste was the possible primary emission source of PAEs in these riverine catchments. Excluding highly soluble dimethyl phthalate (DMP), air-water exchange processes reflected the secondary emission of all the PAEs from the surface water along the open burning sites. Despite the cleansing effect of the oceanic air mass from the Bay of Bengal and the Indian Ocean, the average atmospheric PAE level was two-fold higher in Chennai than Vapi. Even though Vapi is a coastal city along the Arabian Sea, it was impacted by inland air masses during the sampling event. Open burning dumpsites showed a five-fold increase in atmospheric priority PAEs in Chennai city after the outbreak of the COVID-19 pandemic. DnBP was the major contributor to estrogenicity in CSW and DG, and also posed maximum risk for fishes in the open burning transect of these tropical rivers.

Atmospheric depositional fluxes of 210Pb in bulk precipitation at the Adriatic coast, Croatia

The atmospheric bulk depositional fluxes of 210Pb were measured at a station on the Adriatic coast, Croatia over 4 years period from March 2017 to December 2020. The monthly depositional fluxes followed oceanic deposition patterns with a lower flux between 0.0735 and 16.9 Bq m−2 month−1. The volume-weighted activities were 0.000514 and 1.35 Bq L−1 and decreased with increasing precipitation. A clear seasonal trend was observed with higher depositional flux in autumn and minimum value in the winter season. The average annual bulk depositional flux and volume-weighted activities of 210Pb were 73.8 Bq m−2 y−1 and 0.119 Bq L−1 respectively. The precipitation normalized enrichment factor (α) indicates higher depositional fluxes of 210Pb during summer and spring than desired value according to the amount of precipitation. We found that the 210Pb depositional fluxes in the coastal stations are lower due to 210Pb-depleted oceanic air masses and increase with the amount of precipitation.

New and legacy pesticidal persistent organic pollutants in the agricultural region of the Sultanate of Oman

Comprehensive air and surface soil monitoring was conducted for new and legacy organochlorine pesticides (OCPs) to fill the knowledge and data gap on the sources and fate of pesticidal persistent organic pollutants (POPs) in the Sultanate of Oman. DDTs in agricultural soil samples ranged from 0.013 to 95.80 ng/g (mean: 8.4 ± 25.06 ng/g), with a median value of 0.07 ng/g. The highest concentration was observed at Shinas, where intensive agricultural practice is prevalent. The dominance of p,p′-DDT in soil and air reflected technical DDT formulation usage in Oman. Among newly enlisted POPs, pentachlorobenzene had the maximum detection frequency in air (47%) and soil (41%). Over 90% of sites reflected extensive past use of hexachlorobenzene. Major OCP isomers and metabolites showed net volatilisation from the agricultural soil, thereby indicating concurrent emission and re-emission processes from the soil of Oman. However, the cleansing effect of oceanic air mass is the possible reason for relatively lower atmospheric OCP levels from a previous study. Although DDT displayed maximum cancer risk, the level is below the permissible limit. DDT primarily stemmed from obsolete stock and inadequate management practices. Hence, we suggest there is a need for DDT regulation in Oman.

Tethered balloon-borne profile measurements of atmospheric properties in the cloudy atmospheric boundary layer over the Arctic sea ice during MOSAiC: Overview and first results

The tethered balloon-borne measurement system BELUGA (Balloon-bornE moduLar Utility for profilinG the lower Atmosphere) was deployed over the Arctic sea ice for 4 weeks in summer 2020 as part of the Multidisciplinary drifting Observatory for the Study of Arctic Climate expedition. Using BELUGA, vertical profiles of dynamic, thermodynamic, aerosol particle, cloud, radiation, and turbulence properties were measured from the ground up to a height of 1,500 m. BELUGA was operated during an anomalously warm period with frequent liquid water clouds and variable sea ice conditions. Three case studies of liquid water phase, single-layer clouds observed on 3 days (July 13, 23, and 24, 2020) are discussed to show the potential of the collected data set to comprehensively investigate cloud properties determining cloud evolution in the inner Arctic over sea ice. Simulated back-trajectories show that the observed clouds have evolved within 3 different air masses (“aged Arctic,” “advected over sea ice,” and “advected over open ocean”), which left distinct fingerprints in the cloud properties. Strong cloud top radiative cooling rates agree with simulated results of previous studies. The weak warming at cloud base is mostly driven by the vertical temperature profile between the surface and cloud base. In-cloud turbulence induced by the cloud top cooling was similar in strength compared to former studies. From the extent of the mixing layer, it is speculated that the overall cloud cooling is stronger and thus faster in the warm oceanic air mass. Larger aerosol particle number concentrations and larger sizes were observed in the air mass advected over the sea ice and in the air mass advected over the open ocean.

