Northern South China Sea Shelf Research Articles

Nonnegligible contribution of terrigenous sediment inputs from local small watersheds to west regions of the Pearl River Estuary, northern South China Sea shelf

As a crucial “sink” for terrigenous material entering the ocean, provenance of sediments within the coastal zone and continental shelf sea regions holds significant scientific importance in the investigation of global material cycling. Environmental magnetism was proved as an effective and rapid approach for sediment source identification. Detail and systematic magnetic measurements were performed for surface sediment samples collected from the mega Pearl River, local small rivers (Tan, Moyang and Jian rivers) of west Guangdong, coastal zone (CZ) and continental shelf (CS) to analyze the contribution of local small watersheds to marine sediments. The results indicate that detrital river input magnetite and hematite are coexisted in both CZ and CS sediments. Compared to CZ sediments, relatively higher concentration of hematite and finer grain size of magnetite are appeared at CS sediments. By comparing of magnetic parameters, it was inferred that magnetic minerals from the Pearl and Tan rivers are transported and deposited on the coastal zone by Guangdong longshore current. Meanwhile, sediment magnetic parameters in the Moyang and Jian Rivers are similar to the CS sediments, implying the two rivers-sourced materials were directly transported and deposited at the CS due to their narrow and restricted estuaries, and/or the CS preserves the residual deposits from the two rivers formed during the Last Glacial. Except for the Pearl River, sources of local small rivers significantly contribute to marine sediments at the coastal zone and continental shelf.

Seasonality of Water Exchange in the Northern South China Sea from Hydrodynamic Perspective

In this study, we utilized exposure time (θ¯) as a key metric to investigate water exchange and its spatiotemporal variations in the Northern South China Sea (NSCS). The Eulerian adjoint method and Lagrangian tracking were adopted to capture a comprehensive view of water exchange in coastal regions. Our findings reveal distinct spatial and seasonal variations in θ¯. Spatially, a long θ¯ (exceeding 150 days) appears in the coastal region, and the largest values occur in the Beibu Gulf (300 days). Temporally, θ¯ exhibits clear seasonal patterns across the extensive shelf area, influenced by the seasonal monsoon which induced seasonally reversing shelf current and results in symmetrical distribution patterns of θ¯ across the board shelf during both winter and summer months. θ¯ is longer in winter than in summer. The study also revealed pronounced vertical contrasts in cross-isobath transport over the NSCS shelf, though significant vertical variations in net exchange time were noted only in specific locations, including the northeast side of Hainan Island, the Beibu Gulf mouth, and along the west side of Taiwan Island. The Beibu Gulf emerged as a critical factor in the NSCS’s water exchange dynamics in both seasons. In summer, it impacts more than 20% of the water exchange over adjacent areas, particularly through its westward transport against typical northeastward shelf currents. This highlights the combined effect of the westward spread of the Pearl River freshwater and the stable slope current on regional hydrodynamics. In winter, the Gulf’s retention characteristics profoundly affected even distant areas, contributing to up to 50% of water exchange, showing its broad impact on the NSCS’s water dynamics throughout the year.

Neogene morphotectonic evolution of the East Asian Continental Shelf

The offshore basins in the East Asian Continental Shelf have undergone distinct tectono-geomorphic-sedimentary evolution since the Neogene, driven by complex interactions between tectonic and surface Earth processes. However, the contribution of the latter to the evolution of the offshore basins has been less studied. The landscape simulation software Badlands serves as an ideal tool to investigate the impacts of tectonic and surface processes on sedimentation as it simulates the sediment routing in a source-to-sink context. Focusing on the southern East China Sea Basin (ECSB) and the northern South China Sea Shelf Basin (SCSSB), two key components of the East Asian Continental Shelf, we used Badlands to reconstruct the tectono-geomorphic-sedimentary evolution since the Neogene. It revealed two-phase evolutionary processes: (1) the southern ECSB and the northern SCSSB were in the unified shelf environment and represented as an integral during the Early Miocene, though the northern SCSSB experienced anomalous subsidence due to the southward jump of the SCS mid-ocean ridge. The integrated southern ECSB and northern SCSSB experienced uplift and denudation since the Middle Miocene, under the influence of the Philippine Sea Plate extrusion. (2) Subsequently, the southern ECSB and the northern SCSSB were separated into two independent basins in the Late Miocene, when Taiwan Island was significantly uplifted due to the Philippine Sea Plate extrusion and the arc-continental collision. Then Taiwan Island experienced a multi-stage uplift characterized by southward and westward migration. It concluded that tectonics (i.e. Taiwan Orogeny and the subduction of the Philippine Sea Plate) primarily dominated the differential evolution of the southern ECSB and the northern SCSSB. Surface Earth processes (i.e. the intensification of the East Asian Monsoon and the sea-level fluctuation) are the secondary contributors.

