Ocean Bottom Water Research Articles

Unusual weakening trend of the East Asian winter monsoon during MIS 8 revealed by Chinese loess deposits and its implications for ice age dynamics

A fundamental aspect of marine benthic foraminiferal δ18O records of the last one million years is their “saw-tooth” pattern, characterized by gradual cooling to full glacial conditions followed by very rapid glacial terminations. Understanding the mechanism of this pattern is crucial for understanding ice age dynamics. We investigated the climatic trend within each glacial of the last 880 kyr by comparing the signal of the East Asian winter monsoon (EAWM) with global terrestrial and marine paleoclimate records. Our new grain size record from the Huining loess-paleosol section in the western Chinese Loess Plateau, together with published climate records from the Yimaguan and Luochuan sections in the central Chinese Loess Plateau, demonstrates a strengthening trend of the EAWM within most glacials, which largely mirrors the “saw-tooth” pattern of the benthic foraminiferal δ18O record. However, the EAWM record during Marine Isotope Stage (MIS) 8 shows an unusual weakening trend which is the exception over the last 880 kyr. Based on the linkages between Arctic ice sheets, the Siberian High Pressure system, and the EAWM, we propose that the weakening trend of the EAWM throughout MIS 8 reflects the overall shrinking of Arctic ice sheets towards the glacial termination, in contrast to the increasing trend of the benthic foraminiferal δ18O values. This conclusion is supported by a compilation of global paleoclimate records suggesting that MIS 8 was a unique glacial period over the last 900 kyr, characterized by a mild climate in middle to high northern latitudes and a cold climate in high southern latitudes, during late MIS 8. The inferred changes in Arctic ice sheets would alone cause a decreasing trend in benthic foraminiferal δ18O values during MIS 8, which is the opposite to the observed trend. We suggest that an increased ice volume in high southern latitudes led to the cooling of Antarctic Bottom Water and hence to a decrease in ocean bottom water temperature with an effect to increase benthic foraminiferal δ18O during MIS 8 as observed. Our results highlight the complexity of using the benthic δ18O signal alone as a paleoclimate proxy, and that MIS 8 is an important time window for better understanding glacial dynamics driven by changes in the polar regions of both hemispheres.

Implications of transient methane flux on associated biological communities in high-arctic seep habitats, Storbanken, Norwegian Barents Sea

The continental margins of the Arctic Ocean basin contain methane seeps, where transient fluxes of seafloor methane are released due to the thermal dissociation of gas hydrates. An increase in shallow methane seeps identified over the past decade, potentially due to enhanced warming of the Arctic Ocean bottom water and associated destabilization of hydrate structure. Biological communities associated with methane release east of Svalbard in the Barents Sea (Storbanken Crater site, 76° 46.7′N, 35° 43.5′E, depths between 120 m–300 m depths) were investigated using towed camera imagery and ship-based platforms during a 2017 CAGE17-2 cruise on the RV Helmer Hanssen. We analyzed relationships among methane flux data, seafloor habitat characteristics, and biological community structure (i.e., presence and distribution of megafauna and expression of microbial mats) from a total of 14 surveys (6827 images and 40 multicore sediment cores) within the Storbanken Crater area and compared it to 2015 data. Unlike seep expressions at deeper sites (∼1200 m) in the Norwegian margin region, no seep-endemic, chemosynthetic-associated megafaunal species were observed at the shallow surveyed sites and all sites hosted similarly diverse communities of non-seep species, including commercially important fish and crustaceans. Methane concentrations did not markedly differ between the crater and non-crater sites. Rates of methane gas advection through sediments (in the form of flares) were relatively low and concentration of methane was even lower in porewater samples at the crater site. We present the first evidence of methane flare flux and intermittent microbial mat distribution with associated folliculinid ciliates, which suggests a long history of methane emissions and a transient seep environment in spatial and temporal flux. Together, this study presents a critical baseline on the temporal release of arctic methane and benthic biological communities to initiate temporal studies that identify future changes and predict the impact of climate change.

