Ocean Island Basalts Research Articles

Double-diffusive layering during the evolution of planetary mantles

Summary The degree of layering during planetary mantle evolution has been a key issue and is still heavily debated, especially since the observation of seismic discontinuities within the Earth mantle and their correlation to phase transitions within the mantle mineral assemblage and the detection of geochemical differences in mantle derived basalts (Mid Ocean Ridge Basalts and Ocean Island Basalts). We present the phenomenon of double-diffusive layering in a fluid with strongly temperature dependent viscosity, as relevant for planetary mantle material, to study the influence of an initial compositional gradient with regard to the thermal and chemical evolution of a planet. The numerical experiments show that in a wide parameter range distinct layers are formed self-organized from a continuously stratified state by dynamical fractionation and are thus likely to appear as a generic. Considering this as a plausible model for planetary mantle evolution it provides a dynamical explanation for the existence of distinct chemical reservoirs within the history of a planet's mantle.

Parental magma and mantle source compositions of chromitites in the Mesoarchean Nuggihalli greenstone belt, India: Evidence for Archaean subduction zone magmatism

We present comprehensive petrological and geochemical analyses of chromitites from the 3.3-3.1 Ga Nuggihalli greenstone belt in Western Dharwar Craton, India. Our findings provide insights into the primary magma and mantle source compositions associated with these Archean oceanic lithosphere chromitites. Major and trace element data from chromites and clinopyroxenes in the chromitites, combined with thermobarometry and hygrometry calculations, and numerical modeling, indicate that the Nuggihalli chromites are characterized by high-Cr chromites (Cr# = 68.1-78.6) with low TiO 2 (0.19-0.29 wt. %), Al 2 O 3 (9.10-13.13 wt. %) and Ga (4.24-10.37 ppm). These chemical signatures are comparable to those of chromites from high-Cr podiform chromitites and boninites. Clinopyroxenes are mainly augites with high Mg# (93-95). Equilibrated melts with the clinopyroxenes from the Nuggihalli chromitites have high Mg# values (79-86), similar to ancient komatiitic or picritic magmas (Mg# = 75-90). Thermobarometry and hygrometry calculations indicate that the clinopyroxenes likely formed at temperatures of 1194-1221℃ and pressures of 0.7-5.8 kbar with high water contents (∼2.4-2.6 wt. %), exceeding water contents of mid-ocean basalts (MORB) and oceanic island basalts (OIB). Numerical modeling of rare earth elements indicates moderate degrees of partial melting (1% to ∼10%) of a hydrated spinel lherzolite mantle source (water content: ∼478-5408 ppm). The parental magmas of the 3.3-3.1 Ga Nuggihalli chromitites are characterized by enrichment of water contents (∼2.4-2.6 wt. %) and depletion of high field strength elements (HFSEs, e.g., Nb and Hf), which are similar to boninites and arc magmas. Furthermore, the rock associations, including ultramafic rocks with chromitites, high-Mg basalts, and sheets of gabbro-anorthosites in the Nuggihalli greenstone belt, are similar to the rock assemblages of ophiolites, which could represent a relic of a Mesoarchaean oceanic lithosphere formed in a forearc setting.

Magmatic and metamorphic evolution of the Late Cretaceous Muslim Bagh Ophiolite, western Pakistan: implications for ridge subduction after subduction initiation

ABSTRACT The magmatic and metamorphic evolutions of the Muslim Bagh Ophiolite (MBO) can help understand the relationship among supra-subduction ophiolite, subduction initiation, and the spreading centre in the forearc. Here, we investigated the whole-rock chemistry, mineral composition, P–T conditions, and K–Ar ages of the MBO and its associated units. The whole-rock and magmatic clinopyroxene compositions indicate that the MBO amphibolites and tholeiitic basalts of the underlying Bagh Complex originated in a supra-subduction setting and mid-ocean ridges, respectively. Late Cretaceous oceanic island basalts found in the Bagh Complex and the Bibai Formation occurred in oceans and near the passive continental margin of western India, respectively. Metamorphic Mg-hornblendes in the MBO amphibolites record low-P/T type upper amphibolite-facies metamorphism (2.4–2.9 kbar, 612–690 °C), indicating a > 50 ºC/km geothermal gradient. The K–Ar hornblende and plagioclase ages suggest contemporaneous low-P/T type metamorphism at ca. 78–71 Ma in the MBO formed in a forearc and tholeiitic ridge-related magmatism of ca. 78–77 Ma in the Bagh Complex, indicating a spreading ridge was active during the subduction. Our results, combined with plate kinematic reconstructions of the Neotethys Ocean in the previous studies, suggest that the abnormally high geothermal gradient in the MBO could be due to orthogonal ridge subduction near the triple junction after the ca. 80 Ma subduction initiation in the forearc. It is also likely that the geothermal gradient in the MBO dropped from >50 °C/km at 78–71 Ma, through 35–45 °C/km, to <25 °C/km at approximately 65 Ma due to gradual steepening of the subducting slab, followed by the obduction of the MBO during the Paleocene to Eocene period.