Particulate Matter Pollution in Urban Cities of India During Unusually Restricted Anthropogenic Activities

The outbreak of COVID-19 is a global public health challenge and has affected many countries, including India. The nationwide lockdown was imposed in India from March 25 to May 31, 2020 to prevent the transmission of COVID-19. The study intends to assess the impact of the absence of major anthropogenic activities during the various phases of the COVID-19 lockdown (LDN) period on the daily mean concentrations of PM2.5 and PM10 in six populated cities of Jaipur, Jodhpur, Kota, Udaipur, Ajmer, and Alwar in the state of Rajasthan. Investigation has been done for the different periods, including the pre-lockdown—PRELD (January 1–March 4, 2020), partial lockdown—PLDN (March 5–24, 2020), COVID-19 lockdown—LDN (March 25–May 31, 2020), and unlocking—ULC (June 1–August 31, 2020) phases. We have also compared the mean concentrations of PM2.5 and PM10 with the same period of the year 2019. A significant improvement in air quality during the COVID-19 LDN period was noticed in all cities compared to 2019 and for the same period of the year 2020. However, the levels of PM2.5 and PM10 were seen to rise during the second, third, and fourth LDN phases compared to the first LDN, indicating that the subsequent lockdowns started with some relaxations and dusty conditions. On the other hand, wind-blown dust is another vital source of PM10, resulting in high concentrations in the summer months (April–May). Significant reductions in PM2.5 (~25–50%) and PM10 (20–37%) in all six cities during the LDN period compared with PRELD were estimated. However, with significant variations from city to city, the lowest reductions in PM2.5 (~25%) and PM10 (~20%) were measured in Jodhpur and Ajmer, respectively. It was noticed that the episodes of rainfall and transport of oceanic air masses resulted in a reduction of particles during the ULC period compared to the LDN period. The air quality index was, more or less, in the “good to satisfactory” category during the first 3 LDN periods, whereas it was moderate for Jodhpur, Jaipur, and Ajmer during the last LDN period. The study will be helpful to determine mitigation policies to minimize air pollution, especially in developing regions.

Dry-deposition of inorganic and organic nitrogen aerosols in Xiamen Bay: Fluxes, sources, and biogeochemical significance

Increased dry deposition of nitrogen aerosols (aerosol-N) as a result of anthropogenic emissions has caused large negative impacts on marine ecosystems. We monitored the number concentrations and sizes of inorganic nitrogen aerosols (aerosol-IN: NH4+ and NO3−) and organic nitrogen aerosols (aerosol-ON: methylamine, dimethylamine, trimethylamine, ethylamine, diethylamine, and triethylamine) by single-particle aerosol mass spectrometry (SPAMS) during the warm season (WS) and cold season (CS) of 2013 and 2015 in Xiamen Bay. The mean hourly number concentration of aerosol-IN (874/h) overwhelmed that of aerosol-ON (103/h), accounting for 83.9 ± 16.1% of aerosol-N. More than 90% of aerosol-N was concentrated in the condensation mode (0.1–0.5 μm) and droplet mode (0.5–2.0 μm). Aerosol-IN was the main contributor (80.1–94.2%) to aerosol-N deposition. New production potentially supported by the ocean's external nitrogen supply provided aerosol-N input of 11.51–11.96 g C m−2 yr−1, which contributed 17.5–18.2% of total new production in the southern East China Sea. Four potential sources of aerosol-N were identified based on the results of positive matrix factorization analysis, including secondary formation (F1), biogenic source (F2), sea spray, soil dust, biomass burning (F3), and anthropogenic sources (F4). Aerosol-N concentrations in Xiamen Bay were mainly affected by the ocean air masses during the WS and inland air masses during the CS. The percentages of aerosol-N at each backward trajectory cluster showed that the inland air masses brought more aerosol-IN emitted from biomass burning, soil dust, and secondary formation sources, whereas the ocean air masses brought more aerosol-ON emitted from a marine biogenic source into Xiamen Bay. This study provides an example of determining the number concentrations and sizes of IN and ON in aerosols by SPAMS, and helps us further understand the dry deposition and sources of IN and ON in aerosols in Xiamen Bay.