Sedimentary deformation relating to episodic seepage in the last 1.2 million years: a multi-scale seismic study from the Vestnesa Ridge, eastern Fram Strait

Seafloor hydrocarbon seepage is a natural fluid release process that occurs worldwide on continental shelves, slopes, and in deep oceanic basins. The Vestnesa sedimentary ridge in the eastern Fram Strait hosts a deep-water gas hydrate system that became charged with hydrocarbons ∼2.7 Ma and has experienced episodic seepage along the entire ridge until a few thousand years ago, when seepage activity apparently ceased in the west but persisted in the east. Although it has been documented that faults and fractures play a key role in feeding the seeps with thermogenic gases, the mechanisms controlling seepage periodicity remain poorly understood. Here we integrate high-resolution P-cable 3D seismic and Chirp data to investigate the spatial and temporal evolution of high-resolution fractures and fluid flow features in the west of the Vestnesa Ridge. We characterize sediment deformation using a fracture density seismic attribute workflow revealing two highly deformed stratigraphic intervals and associated small-scale pockmarks (<20 m diameter). Chronostratigraphic constraints from the region show that these two highly deformed intervals are influenced by at least three major climatic and oceanic events during the last 1.2 million years: the Mid-Pleistocene Transition (∼1.25–0.7 Ma), the penultimate deglaciation (∼130 ka) and the last deglaciation (Heinrich Stadial 1: ∼16 ka). These periods of deformation appear associated with seismic anomalies potentially correlated with buried methane-derived authigenic carbonate and have been sensitive to shifts in the boundary of the free gas-gas hydrate interface. Our results show shifts (up to ∼30 m) in the depth of the base of the gas hydrate stability zone (GHSZ) associated with major changes in ocean bottom water temperatures. This ocean-driven effect on the base of the GHSZ since the Last Glacial Maximum coincides with the already highly deformed Mid-Pleistocene Transition sedimentary interval and likely enhanced deformation and gas leakage along the ridge. Our results have implications for understanding how glacial cycles impact fracture formation and associated seepage activity.

Geochemical and paleontological evidence of early Cambrian dynamic ocean oxygenation and its implications for organic matter accumulation in mudrocks at the Three Gorges area, South China

The evolution of global ocean oxygenation during the early Cambrian remains highly controversial, making it difficult to evaluate how environmental triggers play a role in controlling the organic matter (OM) accumulation in black shales. In this study, an integrated approach, including total organic carbon (TOC) content, major and trace element geochemistry, and microscope images, was systematically conducted in a continuous core well that penetrated through the Lower Cambrian Yanjiahe (YJH)–Shuijingtuo (SJT, subdivided into SM Ⅰ, SM Ⅱ, SM Ⅲ, and SM Ⅳ members) successions (∼541-514Ma) at the Three Gorges area, Yangtze Platform, South China. Our results showed that the ocean stepwise oxidation evolution in shelf-slope environments occurred even though the marine redox state showed highly dynamic fluctuations during the early Cambrian. Based on geochemical proxies and sedimentological and faunal criteria, the OM-rich mudrocks in the SJT Formation can be divided into two units. The lower part (SM Ⅰ) contains a higher TOC content (average value 5.71 wt%) than the upper part (SM II, average TOC value of 2.73 wt%). SM Ⅰ are characterized by high MoEF, UEF, Corg/P, and U/Th ratios, indicating that SM I was deposited under constantly euxinic conditions. The relatively declining MoEF, UEF, Corg/P, and U/Th ratios at the transition interval between the SM Ⅰ and SM II records a change in bottom-water to predominantly anoxic conditions with intermittent oxygenation. Correspondingly, the biological record evolved from extremely limited benthic organisms to diverse sponge spicules. The high paleoproductivity, sustained euxinic conditions, and limited dilution linked to sea-level rising are responsible for the OM enrichment in SM I black shales. In comparison, SM II was deposited under mainly suboxic/dysoxic conditions with the lower Corg/P, U/Th ratios, and moderate enrichment of Mo (<25 ppm), which were accompanied by the abundant development of agglutinated benthic foraminifera, sponge spicules, radiolarians, etc. The OM accumulated under low-oxygen conditions and increased terrigenous input even though the paleoproductivity remained at a high level during the deposition of SM Ⅱ. The ocean bottom-water then evolved into oxic conditions with extremely low Corg/P, U/Th ratios, and no Mo concentrations in OM-lean calcareous mudrocks and limestone developed in the upper part of the SJT Formation, including SM Ⅲ (avg. TOC is 0.6 wt%) and SM Ⅳ (avg. TOC is 0.09 wt%). The combination of an oxic depositional environment, limited primary productivity, and dilution of terrigenous inputs was unfavorable for OM enrichment during that period.