Upper mantle scale enrichment of Cenozoic intraplate magmatism in Northeast Asia: He-Sr-Nd-Pb-O isotope geochemistry of the basalts around the Korean peninsula

The Earth’s mantle is considered to be geochemically heterogeneous, which is reflected by the diverse composition of oceanic island basalts (OIB). The mantle enrichment resulting in this is attributed primarily to the influx of recycled crustal materials into the mantle through subduction. Additionally, the sub-continental lithospheric mantle (SCLM) complicates the elucidation of mantle heterogeneity. From this perspective, Northeast Asia, where the Pacific stagnant slab in the mantle transition zone and the SCLM distribution are presented, is the suitable site for examining the upper mantle scale enrichment. Here we report He-Sr-Nd-Pb-O isotope values of basalts that erupted around the Korean Peninsula to illustrate the source lithology and components that led to mantle heterogeneity. Our measured helium isotope ratios ranging from 5.7 to 7.3 Ra (3He/4He ratio of air, Ra = 1.39 x 10-6) are mostly within the SCLM range (6.1 ± 0.9 Ra) but lower than the mid-ocean ridge basalt range (MORB; 8 ± 1 Ra). The Sr-Nd-Pb isotope compositions of the basalts generally display a mixture of depleted MORB mantle (DMM), enriched mantle 1 (EM1), and enriched mantle 2 (EM2) components. In addition, the basalts have δ18Oolivine (vs. V-SMOW) values ranging from 4.7 to 5.7 ‰ that deviate from the DMM range (δ18Oolivine = 5.1 ± 0.2 ‰). Our isotopic analysis results highlight the role of the pyroxenite source in the metasomatized SCLM in the genesis of basalts. The low 3He/4He range of the basalts indicates a significant role in the SCLM. Moreover, the delaminated cratonic SCLM and asthenosphere-lithosphere interaction are candidate scenarios for the low 3He/4He ratios. Therefore, we propose that mixing of DMM (high 3He/4He ratio; 7 to 9 Ra) and the metasomatized SCLM (low 3He/4He ratio; 5 to 7 Ra) allowed enrichment within the upper mantle scale for the Cenozoic intraplate magmatism in Northeast Asia.

The geodynamics of plume-influenced mid-ocean ridges: insights from the Foundation Segment of the Pacific-Antarctic Ridge

The intersection of the Foundation Plume with the Pacific-Antarctic Ridge is a key location in global geodynamics where a mantle plume is approached by and interacting with a fast-spreading mid-ocean ridge. Here, we discuss a comprehensive major and trace element and Sr-Nd-Pb isotope dataset of new and existing samples from the young Foundation Seamount Chain (&amp;lt;5 Ma) and adjacent section of the Pacific-Antarctic Ridge. We use the geochemistry of axial, off-axis and intraplate lavas to map the spatial extent of plume dispersal underneath the ridge as well as the internal zonation of the upwelling plume. We show that the unusual length, increased crustal thickness and occurrence of silicic rocks on the axis of the Foundation Segment are the direct result of plume being tapped by the axial melting zone. We demonstrate that the plume is not homogeneous but shows a HIMU-like (high time-integrated 238U/204Pb) OIB (Ocean Island Basalt) component characterized by 206Pb/204Pb of up to 20.5 in its center and a more EM1-like (Enriched Mantle one) OIB component characterized by low U/Pb and 206Pb/204Pb but high Rb/Nb and 87Sr/86Sr towards its edges. Plume entrainment leads to a high magma supply rate that fosters the formation of silicic rocks and triggers the lengthening of the segment over time. However, plume dispersal is not symmetric as the geochemical tracers for the OIB component are extending &amp;lt;100 km northwards but &amp;gt;300 km southwards. We relate this to the current plate tectonic framework in which the obliquity between the migrating ridge and the absolute plate motions induces a sub-axial asthenospheric flow that preferentially channels plume material southwards.