The Analysis of the Contribution of the Southwestern Indian Ocean Tropical Cyclones (TCs) to December, January, February, March (DJFM) Rainfall Season over Tanzania

The contribution of Southwestern Indian Ocean (SWIO) Tropical cyclones (TCs) to the December to March (DJFM) rainfall season over Tanzania was analyzed. Seasonal, monthly and daily rainfall data were obtained from Tanzania Meteorological Authority (TMA), while data for sea surface temperatures (SSTs), relative and specific humidity, zonal and meridional winds were acquired from NOAA (NCEP – NCAR). Tropical Rainfall Measuring Mission (TRMM) daily average gridded rainfall estimates were used. The observed and gridded rainfall data for each TC day were extracted and computed to monthly and seasonal totals for all TCs and non TCs days. Correlation between DJFM TCs and DJF/DJFM rainfall were determined. Inter annual variability between TCs and DJF rainfall was analyzed. Wind patterns at 850 - 200 mb, relative humidity (850-700mb), vertically integrated horizontal wind and moisture divergence (1000-500 mb) for two TC events (Izilda and Fobane) were analyzed. The results revealed that, TCs contribution to the DJFM rainfall was very significant. The influence of TCs to monthly total rainfall showed a general increasing trend from north to south along the coast of Tanzania, with a southwest to northeast alignment. On the other hand correlation between DJFM TCs with DJF rainfall was relatively weak at some stations while few stations including Dodoma and Tabora were showing relatively higher correlations of about 0.39 (p ≤ 0.05) suggesting that these stations are highly vulnerable to the TCs impacts. Moreover, results had shown that the distribution of TCs rainfall prone areas run from southern parts (Mtwara) through central parts (Dodoma) to northeastern highlands (Kilimanjaro). Analyses revealed that 700 mb wind vectors, integrated moisture fluxes and their convergence from Congo air mass, northwesterly and northeastern Indian Ocean air masses were the main contributors of rainfall over Tanzania during TCs events. Conclusively, the study showed that TCs has significant contribution to the DJF and DJFM rainfall in Tanzania, thus more studies for understanding the dynamic of TCs in relation to rainfall is required for improving the weather forecasts in Tanzania.

Degree of connectivity in reconstructed precipitation dynamics and extremes for semiarid regions across South Siberia

Tree rings from forest-steppes of temperate continental Asia are useful proxies for the moisture regime reconstructions, encompassing environmental variations such as warming climate, changing frequency and intensity of droughts. Heterogeneity of precipitation leaves open the question of the probability of spatially large-scale droughts in this macro-region. Theoretically, such events could be driven by global tele-connections and/or common astronomic cycles. We have attempted the precipitation reconstructions of two distant (~1000 km) intermountain valleys in South Siberia, based on the tree ring width of Pinus sylvestris L. To enhance the quality of the precipitation reconstruction models, networks of existing tree-ring data were expanded and daily precision of instrumental precipitation series was implemented for calibration. Within-region (150–200 km) common signal between local chronologies r = 0.37–0.90 (p < 0.05) allowed obtaining regional ones, registering precipitation up to annual temporal scale. High correlations of both regional chronologies with annual precipitation were found for period from previous July 22 to current July 21 (r = 0.71–0.72). These precipitation series were further reconstructed. Reconstruction models explaining 50–52% of variation were developed for the years 1753–2015 and 1798–2015. Although both valleys do not record many concurrent extreme precipitation events, some common and opposite extremes have been revealed. For both regions, an 11-year and 26–29-year cycles were commonly observed. These were probably associated with the solar activity and Pacific Decadal Oscillation (PDO). However, phase shifts of these cycles were recorded between the regions and with PDO. Stronger impact of oceanic air masses was observed in the eastern one of the two considered territories. Whereas higher significance of frequencies associated with astronomic cycles (solar and lunar-nodal) was found in the western one. Data availabilityTemperature and precipitation series of climatic stations were obtained from the website of All-Russia Research Institute of Hydrometeorological Information, World Data Centre (RIHMI-WDC, http://meteo.ru/data). Other climatic time series and solar activity series were obtained from the website of The Royal Netherlands Meteorological Institute (KNMI) Climate Explorer (https://climexp.knmi.nl). Used in the study tree-ring width measurements will be submitted to the International Tree-Ring Data Bank (ITRDB; https://www.ncei.noaa.gov/products/paleoclimatology/tree-ring) upon publication of the manuscript and with reference to it.

