NW Tethys Research Articles

Short-term middle Eocene (Bartonian) paleoenvironmental changes in the sedimentary succession of Olivetta San Michele (NW Italy): the response of shallow-water biota to climate in NW Tethys

This study focuses on the paleontological content of the middle Eocene (Bartonian) carbonate–siliciclastic sediments of the Capo Mortola Calcarenite Formation from Olivetta San Michele (Liguria, Italy). Along the succession, there are significant paleoecological changes triggered by the variation in neritic input as a consequence of tectonic and climatic instability. Among microfossils, nummulitids prevail, followed by orthophragmines, smaller benthic, and planktonic foraminifera, whereas mollusks and ichnofossils are the most abundant macrofossils. The sudden changes in the benthic communities due to the progressive increase in fluvial input are recorded throughout the sedimentary succession. An increase in water turbidity caused stressful conditions for autotrophic taxa, reducing their size and abundance. In contrast, filter feeders became dominant, suggesting an increase in dissolved and suspended nutrients. Ichnological analysis shows environmental fluctuations controlled by the transport of neritic material offshore, thus confirming the general deepening trend of the studied succession. In the upper part of the succession, we recorded an alternation between gravity flows and marly sediments that are interpreted as short-term alternations between low and intense precipitations. The gravity flows yield taxa such as larger benthic foraminifera (LBF), smaller benthic and planktonic foraminifera, mollusks, and corals. In turn, marls display only a few LBF and abundant smaller benthic and planktonic foraminifera. In these intervals, the increase in planktonic foraminifera also suggests a deepening of the carbonate ramp coinciding with a reduction of light that did not favor the development of LBF. These changes are probably related to the climatic dynamics that occurred in the Bartonian in the western Tethys.

Calcareous nannofossil communities during Late Triassic Mass Extinction and Early Jurassic rejuvenation in the NW Tethys: evidence from Slovakia, Western Carpathians

Calcareous nannofossil communities during Late Triassic Mass Extinction and Early Jurassic rejuvenation in the NW Tethys: evidence from Slovakia, Western Carpathians

Multiple carbon isotope excursions during the Carnian (Late Triassic) pluvial event: implications for global and regional perturbation

The Late Triassic Carnian pluvial event (CPE) was an interval marked by global climatic and environmental changes that occurred simultaneously with enhancement of the hydrological cycle. This event is characterized by multiple negative carbon isotope excursions (NCIEs). However, the driving mechanism behind these multiple NCIEs remains elusive because each of the NCIEs had different magnitudes in different geological settings. In this study, we present a high-resolution record of carbonate carbon isotope ( δ 13 C carb ) and major and trace element data from Well QZ-8 in the Qiangtang Basin, eastern Tethys. The carbon isotope profile from this well displays a similar trend to those for contemporaneous strata in the NW Tethys and South China. This trend is characterized by a distinct negative excursion during the CPE, supporting a global event. Interestingly, our results reveal five NCIEs for the first time in the marine sedimentary succession. Furthermore, each of these NCIEs corresponds well to changes in Ti/Al, Sr/Al and Sr/Ba, suggesting a regional effect of the hydrological cycle on carbon isotope excursions. This study emphasizes that each of the NCIEs was influenced by regional hydrological cycles although the long carbon isotope excursion during the CPE was driven by the global carbon cycle. Supplementary material: Tables showing major element, isotope and trace element data and element ratios, and a supplementary figure are available at https://doi.org/10.6084/m9.figshare.c.6805266

Coral assemblages and environments from Bajocian reefs in the Western Carpathians

The systematics of the coral assemblages of the Vršatec Limestone from the Pieniny Klippen Belt (Western Carpathians) that inhabited the NW Tethyan margin during the Bajocian is revisited here based on a new and extensive sampling of coral specimens collected at four outcrops. The assemblage consists of 12 genera and 13 species, including the new species Proaplophyllia slovakensis and the first Bajocian occurrence of the genus Enallhelia. Morphometric analyses also allow us to synonymize multiple species citations of the genus Thecosmilia into a single species. A quantitative study shows that five genera tend to be most common at all outcrops, namely Cladophyllia, Dendraraea, Isastrea, Periseris, and Thecosmilia, documenting relatively high homogeneity in the qualitative generic composition of coral assemblages but quantitative differences among the four outcrops. Coral specimens are frequently affected by macroborings (Gastrochaenolites, Entobia, and Trypanites) and coated by microbialitic components. We suggest that these reefs grew in the optimum of the Bajocian reefal window (i.e., shallow-water photic environments above storm wave base). We also identify three traps (typological, nominal, and induction traps) that led in the past to the false stratigraphic attribution of these reefs, when they were erroneously assigned to the Oxfordian rather than to the Bajocian.