Heavy iron isotopes reveal mantle oxidation in addition to pyroxenite sources for intraplate basalts

The heavier iron isotopic composition of some oceanic island basalts (OIB) relative to primary mid-ocean ridge basalts (MORB) has commonly been interpreted to reflect the heavy bulk isotopic compositions of their sources (e.g., of a pyroxenite-dominated mantle region). Alternatively, comparable Fe isotopic signatures observed in continental intraplate basalts (CIB) may record enhanced isotope fractionation during partial melting of an oxidized source, offering valuable insights into mantle oxidation induced by subducted carbonate. To distinguish between these two independent contributions, here we present high-precision Fe isotopic data (δ57Fe) and Fe3+/∑Fe ratios for a suite of Cenozoic intraplate basalts from Inner Mongolia, East Asia. These basalts are distributed along a northwest-southeast (NW–SE) profile and associated with earlier subduction of the Paleo-Asian oceanic slab. Variations in Fe/Mn ratios and zinc isotopic compositions (δ66Zn) of these basalts reveal that altered oceanic crust has always contributed to their mantle sources but the amounts of recycled carbonate gradually vary. Together with existing data, we demonstrate that all of these basalts generally exhibit heavier δ57Fe (0.07 ‰ to 0.31 ‰), higher Fe3+/∑Femelt (0.08 to 0.39) and Fe/Mn (> 65) relative to primary MORB (δ57Fe ∼0.10 ‰; Fe3+/∑Femelt ∼0.10; Fe/Mn ∼60), pointing to a common origin of heavy Fe isotopes in intraplate basalts that may reflect those of pyroxenite sources (e.g., recycled crust). However, these basalts containing larger amounts of recycled carbonate in their sources (i.e., higher δ66Zn) have heavier δ57Fe at similar Fe/Mn ratios and proportions of pyroxenite melt. Such Fe isotopic signatures exceed the exclusive role of pyroxenite and are best attributed to partial melting at oxidizing conditions (i.e., high Fe3+/∑Fesource) with an inferred enlarged fractionation factor. This oxidized mantle source formed through the reduction of recycled carbonate to graphite/diamond at depths greater than 150 km. A global dataset of Fe isotopes in intraplate basalts is compiled in order to examine this interpretation further. Compared with OIB typically from a pyroxenite/eclogite-dominant source, CIB with similarly heavy δ57Fe and formed by similar melting degrees are commonly more silica-undersaturated, indicating a widespread carbonated mantle source. Thus, these observations highlight that heavy Fe isotopes can record carbonate-induced mantle oxidation in addition to source lithological heterogeneity for intraplate basalts.

Trace element abundances in mineral phases and the groundmass of ocean island basalts

Incompatible trace elements are important tracers in igneous petrogenesis for determining processes acting: (i) prior to partial melting on magma sources; (ii) during partial melting, fractional crystallization or contamination of magmas, and (iii) after emplacement of lavas or intrusive rocks close to Earth's surface. Of particular interest are the high field strength elements (HFSE: Ti, Zr, Nb, Hf, Ta) which are incompatible elements with high valence states that are also relatively immobile in aqueous fluids. Abundances of Ti, Ta, and Nb (TITAN) in ocean island basalts (OIB) have been suggested to reflect recycled oceanic crust in mantle source regions, due to retention of these elements in subducted eclogitic rutile. Some of these elements have also been used to determine ‘canonical’ trace element ratios, such as Nb/U and Ta/U, that are considered invariant during petrogenetic processes. In this contribution, we present an extensive set of in situ trace element data for olivine, clinopyroxene, oxide minerals and groundmass for a suite of well-studied ocean island basalt (OIB) lavas from the Canary Islands, Azores, Samoa, Tubuai and La Réunion. The data were obtained using laser-ablation inductively coupled plasma mass spectrometry, and we also report a new open-source reduction routine for abundance determination using this method. Mineral-groundmass partitioning behavior is determined for olivine, clinopyroxene and oxides, showing that these are consistent with published partition coefficients for clinopyroxene and olivine, but are more variable for oxide phases. This variability is due to the wide variety of oxide phases possible in OIB (e.g., Cr-spinel, ilmenite, titanomagnetite) and their formation within the crystallization sequence. The new data shows that Nb and Ta budgets are dominated by fine-grained groundmass, as are most other incompatible trace elements, while the Ti budget is divided between clinopyroxene, oxide and groundmass. Modally reconstructed TITAN anomalies closely reproduce bulk rock compositions in samples with >40 % groundmass. Olivine and clinopyroxene fractional crystallization have negligible effects on TITAN anomalies, while oxide fractionation has more marked effects, with Ti anomalies being most affected. Variability in the HFSE in OIB and their association with other elements (e.g., Nb/U and Ta/U) can reflect source characteristics, although careful screening for petrogenetic effects should be done prior to ascribing significance to TITAN anomalies or canonical trace element ratios.