Responses of Phytoplankton Communities to the Effect of Both River Plume and Coastal Upwelling

AbstractRiver plumes and coastal upwelling systems are both nutrient‐abundant habitats compared to the open ocean, and the mechanisms that structure the phytoplankton community when these occur together are unclear. In this study we investigated the dynamics and drivers of phytoplankton biomass and community composition in the Pearl River plume‐coastal upwelling system on the northern South China Sea shelf during summer. We found that phytoplankton biomass was lower in the plume than in upwelled water. Diatoms were the only dominant group in the upwelled water. In contrast, diatoms and Synechococcus were co‐dominant in the plume, and the negative correlation between the proportions of these two groups indicated that they occupied distinct niches. The lower phytoplankton biomass in plume waters was due to nutrient limitation, and there was a transition from limitation by phosphorus to limitation by nitrogen in the plume along its path. This bottom‐up control limited only diatoms, whereas Synechococcus was limited mainly by top‐down control via microzooplankton grazing. This difference led to niche differentiation of the dominant phytoplankton groups in the plume‐upwelling system. This discovery of niche differentiation enhances understanding of food web structure and will facilitate modeling of marine biogeochemical cycles.

Contrasting sources and fates of sedimentary organic carbon in subtropical estuary-marginal sea systems

Sediments deposited in subtropical deltas and continental shelves are the “recorders” of sources, transport processes, and accumulation of organic carbon (OC) at the land-ocean interface, but their role in the global carbon cycle remains poorly constrained. In this study, we determined the abundance and carbon isotopic composition (δ13C and Δ14C) of bulk OC, as well as characteristics of specific biomarker compounds (plant wax n-alkanes, n-fatty acids, and phytoplankton sterols) in surface sediments from the Pearl River estuary (PRE) and adjacent continental shelf of the northern South China Sea (SCS) in order to examine the sources and fates of OC delivered to a large subtropical river-marginal sea system. We observed marked spatial variability in the sources, hydrodynamic processes and accumulation of sedimentary OC in PRE and northern SCS shelf, with the emergence of two distinct regimes reflected in the bulk OC isotopic characteristics of surface sediments. In Pearl River impacted regions, relatively fresh terrestrial OC (OCterr) was subject to substantial degradation and aging during transport within the estuary and from the estuary to the shelf. In contrast, sedimentary OC in the Taiwanese river impacted region comprised a mixture of fluvially-derived refractory OCterr from the Choshui River and modern marine OC. Burial efficiencies of OCterr are also spatially heterogeneous as a result of these different OC sources and hydrodynamic processes. The overall OCterr burial efficiencies are relatively low in the Pearl River influenced region, with an average value of 27 ± 10% in the PRE and an average value of 17 ± 6% in the western shelf, in contrast to the higher values in the region impacted by Taiwanese rivers (55% ± 39%).These findings suggest both sources and hydrodynamic processes during transport exert strong influence on the fate of OC, with important implications for the role of river-dominated marginal seas in the global carbon cycle.