Marine bioturbation collapse during Early Jurassic deoxygenation: implications for post-extinction marine ecosystem functioning

Abstract Climate change is undermining the health and integrity of seafloor ecosystems, with declines in bioturbation expected to impact future ecosystem functioning. We explored changes in the nature and degree of bioturbation during Early Jurassic global warming and ocean deoxygenation. Understanding how these communities responded can help anticipate how bioturbation and ecosystem functioning might change over large spatial and temporal scales. Trace and body fossils from outcrop and core in the Cleveland Basin, UK show how healthy seafloor communities deteriorated through the Pliensbachian spinatum Zone, and macroinfaunal behaviour fluctuated across the Pliensbachian–Toarcian boundary coincident with mass extinction. Deoxygenation began above the stage boundary, and conditions deteriorated until bioturbation ceased completely (upper tenuicostatum Zone) for 0.6–2.5 Ma, longer than anywhere else in NW Tethys. The macroinfaunal record revealed new details on the progression and timing of deoxygenation, benthic recovery and fluctuations in the palaeoredox boundary. After the oceanic anoxic event infauna were fewer, smaller and did not mix sediments to depth, and while the depth and diversity of bioturbation had increased by the fibulatum Subzone ( bifrons Zone), the benthos had not recovered to late Pliensbachian pre-oceanic anoxic event state. Bioturbation collapse over large parts of the Northern Hemisphere probably contributed to regional-scale changes in ecosystem functioning.

Extreme continental weathering in the northwestern Tethys during the end-Triassic mass extinction

The end-Triassic mass extinction (ETE) is thought to have been triggered by widespread eruption and emissions of volcanic and contact metamorphic carbon and sulfur gases from the Central Atlantic Magmatic Province (CAMP) flood basalts. Although palynological studies of shallow marine deposits in the basins of Denmark and Germany suggest that deforestation and catastrophic soil loss occurred during the CAMP volcanism and ETE interval, the intensity and timing of continental weathering in the region of northwestern Tethys Ocean remain unclear. Here we present Sr, C, and O isotope data, as well as multivariate statistical analyses of major element contents, for carbonate–clastic deposits in the Kardolína section, Slovakia, to develop a continental weathering record in the NW Tethys during the ETE event. This section consists of a shallow marine carbonate sequence in the Rhaetian Fatra Formation and the overlying Hettangian Kopieniec Formation. The Fatra Formation represents ramp facies deposits that formed in a restricted pull-apart basin of the Fatric Zone along the southern margin of the Bohemian Massif in the region of northwestern Tethys. Carbon isotope analysis of the limestones revealed two negative carbon isotope excursions (NCIEs) in the uppermost Fatra Formation. These two NCIEs occurred in the latest Rhaetian and can be compared to the “precursor” and “initial” NCIEs reported for the northwestern Tethys. Strontium isotope analysis of the limestones revealed an abrupt increase in Sr isotope ratios between the precursor and initial NCIEs, which indicates that continental weathering of the Bohemian Massif increased rapidly in the latest Rhaetian. Multivariate analysis of major element contents in the carbonate rocks also shows that intense chemical weathering of the hinterland was accelerated after the precursor NCIE, supporting the inferences drawn from Sr isotopes. Furthermore, our study reveals that the carbonate depositional environments of the Fatra Formation changed to the formation of specific Fe-rich oolites with increased continental weathering after the precursor NCIE. The concentrations of redox-sensitive major elements (e.g., Mn and Fe) and multivariate analysis of the major element data suggest that the Fe-rich oolites were formed by an influx of O-depleted water into the shallow water depositional environment of the Fatra Formation. A possible origin for this O-depleted water is the oxygen minimum zone (OMZ) that formed at intermediate water depths in European basins (e.g., the German and Eiberg basins) during the latest Rhaetian. Our results suggest that the marine environment in the European basins may have developed an OMZ due to the increase in continental weathering during the latest Rhaetian, and these environmental changes may have had an important role in the marine ETE event. • Sr, C, and O isotope data of the Rhaetian succession in Slovakia were determined. • Two negative carbon isotope excursions (NCIEs) were detected in latest Rhaetian. • Abrupt increase in Sr isotope ratios recognized between these two NCIEs. • Continental weathering was temporarily enhanced during the end-Triassic extinction. • Intense weathering led to development of oxygen minimum zone in NW Tethys.