Mantle melting in regions of thick continental lithosphere: Examples from Late Cretaceous and younger volcanic rocks, Southern Rocky Mountains, Colorado (USA)

Major- and trace-element data together with Nd and Sr isotopic compositions and 40Ar/39Ar age determinations were obtained for Late Cretaceous and younger volcanic rocks from north-central Colorado, USA, in the Southern Rocky Mountains to assess the sources of mantle-derived melts in a region underlain by thick (≥150 km) continental lithosphere. Trachybasalt to trachyandesite lava flows and volcanic cobbles of the Upper Cretaceous Windy Gap Volcanic Member of the Middle Park Formation have low εNd(t) values from −3.4 to −13, 87Sr/86Sr(t) from ~0.705 to ~0.707, high large ion lithophile element/high field strength element ratios, and low Ta/Th (≤0.2) values. These characteristics are consistent with the production of mafic melts during the Late Cretaceous to early Cenozoic Laramide orogeny through flux melting of asthenosphere above shallowly subducting and dehydrating oceanic lithosphere of the Farallon plate, followed by the interaction of these melts with preexisting, low εNd(t), continental lithospheric mantle during ascent. This scenario requires that asthenospheric melting occurred beneath continental lithosphere as thick as 200 km, in accordance with mantle xenoliths entrained in localized Devonian-age kimberlites. Such depths are consistent with the abundances of heavy rare earth elements (Yb, Sc) in the Laramide volcanic rocks, which require parental melts derived from garnet-bearing mantle source rocks. New 40Ar/39Ar ages from the Rabbit Ears and Elkhead Mountains volcanic fields confirm that mafic magmatism was reestablished in this region ca. 28 Ma after a hiatus of over 30 m.y. and that the locus of volcanism migrated to the west through time. These rocks have εNd(t) and 87Sr/86Sr(t) values equivalent to their older counterparts (−3.5 to −13 and 0.7038–0.7060, respectively), but they have higher average chondrite-normalized La/Yb values (~22 vs. ~10), and, for the Rabbit Ears volcanic field, higher and more variable Ta/Th values (0.29–0.43). The latter are general characteristics of all other post– 40 Ma volcanic rocks in north-central Colorado for which literature data are available. Transitions from low to intermediate Ta/Th mafic volcanism occurred diachronously across southwest North America and are interpreted to have been a consequence of melting of continental lithospheric mantle previously metasomatized by aqueous fluids derived from the underthrusted Farallon plate. Melting occurred as remnants of the Farallon plate were removed and the continental lithospheric mantle was conductively heated by upwelling asthenosphere. A similar model can be applied to post–40 Ma magmatism in north-central Colorado, with periodic, east to west, removal of stranded remnants of the Farallon plate from the base of the continental lithospheric mantle accounting for the production, and western migration, of volcanism. The estimated depth of the lithosphere-asthenosphere boundary in north-central Colorado (~150 km) indicates that the lithosphere remains too thick to allow widespread melting of upwelling asthenosphere even after lithospheric thinning in the Cenozoic. The preservation of thick continental lithospheric mantle may account for the absence of oceanic-island basalt–like basaltic volcanism (high Ta/Th values of ~1 and εNd[t] &amp;gt; 0), in contrast to areas of southwest North America that experienced larger-magnitude extension and lithosphere thinning, where oceanic-island basalt–like late Cenozoic basalts are common.

Silurian ocean island basalt magmatism and Devonian−Carboniferous polymetamorphism: 100 million years in the Western Blue Ridge, USA

The tectonic configuration and evolution of southern Appalachian orogenic episodes are constrained, to a large extent, by knowledge of the timing and environment of pre- or syn-orogenic sediment deposition along with their subsequent thermal and deformational histories. The orogenic events that gave rise to regional folding and Barrovian metamorphism of the Western Blue Ridge (WBR) terrane are a classic example. We present new U-Pb and 40Ar-39Ar results bearing on the timing of magmatism and subsequent metamorphism of the Marble Hill Hornblende Schist (MHHS) of the WBR (southeastern USA). The schist is a key marker unit in the Murphy synclinorium, a central structure in the tectonic configuration of the WBR. The MMHS originated as basaltic volcanics overlying the Murphy Marble at the base of the Mineral Bluff Group. Ocean island basalt geochemistry and a zircon U-Pb age of ca. 437 Ma for the MHHS is consistent with plume-related volcanism in a Silurian remnant ocean basin of the Iapetus Ocean. Hornblende 40Ar-39Ar and rutile U-Pb ages for the MHHS are ca. 380−340 Ma and ca. 320 Ma, respectively, and record subsequent amphibolite facies metamorphism during Devonian Acadian orogeny and the deformation through regional folding and thrusting during the Carboniferous Alleghanian orogeny. The new age constraints for the MHHS require that “isograds” mapped in the region of the Murphy Belt are actually polymetamorphic mineral distributions that developed at least in part through post-Silurian tectonic events.

