Observed Delay Times Research Articles

Importance of Site Diversity and Connectivity in Electrochemical CO Reduction on Cu.

Electrochemical CO2 reduction on Cu is a promising approach to produce value-added chemicals using renewable feedstocks, yet various Cu preparations have led to differences in activity and selectivity toward single and multicarbon products. Here, we find, surprisingly, that the effective catalytic activity toward ethylene improves when there is a larger fraction of less active sites acting as reservoirs of *CO on the surface of Cu nanoparticle electrocatalysts. In an adaptation of chemical transient kinetics to electrocatalysis, we measure the dynamic response of a gas diffusion electrode (GDE) cell when the feed gas is abruptly switched between Ar (inert) and CO. When switching from Ar to CO, CO reduction (COR) begins promptly, but when switching from CO to Ar, COR can be maintained for several seconds (delay time) despite the absence of the CO reactant in the gas phase. A three-site microkinetic model captures the observed dynamic behavior and shows that Cu catalysts exhibiting delay times have a less active *CO reservoir that exhibits fast diffusion to active sites. The observed delay times and the estimated *CO reservoir sizes are affected by catalyst preparation, applied potential, and microenvironment (electrolyte cation identity, electrolyte pH, and CO partial pressure). Notably, we estimate that the *CO reservoir surface coverage can be as high as 88 ± 7% on oxide-derived Cu (OD-Cu) at high overpotentials (-1.52 V vs SHE) and this increases in reservoir coverage coincide with increased turnover frequencies to ethylene. We also estimate that *CO can travel substantial distances (up to 10s of nm) prior to desorption or reaction. It appears that active C-C coupling sites by themselves do not control selectivity to C2+ products in electrochemical COR; the supply of CO to those sites is also a crucial factor. More generally, the overall activity of Cu electrocatalysts cannot be approximated from linear combinations of individual site activities. Future designs must consider the diversity of the catalyst network and account for intersite transportation pathways.

Time delays between radio and X-ray and between narrow radio bands of Sgr A* flares in the shock oscillation model

ABSTRACT We examine the time delay between radio and X-ray and between narrow radio frequency flares in Sagittarius A* (Sgr A*), from analyses of the synchrotron, bremsstrahlung, and monochromatic luminosity curves. Using the results of 2D relativistic radiation magnetohydrodynamic (MHD) simulations based on the shock oscillation model, we find three types of time delay between the synchrotron and bremsstrahlung emissions: Type A with a time delay of 2–3 h on the shock descending branch, Type B with no time delay, and Type C with an inverse time delay of 0.5–1 h on the shock ascending branch. The time delays in Types A and C are interpreted as a transit time of Alfvén and acoustic waves between both emission dominant regions, respectively. The delay times between 22 and 43 GHz flares and between 8 and 10 GHz flares are ∼13–26 and 13 min, respectively, while the inverse delay also occurs dependently on the shock location branch. These time delays between the narrow radio bands are interpreted as the transit time of the acoustic wave between the frequency-dependent effective radii $R_{\tau _{\rm \nu =1}}$, at which the optical depth τν at the accretion disc surface becomes approximately unity. The shock oscillation model explains well the observed delay times of 0.5–5 h between radio and X-ray, 20–30 min between 22 and 43 GHz, and ∼18 min between 8 and 10 GHz in Sgr A*.

Upper mantle and continental crust anisotropy in southeastern Mexico determined from shear-wave splitting measurements using local intraslab earthquakes

