Reduction In Number Concentration Research Articles

Advancing marine post-combustion soot control: Diesel engine particles and soot capture through electrostatic-enhanced filtration

Marine post-combustion soot emission has become a critical issue due to its detrimental effects on global warming and accelerated glacier melting. In this study, a high-efficiency and low-resistance marine soot control method through electrostatic-enhanced filtration (EC-PF) was adopted. The effectiveness of EC-PF on diesel engine particles of different sizes and soot emissions under various engine loads and filtration temperatures was evaluated. EC-PF exhibited the best concentration enhancement effect at 25 % engine load, with an 82.2 % reduction in the number concentration of particles below 9.2 nm compared to PF, leading to an order of magnitude reduction in the total number concentration. As for the effect on pressure drop, under high engine loads at 373 K, EC-PF could even reduce the pressure drop rather than increase it by generating plasma to oxidize particles deposited in PF, reaching 40 % of the PF’s pressure drop. As the filtration temperature increased, EC-PF could still reduce the pressure drop increase by 26.3 % under full load conditions at 573 K. In addition, EC-PF could reduce the soot emission concentration to below 0.5 mg/m3 at different engine loads and temperatures, with a soot collection efficiency reaching 99 %, an over 3 % improvement over PF. During the long-term operation of EC-PF, it was necessary to reduce the operating voltage and perform purging of the electrostatic charger to prevent breakdown, which could fail pressure drop reduction. These findings hold significant implications for developing methods and legislation governing marine soot emissions control.

Comparison of Portable and Large Mobile Air Cleaners for Use in Classrooms and the Effect of Increasing Filter Loading on Particle Number Concentration Reduction Efficiency

This study focuses on the effect of portable and large filter-based air cleaners (HEPA filters), which became popular indoors during the COVID-19 pandemic, and their suitability for classrooms (here 186 m3). The decay rates of the particle number concentration (PNC) were measured simultaneously at up to four positions in the room. It was found that the different air outlet configurations of the units have an effect on the actual PNC removal in the room when operated at the same volume flow rates. This effect of the airflow efficiency of the air cleaners (AP) in a classroom is quantified with an introduced Air Cleaning Efficiency Factor in this study to identify beneficial airflows. In this context, the effect of filter loading in long-term operation on the cleaning effect is also investigated. The emitted sound pressure levels of the APs are given special attention as this is a critical factor for use in schools, as well as power consumption. A total of six different devices were tested—two portable APs and four large APs. In order to achieve the necessary volume flow rates, three or four of the portable units were used simultaneously in one room, while only one of the large units was used per room. When used at the same air circulation rates in the room, the portable APs exhibit higher sound pressure levels compared to the large APs. At air circulation rates of 4–5 h−1, the portable APs exceeded a value of 45 dB(A). Two of the four large units reach sound pressure levels below 40 dB(A) at air circulation rates of 4–5 h−1, whereby both large units, which are positioned on the rear wall, realize a homogeneous dilution of the room air. This is achieved by an air outlet directed horizontally at a height above 2 m or diagonally towards the ceiling, which points into the room and partly to the sides. On the other hand, an air outlet directed exclusively to the sides or horizontally into the room at floor level to all sides achieves lower particle decay rates. To investigate the influence of the filter loading, three large APs were operated in a school for a period of one year (190 days with 8 h each). For the three APs, long-term operation leads to different changes in PNC reduction efficiency, ranging from −3% to −34%. It is found that not only the size of the prefilter and main filter has a significant influence, but also whether there is a prefilter bypass that negatively affects the loading level of the main filter. At the same time, it was shown that one type of AP, measuring the pressure drop across the filters and readjusting the fan, kept the circulation rate almost constant (up to −3%) over a year.