Molybdenum isotope evidence for recycled oceanic crust in the mantle sources of continental intraplate mafic lavas, Emeishan Large Igneous Province

The chemical and lithological heterogeneities of Earth's mantle in oceanic settings have long been attributed to the presence of recycled materials such as subducted crust, oceanic or subcontinental lithosphere mantle and sediment, as evidenced by Mid-Ocean Ridge Basalts (MORB) and Ocean Island Basalts (OIB). However, the extent to which recycled materials contribute to mantle heterogeneity in continental settings remains uncertain. Here we present systematic Sr-Nd-Pb-Mo isotope data for the Pingchuan picritic porphyries and associated mafic rocks (basalts and gabbros) in the central Emeishan Large Igneous Province, southwestern China, to resolve this issue. In contrast to the gabbro samples that show continental crust contamination in variations of δ98/95Mo (relative to NIST SRM 3134, −0.35 ± 0.03 to 0.03 ± 0.02 ‰), the Pingchuan picritic porphyries and basalts show a large range of δ98/95Mo (−0.32 ± 0.01 to −0.15 ± 0.06 ‰) and broadly negative trend between δ98/95Mo and Ce/Mo ratios, which cannot be explained by post-magmatic alteration, crustal contamination, fractional crystallization, olivine accumulation, metasomatism or fluid-activity in the mantle source. They were most likely derived from incongruent melting of a heterogeneous mantle source, i.e., a deep mantle with chondritic-like δ98/95Mo (−0.15 ± 0.01 ‰) containing recycled oceanic crust (+ sediment) with light δ98/95Mo (< −0.32 ‰). The basalts display low δ98/95Mo (−0.32 ± 0.01 to −0.24 ± 0.04 ‰), high 87Sr/86Sri (0.7046 to 0.7059), TiO2, Sm/Yb, Dy/Yb and Ce/Mo, pointing to characteristics of melts produced by MORB-type eclogite (+ sediment) at relatively low degrees of partial melting. With increasing degrees of partial melting, melts produced by peridotite (87Sr/86Sri = 0.7035 to 0.7043, chondritic-like δ98/95Mo = −0.18 ± 0.03 to −0.15 ± 0.06 ‰) come to dominate, resulting in low TiO2, Sm/Yb, Dy/Yb and Ce/Mo of the Pingchuan picritic porphyries. From a global perspective, continental basalts also plot on the negative trend defined by the OIB datasets (δ98/95Mo vs. Ce/Mo). As such, Mo isotope may provide a robust tracer of recycled oceanic crust in shaping mantle heterogeneities that occur in both oceanic and continental settings.

The helium and carbon isotopic signature of Ocean island basalts: Insights from Fogo volcano (Cape Verde archipelago)

Fluid inclusions (FI) entrapped in phenocrysts carried by Ocean Island Basalts (OIB) contain key information on volatiles’ abundance and origin in their mantle sources. Here, we add new piece of knowledge to our understanding of volatile geochemistry in global OIB magmas, by presenting new noble gas (He-Ne-Ar) and carbon (C) isotope results for olivine- and clinopyroxene-hosted FI from enclaves, lavas, tephra and volcanic gas samples from Fogo, the only frequently active volcano at the Cape Verde archipelago (eastern Atlantic Ocean). FI, together with crater fumaroles, constrain the Fogo 3He/4He signature at 7.14–8.44 Rc/Ra (where RC is the air-corrected 3He/4He isotope ratio, and Ra is the same ratio in air), which is within the typical MORB (Mid-Ocean Ridge Basalt) mantle. The carbon isotopic ratio (δ13C vs. Pee Dee Belemnite) of CO2 in FI and fumaroles range from -6.04 to -4.41 ‰. We identify systematic variations of δ13C and He/Ar* with FI entrapment pressure (estimated from a combination of host mineral barometry and FI microthermometry), from which we develop a model for volatile degassing in the mantle-to-crustal magma storage system. The model predicts a crustal-like signature for carbon (δ13C of -0.4 ± 1.0 ‰) in primary melts formed by mantle melting at ∼2200 MPa (∼77 km) and a source He/Ar* ratio of 0.90–0.24, which are indicative of variably depleted mantle metasomatized by carbon enriched melts/fluids from a crustal component. We also use our results to characterise regional (in the Cape Verde and Canary archipelagos) and global trends in C and He isotope composition from OIB. From a comparison with the few other OIB localities for which δ13C are available, we propose that a carbon enriched crustal component could be recurrent at a global scale in OIB magmatism, although often masked by isotope fractionation during magmatic degassing. We additionally find that, at regional scale, He isotopes in OIB scale inversely correlate with the degree of partial melting of the mantle beneath individual islands’ (inferred from the La/Yb ratio of erupted basalts). More widely, our results corroborate previously established global relationships between OIB He isotopic signature, plume buoyancy flux and overlying plate velocity. In this interpretation, the MORB-like 3He/4He (8 ± 1 Ra) at Fogo reflects a combination of (i) low to medium magma productivity, (ii) relatively low plume buoyancy flux (∼1.1 Mg/s), and (iii) slow average velocity (∼3 cm/yr) of the overlying plate.