Zircon of Triassic Age in the Stuttgart Formation (Schilfsandstein)—Witness of Tephra Fallout in the Central European Basin and New Constraints on the Mid-Carnian Episode

The Carnian Stuttgart-Formation (Schilfsandstein) of the Central European Basin contains relics of Triassic volcanic detritus in form of euhedral zircon grains and authigenic analcime. Multiple LA-ICP-MS spot analyses of single zircon crystals from an outcrop near Heilbronn (SW Germany) yielded weighted average 206Pb/238U ages between 250 and 230 Ma, providing evidence for tephra fallout in the southern part of the Central European Basin related to Olenekian, Anisian–Ladinian and Carnian volcanic activity. The tephra was probably transported by monsoonal circulations from volcanic centres of the NW Tethys to the Central European Basin. The four youngest zircon crystals gave a weighted average 206Pb/238U age of 231.1 ± 1.6 Ma (10 analyses), which is interpreted to date syn-depositional tephra fallout into the fluvial Lower Schilfsandstein Member of the Stuttgart Formation. This new maximum depositional age provides the first evidence that deposition of the Stuttgart Formation, which represents the type-example of the mid-Carnian episode, a global episode of enhanced flux of siliciclastic detritus and related environmental perturbations, occurred during the Tuvalian 2 substage at ca. 231 Ma, about 3 million years later than suggested by previous correlations. Zircon grains with weighted average 206Pb/238U ages of 236.0 ± 1.2 Ma (n = 17) and 238.6 ± 1.5 Ma (n = 6) and 206Pb/238U ages between 241 ± 6 and 250 ± 3 Ma point to the presence of tephra in early Carnian to Olenekian strata of the Keuper to Buntsandstein Groups. Traces of these reworked tephra were incorporated into the Stuttgart Formation due to fluvial erosion in the southern Central European Basin and at its margins.

Onychites from Polish Jura and Their Functional Morphology

Onychites aff. barbatus is excessively rare in the Polish Jura. This paper describes a recent find from the basal middle Oxfordian. The specimen is preserved in a manner typical for other finds of this kind in platy limestones, i.e., as compressed and flattened imprints with remnants of carbonized organic matter. Excellent preservation of the surfaces enables a precise reconstruction of the original structure. Accordingly, I hypothesize on the attachment to soft parts and the function of the belemnite onychites. The high diversity of known onychites, especially from Europe (NW Tethys), indicates that they served a variety of purposes.

Diagenetic and environmental control of the clay mineralogy, organic matter and stable isotopes (C, O) of Jurassic (Pliensbachian-lowermost Toarcian) sediments of the Rodiles section (Asturian Basin, Northern Spain)

