Direct spray frost-free air source heat pumps (FFASHPs) base on liquid desiccant solutions are a more promising renewable energy technology for developing net-zero emission buildings. In order to improve the thermal performance of the frost-free evaporator, a numerical mode was established based on the penetration theory and the two-film theory to reveal the interfacial heat and mass transfer mechanism of LiCl solution falling film absorption on the air side of the frost-free evaporator. The distribution characteristics of temperature, water vapor concentration, effective diffusion coefficient, morphology, velocity and pressure at the interface under different air Reynolds numbers and temperatures were analyzed. The results show that the distribution uniformity of interface parameters has a greater effect on heat transfer performance than its average value. The critical Reynolds number is 391.0 under the present study, and the distribution uniformity of interface parameters and the intensity of interface fluctuation are improved, and the thermal performance reaches the peak. The COP of FFASHP system can be improved effectively when the frost-free evaporator is operated under the critical condition matching its parameters. The purpose of the study is to provide theoretical support for the performance improvement and efficient operation of frost-free evaporators.
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