Some like it cool: Benthic foraminiferal response to Paleogene warming events

Long-term climatic trends of the Paleogene were interrupted by global perturbations of the carbon cycle, commonly associated with warming of surface and bottom waters and ecosystem disturbance. Most of these perturbations occurred in the Paleocene - Eocene greenhouse climate, but others were superimposed on the transition of greenhouse-to- icehouse conditions during the middle to late Eocene. Here we analyze deep-sea benthic foraminifera to focus on the impact of Paleogene warming events on ocean bottom water ecosystems. We compare changes in assemblage diversity (Fisher-α index) across nine warming events at 16 locations (ocean drilling sites and land sections; 25 case studies) by applying the Epps-Singleton and Fligner-Killeen non-parametric statistical tests. Generally, diversity decreased whereas the coefficient of variation increased during warming events, but not all changes were statistically significant. The declines in diversity may have been due to adaptation to stressed conditions, whereas the higher coefficients of variation may have been caused by unstable environmental conditions. The most severe events, the Paleocene-Eocene Thermal Maximum (PETM, ~56 Ma) and Eocene Thermal Maximum 2 (ETM2, ~53.7 Ma), had a higher impact on bottom water ecosystems, as shown in major drops in diversity. Regression analysis of data for ODP Sites 1262 and 1263 (SE Atlantic) shows that only up to 62% of the variability of benthic foraminiferal diversity at these sites depends on δ 13 C and δ 18 O values, indicating that changes in diversity were not exclusively determined by the magnitude of the events as defined by the magnitude of changes in carbon isotope excursion and temperature. No major changes in diversity were identified during middle Eocene warming events, and post-event diversity became significantly more stable, suggesting that the overall cooler middle Eocene conditions supported higher faunal diversity and stability of benthic foraminiferal assemblages. • Declined diversity at warming events correlated to magnitude and local factors. • Background climate conditions influenced the impact of warming on marine biota. • Cooler middle Eocene conditions promoted higher diversity of benthic foraminifera.

Holocene variability in chemical weathering and ocean redox state: A reconstruction using sediment geochemistry of the Arabian Sea

• Geochemistry of a core (0.8–7.2 kyr) from the eastern Arabian Sea was studied. • Provenance and chemical weathering show the minimal change between 7.2 and 2.6 kyr. • Changes in weathering patterns were observed during the Roman Warm Period. • Transition from oxic to reduced bottom water condition was observed since ∼4.2 kyr. Major and trace elemental geochemistry of a sediment core (SSK40/GC10; water depth ∼ 50 m) from the eastern Arabian Sea (17° 59.89123 N, 72° 22.45161 E) have been investigated to reconstruct the continental weathering pattern and ocean redox state between 7.2 and 0.8 kyr BP (kyr, hereafter). The covariations of Fe/Al with K/Al and Ti/Al ratios indicate that the western-flowing Indian rivers (e.g., Narmada, Tapi, and Mahi) and eolian supply from the Thar regions are the major sediment suppliers to this location. Factor analysis of the geochemical dataset identifies four major factors explaining about 80 % of the total variance. Down-core profiles of several detrital proxies (Fe/Al, Ti/Al, V/Al, and Co/Al) show that the sediment sources were nearly uniform until 2.6 kyr. In contrast, changes in provenance indices, K/Al ratios, and CIA* (modified Chemical Index of Alteration) have been observed in the upper part of the core. The period of these weathering changes (2.6–1.6 kyr) mostly overlaps with the Roman Warm Period, indicating a weathering-climate linkage. Variations in the Ba/Al ratios and enrichment factors of U (EF-U) and Mo (EF-Mo), along with TOC/Al, and S/Al trends, indicate a fluctuating oceanic (bottom water) redox state during the studied period. These trends point to a shift from oxic to anoxic bottom water condition since ∼4.2 kyr. The timing of this change is synchronous to the earlier reported drought phase at the beginning of the Meghalayan stage, underscoring climatic control on the bottom water redox state.