Cocos intraslab earthquakes were used to make shear-wave splitting measurements to explore the factors that control seismic anisotropy and to study the mantle wedge flow patterns in southeastern Mexico, where the Cocos plate subducts beneath the North American plate. Cocos intraslab earthquakes reach depths of 250 km, making it possible to sample the mantle wedge. The Silver and Chan (1991) covariance method was used to measure the splitting parameters: the fast polarization direction (φ) and the delay time (δt). The measurements can be divided into three regions: (1) northwest and (2) southeast of the Tehuantepec Ridge extension (i.e., the subducted Tehuantepec Ridge within the Cocos slab) and (3) the region above the subhorizontal Cocos slab. (1) In the first region, northeast of the 100 km isodepth contour of the Cocos slab, the fast axes are trench-perpendicular. This can be explained assuming the development of A-type olivine fabric and the existence of 2-D corner flow driven by the downdip motion of the Cocos slab. Southwest of the 100 km isodepth contour, measurements show trench-parallel fast polarization directions that are also consistent with corner flow, albeit in a serpentinized mantle wedge. Right above the Tehuantepec Ridge extension (northeast of the 100 km isodepth contour of the subducting slab), a change in the fast polarization directions from trench-normal to trench-parallel while going from northwest to southeast is observed and signals a change in the mantle flow pattern possibly through a vertical tear in the Cocos slab. 3-D toroidal flow could drive subslab mantle material around this slab edge and into the mantle wedge. (2) In the second region, the measured fast polarization directions show a trench-parallel orientation that is interpreted to result from southeastward trench-parallel flow through a serpentinized mantle wedge tip and also through a mantle wedge core made up of A- or C-type olivine fabrics with their fast axes oriented parallel to the flow direction. Trench-perpendicular fast polarization directions are observed beneath the fore-arc region of the Central America Volcanic Arc, near Tacaná Volcano, and trench-parallel polarizations are observed beneath the arc. These orientations could be explained by assuming the presence of B-type olivine fabric in the mantle wedge tip, A- or C-type olivine fabric in the mantle wedge core, and trench-parallel flow, so that the orientations of the fast axes become perpendicular to the mantle flow direction beneath the fore-arc and parallel to it beneath the arc. Lastly, (3) in the third region, over the flat slab, the observed delay times (0.04–0.42 s) are consistent with crustal anisotropy magnitudes, and the fast polarization directions seem to be controlled by the orientations of fault systems and alignments in foliations. Therefore, crustal faults and folds seem to be the dominant factors controlling the observed anisotropy.

Geometrically controlled slow slip enhanced by seismic waves: A mechanism for delayed triggering

Seismic waves generated during earthquakes induce transient stress changes in the crust. These ephemeral perturbations can trigger critically stressed asperities at remote distances, often with significant time delays. The physical mechanism that governs this phenomenon is not completely resolved. Numerical simulations of dynamic perturbations passing along a heterogeneous pre-stressed fault, demonstrate that weak portions of the fault that host ongoing slow slip can transfer stress in response to the perturbations, loading asperities poised for failure. We find that the magnitude of perturbation, the state of the asperity, as well as deformation of the surrounding material, jointly control the delay time between perturbation and triggered event. The slow-slip modulated delayed triggering model that we propose can account for the wide range of observed delay times in nature, including the two end-member cases of no delay and no triggering. Triggered slow slip events in nature might provide warning signs of impending earthquakes, underscoring the importance of high-resolution monitoring of active fault zones.

Body Wave Tomography of the Cascadia Subduction Zone and Juan de Fuca Plate System: Identifying Challenges and Solutions for Shore‐Crossing Data

AbstractRecent seismic results from the Cascadia Initiative indicate that heterogeneity in the oceanic asthenosphere affects subduction dynamics. Accurate characterization of the oceanic upper mantle is thus necessary to fully understand subduction processes, including the behavioral segmentation of the megathrust. A key challenge is integrating onshore and offshore datasets, which span large variations in near‐surface features that teleseismic body wave tomography is ill‐posed to resolve. Here, we perform a series of P and S forward modeling predictions to better understand the relative contribution of elevation, crustal thickness, offshore sedimentation, and near‐surface velocity structure to teleseismic delay times. Crustal thickness and elevation variations dominate the signal, contributing ∼1 s of delay time difference for P‐waves (roughly double for S). We test several inversion strategies to account for near‐surface features, identifying potential artifacts and causes of imaging errors. Undamped station statics are found to absorb mantle structures and introduce low‐velocity artifacts beneath the forearc. Our preferred inversion strategy utilizes a three‐dimensional starting model (including elevation) of the upper 50 km and heavily damped station statics, which we find leads to better resolution of mantle structure, particularly at asthenospheric depths. These insights guide inversions of observed delay times from the Cascadia subduction zone and Juan de Fuca plate system. We present a new onshore‐offshore S model and an updated P model. Major features are common to both models, including localized subslab low‐velocity anomalies, along‐strike variations in slab structure, and offshore heterogeneity, while regional differences may reflect changes in Vp/Vs.