Abstract Clay mineralogical and geochemical analyses (δ18Ocarb, and paired carbonate and organic matter carbon isotope), completed by the characterization of organic matter, have been performed on the Pliensbachian sediments exposed on the Rodiles section (Asturian Basin, Northern Spain). The objectives were to precise the Pliensbachian climate evolution at a relatively low paleolatitude of the Tethyan domain by comparison with previously published high-resolution clay mineralogical and geochemical data from the NW Tethyan domain (e.g. Paris Basin and Cardigan Bay Basin, West Wales). The clay mineral assemblages are dominantly composed of illite and illite-smectite mixed-layers (I–S) associated with minor proportions of chlorite and kaolinite. Smectites are not identified what may result either to their absence at the time of sedimentation or to their progressive illitization due to the burial diagenesis. Rock-Eval data show that organic matter reaching more than 5% in black-shale horizons is thermally mature with Tmax comprised between 444 and 454 °C indicating that the section is in the oil window and that the burial temperature reached or exceeded 80–90 °C. The low δ18Obulk values comprised between −3 and −6‰ clearly results from a diagenetic influence (thermal effect due to burial) but their fluctuations compared with δ18O measured on well-preserved belemnites guards show that the overall trend is however preserved. By comparison with higher latitude sedimentary basins, the most striking feature is the very small proportions of kaolinite (generally less than 5% while the proportions of this mineral reach 40% at higher paleolatitudes), except at the Pliensbachian/Toarcian transition, where the proportion of kaolinite increases significantly. Clay minerals likely originated from the erosion of the Iberian Massif located to the South of the Asturian Basin in a semi-arid climatic belt. This may explain the scarcity of kaolinite by comparison with sedimentary basins located at higher latitude influenced by more humid climate. The increasing proportions of kaolinite by the end of the Pliensbachian suggest southward expansion of the humid belt as a consequence of cooler temperatures and the establishment of steeper latitudinal gradients of temperature likely resulting from the formation of restricted polar ice cap. The main δ13C (on both 13Cinorg and 13Corg) Pliensbachian excursions including the negative excursion of the Sinemurian/Pliensbachian Boundary Event (SPBE) and the Late Pliensbachian positive excursion are well recognized.

Oscillating redox conditions in the Middle–Late Jurassic Alpine Tethys: Insights from selected geochemical indices and 57Fe Mössbauer spectroscopy

Abstract: The Middle–Late Jurassic greenhouse conditions included CO2 levels that have been estimated to be four to five times higher than they are presently. By analysing the pattern of selected trace elements as redox proxies (V, U, and Mo) and the variations in the chemical state of iron using 57Fe Mossbauer spectroscopy, we demonstrate the occurrence of major changes in sediment redox conditions from the Late Bajocian through the Late Oxfordian in the pelagic environment of the Alpine Tethys in its Carpathian domain. Our interpretation is based on analysis of siliceous limestones rich in radiolarians intercalated with red nodular limestones of Ammonitico Rosso-type facies from the Križna Nappe in the eastern part of the Tatra Mountains, Poland. The presented redox potential (Eh values) shows its changeable pattern along the section (from −0.74 V to 0.16 V). The low values of Eh (from −0.74 V to −0.4 V) create the long-term (ca. 7 Myr) trend of the medium-scale fluctuations comprising the Upper Bajocian through the Lower Oxfordian interval of predominately grey and green radiolarian siliceous limestones. This interval comprises the three short-term (less than 0.5 Myr) periods of slightly increasing Eh (from −0.35 V to −0.17 V) observed in the uppermost Bajocian, Lower Bathonian, and Lower Callovian, as well as the significant changes in sediment redox conditions from oxic to dysoxic in the Upper Bajocian. The overlying succession corresponding to the Middle–Upper Oxfordian (ca. 4 Myr) is characterized by red radiolarian siliceous limestones with positive Eh values that indicate deposition under more oxic conditions than those during any other period in the study section. The negative values of Eh, attributed to the upwelling periods, coincide with the decreasing sea surface water temperature (SST) and increasing organic matter flux. The largest negative shift is noted in the Upper Callovian, which coincided with the cool climatic phase. The positive Eh values indicate oxic conditions due to the lowering of organic matter input, coinciding with an increased SST caused by surface water stratification. Based on the observed long-term variation in the redox, we postulate thermally driven east–west atmospheric circulation along the equatorial Tethys Ocean, caused by the sharp contrast in sea surface temperature, similar to the Walker Circulation operating across the modern Pacific. This phenomenon would have been the dominant periodical mode over the tropics and subtropics regions of the NW Tethys during the Middle–Late Jurassic. Global warming reduces the long-term strength of the mean tropical atmospheric circulation, leading to sea water stratification near the surface and consequently lowering the organic matter flux. However, additional seaways of heat transport could also exist, as they are associated with the opening/closing of the Hispanic Corridor.