Examining the effects of chemical cleaning, leaching, and partial dissolution on zinc and cadmium isotope fractionation in marine carbonates

The application of zinc (Zn) and cadmium (Cd) isotopes as palaeo-proxies in carbonate sediment is rapidly expanding due to their potential for tracing changes in biological productivity in the modern and past oceans. However, there are limited investigations into the chemical cleaning methods required to produce the most consistent and accurate data for these novel isotope systems. This could impact their use as palaeo-proxies to reconstruct ocean-atmosphere-climate interactions throughout Earth's history.To address this concern and expand the utility of the Zn and Cd stable isotope systems as palaeo-productivity tracers, the performance of two standard chemical cleaning protocols for acquiring robust and reliable Zn and Cd isotope datasets were assessed. These include (i) the Cd-cleaning method that uses a reductive step to selectively leach contaminating secondary iron (Fe)‑manganese (Mn) (oxyhydr)oxide coatings from the carbonate surface, and an oxidative step that is used to remove post-depositional organic matter and sulphide precipitates; and (ii) the magnesium/calcium cleaning protocol that includes an oxidative step only, leaving secondary FeMn (oxyhydr)oxide coatings largely intact. Well-preserved Holocene-, and Mesozoic-aged carbonate sediments were used to test the reliability of these two chemical cleaning methods. The Holocene samples comprised not only aliquots of bulk sediment, but also individual species of planktic and benthic foraminifera.Our results show that the best practice chemical cleaning method for retrieving consistent and accurate Zn and Cd isotope, and Zn/Ca and Cd/Ca datasets for carbonate sediments, requires both reductive and oxidative cleaning following the Cd-cleaning method. This differs from most methodological approaches applied to date that remove the reductive step from the chemical cleaning protocol and apply an oxidative step only, or no chemical cleaning at all. Inclusion of the reductive step in the chemical cleaning method typically shifts δ66Zn by ~0.1‰ lower and δ114Cd by 0.3‰ higher in the solid phase, while Zn/Ca and Cd/Ca typically decrease 2-fold. The benthic foraminifera, C. wuellerstorfi, that live in ocean bottom waters where the seawater Zn and Cd isotope composition is homogeneous display evidence of Zn and Cd isotope fractionation between seawater and carbonate on the order of 0.08 ± 0.08‰ (2SE, n = 4) and − 0.25 ± 0.13‰ (2SE, n = 4), respectively, in agreement with experimental constraints. Furthermore, evidence of Zn isotope fractionation effects are recorded in a naturally-dissolved carbonate sediment, together with laboratory-controlled carbonate dissolution experiments. Based on these results, we recommend the Cd-cleaning method and the application of Zn and Cd isotope fractionation factors to accurately reconstruct past seawater Zn and Cd isotope compositions from carbonate sediments.

Geothermal heating and episodic cold-seawater intrusions into an isolated ridge-flank basin near the Mid-Atlantic Ridge

Six-year records of ocean bottom water temperatures at two locations in an isolated, sedimented deep-water (∼4500 m) basin on the western flank of the mid-Atlantic Ridge reveal long periods (months to >1 year) of slow temperature rises punctuated by more rapid (∼1 month) cooling events. The temperature rises are consistent with a combination of gradual heating by the geothermal flux through the basin and by diapycnal mixing, while the sharper cooling events indicate displacement of heated bottom waters by incursions of cold, dense bottom water over the deepest part of the sill bounding the basin. Profiles of bottom water temperature, salinity, and oxygen content collected just before and after a cooling event show a distinct change in the water mass suggestive of an incursion of diluted Antarctic Bottom Water from the west. Our results reveal details of a mechanism for the transfer of geothermal heat and bottom water renewal that may be common on mid-ocean ridge flanks.