The Role of Variable Slab Dip in Driving Mantle Flow at the Eastern Edge of the Alaskan Subduction Margin: Insights From Shear‐Wave Splitting

AbstractAlaska provides an ideal tectonic setting for investigating the interaction between subduction and asthenospheric flow. Within the span of a few hundred kilometers along strike, the geometry of the subducting Pacific plate varies significantly and terminates in a sharp edge. Furthermore, the region documents a transition from subduction along the Aleutian Arc to strike‐slip faulting along the Pacific Northwest. To better understand mantle interactions within this subduction zone, we conduct an SKS shear‐wave splitting analysis on passive‐source seismic data collected between 2011 and 2018 at 239 broadband seismometers, including those from the Transportable Array. Anisotropic fast directions in the east of our study area parallel the Queen Charlotte and Fairweather transform faults, suggesting that the ongoing development of lithospheric anisotropy dominates the results there. However, our observed delay times (δt = 1–1.5 s) obtained across the study region may also imply an asthenospheric contribution to the splitting pattern. Our splitting observations exhibit slab‐parallel fast directions northwest of the trench and a rotation of fast directions around the northeastern slab edge. These observations suggest the presence of toroidal asthenospheric flow around the edge of the downgoing Pacific plate. We suggest that Wrangell Volcanic Field volcanism might be caused by mantle upwelling associated with this flow. Splitting observations closer to the trench can be explained by fossil anisotropy within the downgoing Pacific‐Yakutat plate combined with entrained subslab mantle. The geometry of the slab, including its variable dip and its abrupt eastern edge, thus plays an important role in governing mantle flow beneath Alaska.

Ultrafast photochemistry with two product channels: Wavepacket motion through two distinct conical intersections

Light induced bond cleavage is an ubiquitous process in large molecules, yet its quantum nature is not fully understood. We present a comprehensive description of the ultrafast light induced CCl bond cleavage in diarylmethyl chlorides combining femtosecond transient absorption measurements with ab initio calculations. We observe a delayed appearance of radicals (80fs) and cations (125fs). The excited state wavepacket moves initially toward two conical intersections and the passing through these intersections determines the partitioning into the differing product channels. Different locations of the conical intersections explain the observed delay times.

Vertical coherence of deformation in lithosphere in the NE margin of the Tibetan plateau using GPS and shear-wave splitting data

We present 817 new SKS/SKKS shear-wave splitting observations to infer the mantle deformation field in the NE margin of the Tibetan plateau. The obvious pattern of dense splitting measurements shows that the fast wave polarization directions (φ) are oriented along a dominant NW-SE in the northeastern Tibetan plateau, Alxa block, and the western margin of the Ordos block and rotate to near E-W in the Qinling orogen, Weihe graben and Ordos block. Based on a continuous surface deformation field inferred from GPS observations and faults slip data, we model the predicted fast axis orientations (φc) at each location of averaged splitting observation. Exclusion of 32 averaged observations with larger misfits within the interior of the Ordos block, comparing splitting observations (φ) with predictions (φc) produces an average misfit of 11° indicating vertical coherent of lithospheric deformation in the NE margin of the Tibetan plateau. However, in the Qinling orogen, the thin lithosphere (<100km) could not account for the observed delay times (δt, ~1.2s), and the measured fast directions are parallel to the absolute plate motion (APM) direction, we infer that both the eastward asthenospheric flow and lithospheric left-lateral shear deformation contribute to the observed anisotropy. Within the interior of the Ordos block, where has thick lithospheric root (>300km) and weak anisotropy (δt, ~0.6s), the average misfit increases to 63°, and vertical coherence is no longer present, which suggests the rigid and stable Ordos block with little deformation still remains the lithospheric root of North China Craton.