Fluorescent biological aerosol particles over the central Pacific Ocean: covariation with ocean surface biological activity indicators

Abstract. Combining wideband integrated bioaerosol sensors and DNA-staining techniques, online and offline shipboard observations of fluorescent aerosol particles in the atmosphere were carried out over the central Pacific Ocean during March 2019 to identify bioaerosols and determine their spatiotemporal distribution. To understand the origins of and processes associated with bioaerosols, we conducted correlation analyses of fluorescent particle number concentration, wind speed, and a variety of chemical and biological indicators, including concentrations of chlorophyll a, bacteria, and marine organic gel particles such as transparent exopolymer particles (TEPs) and Coomassie stainable particles (CSPs). Five-day backward trajectory analysis indicated that oceanic air masses were dominant between 6 and 18 March, after which the influence of long-range transport from the continent of Asia was prominent. For the first period, we identified certain types of fluorescent particles as bioaerosols with marine origins, because their number concentrations were highly correlated with concentrations of TEPs and bacteria (R: 0.80–0.92) after considering the wind speed effect. For the second period, there was strong correlation between another type of fluorescent particles and CSPs irrespective of wind speed, implying that the fluorescent particles advected from land were mixed with those of marine origins. From the results of our correlation analysis, we developed equations to derive atmospheric bioaerosol number density in the marine atmosphere over the central Pacific Ocean from a combination of biogenic proxy quantities (chlorophyll a, TEPs, and bacteria) and wind speed. We conclude that it is likely that TEPs were transported from the sea surface to the atmosphere together with bacteria to form fluorescent bioaerosols.

A quantitative understanding of total OH reactivity and ozone production in a coastal industrial area during the Yokohama air quality study (AQUAS) campaign of summer 2019

Field measurements performed in the Keihin coastal industrial area during summer 2019 were used to characterize the air quality and ozone production potential. The total hydroxyl radical (OH) reactivity was found to be moderate, peaking with a 2-h average of 29.0 s−1, corresponding to an OH lifetime of ∼34 ms. The average hourly total OH reactivity was 11.4 ± 5.2 s−1 (average ± standard deviation), and the measured OH sinks (from over 90 trace species) accounted for 92.3% of the total OH reactivity. Compared with a previous series of campaigns in urban/suburban Japan, this field work investigated an area often overlooked for atmospheric observations and found the smallest missing OH reactivity (on average, 0.88 s−1). The near-zero missing OH reactivity indicated that photochemical procedures were less important to the Yokohama air quality study (AQUAS–Yokohama) than the ubiquitous substantial secondary products in other areas. This study also demonstrated that oceanic air masses may quickly flush coastal industrial areas and that a limited activity of photochemistry due to elevated NOx effectively terminates OH radical recycling. A comparison with other campaigns in Japan exhibited a positive correlation with oxidants (ozone and formaldehyde), indicating secondary products have a critical role in explaining missing OH reactivity. The ozone production potential was corresponding to a volatile organic compound (VOC)-limited regime, while the missing OH reactivity led to an ∼8% increase in ozone formation. Finally, a positive correlation was found between the ozone production rate and the reactivity ratio between VOCs and NOx, in both the current study and various other field campaigns in urban areas.