Geochemical consequences of oxygen diffusion from the oceanic crust into overlying sediments and its significance for biogeochemical cycles based on sediments of the northeast Pacific

Abstract. Exchange of dissolved substances at the sediment–water interface provides an important link between the short-term and long-term geochemical cycles in the ocean. A second, as yet poorly understood sediment–water exchange is supported by low-temperature circulation of seawater through the oceanic basement underneath the sediments. From the basement, upwards diffusing oxygen and other dissolved species modify the sediment, whereas reaction products diffuse from the sediment down into the basement where they are transported by the basement fluid and released to the ocean. Here, we investigate the impact of this “second” route with respect to transport, release and consumption of oxygen, nitrate, manganese, nickel and cobalt on the basis of sediment cores retrieved from the Clarion Clipperton Zone (CCZ) in the equatorial Pacific Ocean. We show that in this abyssal ocean region characterised by low organic carbon burial and sedimentation rates vast areas exist where the downward- and upward-directed diffusive fluxes of oxygen meet so that the sediments are oxic throughout. This is especially the case where sediments are thin or in the proximity of faults. Oxygen diffusing upward from the basaltic crust into the sediment contributes to the degradation of sedimentary organic matter. Where the sediments are entirely oxic, nitrate produced in the upper sediment by nitrification is lost both by upward diffusion into the bottom water and by downward diffusion into the fluids circulating within the basement. Where the oxygen profiles do not meet, they are separated by a suboxic sediment interval characterised by Mn2+ in the porewater. Where porewater Mn2+ in the suboxic zones remains low, nitrate consumption is low and the sediment continues to deliver nitrate to the ocean bottom waters and basement fluid. We observe that at elevated porewater manganese concentrations, nitrate consumption exceeds production and nitrate diffuses from the basement fluid into the sediment. Within the suboxic zone, not only manganese but also cobalt and nickel are released into the porewater by reduction of Mn oxides, diffusing towards the oxic–suboxic fronts above and below where they precipitate, effectively removing these metals from the suboxic zone and concentrating them at the two oxic–suboxic redox boundaries. We show that not only do diffusive fluxes in the top part of deep-sea sediments modify the geochemical composition over time but also diffusive fluxes of dissolved constituents from the basement into the bottom layers of the sediment. Hence, the palaeoceanographic interpretation of sedimentary layers should carefully consider such deep secondary modifications in order to prevent the misinterpretation of primary signatures.

Biotic and Isotopic Vestiges of Oligotrophy on Continental Shelves During Oceanic Anoxic Event 2

AbstractThe widespread expansion of the oxygen minimum zone onto shelves has been commonly regarded as a primary cause of benthos extinction in epicratonic sea ecosystems during the Cenomanian–Turonian boundary event (CTBE). However, neither lithology, geochemical proxies, nor micropaleontological data support this hypothesis. Instead, our integrated foraminiferal and dinoflagellate cyst study, corroborated by δ13Corg and δ15Norg data, indicate that the biota were impacted by an abrupt shift to well oxygenated oligotrophic conditions and a collapse of primary productivity in the epicontinental Central European Basin. Because the event was concurrent with the development of extensive and extreme oceanic bottom water anoxia that reached the photic zone in oceanic settings, we infer that the biotic crisis in the shelf seas during Oceanic Anoxic Event 2 (OAE2), and possibly during other OAEs, was triggered by this anomalous nutrient cycling in Earth's oceans. This phenomenon was presumably associated with intensive denitrification combined with anammox activity in the deep “ammonium oceans,” which caused a significant loss of biologically reactive nitrogen from the ocean system. Impingement of ammonium‐rich anoxic waters on the photic zone resulted in primary productivity based primarily on ammonium assimilation, as recorded by strongly 15N‐depleted organic matter deposited in the oceans during the CTBE. We propose that, unlike in the oceanic settings, productivity in the well‐oxygenated, oligotrophic epicontinental seas was nitrate‐based, as evidenced by strongly 15N‐enriched organic matter deposited in the contemporaneous epicontinental sea. These very high δ15Norg values (&gt;+5‰) were related to the spreading of shallow oceanic waters carrying 15N‐enriched nitrate onto epicontinental settings.