Overriding plate, mantle wedge, slab, and subslab contributions to seismic anisotropy beneath the northern Central Andean Plateau

AbstractThe Central Andean Plateau, the second‐highest plateau on Earth, overlies the subduction of the Nazca Plate beneath the central portion of South America. The origin of the high topography remains poorly understood, and this puzzle is intimately tied to unanswered questions about processes in the upper mantle, including possible removal of the overriding plate lithosphere and interaction with the flow field that results from the driving forces associated with subduction. Observations of seismic anisotropy can provide important constraints on mantle flow geometry in subduction systems. The interpretation of seismic anisotropy measurements in subduction settings can be challenging, however, because different parts of the subduction system may contribute, including the overriding plate, the mantle wedge above the slab, the slab itself, and the deep upper mantle beneath the slab. Here we present measurements of shear wave splitting for core phases (SKS, SKKS, PKS, and sSKS), local S, and source‐side teleseismic S phases that sample the upper mantle beneath southern Peru and northern Bolivia, relying mostly on data from the CAUGHT experiment. We find evidence for seismic anisotropy within most portions of the subduction system, although the overriding plate itself likely makes only a small contribution to the observed delay times. Average fast orientations generally trend roughly trench‐parallel to trench‐oblique, contradicting predictions from the simplest two‐dimensional flow models and olivine fabric scenarios. Our measurements suggest complex, layered anisotropy beneath the northern portion of the Central Andean Plateau, with significant departures from a two‐dimensional mantle flow regime.

Upper mantle anisotropy beneath northeast India–Asia collision zone from shear-wave splitting analysis

Teleseismic earthquake data recorded by 11 broadband digital seismic stations deployed in the India–Asia collision zone in the eastern extremity of the Himalayan orogen (Tidding Suture) are analyzed to investigate the seismic anisotropy in the upper mantle. Shear-wave splitting parameters (Φ and δt) derived from the analysis of core-refracted SKS phases provide first hand information about seismic anisotropy and deformation in the upper mantle beneath the region. The analysis shows considerable strength of anisotropy (delay time ~0.85–1.9 s) with average ENE–WSW-oriented fast polarization direction (FPD) at most of the stations. The FPD observed at stations close to the Tidding Suture aligns parallel to the strike of local geological faults and orthogonal to absolute plate motion direction of the Indian plate. The average trend of FPD at each station indicates that the anisotropy is primarily originated by lithospheric deformation due to India–Asia collision. The splitting data analyzed at closely spaced stations suggest a shallow source of anisotropy originated in the crust and upper mantle. The observed delay times indicate that the primary source of anisotropy is located in the upper mantle. The shear-wave splitting analysis in the Eastern Himalayan syntaxis (EHS) and surrounding regions suggests complex strain partitioning in the mantle which is accountable for evolution of the EHS and complicated syntaxial tectonics.

Seismic anisotropy structure beneath the southeastern Mediterranean from shear-wave splitting

Analysis of seismic anisotropy in the crust and the uppermost mantle gives lots of information about the ambient mantle flow, stress state, and the dynamic processes inside the Earth. Thus, seismic anisotropy and its main distinctive features beneath the southeastern Mediterranean region are studied through the analysis of teleseismic shear-wave splitting observed at six broadband seismic stations belonging to the GEOFON and the MedNet. Although the number of the recording stations is small; a total of 495 splitting parameters are obtained, which revealed significant variations in the observed fast polarization directions beneath the study area. The stations in northern Egypt and Cyprus show fast velocity directions oriented roughly N–S to NNE–SSW, coincident with many previous results. A slightly different splitting pattern comprising NE–SW fast polarization directions is observed in the stations located along the Dead Sea fault in the southeastern Mediterranean; which are consistent with the current strike-slip motion between Africa and Arabia. In addition, NW–SE fast polarization directions are recognized in the latter group. The observed delay times vary greatly but their averages lie between 0.35 and 1 s. Although large-scale mechanisms, such as the absolute plate motion of Africa and Arabia towards Eurasia and the differential motion between Arabia and Africa can be invoked to predominantly explain the origin of anisotropic features, we suggest that density-driven flow in the asthenosphere is a possible additional cause of the wide range of the splitting pattern observed beneath some stations.

A Misfire Identification Method using Wavelet Transform and its Application

The misfire in millisecond blasting is usually difficult to identify in a complicated environment. On the basis of abrupt changes of the signal energy induced by the blasting load, a new method to identify the misfire is proposed using the theory of the wavelet transform. Firstly, the energy distribution graphic of various signals was obtained through analyzing the monitored blasting signals in field. And the peak value of signal energy density in the graphic is just the blasting time of short-delay detonators. Secondly, the explosive and no explosive detonators are identified by comparing the differences between the designed and observed delay times of detonators in millisecond blasting. The proposed method is applied in experiments of the medium-length hole blasting in Xinchen golden Mine of Laizhou and Luoshan golden Mine of Lingbao in China. In the experiments, the misfire phenomena are observed in Luoshan golden Mine, but are not observed in Xinchen golden Mine. The results are consistent with the identified results by proposed method. It provides a new effective approach to identify the misfire in mining engineering and other geotechnical engineering.