Carbon-isotope events during the Pliensbachian (Lower Jurassic) on the African and European margins of the NW Tethyan Realm

Early Jurassic palaeoenvironments and palaeoclimates, based on chemostratigraphy, have been extensively studied for the northern Tethyan margin. For the first time, high-resolution chemostratigraphy for the entire Pliensbachian is proposed for the African Tethyan margin (Morocco), and compared with new sections from the European Tethyan margin (France). Precise ammonite determinations, completed by calcareous nannofossil distribution, provide an accurate biostratigraphic framework from the Upper Sinemurian to the Upper Pliensbachian. Bulk inorganic carbon (δ13Ccarb) and organic carbon (δ13Corg) isotope signals are used to characterise and compare carbon-cycle trends in the Central High Atlas Basin (Amellago-Ikis section, Morocco), the Paris Basin (Montcornet borehole, France), and the Subalpine Basin (Serre-Poncon section, France). Comparison of this new dataset with previously published geochemical data from European basins confirms the existence of five distinct carbon-isotope events, synchronous at the scale of the NW Tethyan Realm: (1) a clear –2‰ negative excursion of δ13Ccarb and δ13Corg, corresponding to the Sinemurian–Pliensbachian Boundary Event (SPBE), probably associated with a massive release of light carbon by volcanism and hydrothermalism during the breakup of Pangea; (2) a positive excursion (+1 to +1.5‰) in the Valdani and Luridum subzones (Ibex Zone), reflecting increased organic matter storage under warm climate conditions; (3) a broadly negative event from the Davoei Zone to the lower part of the Margaritatus Zone, associated with major oceanographic reorganisation in a transgressive context, and possible enhanced hydrothermalism related to the opening of the Hispanic corridor; (4) a positive carbon excursion (+2‰) during the Subnodosus and Gibbosus subzones (Margaritatus Zone), corresponding to the Late Pliensbachian Event (LPE), associated with organic matter storage; (5) an end-Margaritatus–Spinatum negative excursion, associated with sea-level fall, probably driven by glacio-eustasy. This new high-resolution carbon-isotope dataset highlights the synchroneity of carbon-cycle trends throughout the NW Tethyan Realm. Several major isotopic events, prior to those of the Toarcian, must therefore have occurred at a supra-regional to global scale during the Pliensbachian, involving significant internal and external geodynamic mechanisms.

The Jurassic/Cretaceous boundary and high resolution biostratigraphy of the pelagic sequences of the kurovice section (Outer Western Carpathians, the northern Tethyan margin)

Abstract Microfacies and high resolution studies at the Kurovice quarry (Czech Republic, Outer Western Carpathians) on calpionellids, calcareous and non-calcareous dinoflagellate cysts, sporomorphs and calcareous nannofossils, aligned with paleomagnetism, allow construction of a detailed stratigraphy and paleoenvironmental interpretation across the Jurassic/Cretaceous (J/K) boundary. The Kurovice section consists of allodapic and micrite limestones and marlstones. Identified standard microfacies types SMF 2, SMF 3 and SMF 4 indicate that sediments were deposited on a deep shelf margin (FZ 3), with a change, later, into distal basin conditions and sediments (FZ 1). The sequence spans a stratigraphic range from the Early Tithonian calcareous dinoflagellate Malmica Zone, nannoplankton zone NJT 15 and magnetozone M 21r to the late Early Berriasian calpionellid Elliptica Subzone of the Calpionella Zone, nannoplankton NK-1 Zone and M 17r magnetozone. The J/K boundary is marked by a quantitative increase of small forms of Calpionella alpina, the base of the Alpina Subzone (that corresponds to NJT 17b and M 19n.2n) and by the rare occurrence of Nannoconus wintereri. Palynomorphs include Early Berriasian terrestrial elements — non-calcareous dinoflagellate cysts Achomosphaera neptunii, Prolixosphaeridium sp. A and Tehamadinium evittii. The depositional area for Kurovice was situated at the margin of the NW Tethys. The influence of cold waters from northern latitudes and potential upwellings is highlighted by: 1) the high proportion of radiolarians and sponge spicules, 2) rare calpionellids represented mostly by hyaline forms, 3) the absence of microgranular calpionellids — chitinoidellids, 4) the small percentage of the genera Nannoconus, Polycostella and Conusphaera in nannofossil assemblages, as compared to other sites in Tethys, 5) scarce Nannoconus compressus, which has otherwise been mentioned from the Atlantic area.