Reducing the particles generated by flushing institutional toilets

Airborne particles play a significant role in the transmission of SARS-CoV-2, the virus that causes COVID-19. A previous study reported that institutional flush-O-meter (FOM) toilets can generate 3–12 times as many droplets as other toilets by splashing (large droplets) and bubble bursting (fine droplets). In this study, an aerosol suppression lid was evaluated to measure the reduction of particles by size using three metrics; number, surface area, and mass concentrations. To quantify toilet flush aerosol over time, detailed particle size distributions (from 0.016–19.81 µm across 152 size bins) were measured from a FOM toilet in a controlled-environment test chamber, without ventilation, with and without use of the suppression lid. Prior to each flushing trial, the toilet bowl water was seeded with 480 mL fluorescein at 10 mg/mL. A high-speed camera was used to record the large droplet movements after flushing. An ultraviolet-visible spectrophotometer was used to analyze the wipe samples to evaluate the contamination on the lid. The particle number, surface area, and mass concentrations without a lid were elevated compared to a lid in the first 90 sec. Overall, the lid reduced 48% of total number concentration, 76% of total surface area concentration, and 66% of total mass concentration, respectively. Depending on the particle size, the number concentration reduction percentage ranged from 48–100% for particles larger than 0.1 µm. Large droplets created by splashing were captured by the high-speed camera. Similar studies can be used for future particle aerodynamic studies. The fluorescein droplets deposited on the lid back sections, which were closer to the FOM accounted for 82% of the total fluorescein. Based on two-way ANOVA analysis, there were significant differences among both the experimental flushes (p = 0.0185) and the sections on the lid (p = 0.0146). Future work should explore the aerosolization produced by flushing and the performance of the lid in real restroom environments, where feces and urine exist in the bowl water and the indoor ventilation system is in operation.

Contributions of Coagulation, Deposition, and Ventilation to the Removal of Airborne Nanoparticles in Indoor Environments.

Airborne nanoparticles are frequently released in occupied spaces due to episodic indoor source activities. Once generated, nanoparticles undergo aerosol transformation processes such as coagulation and deposition. These aerosol processes lead to changes in particle concentration and size distribution over time and accordingly affect human exposure to nanoparticles. The present study establishes a framework for an indoor particle dynamic model that can predict time- and size-dependent particle concentrations after episodic indoor emission events. The model was evaluated with six experimental data sets obtained from previous measurement studies in the literature. The indoor particle dynamic model quantified the relative contributions of three particle loss mechanisms (i.e., coagulation, deposition, and ventilation) to the total reduction in number concentration. The results show that particle coagulation and indoor surface deposition are two dominant processes responsible for temporal changes in particle size and concentration following indoor emission events. The first-order equivalent coagulation loss rate notably varies with indoor emission source and accounts for up to 59% of the total particle loss for burning a candle, 42% for broiling a fish, and 10% for burning incense. The results reveal that while the coagulation loss rate changes markedly with the particle concentration and source type, the deposition loss rate is more dependent on particle size. Compared to coagulation and deposition, the effect of ventilation is marginal for most of the nanoparticle emission events indoors; however, ventilation loss becomes pronounced with the decrease of particle concentration below 5 × 104 cm-3, especially for particles larger than 100 nm in aerodynamic diameter.

An Experimentally Validated Analytical Model for Aerosol Number Concentration Reduction in Classrooms

To predict the aerosol number concentration decay in modern classrooms, this study derived an analytical model that addresses various indoor factors, viz., the filtration efficiency of air ventilation systems, effects of indoor air cleaners, particle deposition on walls, and particle emission from occupants. We also conducted experimental measurements to determine the wall-loss coefficient and the occupants’ particle generation rate, and the modeling results agreed with the experimental data reasonably well. Additionally, we investigated the behavior of the particle concentration decay in different ventilation scenarios. The model has been incorporated into web-based software that is freely available to the public. © The Author(s).

An experimental study on particle evolution in the exhaust gas of a direct injection SI engine

The measurement results for exhaust nucleation mode particles in internal combustion engines are not easy to repeat and very sensitive to the measurement processes in laboratory experiments. In this study, particle numbers and size distributions were measured at different sampling points along an exhaust system of a single-cylinder gasoline direct injection engine, which consists of an exhaust plenum chamber and circular steel pipes. Different injection timings and two fuels including gasoline and ethanol were tested. Particle evolution in the exhaust gas was analyzed. One sampling point upstream and five sampling points downstream the exhaust plenum chamber were measured with the exhaust temperature dropping from 630 °C to 170 °C. For gasoline, when the sampling point shifts from the upstream to the downstream of the exhaust plenum chamber, the particle number concentrations of accumulation mode decrease by 7%–10%, and the particle number concentrations of nucleation mode decrease by 50%–98%. A trade-off between the particle number concentrations of nucleation mode and accumulation mode with varied injection timings is observed downstream of the exhaust plenum chamber, indicating that coagulation between solid core particles and accumulation mode particles occurs in the exhaust plenum chamber. It is concluded that intensive particle coagulation occurs inside the exhaust plenum chamber, leading to reduction of solid core particle number concentration and the resultant different measurement results of nucleation mode particles in the downstream exhaust gas. For ethanol, the particle number concentration reduction is less than 20% regardless injection timings due to the ultra-low accumulation mode particles. The particle number concentration reductions along the five sampling points downstream of the exhaust plenum chamber are negligible.