Seismic anisotropy beneath the Chinese mainland

We investigated the upper mantle anisotropy beneath China by applying teleseismic shear wave splitting measurements at 119 seismic stations from CDSN and GSN/IRIS networks in China. The splitting observations are characterized by apparent diversity of anisotropy pattern in adjacent tectonic domains, including the Tianshan orogenic belt, Tibetan plateau, the Yangtze craton, the North China craton and northeastern region. In western China (Tianshan orogenic belt and Tibetan plateau), fast polarization directions of split SKS waves coincide strikingly well with the dominating trend of deformational crustal features and delay times range from 0.5 s to 1.6 s. While in eastern China, seismic anisotropy deduced from shear wave splitting reveals a homogeneous NW-SE trending structure, almost perpendicular to the strike of large-scale surface structures. The observed delay times of 1.5 s to more than 2 s favor consistent mantle flow over large mantle thicknesses. Based upon the straightforward relationships between seismic anisotropy and the development of lattice preferred orientation of mineral in upper mantle rocks, we interpret the splitting results in terms of tectonic fabric within the upper mantle. Since the lithosphere is less than 100 km thick beneath eastern China and the observed fast directions are subparallel to the trend of the absolute plate motion (APM) of Eurasian plate, we propose that the asthenosphere may mainly contribute to the anisotropic effects beneath eastern China. However, the upper mantle anisotropy beneath western China may have developed more recently in the subcrustal lithosphere because of rather small delay times and thick lithosphere. We also use the opportunity of the dense geodetic measurements available in China to discuss the coupling between the crust and mantle. In the Eurasia-fixed reference frame, GPS and shear wave splitting both depict a similar trend beneath eastern China, suggesting a lithospheric block “escaping” toward the east that could orient olivine [001] axis in the upper mantle. There is a strong coupling between the crust and the mantle in eastern China. A different behavior is observed in western China. The GPS vectors trend NS-NE in Tibet and NW in Tianshan, close to the regional compression direction, whereas the fast directions trend EW in Tibet and NE in Tianshan, suggesting a tectonic regime close to a mode of axial shortening, generating the development of EW-trending foliation in Tibet and NE-trending foliation in Tianshan at depth. The crust and mantle deform independently in western China.

Time delays in the synchronization of chaotic coupled lasers with feedback

Isochrony and time leadership was studied in the synchronized excitable behavior of coupled chaotic diode lasers. Each unit of the system had chaos due to feedback with a fixed delay time. The inter-units coupling signal had a second, independent, characteristic time. Synchronized excitable spikes present isochronous, time leading or time lagging behavior whose stability is shown to depend on a simple relation between the feedback and the coupling times. Experiments on the synchronized low frequency fluctuations of two optically coupled semiconductor lasers and numerical calculations with coupled laser equations verify the predicted stability conditions for synchronization. Synchronism with intermittent time leadership exchange was also observed and characterized.

SU‐FF‐T‐473: Time Response Study of Calypso Localization and Tracking System for Moving Tumors

Purpose: To study the time response of the Calypso 4D localization and tracking system for prostate and pancreatic tumors Method and Materials: We have implanted Calypso beacon transponders into pancreas of three patients for tumor tracking during the radiation delivery. The system is originally designed for localization and tracking of prostate during radiotherapy. We have observed delay times for localization and delay of start time for tracking longer for pancreatic cases as compared to prostate cases. The system has successfully tracked our pancreatic patients for each treatment. To investigate the delay time as a function of tumor motion, we assembled a moving platform and placed a phantom with imbedded transponders on it. The phantom was moved sinusoidally with various frequencies. The ranges of frequencies included the motion correlated with prostate and pancreas. In the case of pancreas, there is direct correlation with the breathing cycle. Results: The usual delay time for prostate localization and delay time for start of tracking is about 10 to 12 seconds. For pancreatic cases, the time of localization and tracking increases by a factor of 9 to 10. The system delay does not affect its ability to accurately track tumor motion. Conclusion: The Calypso is a robust system that is capable of tracking tumors covering a wide spectrum of motion including respiratory motion. The delay time for localization and tracking modules are well accepted clinically.