Magmatic water content in HIMU basalts from the Cook-Austral Islands: constraints on degassing processes and source composition from clinopyroxene phenocrysts

The amount of water recycled during subduction is unclear. Water/Ce estimates in HIMU (high-238U/204Pb) basalts are variable, ranging from < 100 to > 250 in glasses and melt inclusions. Because clinopyroxene (cpx) is a common early liquidus phase and the cpx/melt partitioning of water is well constrained, cpx phenocrysts provide an additional constraint on magmatic water contents. We present water and trace element concentrations in HIMU-basalt-hosted cpx phenocrysts from the Austral Islands. Calculated melt [H2O] (up to 4.3 wt.%) and H2O/Ce ratios (22–825) are higher than in olivine-hosted inclusions, as are estimated equilibration pressures. Correlation between estimated melt [H2O] and crystallization or entrapment pressure suggests significant water loss during magma ascent. Most ocean island basalts (OIBs) span a limited range in H2O (~ 1–1.5 wt.%), and low (< 100) H2O/Ce ratios are primarily observed in melts with unusually high [Ce] (up to 350 ppm). Additionally, [H2O] and H2O/Ce in some suites correlate with entrapment pressure despite having quench pressures high enough to prevent significant water loss from open- or closed-system degassing (< 100 MPa). Polybaric “sparging”, whereby low-P melts re-equilibrate with CO2-rich fluids exsolved at higher pressure, may result in water loss at pressures less than CO2 saturation. This may more accurately describe OIB degassing processes than open or closed system degassing. After correcting for degassing, primary Australs melts likely have H2O/Ce of ~ 300–600. If applicable to OIB sources in general, this limits the total water budget of the mantle, including the mantle transition zone, to < 2.4 ocean masses.

Paleoseamounts in Yarlung Zangbo suture zone reveal dynamic processes of the Early Cretaceous Neo-Tethys lithosphere

Dynamic processes of the oceanic crust of seamounts trapped in continental sutures are poorly understood. The discovery and analysis of seamount sequences in the Yarlung Zangbo suture zone allowed us to detect vertical lithospheric movements of the eastern Neo-Tethys Ocean. In this study, we used petrological, geochemical, facies, paleontological, and stratigraphic methods to study composite blocks of mafic and sedimentary rocks in the Zhongba area of Xizang, China. Radiolarian fossils indicate an (early) Early Cretaceous age. Petrofacies and geochemistry show that most basalts occur as pillow lava and are enriched in light rare earth elements and high field strength elements, which suggests an oceanic-island basalt tectonic setting. Sedimentary lithofacies are grouped into breccias, shales, cherts, and limestones (ooid and cortoid grainstone microfacies). Three types of contact between basaltic basements and caps were identified as regular, talus, and erosive. These results demonstrate that two more superposed seamounts exist in the western Yarlung Zangbo suture zone than was known previously, and they comprise at least eight seamount sequences of basalts to sediments. Cap lithofacies and seamount textures illustrate that overall, the Zhongba paleo-seamounts record multiple cycles of abrupt deepening to shallowing, with water depth variations of ∼3000 m to ∼5 m due to multiple episodes of quick subsidence and uplift of seamounts (lithospheric “ups and downs”). The model of oceanic bypass recurrence and plume rejuvenation is hypothesized to explain the dynamic subsidence and uplift. While plume activities produced the mafic basement and considerable buoyancy-related lift, oceanic crust bypassed drift, created distance from the plumes, and led to cooling, loss of buoyancy, and rapid subsidence. This model provides a new approach to interpret the evolution of oceanic crusts that have disappeared.

Alkaline Devonian magmatism of the Menorca Island: Tracking the mantle isotopic sources in the realm of the western Paleo-Tethys Ocean

Several locations with alkaline magmatism are recognised in Silurian-Devonian basins along the southern variscan autochthon units (e.g. Central Iberian Zone) of the northern Gondwana margin. The origin of the Devonian basins and their magmatism has not been studied in the context of the passive margin of Gondwana. The basement of Menorca, Balearic Islands, consists of a deep Devonian-Carboniferous basin with mafic igneous rocks, the Tramuntana Gabbros. In this study, we trace the geodynamic setting and isotopic sources of the Tramuntana Gabbros through elemental geochemistry, isotopic geochemistry (SrNd) and UPb geochronology in zircons. These gabbros are the product of an intraplate alkaline magmatism with immobile trace element and REE contents similar to those of Ocean Island Basalts. Average 87Sr/86Sr(370) of 0.708456 and εNd(370) of +4.0 indicate a source similar to a Type-2 enriched mantle with average TDM of 665 Ma, suggesting a relatively old metasomatized mantle. Concordant UPb ages of c. 597 Ma (Ediacaran, radiometric age) from a single population of 31 zircons separated from the Tramuntana Gabbros (Devonian, biostratigraphic age) reinforce the presence of older units in the corresponding lithospheric mantle. The Tramuntana Gabbros and the Devonian-Carboniferous sequences of Menorca limit the westward extension of the Paleo-Tethys Ocean, whose development never reached these westernmost regions. Assuming a common sublithospheric mantle source for the peri-Gondwanic Devonian alkaline rocks and considering the previous Cadomian (Neoproterozoic) subduction to be the most favourable origin of the separated zircons, the bulk rock TDM and zircon UPb data obtained from the Tramuntana Gabbros track the mixing, recycling, and mantle accretion in this peri-Gondwanic section from Precambrian to Devonian times.