Triassic Foraminifera from the Great Bank of Guizhou, Nanpanjiang Basin, south China: taxonomic account, biostratigraphy, and implications for recovery from end-Permian mass extinction

AbstractForaminifera are important components of tropical marine benthic ecosystems and their recovery pattern from the end-Permian mass extinction can yield insights into the Mesozoic history of this group. Here we report the calcareous and agglutinated foraminifera recovered from five measured stratigraphic sections on the Great Bank of Guizhou, an uppermost Permian to Upper Triassic isolated carbonate platform in the Nanpanjiang Basin, south China. The material contains &gt;100 Triassic species, including three that are newly described (Arenovidalina weiin. sp.,Meandrospira?enosin. sp., andSpinoendotebanella lehrmannin. gen., n. sp.), ranging from Griesbachian (Induan) to Cordevolian (Carnian) age. The species belong to the classes Miliolata, Textulariata, Fusulinata, Nodosariata, and to an unknown class housing all aragonitic forms of the orders Involutinida and Robertinida. Based on previously established conodont zones and carbon isotope chemostratigraphy, the Griesbachian (early Induan) through Illyrian (late Anisian) interval has been subdivided into 12 foraminiferal zones and two unnamed intervals devoid of foraminifera. Following the extinction at the Permian-Triassic boundary, habitable ecological niches of Griesbachian age were invaded by disaster taxa that subsequently became extinct during the Dienerian (late Induan) and left no younger descendants. The disaster taxa were replaced by Lazarus taxa with Permian origins, which were then decimated by the Smithian-Spathian (mid-Olenekian) boundary crisis. The tempo of recovery appears to have been modulated by environmental changes during the Griesbachian through Smithian that involved both climate change and expansion of anoxic ocean bottom waters. Uninterrupted and lasting recovery of benthic foraminifera did not begin until the Spathian.UUID:http://zoobank.org/2a6e9061-b163-402a-9098-8765a80576b3

The role of oceanographic processes and sedimentological settings on the deposition of microplastics in marine sediment: Icelandic waters

The global distribution of microplastic debris on the sea floor poses an increasing risk to marine organisms and ecosystems. Here, we present a distribution analysis of microplastics collected from eight marine multicores recovered from the Iceland continental shelf and surrounding areas at water depth between 241 and 1628 m. We report a total of 306 microplastics from the size range > 250 μm −5 mm, of which all were fibers. Microplastic numbers range between 0.119 and 0.768 per gram of dry sediments. In the analysis we assess the potential role of oceanic surface and bottom water currents, organic content, and sediment type on the distribution, deposition, and burial of microplastics in marine sediments. Our results provide the first record of microplastic pollution of marine sediments from the Iceland continental shelf and identify Atlantic Cod feeding and breeding grounds as potential hot spot for the accumulation of marine debris.

Ocean surface and bottom water conditions, iceberg drift and sediment transport on the North Iceland margin during MIS 3 and MIS 2

Radiocarbon dates and marine tephra suggest that the upper 10 m of core MD99-2274 off North Iceland extends from ∼0 to ∼65 ka BP. A multi-proxy sediment and biomarker study at a ∼0.5 ky resolution is used to derive a paleoclimate scenario for this area of the southwestern Nordic Seas, which during the Holocene had intermittent excursions of icebergs and a seasonal cover of drifting sea ice across the site. The sortable silt mean size (S̅S̅) suggests a bottom current (1000 m depth) flow speed maximum to minimum range of ∼8 cm/s during Marine Isotope Stages 2–3, but the data are unreliable for the Holocene. Slow-down in flow speeds may be associated with massive ice and water discharges linked to the Hudson Strait ice stream (H-events) and to melt of icebergs from Greenland in the Nordic seas where convection would have been suppressed. Five pulses of sediment with a distinct felsic component are associated with iceberg transport from E/NE Greenland. Sea ice, open water and sea surface temperature (SST) biomarker proxies (i.e. IP25, HBI III, brassicasterol and alkenones) all point towards near-perennial sea ice cover during MIS 3 and 2, rather than seasonal sea ice or open water conditions. Indeed, our biomarker and sediment data require that the seas north of Iceland experienced a nearly continuous cover of sea ice, together with icebergs calved from ice stream termini, which drifted southward. The cross-correlation of the quartz % records between MD99-2274 and the well-dated core PS2644 in Blosseville Basin indicates significant coherence in the records at a multi-millennial (∼8 ky) timescale. A transition to open ocean conditions is evident from the early Holocene onwards, albeit with the occurrence of some drift ice and icebergs.