REMOVED: Experimental investigation of impacts of engine hardware, operating parameters and combustion performance on particulate emissions in a DISI engine

With increasing concern over ultrafine Particulate Matter (PM) emissions from Direct Injection Spark Ignition (DISI) engines and ever tightening emissions legislation, substantial research work is required to obtain a better understanding of influence of advanced engine technologies on particulate formation and oxidation. In this work, experimental investigation of engine-out particulate emissions were carried out on a single cylinder spray-guided DISI engine. With regard to effects of engine hardware on PM emissions; impacts of fuel spray angle, fuel flow rate and intake valves’ lift and camshaft phasing were examined over a wide start of injection sweep window. Injector tests highlighted a complex relation between injector characteristics and engine operating parameters with PM emissions as a result of fuel impingement and poor mixture preparation. Valvetrain tests indicated some benefits from engine throttling by valve lift and intake camshaft phasing in particulate number concentration reduction at low load. This was associated with increased intake flow turbulence and improved mixture preparation. Number-weighted particle size distribution was also affected by intake valve modes at low load. Nevertheless, at high load, impacts of variable valve lift and camshaft phasing on particulate number concentration and size distribution became negligible. Furthermore, combustion phase indicators were studied in order to probe impacts of combustion performance on PM emissions. While no satisfactory correlation of initial flame development with PM emissions was identified; shorter rapid-burning angles were observed with lower particulate number concentrations.

The effects of operating conditions on particulate matter exhaust from diesel locomotive engines

Numerous reports have shown that fine particulates threaten human health. Since their health impact is associated with both mass and number concentrations, it is necessary to evaluate the emission standards for particulate mass accordingly. This study examined the particulate matter characteristics of diesel locomotive engine exhaust at various engine ratings. Diesel engine exhaust was collected via a dilution tunnel and the concentration and size distribution of fine particles were measured by a scanning mobility particle sizer. Exhaust gasses were measured simultaneously by a stack sampler. The maximum carbon monoxide emission was reached at 59% of the maximum rating, after which emissions decreased. The particle count median diameter increased with the engine rating, until a maximum was reached at 40% of the maximum rating. Most exhaust particles were nanoparticles with the nuclei mode range, a particle diameter (DP)<50nm. The increase in particles with the accumulation mode range, 50<DP<1000nm, led to a mass concentration increase and number concentration reduction. The count median diameter was within the nuclei mode range at lower engine ratings, and within the accumulation mode range at higher engine ratings. Since diesel engines mainly generate fine particles, exhaust particle mass and size distribution should be considered in emission regulations.

Spatial and vertical extent of nucleation events in the Midwestern USA: insights from the Nucleation In ForesTs (NIFTy) experiment

Abstract. Measurements of aerosol particle physical and chemical properties, gas phase concentrations and meteorological parameters were made along a transect in southern Indiana during the Nucleation In ForesTs (NIFTy) experiment conducted in May 2008. These measurements indicate nucleation was observed at all three measurement sites on almost half of all sampling days. The intensity of the nucleation events, as measured by the increase in ≥10 nm aerosol particle number concentrations of approximately 2×104 cm−3 over a layer of at least 300 m depth, is in good agreement with recent model results for the Midwestern USA derived using PMCAMx-UF. During the hour after termination of nucleation approximately half of the number concentration reduction is due to coagulation, while the remainder is due in equal parts to dry deposition and entrainment of relatively ultra-fine aerosol particle free troposphere air. Clear nucleation with continuous subsequent growth is only observed on days when the morning fractional cloud cover was less than 30%. It is associated with a clear transition from a strongly stratified atmosphere with low turbulence intensity and weak vertical velocities, to much a weaker vertical gradient of wind speed, increased turbulence intensity and stronger downwards vertical velocities, consistent with growth of the mixed layer and entrainment of air from the residual layer. Nucleation intensity is not very strongly determined by the prevailing condensational sink. However, there is a strong correlation between both a modified version of the Nucleation Parameter from Boy and Kulmala (2002) and ultrafine aerosol particle number concentrations, and mean morning H2SO4 concentrations and ultrafine aerosol particle number concentrations. Five A-class event days during NIFTy were characterized by values of the dimensionless nucleation parameter of Kuang et al. (2010) that are below 0.3, further indicating the applicability of their postulate that nucleation is favored by LΓ values below 0.7. Based on aerosol particle composition measurements it appears that aerosol particle formation and initial growth to approximately 30 nm diameter is dominated by ammonium and sulfate. Conservative estimates of the percent contribution of H2SO4 to aerosol particle growth (for sub-30 nm aerosol particles) on five A-class event days ranged from 23 to 85%.