The petrogenesis of Cenozoic basalts from Daihai, western North China Craton: Constraints from 40Ar-39Ar chronology, major and trace elements, and Sr-Nd-Pb-Hf isotopes

The Daihai Cenozoic intraplate basalts are distributed in the western North China Craton (NCC), which is a part of the Cenozoic volcanic province in eastern China, and they are all alkaline basalts. The fine-scale determination of their mantle source region properties, partial melting mechanisms, and petrogenesis can provide crucial information for exploring lithospheric destruction and thinning in the western NCC. 40Ar-39Ar dating of potassium feldspar grains from the Daihai alkaline basalts yielded plateau ages of 18.22 ± 1.84 Ma and 26.86 ± 0.72 Ma, indicating that the Daihai basalts underwent multiple eruptive cycles during the Late Oligocene-Middle Miocene. These basalts exhibit ocean island basalt (OIB)-like geochemical features and were subjected to negligible crustal contamination. Moreover, basaltic magmas underwent intense fractional crystallization of olivine and clinopyroxene. The geochemical differences in the Daihai basalts were controlled by partial melting. The Daihai basaltic magmas were composed of at least two types (type I-enriched mantle and prevalent mantle) of mantle end-members that partially melted and then mixed, and the lithology of the mantle source region was predominantly peridotite. Under enriched mantle conditions, the mixing of garnet lherzolite partial melts (<1%) and spinel lherzolite partial melts (2-5%) can reasonably explain the elemental variations characteristic of the Daihai basalts. Most importantly, the melting depth and lithospheric thickness of the Daihai basalts were < 70 km or even close to 50 km, implying that the western NCC underwent lithospheric destruction and thinning during the Cenozoic. However, these effects were spatially heterogeneous. The most plausible genetic mechanism for the generation of the Daihai basalts was the coupled effects of subduction of the Pacific slab and subduction–collision of the Indo–Eurasian Plate since the Oligocene. The mantle flows generated by these two events convected, blocked and triggered upwelling mantle flows at the eastern margin of the Ordos Block. The upwelling mantle flows resulted in frequent magmatism in the region.

The Underwater Esmeralda Volcano (Mariana Island Arch) and some Features of the Composition of its Composition Rocks

A generalization of the available original data and literature data on the geological and geophysical knowledge of the underwater volcano Esmeralda, located in the Mariana Island Arc, has been carried out. As a result of studying the rocks dredged during the 4th and 5th cruises of the R/V Vulkanolog at the present level, new data were obtained on the silicate and rare-element composition of the rock samples that make up this underwater volcano. It has been established that the studied volcanic edifice is composed of five types of rocks: basalts, basaltic andesites, dacites, gabbro, and basanites. For the first time, samples of dacite and basanite have been discovered, indicating that the petrochemical diversity of the underwater volcano Esmeralda is wider than previously thought. All dredged rocks are characterized by a slightly increased content of incoherent elements LILE and HFSE. The studies carried out made it possible to attribute the main part of the dredged rocks to the association of island-arc ferruginous tholeiites (IAB, IAT) and only the composition of a single sample of alkaline basalt (basanite) falls into the field of alkaline basalts of oceanic islands (OIB, OIA). The increased content of iron in plagioclase phenocrysts confirms that the rocks belong to the high-iron tholeiite association.

Intraplate alkali basalts related to end-Cretaceous Deccan magmatism: implications for tectonomagmatic processes

This study aims to investigate the earliest imprint of Deccan rift magmatism as preserved in alkali basalts from the northwestern Indian shield. The alkali basalts are petrographically classified as nephelinites and basanites. They are silica undersaturated and their high Mg numbers, CaO/Al 2 O 3 , Cr and Ni indicate their primitive character. Geochemically, they are similar to global ocean island basalts; their bulk rock trace elements and Sr–Nd–Hf isotopic signatures suggest their derivation from a garnet-bearing peridotite field. However, their elevated values of Sr/Sm, Sm/Hf, Zr/Hf, Nb/Ta; positive Ba, Sr and negative Zr, Hf spikes suggest that the magma source represents a mixture of garnet peridotites and carbonated melts. Estimated primary melt compositions closely follow the trajectory defined by the high-pressure experimental partial melting trend of a low-carbonated peridotite source. The melting environment approximates to a high mantle potential temperature. A low 87 Sr/ 86 Sr ratio and a negative correlation between 176 Hf/ 177 Hf and 143 Nd/ 144 Nd of the alkali basalts suggest that the mantle source is a mixture of a depleted Indian MORB-type mantle and an enriched mantle type 2. We correlate this event with the melting of the leading edge of the Réunion plume head during Gondwana break-up in a relatively short span of the Cretaceous/Paleogene boundary.