Spatial and temporal facies evolution of a Lower Jurassic carbonate platform, NW Tethyan margin (Mallorca, Spain)

The variety of depositional facies of a Lower Jurassic carbonate platform has been investigated on the island of Mallorca along a transect comprising six stratigraphic profiles. Twenty-nine facies and sub-facies have been recognized, grouped into seven facies associations, ranging in depositional environment from supratidal/terrestrial and peritidal to outer platform. Spatial and temporal (2D) facies distribution along the transect reflects the evolution of the carbonate platform with time showing different facies associations, from a broad peritidal platform (stage 1) to a muddy open platform (stage 2), and finally to a peritidal to outer carbonate platform (stage 3). Stage 1 (early Sinemurian to earliest late Sinemurian) corresponds to a nearly-flat peritidal-shallow subtidal epicontinental platform with facies belts that shifted far and fast over the whole study area. The evolution from stage 1 to stage 2 (late Sinemurian) represents a rapid flooding of the epicontinental shallow platform, with more open-marine conditions, and the onset of differential subsidence. During stage 3 (latest Sinemurian), peritidal and shallow-platform environments preferentially developed to the northeast (Llevant Mountains domain) with a rapid transition to middle-outer platform environments toward the northwest (Tramuntana Range domain). Stages 1 and 3 present facies associations typical of Bahamian-type carbonates, whereas stage 2 represents the demise of the Bahamian-type carbonate factory and proliferation of muddy substrates with suspension-feeders. The described platform evolution responded to the interplay between the initial extensional tectonic phases related to Early Jurassic Tethyan rifting, contemporaneous environmental perturbations, and progressive platform flooding related to the Late Triassic–Early Jurassic worldwide marine transgression and associated accommodation changes.

Carbon and oxygen isotope stratigraphy of Jurassic platform carbonates from Saudi Arabia: Implications for diagenesis, correlations and global paleoenvironmental changes

Major carbon cycle disturbances reflected by carbon isotope excursions (CIE) have been reported in the Jurassic successions of Euro-Boreal and Mediterranean basins. However, sedimentary and geochemical data from other domains are still required to unravel the global or regional nature of paleoenvironmental disturbances and identify the potential triggers. Here, we present biostratigraphically well-constrained (middle Toarcian to lower Kimmeridgian) bulk-rock δ13C and δ18O data from central Saudi Arabia. Five major negative δ18O excursions are identified in back-reef facies below sequence boundaries and disconformities (Aalenian-Bajocian boundary, upper Bajocian, middle Bathonian, upper Callovian and lower Kimmeridgian), suggesting that these carbonates underwent intense meteoric diagenesis during partial or major subaerial exposures of the Arabian Platform. The δ13C record is less altered and shows correlations with the regional relative sea-level changes influencing the productivity levels and inflows of fluvial (12C-enriched) or oceanic (12C-depleted) waters onto the platform. Overall, most of the δ13C variations recorded at the scale of the Arabian Platform within the lower and middle Jurassic are in agreement with NW Tethyan data. Among these variations, the increase in δ13C values recorded in the middle Toarcian, lower Bajocian, and lower Bathonian zigzag Zone indicate a considerable increase of productivity and 12Corg burial concomitant with global sea-level rises. Conversely, the occurrence of major but diachronous negative CIEs at the Aalenian-Bajocian boundary and around the lower-upper Bajocian transition are interpreted as accelerations of terrestrial 12Corg transfer to the ocean and atmosphere linked to regional but widespread emergences of landmasses. Whether global (eustatic) or regional (tectonic), all these sea-level changes and carbon transfers could be distal consequences of successive episodes of the Pangean breakup.

The Santonian – Campanian boundary and the end of the Long Cretaceous Normal Polarity-Chron: Isotope and plankton stratigraphy of a pelagic reference section in the NW Tethys (Austria)