Pollution Characteristics and Source Analysis of Atmospheric VOCs in the Coastal Background of the Pearl River Delta

As an important precursor of ozone, volatile organic compounds (VOCs) have attracted much attention. This study analyzed the temporal variation and composition of atmospheric VOCs in the coastal background of the Pearl River Delta, using real-time online monitoring data of VOCs obtained at the Yangmeikeng Ecological Environment Monitoring Station from August 2019 to July 2020. The major sources of VOCs were identified using a receptor model based on the PMF (positive matrix factorization) and HYSPLIT (hybrid single particle Lagrangian integrated trajectory) models. The results showed that the annual mean concentration of anthropogenic VOCs in the coastal background area of the Pearl River Delta was 9.30×10-9(volume fraction). There was obvious seasonal variation of VOCs in this area, with higher values in autumn and winter and lower values in summer. The coastal background area of the Pearl River Delta exhibited a different diurnal variation pattern to that of cities and other backgrounds. While the peak of VOCs concentration mainly occurred in the morning, from 10:00 to 11:00, concentration remained at a low level during the early morning and after 15:00. Ethylene, propylene, toluene, isopentane, isoprene, m/p-xylene, n-butane, and acetylene were the key species that affected the chemical composition of VOCs. The air masses affecting the coastal background area of the Pearl River Delta were mainly short-distance air masses from elsewhere in the province (25%), ocean air masses (27%), coastal air masses (31%), and inland air masses outside the province (17%). Among them, the average concentration of VOCs was lowest under the influence of ocean air masses, which is mainly affected by the mixed source of ship emissions and aging VOCs, gasoline volatilization, and vehicle emissions. In comparison, the concentration level of VOCs increased by 70.1% to 148.8% under the influence of other air masses. The transmission effects of industrial sources, LNG and LPG volatiles, and petrochemical sources were more prominent. Generally, the atmosphere of coastal background areas was severely affected by anthropogenic pollution, especially by air pollution masses transported from the land, while the impact of pollution by ships near shore and tourist traffic cannot be ignored.

Chemical Characteristics, Size Distributions, Molecular Composition, and Brown Carbon in South Asian Outflow to the Indian Ocean

AbstractThe transport of South Asian (SA) anthropogenic haze to the northern Indian Ocean (NIO) is often observed during winter, however, its chemical and molecular constituents are not well explored. To better address this problem, shipborne measurements of size‐resolved aerosol sampling were carried out over the northern and equatorial Indian Ocean (EIO) for the quantification of aerosol composition (organic and inorganic) and molecular markers during the winter of 2018. The most striking outcome was the dominance of anthropogenic aerosols derived from biomass‐burning and combustion‐related emissions over the NIO during the SA outflow. Low‐level concentrations were noticed over the EIO where oceanic air mass was dominated. Organic carbon (OC), sea‐salts (Na+ and Cl−), calcium (Ca2+), and nitrates (NO3−) were enriched in the coarse mode (&gt;2.0 µm) while elemental carbon (EC), water‐soluble OC, sulfates (SO42−), and potassium (K+) were abundant in fine mode (&lt;2.0 µm) aerosols. Water‐soluble nitrogen aerosols showed a bimodal size distribution with a significant peak in fine mode. The molecular composition of organic aerosols (OAs) in PM1.1 was characterized by high abundances of sugars and lignin/resin products followed by hydroxy/polyacids and plasticizers. These results underscore that biomass‐burning emissions (BBEs), plastic combustions, and secondary anthropogenic aerosols are the leading sources of OAs in the SA outflow as further corroborated by the linear‐regression analysis between organic and inorganic marker compounds. The mass absorption efficiency (MAE) of organic (brown carbon; BrC) aerosols (MAEOC‐BrC‐365nm) was two times higher in SA outflow and largely contributed from BBEs as confirmed by the positive relationship with levoglucosan.

Охотский тропосферный циклон и его роль в формировании экстремальной температуры воздуха в январе 1950–2019 гг.

