Such data suggest that the conductivity of solid solutions based on zirconia at temperatures below 900-I000~ can be increased by the partial removal of the anions and the cations of the stabilizer from the crystal lattice of the solid solution being formed. It is known that during vacuum firing oxygen vacancies are formed in the zirconia [i, 2], and there is rapid volatilization of the Ca and Mg cations [3, 4]. The volatilization of the cations of stabilizer containing yttrium oxide. The present authors attempted to establish whether it is possible in principle to improve the electrophysical properties of zirconia stabilized with oxides of alkaline-earth elements at temperatures below 900-I000~ Investigations were carried out using as an example, solid solutions ZrO=-CaO and zirconium dioxide, stabilized with a mixture of oxides of alkaline earth and rare-earth elements (Table i). The powders for the solid solutions were prepared with the method developed in the East Institute of Refractories, involving combined precipitation of the components from solutions of their chlorides and employing a solution of ammonia and ammonium carbonate as the precipitants [5]. Using the solid solution powders and a pressure of i00 N/mm 2 we pressed specimens of diameter i0 and height 10-15 mm. Firing was done at 1700~ in air and in vacuum. To eliminate breakdown of the stoichiometric composition with respect to oxygen occurring in specimens subjected to vacuum heat processing, subsequently they were fired at 1400~ in air. The results of x-ray analysis indicate that the specimens fired both in air and in vacuum consist only of the cubic solid solution of the fluorite type. X-ray structural analysis did not reveal any significant change in the lattice parameters of the solid solutions heated with either method (see Table i). However, for specimens fired in vacuum we noted a marked reduction in the apparent density compared with the specimens fired in air. In our view, this indicates the occurrence of volatilization of cations of alkaline-earth elements from the crystal lattice of the solid solution; its geometry under these conditions is not altered.
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