The base of the Campanian still lacks a designated primary marker and a defined GSSP (Global Boundary Stratotype Section and Point). We present a Santonian–Campanian boundary section from the Postalm in the Northern Calcareous Alps of Austria as a possible reference section for the northwestern Tethys. Including nearby complementary Gosau Group sections, the stratigraphy for this time interval is based on palaeomagnetic and stable isotope data, planktonic foraminifera and calcareous nannoplankton bio-stratigraphy, and strontium isotope stratigraphy, together with published ammonite, crinoid and inoceramid data. The Postalm section shows a deepening trend from upper Santonian conglomerates and grey shelf marls to pelagic bathyal red marly limestones of mainly Campanian age. Palaeomagnetic data allow identifying the top of the Long Cretaceous Normal Polarity-Chron C34n and the following reversal in the lower part of the red marly limestones. A 1 m-thick interval of high magnetic susceptibility is present at the end of C34n. Two of the main suggested biomarkers to pinpoint the Santonian–Campanian boundary, i. e. the last occurrence of the planktonic foraminifer Dicarinella asymetrica and the first occurrence of the nannofossil Broinsonia parca parca, occur in close proximity above the reversal, which is suggested herein as the main marker event for the base of the Campanian. Strontium isotope stratigraphy indicates a value of 0.707534 (mean of four measurements at the boundary interval) for the base of the Campanian in the Postalm section. Both carbon and oxygen isotope values show a negative excursion just below the boundary. The positive Santonian–Campanian carbon isotope event starts probably just below the reversal but seems to be diagenetically distorted. This interval is considered to correspond to a short sea-level high in the late Santonian followed by a distinct lowstand at the Santonian–Campanian boundary.

Ocean Circulation in the Toarcian (Early Jurassic): A Key Control on Deoxygenation and Carbon Burial on the European Shelf

AbstractThe Toarcian Oceanic Anoxic Event (T‐OAE, ∼183 Myr) was a long‐lasting episode of ocean deoxygenation during the Early Jurassic. The event is related to a period of global warming and characterized by major perturbations to the hydrological and carbon cycles with high rates of organic matter burial in shelf seas. Ocean circulation during the Toarcian and its influence on marine biogeochemical cycles are still not fully understood. Here we assess the spatial extent of anoxia in the NW Tethys Ocean during the T‐OAE, the relationship with ocean circulation and the impact on organic carbon burial, using new and existing sedimentary records from the European Epicontinental Shelf in combination with general circulation model results. We demonstrate that bottom waters on the southwestern part of the shelf were mainly oxic during the T‐OAE, while those in the northeastern basins were mostly anoxic or even sulfidic. Results for two ocean‐atmosphere models (Fast Ocean‐Atmosphere Model and Massachusetts Institute of Technology general circulation model) suggest the presence of a strong clockwise gyre over the European Epicontinental Shelf, which brought oxygenated equatorial waters from the Tethys Ocean to the southern shelf. The northward limb of the gyre was significantly weakened due to the rough bathymetry of the northern shelf, making this relative small region highly sensitive to local ocean stratification. These sluggish ocean dynamics promoted bottom water anoxia and enhanced burial of organic carbon in the northeastern basins, which accounted for 3–5% of the total carbon extracted from the ocean‐atmosphere system as recorded by the positive carbon isotope shift.

Environmental response to the early Toarcian carbon cycle and climate perturbations in the northeastern part of the West Tethys shelf

