Sustainable energy transition is essential for global climate change mitigation, requiring substantial amounts of metals to support clean energy technologies. However, a key challenge is ensuring the stable metals mining operations while achieving economic viability, social benefits, and environmental responsibilities. Through a comprehensive literature review, this study identifies 30 risks impeding sustainable energy transition related to metals mining at two levels: the micro level risk and the macro level risk. A cross-evaluation method, by considering literature analysis and expert assessments, is proposed to develop a framework of 15 key risks. The findings reveal inappropriate classification in current literature, as the causes, consequences, and certain objective facts of risk events have been categorized as risks by academics. Additionally, there exist conflicting opinions between academics and practitioners on the key risks. Based on the findings, a multi-stakeholder governance approach is proposed to effectively mitigate these key risks and ensure the sustainable energy transition.