The field of Н500 geopotential height over the central part of the second natural synoptic region in January during 1950–2019 is analysed to determine regime characteristics of the Okhotsk tropospheric cyclone and its role in the formation of air temperature anomalies over the eastern coast of Asia. A mechanism of occurrence of extreme surface air temperatures using this technique is presented. Extremely low air temperature in the area of the minimum and related deep through are formed during the years when the Н500 minimum is localized over the Sea of Okhotsk. A methodology for constructing ellipses approximating the Н500 level lines in a small neighborhood of the Н500 minimum is developed, the ellipse characteristics are calculated, and their relation to the tropospheric cyclone evolution is analysed. The characteristics of the ellipses constructed in the neighborhood of the geopotential height minimum outside the Sea of Okhotsk significantly differ from those of the ellipses over the Sea of Okhotsk. A high compression of the ellipses towards the major axis is reported when the Far Eastern through intensity is reduced. In this case, an outflow of warm oceanic air masses to the Sea of Okhotsk is observed. The location of the Н500 minimum and the characteristics of the ellipses located within the center circle may be used to explain reasons for dramatic changes in air temperature in the study region. Keywords: Оkhotsk tropospheric cyclone, Н500 minima centers, extreme surface air temperature, ellipse characteristics

Evaluation of origin-depended nitrogen input through atmospheric deposition and its effect on primary production in coastal areas of western Kyusyu, Japan

Long term monitoring of atmospheric wet and dry depositions and associated nutrients fluxes was conducted on the coast of Japan facing the East China Sea continuously for 1 year and 2 months, with the origin of air mass investigated based on isotope analyses (Sr, Nd, and NO3). During the same period, intensive observations of ocean conditions and the chemical composition of sinking particles collected using sediment traps were conducted to investigate the effects of atmospheric deposition-derived nutrients on phytoplankton blooms. Dry-deposition-derived nutrient inputs to the surface ocean were larger during autumn to spring than in summer due to the effect of continental air mass occasionally carrying Asian dust (yellow sand). However, these nutrients fluxes were limited (1.1–1.5 mg-N m−2 day−1 on average) and didn't appear to cause phytoplankton blooms through the year. Although average dissolved inorganic nitrogen (DIN) concentrations in rainwater were lower in oceanic air masses compared to continental air masses, wet-deposition-derived nutrient inputs to the surface ocean on rainy days during the summer (26.0 mg-N m−2 day−1 on average) were large due to higher precipitation from oceanic air masses. Wet-deposition-derived nutrients significantly increased nutrient concentrations in the surface ocean and seemed to cause phytoplankton blooms in the warm rainy season when nutrients in the surface were depleted due to increased stratification. The increase in phytoplankton biomass was reflected in increased particle sinking into the bottom layer, as well as changing chemical characteristics. The supply of flesh phytoplankton-derived labile organic matter into the bottom layer could be expected to promote rapid bacterial decomposition and contribute to the formation of hypoxic water masses in early summer when the ocean was strongly stratified. Atmospheric deposition-derived nutrients in East Asia will have important impacts on not only the oligotrophic outer ocean but also surrounding coastal areas in the warm rainy season.

Mercury concentration and isotopic composition on different atmospheric particles (PM10 and PM2.5) in the subtropical coastal suburb of Xiamen Bay, Southern China

The concentration and isotopic composition of particulate-bound mercury (PBM) on both PM2.5 and PM10 were simultaneously measured (24 months) in a typical subtropical coastal suburb of Xiamen bay (SCXB), southern China. The results showed that most mercury was concentrated in PM2.5 and small particulates enriched heavier isotopes of mercury more than lighter ones. Negative Δ199Hg values and slightly positive Δ200Hg values were observed in both PM2.5 and PM10. PBM input sources were identified with isotopic compositions and meteorological data using the NOAA HYSPLIT model. It revealed that biomass combustion is the main source of particulate mercury in SCXB, and the two other sources are urban anthropogenic emissions and potential marine sources. Seasonal variations in isotopic composition and correlation analysis suggested that PBM in SCXB mainly originate from inland after long-distance transportation in spring and under the influence of oceanic air masses in summer. The Δ199Hg/Δ201Hg ratios in all samples (1.01 ± 0.05, 2SE) indicated that the photoreduction of Hg(II) in the aerosol was the main reaction process of PBM transformation in the atmosphere. Seasonal variations in Δ200Hg values were also found, indicating the possibility of even mass independent fractionation in tracing the mercury sources.