The contrast in suspended particle dynamics at surface and near bottom on the river-dominated northern South China Sea shelf in summer: implication on physics and biogeochemistry coupling

To understand the process-response relations among physical forcing and biogeochemical properties of suspended particles (SPs) in the river-dominated northern South China Sea shelf, a 5-day shipboard observation was conducted at a fixed location on the dispersal pathway of the Zhujiang (Pearl) River plume (ZRP) in the summer of 2016. Instrumented moorings were deployed near the sampling site to record the flow and wave fields every 10 minutes. Hydrographic properties were measured hourly to identify different water masses. Water and SPs samples at the surface (3 m) and near the bottom (3 m above the bed) were taken every 3 h for the analyses of nutrients, chlorophyll-a (Chl-a), and particulate organic matter (POM including POC, PN, and δ13CPOC). Meanwhile, the grain-size composition of SPs and seafloor sediment were also analyzed. Results showed that monsoon winds drove cold upwelling and ZRP waters at the surface. Both the upwelling and ZRP regimes contained newly produced marine phytoplankton based on low POC/Chl-a ratio (PC ratio) and enriched δ13CPOC. However, SPs in the ZRP regime were smaller (<153 µm), having denser particle bulk density, and less enriched δ13CPOC, indicating different bio-communities from the upwelling regime. EOF analysis of the surface data suggested that mixing processes and the dispersal of the ZRP regime were mainly controlled by far-field storm winds, tidal modulation, and strength of mixing. On the other hand, a bottom nepheloid layer (BNL) was observed, mainly consisting of SPs<63 μm with higher bulk density than SPs at the surface. POM in the BNL was degraded and δ13CPOC-depleted according to the PC ratio and δ13CPOC. EOF analysis of the near-bottom data indicated that the dominant physical processes influencing the biogeochemical properties of SPs in the BNL were jointly the upwelling-associated lateral transport (first order) and tide-related resuspension (second order). Our study identified the contrast between the surface and near-bottom regimes with the coupling patterns among physical forcing and physiochemical properties of SPs using good constraints on particle dynamics and particle sources.

A strong summer intrusion of the Kuroshio and residence time in the northern South China Sea revealed by radium isotopes

The Kuroshio intrusion through the Luzon Strait into the northern South China Sea (SCS) is an important contributor to the heat and salt budgets of the SCS and is usually the strongest in winter. The extent of the intrusion in summer and the residence time of the very surface layer (0–5 m) in the northern SCS slope and basin areas, however, are seldom quantitatively evaluated. In this study we investigated surface distributions of radium isotopes (226Ra and 228Ra) across the Luzon Strait into the northern SCS in late spring to mid-summer to reveal the fraction of the Kuroshio water and the transport path of the Kuroshio intrusion in the northern SCS. The activity of 228Ra ranged from 0.67 to 23.5 dpm 100 L-1, with the maximum occurring at the lowest salinity of 28.8 on the northern SCS shelf and the minimum appearing east of the Luzon Strait characteristic of the more saline Ra-depleted Kuroshio water. The activity of 226Ra showed a similar pattern in a smaller range of 4.63–9.64 dpm 100 L-1. Distributions of 226Ra and 228Ra, combined with the distribution of salinity, demonstrate that three water masses contribute to the surface seawater in the northern SCS, the Kuroshio surface water, the plume water, and the island-influenced surface water. We quantified the fraction of the Kuroshio water in the northern SCS, considering the conservation of 226Ra and salinity, to be in the range of 4 ± 7%–51 ± 4% with an average of 23 ± 11%. The fraction decreased southward and westward from the northwest off the Luzon Strait. The intrusion of the Kuroshio reached as far west as 115° E and as far south as 14° N. The residence time of the very surface water in the northern SCS slope and basin areas was estimated using 228Ra as a timer to be 0.22 ± 0.59–9.98 ± 0.54 years with an average of 2.92 ± 2.20 years.