Calibration and accuracy of a particle number measurement system

The particle number method was introduced in the Euro 5/6 light-duty regulation and will also be introduced in the Euro VI heavy-duty regulation. The legislation requires yearly calibration or validation of the particle number systems with monodisperse aerosol for the determination of the particle number concentration reduction factor (PCRF); however, there are some open issues, like the material to be used. In this paper, we describe the new particle number system from AVL (APC) and its calibration procedure which gives repeatability of its PCRFs after 1 year of better than ±6% (two standard deviations of the differences). We show that the most important effect on the calibration results can come from the generation method (material and thermal pre-treatment). The use of neutralizers downstream and upstream of the DMA was found to have a small effect on the results. We also suggest faster and easier procedures for more frequent checks of the proper operation of the systems: (i) the check with polydisperse aerosol with a mean around 50 nm and (ii) the dilution factor check with gases. A third fast way is to compare the systems with a reference system, as two systems measuring at the same sampling position (full dilution tunnel) have <5% differences. Calibrated systems of different manufacturers have <10% differences, while non-(well)-calibrated systems might have >10% differences. Although light-duty legislation requires measurement from the full dilution tunnel, measurement from the partial flow systems (for heavy-duty engines) or directly from the tailpipe is also possible (at least with APC). Finally, the relation between particle number and particulate mass for light-duty and heavy-duty engines of different technologies is shown.

Effect of Open Channel Filter on Particle Emissions of Modern Diesel Engine

Particle emissions of modern diesel engines are of a particular interest because of their negative health effects. The special interest is in nanosized solid particles. The effect of an open channel filter on particle emissions of a modern heavy-duty diesel engine (MAN D2066 LF31, model year 2006) was studied. Here, the authors show that the open channel filter made from metal screen efficiently reduced the number of the smallest particles and, notably, the number and mass concentration of soot particles. The filter used in this study reached 78% particle mass reduction over the European Steady Cycle. Considering the size-segregated number concentration reduction, the collection efficiency was over 95% for particles smaller than 10 nm. The diffusion is the dominant collection mechanism in small particle sizes, thus the collection efficiency decreased as particle size increased, attaining 50% at 100 nm. The overall particle number reduction was 66–99%, and for accumulation-mode particles the number concentration reduction was 62–69%, both depending on the engine load.

Characteristics of droplets generated by bubble bursting from chromic acid solutions

The effects of electrolyte concentration and gas flow rate on the characteristics of droplets generated from bubbles bursting on the surface of CrO 3 solution were studied with an experimental bubbling system. The experimental conditions included two electrolyte concentrations, 125 and 250 g l -1 of CrO 3, and three flow rates of sparging air in the range of 4–8 l min -1. A cascade impactor collected droplet samples for chemical analysis. A laser aerosol spectrophotometer and an aerodynamic particle sizer were employed simultaneously to measure the number concentration and size distribution of the droplets. A layer of foam formed on the liquid surface under all experimental conditions studied except at the gas flow rate of 4 l min -1 in 125 g l -1 CrO 3 solution. Foams had a significant effect on the characteristics of droplets generated from bursting bubbles. At identical gas flow rate and electrolyte concentration, the formation of foams led to a reduction in number concentration of droplets larger than 10 μm in aerodynamic diameter and a lower concentration of airborne Cr(VI). In the ranges of gas flow rate and electrolyte concentration tested, the results showed that the airborne Cr(VI) mass concentration increased significantly with gas flow rate and slightly with electrolyte concentration in the presence of foams. The results obtained in the present study should have applications in the emission control of Cr(VI)-containing droplets in chromium electroplating processes.

Kinematic Coagulation of Charged Droplets in an Alternating Electric Field

An analytic-numerical model has been developed to study kinematic coagulation caused by the vibrational motion of charged particles in an alternating electric field. The primary aim of this study was to find out the reduction in the number concentration of fine particles of diameter 0.1 μm-1.0 μm caused by collisions with larger, supermicron particles. Three cases are considered: (1) unipolar charging, (2) fine particles are neutral, and (3) fine particles and large particles have opposite polarity. We find out that in cases 1 and 2 the rate of kinematic coagulation in negligible and in case 3 significant. The results are demonstrated with two sample calculations with total mass loadings of 2 and 20 g/m3. In the former, where the mass median diameter is 3.0 μm, we discover a 20%-50% reduction in number concentration of particles in the range 0.5–1.0 μm and less significant reduction in smaller particles. The latter (MMD = 6.0 μm) represents power plant conditions. In this case the reduction varies from 10...