Upper mantle anisotropy beneath Indochina block and adjacent regions from shear-wave splitting analysis of Vietnam broadband seismograph array data

The Indochina block is located at the junction of four major plates. It has a close relationship with the uplift of Tibet plateau and the sea-floor spreading of the South China Sea in the geological evolution histories. We deployed a temporary broadband seismograph array in Vietnam from February 2000 to October 2005, and measured shear-wave splitting of core-refracted phases to investigate the upper mantle anisotropy beneath the Indochina block and adjacent regions. The observed delay times of up to 1.5 s are large, indicating a mantle source for the anisotropy. Two distinct regimes of seismic anisotropy are revealed. The fast polarization directions in the northern Indochina block with a main trend of N100°E are almost consistent with the direction of both the surface displacement and the absolute plate motion. These observations suggest the anisotropy is possibly generated by the present-day asthenospheric flow caused by the India–Eurasia collision. The fast polarization directions in the southern Indochina block and the Hainan island are nearly N60°E. The anisotropy in this area may reflect a combination of the India–Eurasia collision and the past orogenies in the lithosphere, or an abrupt variation in the asthenospheric flow.

Upper mantle flow beneath and around the Hangay dome, Central Mongolia

Mongolia represents the northernmost area affected by the India–Asia collision, and it is actively deformed along transpressive belts closely associated with large-scale strike-slip faults. The active and past mantle flow beneath this region is, however, poorly known. In order to investigate deep mantle deformation beneath central Mongolia and its relation with the surrounding major structures such as the Siberian craton, the Gobi–Altay belt and the Baikal rift, a NS-trending profile of broadband seismic stations has been deployed in the summer 2003 from the southern Siberian craton to the Gobi–Altay range, crossing the entire Hangay dome. Mantle flow is deduced from the splitting of teleseismic shear waves such as SKS phases. In eastern Mongolia, the permanent station ULN in Ulaanbaatar reveals the presence of two anisotropic layers, the upper one being oriented NE–SW, close to the trend of lithospheric structures and the lower one NW–SE, close to the trend of Eurasia absolute plate motion. Along the NS profile in central Mongolia, seismic anisotropy deduced from SKS splitting reveals a homogeneous NW–SE trending structure, fully consistent with the observations made in the Altay–Sayan in western Mongolia. The observed delay times of 1.5 to more than 2.0 s favor consistent mantle flow over large mantle thicknesses. Since the lithosphere is less than 100 km thick beneath central Mongolia and since the observed fast directions are parallel to the trend of the lithospheric structures but also close to the trend of the absolute plate motion, we propose that both the lithosphere and the asthenosphere may join their anisotropic effects beneath central Mongolia to explain the large delay times. Although GPS vectors represent the instantaneous displacement of the Earth's surface and SKS splitting the time and vertical integration of finite strain at depth, we use the opportunity of the dense geodetic measurements available in this region to discuss the anisotropy pattern in term of present-day deformation. In the Eurasia-fixed reference frame, GPS and SKS both depict a similar trend beneath central Mongolia, suggesting a lithospheric block “escaping” toward the east that could orient olivine a-axes in the upper mantle, within a transpressive tectonic regime. A different behaviour is observed in western Mongolia: the GPS vectors trend NS, close to the regional compression direction, whereas the fast SKS directions trend EW, suggesting a tectonic regime close to a mode of axial shortening, generating the development of an EW-trending foliation at depth. We therefore propose that Mongolia is a place where active and frozen lithospheric deformation may add their effects, together with the sublithospheric flow. In the three sources of anisotropy inferred, a fundamental role is played by the Siberian craton that acted as an undeformable core of the continent through time: the frozen Paleozoic and Mesozoic structures wrap around the craton, building up the fast anisotropic direction pattern; the present-day sublithospheric flow induced by the plate motion is likely deflecting around its deep roots; finally, the present-day tectonic regime appears to be controlled by the presence of the craton to the north.