A preliminary study on sediment records of possible typhoon in the northern South China Sea during the past 6500 years

Typhoon is an important meteorological phenomenon that affects the living and development of human beings on the southern China coast. However, there is still lack of clarity in the paleo-typhoon history and its influence on the evolution of the ancient human settlement environment since the mid-Holocene. Here, we identify six typhoon-like deposits from a core retrieved from the northern South China Sea shelf, close to the Pearl River Estuary, based on accelerated mass spectrometry 14C dating, grain size, and geochemistry. The sand fractions, CaO, Sr, SiO2/TiO2, and SiO2/Al2O3 were used to indicate the typhoon-like deposits. Results show that the ages with high-frequency typhoons are present ~200–300 cal yr BP, ~800–1000 cal yr BP, ~1500–1700 cal yr BP, ~2000–2100 cal yr BP, ~2400–2500 cal yr BP, and ~2700–3000 cal yr BP. Our results are comparable to the records from adjacent regions. Significantly, the vast tides occurred in the duration of ~2700–3000 cal yr BP in southern China, which probably caused the ancestors’ migration to the inland. Further studies are needed to deeply study the paleo-typhoon history in the southern China coast to verify our results.

Comparison of the U<sub>37</sub><sup>K<sup>′</sup></sup>, LDI, TEX<sub>86</sub><sup>H</sup>, and RI-OH temperature proxies in sediments from the northern shelf of the South China Sea

Abstract. The temperature proxies U37K′, LDI, TEX86H, and RI-OH are derived from lipid biomarkers, namely long-chain alkenones from coccolithophorids and long-chain diols ascribed tentatively to eustigmatophytes, as well as glycerol dialkyl glycerol tetraethers (GDGTs) and OH-GDGTs produced by Archaea. The applicability of these proxies in the South China Sea (SCS) has been investigated previously. However, in each study only one or two of the proxies were compared, and the recently updated calibrations or new calibrating methods such as BAYSPAR and BAYSPLINE were not applied. Here, we investigate four proxies in parallel in a set of surface sediment samples from the northern SCS shelf and relate them to local sea surface temperature (SST), which allows for us to compare and assess similarities and differences between them and also help improve regional multiproxy seawater temperature reconstructions. Our results indicate that U37K′ reflects annual mean SST with a slight bias toward the warm season. Terrestrial inputs appear to have a significant impact on LDI, TEX86H, and RI-OH proxies near the coast, leading to colder LDI- and TEX86H-derived temperatures but a warmer RI-OH temperature estimate. After excluding samples influenced by terrestrial materials, we find that LDI-derived temperature agrees well with annual SST, while TEX86H- and RI-OH-derived temperature estimates are close to SSTs in seasons dominated by the East Asian winter monsoon and summer monsoon, respectively. The different seasonal biases of these temperature proxies provide valuable tools to reconstruct regional SSTs under different monsoonal conditions.

Daily to weekly impacts of mixing and biological activity on carbonate dynamics in a large river-dominated shelf

Large eutrophic river plumes can lead to hypoxic near-bottom water during summer. However, how the carbonate system in this stratified water column varies at a daily-to-weekly scale is still unclear. At the end of the first severe El Niño Southern Oscillation event in the 21st century during 2015/2016, high temperature, high salinity water was observed in the middle of the Pearl River plume on the northern South China Sea shelf over 6 d (July 24–29, 2016). We deployed a sensor pack (conductivity, temperature, pressure, and dissolved oxygen [DO]) along the water column each hour and took discrete samples, including total alkalinity and dissolved inorganic carbon every 3 h, to calculate pH. We observe a pH reduction rate of 0.011 pH unit·d−1 and an oxygen consumption rate of 4.4 μmol kg−1·d−1 in the near-bottom water. The temporal variations in calculated net community production rate and excess DO (measured DO - saturated DO) implies the switch in the dominance of net respiration to net photosynthesis in the near-surface water during this mixing event. We suggest that both net photosynthesis and net respiration were in the water with oversaturated DO on a short-term scale. The pH reduction and oxygen consumption rates in this study could help to estimate the level of coastal acidification and hypoxia better.