Molybdenum isotopic evidence for the initiation of a big mantle wedge beneath eastern Asia

The subduction of the Paleo-Pacific plate and the formation of a big mantle wedge have influenced the tectonic-magmatic evolution of eastern Asia. However, the timing and mechanism of big mantle wedge formation remain obscure. Here we report molybdenum (Mo) isotope compositions of Mesozoic-Cenozoic mafic rocks in eastern China, which provide constraints on the geodynamics of Paleo-Pacific subduction. The >125 Ma rocks have high δ98Mo values of −0.27‰ to 0.17‰ and arc-like features, whereas the <125 Ma rocks have low δ98Mo values of −0.67‰ to −0.04‰ and ocean-island basalt (OIB)-like features. The mantle sources of these two types of rocks contain subducted Paleo-Pacific slab components at sub-arc and mantle transition zone depths, respectively. Therefore, the Paleo-Pacific subduction involves shallow subduction yielding a small mantle wedge in the early stage and deep subduction yielding a big mantle wedge in the late stage. The dramatic change in Mo isotopes reveals that the big mantle wedge beneath eastern Asia was initiated at ∼125 Ma.

The Shalap Mélange of the Salairian Alambay Ophiolite Zone (Northwestern Central Asian Orogenic Belt), Geological Structure and Compositional Features of Amphibolites and Greenstone Basalts

The Alambay ophiolite zone (AOZ) is located in the axial part of the Early Paleozoic Salair orogen and includes the northern extension of the Alambay-Kaim zone, Salair and Altai Mountains. The Shalap area of the AOZ is predominantly composed of clastic mélange with occasional serpentine mélange. The geological and geochemical studies showed that in the Shalap mélange there are basalt blocks of the Alambay formation whose petrogeochemical features are similar to those of the oceanic island basalts (OIB). Metamorphic rocks of the Angurep complex, represented by garnet and non-garnet amphibolites, form a tectonic slab which is a part of the accretionary complex east of the Shalap mélange area. Metamorphic rocks also form blocks in the Shalap mélange. The amphibolites of the Angurep complex are similar in their petrogeochemical features to the basalts of intraoceanic island arcs. The Shalap mélange is a fragment of the Salairian Cambrian paleosubduction zone. The subduction and exhumation processes in this paleosubduction zone terminated by the 500 Ma time stage.

Continental flood basalts sample oxidized mantle sources

Large igneous provinces (LIP) are vast (0.2 to >1 Mkm3) outpourings of basaltic lava and voluminous intrusions of magmas that have had important environmental consequences, in many cases leading to immense greenhouse gas release and mass extinctions. Magmatic oxygen fugacity (fO2) influences the chemistry of volcanic gases and is an important parameter for examining the links between LIP eruptions and environmental change. To constrain the fO2 of LIP magmas, we report olivine elemental chemistry of 399 crystals from a set of fifteen olivine-rich LIP samples, spanning in age from the Proterozoic (∼1270 Ma) to the Miocene (∼17 Ma). Concentrations of V in olivine are used to show that mafic LIP lavas erupted at +1.20 ± 0.95 ΔFMQ, on average more oxidized than mid ocean ridge basalts (MORB) at −0.28 ± 0.28 ΔFMQ. Mafic LIP magmas show a much larger range than MORB, however. Additionally, fO2 shows a negative correlation with parental magma MgO content, with high MgO lavas approaching the MORB range. This correlation is likely due to sampling of a heterogeneous mixture of oxidized and reduced lithologies, as also sampled by ocean island basalts (OIB). Correlation between fO2 and isotopic ratios such as 143Nd/144Nd demonstrates that the oxidized endmember is geochemically enriched, and may result from subduction recycling of oxidized surficial materials. The high fO2 of primitive LIP magmas demonstrate that they largely emitted oxidized gases during eruption, and furthermore, that LIP magmas associated with mass extinctions have similar magmatic fO2 to those that are not. Global plate tectonic position, magnitude and duration of LIP volcanic eruptions and magmatic degassing, as well as interaction with sedimentary basins in the crust - but not mantle source fO2 - are likely to be the critical factors for whether a LIP was associated with a mass extinction.