Warm Middle Miocene Indian Ocean Bottom Water Temperatures: Comparison of Clumped Isotope and Mg/Ca‐Based Estimates

AbstractThe middle Miocene is an important analogue for potential future warm climates. However, few independent deep ocean temperature records exist, though these are important for climate model validation and estimates of changes in ice volume. Existing records, all based on the foraminiferal Mg/Ca proxy, suggest that bottom water temperatures were 5–8°C warmer than present. In order to improve confidence in these bottom water temperature reconstructions, we generated a new record using carbonate clumped isotopes (Δ47) and compared our results with Mg/Ca‐based estimates for the Indian Ocean at ODP Site 761. Our results indicate temperatures of 11.0 ± 1.7°C during the middle Miocene Climatic Optimum (MCO, 14.7–17 Ma) and 8.1 ± 1.9°C after the middle Miocene Climate Transition (MCT, 13.0–14.7 Ma), values 6 to 9°C warmer than present. Our record also indicates cooling across the MCT of 2.9 ± 2.5°C (uncertainties 95% confidence level). The Mg/Ca record derived from the same samples indicates temperatures well within uncertainty of Δ47. As the two proxies are affected by different non‐thermal biases, the good agreement provides confidence in these reconstructed temperatures. Our Δ47 temperature record implies a ~0.6‰ seawater δ18O change over the MCT, in good agreement with previously published values from other sites. Our data furthermore confirm overall high seawater δ18O values across the middle Miocene, at face value suggesting ice volumes exceeding present‐day despite the warm bottom water temperatures. This finding suggests previously underappreciated additional influences on seawater δ18O and/or a decoupling of ice volume and ocean temperature.

Middle Miocene long-term continental temperature change in and out of pace with marine climate records

Reconstructing long-term continental temperature change provides the required counterpart to age equivalent marine records and can reveal how terrestrial and marine temperatures were related during times of extreme climate change such as the Miocene Climatic Optimum (MCO) and the following Middle Miocene Climatic Transition (MMCT). Carbonate clumped isotope temperatures (T(Δ47)) from 17.5 to 14.0 Ma Central European paleosols (Molasse Basin, Switzerland) display a temperature pattern during the MCO that is similar to coeval marine temperature records. Maximum temperatures in the long-term soil T(Δ47) record (at 16.5 and 14.9 Ma) lag maximum ocean bottom water temperatures, lead global ice volume, and mark the initiation of minimum global ice volume phases. The suggested onset of the MMCT, deduced by a marked and rapid decline in Molasse Basin soil temperatures is coeval with cooling reported in high-latitudinal marine records. This is best explained by a change in the seasonal timing of soil carbonate formation that was likely driven by a modification of rainfall seasonality and thus by a major reorganization of mid-latitude atmospheric circulation across Central Europe. In particular, our data suggest a strong climate coupling between the North Atlantic and Central Europe already in the middle Miocene.

Water Mass Characteristics and Distribution Adjacent to Larsen C Ice Shelf, Antarctica

AbstractThe physical oceanographic environment, water mass characteristics, and distribution in the area adjacent to Larsen C Ice Shelf (LCIS) are investigated using hydrographic data collected during the 2019 Weddell Sea Expedition. The results shed light on the ocean conditions adjacent to a thinning LCIS, on a continental shelf that is a source region for Weddell Sea Deep Water (WSDW), a precursor of the globally important Antarctic Bottom Water. Modified Warm Deep Water (MWDW), a water mass of circumpolar origin, is identified on the continental shelf and is observed to mix with Ice Shelf Water (ISW) and High Salinity Shelf Water (HSSW), both source waters of WSDW. A source water type decomposition analysis reveals high levels of mixing in the area, with much spatial variability. Heat content anomalies indicate an introduction of heat, presumed to be associated with MWDW, into the area via Jason Trough. Furthermore, candidate parent sources for ISW are identified in the region, indicating the potential for a flow of continental shelf waters into the ice shelf cavity; however, the impact on LCIS cannot be surmised from the available observations. ISW and HSSW are observed to make dominant contributions to the densest layers within Jason Trough, where waters are likely en route to feed the deep layers of the Antarctic Slope Current. This cross‐shelf flux of water masses links the region of the Weddell Sea adjacent to northern LCIS to global ocean circulation and Bottom Water characteristics via its contribution to ISW and HSSW, and hence WSDW properties.