Early Toarcian (Early Jurassic; ~183 Ma) climate and carbon cycle perturbations were accompanied by widespread accumulation of bituminous sediments, formed during the Toarcian Oceanic Anoxic Event (T-OAE). On the northwestern Tethyan shelf, organic carbon accumulation was particularly widespread in hydrodynamically restricted regions of the European Epicontinental Basin System (EEBS) where it peaked during the formation of euxinic waters extending into the photic zone. In the adjacent northeastern West Tethys shelf (NE-WTS), an area proximal to the deeper and better ventilated NW Tethys, deposition of strata enriched in organic matter was restricted to depressions of limited spatial extent. While numerous works have addressed the bituminous strata from the EEBS, evolution of environmental conditions and drivers of organic matter accumulation in areas proximal to the open Tethys have received much less attention.Here, we investigated a stratigraphically well-constrained, exceptionally organic matter-rich sediment succession from the NE-WTS deposited during the T-OAE. Organic and isotope geochemical investigations provided insights into the evolution and dynamics of environmental conditions during the T-OAE in a setting proximal to the Tethys.The sedimentary rocks sampled for this study originated from a surface outcrop that experienced weathering-related alteration of its mineral constituents. In particular, sulfides (mainly pyrite) were significantly altered, resulting in a near-quantitative loss of sulfur. In contrast, kerogen as well as bitumen fractions have not been significantly affected by weathering processes and carry a robust paleoenvironmental signal.The new data show that organic carbon accumulation occurred as a direct response to changing environmental conditions that also led to the early Toarcian carbon cycle perturbation. Increase in organic carbon burial occurred in a stepwise manner, following multiple injections of 12C-enriched carbon into the Earth's ocean-atmosphere system. High algal productivity and the subsequent organic matter decomposition by sulfate reducing bacteria led to an expansion of H2S-rich waters into the photic zone, which promoted the growth of Chlorobiaceae. A steady increase in nitrogen isotope values testified to intensified denitrification in an expanded oxygen minimum zone. The resulting decline in the availability of bio-utilizable nitrogen in combination with harsh environmental conditions promoted the proliferation of cyanobacteria as indicated by increasing abundances of 2α‑methyl‑hopanes. Formation of euxinic waters in the NE-WTS was not associated with a freshwater driven salinity stratification. Organic geochemical salinity indicators (methylated chromanes) attest to normal marine salinity, supporting a strong influence of Tethyan water masses.This study enhances our knowledge on the environmental response towards the early Toarcian climate and carbon cycle perturbations in a setting proximal to the Tethys. We demonstrate that photic zone euxinia was a common and particularly widespread feature of the T-OAE and has not been confined to the hydrodynamically restricted EEBS.

New 40Ar–39Ar dating of Lower Cretaceous basalts at the southern front of the Central High Atlas, Morocco: insights on late Mesozoic tectonics, sedimentation and magmatism

This study is based upon a stratigraphic and structural revision of a Middle Jurassic–Upper Cretaceous mostly continental succession exposed between Boumalne Dades and Tinghir (Southern Morocco), and aims at reconstructing the relation among sedimentary, tectonic and magmatic processes that affected a portion of the Central High Atlas domains. Basalts interbedded in the continental deposits have been sampled in the two studied sites for petrographic, geochemical and radiogenic isotope analyses. The results of this study provide: (1) a robust support to the local stratigraphic revision and to a regional lithostratigraphic correlation based on new 40Ar–39Ar ages (ca. 120 Ma) of the intervening basalts; (2) clues for reconstructing the relation between magma emplacement in a structural setting characterized by syn-depositional crustal shortening pre-dating the convergent tectonic inversion of the Atlasic rifted basins; (3) a new and intriguing scenario indicating that the Middle Jurassic–Lower Cretaceous basalts of the Central High Atlas could represent the first signal of the present-day Canary Islands mantle plume impinging, flattening, and delaminating the base of the Moroccan continental lithosphere since the Jurassic, and successively dragged passively by the Africa plate motion to NE. The tectono-sedimentary and magmatic events discussed in this paper are preliminarily extended from their local scale into a peculiar geodynamic setting of a continental plate margin flanked by the opening and spreading Central Atlantic and NW Tethys oceans. It is suggested that during the late Mesozoic this setting created an unprecedented condition of intraplate stress for concurrent crustal shortening, related mountain uplift, and thinning of continental lithosphere.

Plate tectonic aspects of the Triassic carbonate-hosted stratiform-stratabound base-metal deposits in the Western Balkan, NW Bulgaria

The Triassic carbonate-hosted stratiform-stratabound base-metal deposits in the Western Balkan, NW Bulgaria, have well defined regional geological and tectonic settings, style ofmineralisation, mineralogical, geochemical and isotopic data. Their genesis, however, remains controversial in the framework of plate tectonic models, and is not supported by comparative analysis of possible counterpart candidates within the NW Tethyan domain. Besides, the crucial missing information is the geochronology of ore mineralisation relative to the Triassic carbonate host rocks. The article stresses the ambiguities due to the lack ofmineralisation age dating, and emphasises the necessity for building a convincing plate tectonic model based on the relevant geodynamic setting. A prospective direction of researchis the critical comparison with equivalent sediment-hosted base-metal deposits within the continental margin environments such as those in the Alps and Dinarides as well as others in the Alpine-Himalayan orogen and worldwide.

The Alpine Wilson cycle and NW Tethyan Metallogeny

The Alpine Wilson cycle and NW Tethyan Metallogeny