Roll moment usually is ignored when analyzing the maneuverability of surface ships. However, it is well known that the influence of roll moment on maneuverability is significant for ships with small metacentric height such as container ships, passenger ships, etc. In this study, a pure roll test is performed to determine the hydrodynamic derivatives with respect to roll motion as added mass and damping. The target ship is an autonomous surface ship designed to carry containers with a small drift and large freeboard. The commercial code of STAR CCM+ software is applied as a specialized tool in naval hydrodynamic based on RANS equation for simulating the pure roll of the ship. The numerical uncertainty analysis is conducted to verify the numerical accuracy. By distinguishing the in-phase and out-of-phase from hydrodynamic forces and moments due to roll motion, added mass derivatives and damping derivatives relative to roll angular velocity are obtained.