Magnesian calcite solid solution thermodynamics inferred from authigenic deep-sea carbonate

Abstract Magnesian calcite is perhaps the most well studied solid solution in the geosciences due to the widespread use of marine carbonates to reconstruct paleoenvironment. Despite decades of research, the low temperature thermodynamic properties of magnesian calcite in seawater are poorly constrained, largely because very slow reaction kinetics prevent the direct measurement of equilibrium distribution coefficients (KdMg) for anhydrous Mg-bearing minerals. In this study, we use the Mg content of authigenic calcite formed in deep-sea marine carbonate sediments to determine the dependence of KdMg on temperature and aqueous Mg/Ca between ∼2 and 25 °C. We find that the solid activity coefficient of magnesite in Mg-calcite is strongly temperature dependent in this range, leading to predicted exsolution of Mg at low temperatures. At the temperatures typical of ocean bottom water, equilibrium Mg distribution coefficients are at least an order of magnitude lower than values inferred from inorganic calcite growth experiments. Moreover, the equilibrium temperature dependence of KdMg agrees well with field-based paleotemperature calibrations determined for low-Mg benthic and planktonic foraminifera at temperatures

TSUNAMI PHASE SPEED REDUCTION DUE TO WATER COMPRESSIBILTY

Most existing tsunami propagation models consider the ocean to be an incompressible, homogenous medium. Recently, it has been shown that a number of physical features can slow the propagation speed of tsunami waves, including wave frequency dispersion, ocean bottom elasticity, water compressibility and thermal or salinity stratification. These physical effects are secondary to the leading order, shallow water or long wave behavior, but still play a quantifiable role in tsunami arrival time, especially at far distant locations. In this work, we have performed analytical and numerical investigations and have shown that consideration of those effects can actually improve the prediction of arrival time at distant stations, compared to incompressible forms of wave equations. We derive a modified Mild Slope Equation for Weakly Compressible fluid following the method proposed by Sammarco et al. (2013) and Abdolali et al. (2015) using linearized wave theory, and then describe comparable extensions to the Boussinesq model of Kirby et al. (2013). Both models account for water compressibility and compression of static water column to simulate tsunami waves. The mild slope model is formulated in plane Cartesian coordinates and is thus limited to medium propagation distances, while the Boussinesq model is formulated in spherical polar coordinates and is suitable for ocean scale simulations.

Coupled microbial bloom and oxygenation decline recorded by magnetofossils during the Palaeocene\u2013Eocene Thermal Maximum

Understanding marine environmental change and associated biological turnover across the Palaeocene–Eocene Thermal Maximum (PETM; ~56 Ma)—the most pronounced Cenozoic short-term global warming event—is important because of the potential role of the ocean in atmospheric CO2 drawdown, yet proxies for tracing marine productivity and oxygenation across the PETM are limited and results remain controversial. Here we show that a high-resolution record of South Atlantic Ocean bottom water oxygenation can be extracted from exceptionally preserved magnetofossils—the bioinorganic magnetite nanocrystals produced by magnetotactic bacteria (MTB) using a new multiscale environmental magnetic approach. Our results suggest that a transient MTB bloom occurred due to increased nutrient supply. Bottom water oxygenation decreased gradually from the onset to the peak PETM. These observations provide a record of microbial response to the PETM and establish the value of magnetofossils as palaeoenvironmental indicators.

What fraction of the Pacific and Indian oceans' deep water is formed in the Southern Ocean?

Abstract. In this contribution we explore constraints on the fractions of deep water present in the Indian and Pacific oceans which originated in the northern Atlantic and in the Southern Ocean. Based on PO4* we show that if ventilated Antarctic shelf waters characterize the Southern contribution, then the proportions could be close to 50–50. If instead a Southern Ocean bottom water value is used, the Southern contribution is increased to 75 %. While this larger estimate may best characterize the volume of water entering the Indo-Pacific from the Southern Ocean, it contains a significant portion of entrained northern water. We also note that ventilation may be highly tracer dependent: for instance Southern Ocean waters may contribute only 35 % of the deep radiocarbon budget, even if their volumetric contribution is 75 %. In our estimation, the most promising approaches involve using CFC-11 to constrain the amount of deep water formed in the Southern Ocean. Finally, we highlight the broad utility of PO4* as a tracer of deep water masses, including descending plumes of Antarctic Bottom Water and large-scale patterns of deep ocean mixing, and as a tracer of the efficiency of the biological pump.