PM2.5 and black carbon (BC) are important air pollutants impacting radiation balance, air quality, health, and ecosystems. Ozone (O3) levels are increasing despite decreases in other pollutants, posing a challenge for pollution control, especially in coastal cities like Zhoushan, where the monsoonal climate can exacerbate PM2.5 and ozone pollution. This study conducted continuous online measurements of major atmospheric pollutants in Zhoushan, Zhejiang Province, in 2020. The results indicate that the highest contribution from local air masses in Zhoushan is observed in spring, accounting for 17.7 %, while the greatest average contribution from northern Zhejiang Province, Jiangsu Province, and Shanghai occurs in winter, at 18.5 %. Pollutant concentrations were seasonally variable, with PM2.5, BC, and sulfur dioxide concentrations 56.6 %, 36 %, and 58.2 % higher in the cold season compared to the warm season. The O3 in spring is approximately 50 % higher than that in summer. Ship emissions significantly contributed to BC, nitrogen oxides (NOx), and carbon monoxide in Zhoushan. In spring, PM2.5 sources included photochemical processes and northern air mass transport, while in winter, PM2.5 was due to regional transport. The inhibitory effect of PM2.5 on O3 formation in the Zhoushan area is relatively weak. Reducing NOx emissions may increase O3, emphasizing the need for volatile organic compounds monitoring and regional control measures to improve air quality and ensure sustainable development in Zhoushan.
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