Solar connections of geoeffective magnetic structures

Coronal mass ejections (CMEs) and high-speed solar wind streams (HSS) are two solar phenomena that produce large-scale structures in the interplanetary (IP) medium. CMEs evolve into interplanetary CMEs (ICMEs) and the HSS result in corotating interaction regions (CIRs) when they interact with preceding slow solar wind. This paper summarizes the properties of these structures and describes their geoeffectiveness. The primary focus is on the intense storms of solar cycle 23 because this is the first solar cycle during which simultaneous, extensive, and uniform data on solar, IP, and geospace phenomena exist. After presenting illustrative examples of coronal holes and CMEs, I discuss the internal structure of ICMEs, in particular the magnetic clouds (MCs). I then discuss how the magnetic field and speed correlate in the sheath and cloud portions of ICMEs. CME speed measured near the Sun also has significant correlations with the speed and magnetic field strengths measured at 1 AU. The dependence of storm intensity on MC, sheath, and CME properties is discussed pointing to the close connection between solar and IP phenomena. I compare the delay time between MC arrival at 1 AU and the peak time of storms for the cloud and sheath portions and show that the internal structure of MCs leads to the variations in the observed delay times. Finally, we examine the variation of solar-source latitudes of IP structures as a function of the solar cycle and find that they have to be very close to the disk center.

Broadband Waveform Modeling of Moderate Earthquakes in the San Francisco Bay Area and Preliminary Assessment of the USGS 3D Seismic Velocity Model

Abstract Recently, the United States Geologic Survey Earthquake Hazards Program developed a 3D seismic velocity model of Northern California based on geology, including a detailed model of the urbanized San Francisco Bay Area. In this study, we report comparisons of observed three-component broadband (0.03–0.25-Hz) waveforms with synthetic seismograms computed with the new 3D model using an elastic finite difference method. We selected a set of 12 moderate earthquakes ( M w 4.0–5.1) that occurred within the greater San Francisco Bay Area, having well-constrained source parameters and broadband recordings with high signal-to-noise ratios. The objective of this study was to investigate how well the 3D velocity model predicts observed waveforms and to identify features of the model that may require revision to improve the waveform fits and predictions of ground motions for future events. We show for the 3 September 2000 Yountville earthquake that reported source parameters accurately predict waveforms at two close strong-motion stations (approximately 10 km from the epicenter). By comparing synthetics for the average 1D model GIL7 (Stidham et al. , 1999) and the 3D structures we show that the effects of seismic wave propagation in the 3D model become important for frequencies at and above 0.1 Hz (periods less than 10 sec). Comparison of observed and synthetic seismograms for the 3D model consistently shows that the model predicts energy arriving earlier than is observed, particularly for the surface waves, indicating that the shear velocities in the upper crust must be reduced. We cross correlated the observed and synthetic waveforms and recorded the delay time and linear correlation for best alignment of the data and delayed synthetic. The results indicate that generally the 3D model predicts the observed waveforms well (mean linear correlations 0.41) and includes features that arise from the interaction of the wave field with 3D structure, especially the major sedimentary basins in San Pablo Bay, San Francisco Bay, Santa Clara Valley, and Livermore Valley. Simple conversion of the observed delay times for optimal alignment suggests shear velocities should be reduced by 4%–5% on average. Based on these findings, we conclude that the model is an excellent first step, suggesting that the overall structure of the model is accurate (i.e., the basin and discontinuity geometry). However, the velocities must be reduced to improve the observed timing of surface-wave arrivals.

New Constraints on Type Ia Supernova Progenitor Models

We use the StarTrack population synthesis code to discuss potential progenitor models of SNe Ia: the single-degenerate scenario, the semidetached double white dwarf binary, and the double-degenerate scenario. Using the most recent calculations of accretion onto white dwarfs, we consider SN Ia explosions of various white dwarfs in binary systems. We calculate the evolutionary delay times from the zero-age main sequence to the explosion and verify which scenarios can satisfy the constraints found by Strolger et al., i.e., a delay time of 2-4 Gyr. It is found that the semidetached double white dwarf binary model is inconsistent with observations. Only SN Ia progenitors in the double-degenerate scenario are compatible with observations in all tested evolutionary models, with a characteristic delay time of ~3 Gyr. If double-degenerate mergers are excluded as SN Ia progenitors, we find that the single-degenerate scenario may explain the observed delay times for models with low common-envelope efficiency. It is also noted that the delay time distributions within the various tested SN Ia scenarios vary significantly and can potentially be used as an additional constraint on progenitor models.