Submesoscale fronts observed by satellites over the Northern South China Sea shelf

Fronts are ubiquitous dynamic processes in the ocean, which play a significant role in the ocean dynamical and ecological environments. In this paper strong temperature fronts are investigated on the shelf of the Northern South China Sea using high resolution satellite data. These fronts have large horizontal gradients exceeding 1 °C km−1 with spatial scales around several kilometers. The fronts generate meanders and eddies due to baroclinic instability, since these instabilities have spatial scales around the local first baroclinic mode deformation radius. The estimated Rossby number of the fronts is O(0.4), suggesting that the fronts tend to be ageostrophic and show submesoscale features. The Finite Size Lyapunov Exponent analysis of the generation mechanism indicates that the fronts are tightly related to the combined flow straining of geostrophic and Ekman currents.

Dispersal and aging of terrigenous organic matter in the Pearl River Estuary and the northern South China Sea Shelf

Large rivers discharge great amounts of terrigenous organic carbon (OCterr) to the ocean, 90% of which are trapped in the coastal areas. The OCterr processing during transport to and within the coastal oceans are not well known. The Pearl River is the second largest river in China in terms of annual runoff. Here, we studied OCterr delivered from the river in the Pearl River Estuary (PRE) and the northern South China Sea (SCS) shelf using stable and radioactive carbon isotope compositions (δ13C and F14C) of OC in surface sediments to (1) constrain sources of OC, (2) explore the role of hydrodynamic processes for OCterr transport, and (3) better understand the burial and degradation processes of OCterr.A three end-member mixing model based on δ13C and 1/(C/N) values of bulk OC was used to calculate relative contributions of OCterr, OC derived from marine (OCmar) and riverine primary production (OCRpp). Results showed that the PRE and its western coastal inshore mud deposit are dominated by OCterr (70 ± 3% and 54 ± 10%, respectively), but other areas receive increasing contributions from OCmar: the slope (49 ± 10%), the eastern coast (58 ± 2%) and the outer shelf (68 ± 3%). OCRpp accounted for substantial proportions in the PRE (14 ± 6%) and rapidly decreased in the offshore area (3–5%), likely due to extensive aerobic respiration of organic matter (OM). Subsequently, average F14C values of OCterr were calculated ranging from 0.271 to 0.639 using a Monte-Carlo simulation strategy and based on the assumption that F14C values of OCRpp and OCmar varied within narrow ranges. Together with OCterr contents and grain sizes of sediments, F14C values of OCterr were used to distinguish two regions of distinctive sedimentological characteristics in the study area. Region I, including the PRE and inner shelf, showed a decrease of OCterr content along the trajectory of westward along-shelf transport, reflecting resuspension-dominated conditions for OCterr transport. Region II, including the outer shelf and one site on the inner shelf (E701), exhibited relatively old OCterr (9180 ± 730 yr BP), which is attributed to preferential accumulation of coarser sediments by bedload movement. Finally, a first-order degradation rate constant was calculated from contents and 14C ages of OCterr, yielding a slow OCterr degradation rate of (2.88 ± 0.61) × 10–4 yr−1, indicating a more refractory nature and likely effective mineral protection of OCterr. The ΣCO2 efflux due to OCterr degradation was estimated to be 3.68 ± 1.39 Gg C yr−1 for the entire surface sediments in the Pearl River derived mud belt, equivalent to only 0.7 ± 0.3% of the total particulate OC flux of the Pearl River. This, hence, suggests that the OCterr is more persistent and the preservation of OCterr in the marine system is better than previously thought, but experiences substantial degradation on centennial to millennial timescales.

Partial pressure of CO2 and air-sea CO2 fluxes in the South China Sea: Synthesis of an 18-year dataset

This study synthesizes spatial and temporal variations in surface seawater pCO2 (partial pressure of CO2) and associated air-sea CO2 fluxes in the largest marginal sea of the North Pacific, the South China Sea (SCS), based on a large dataset collected from 47 surveys during 2000–2018. We categorized the SCS into five domains featuring different physical and biogeochemical characteristics to better understand the seasonality of SCS pCO2 dynamics and constrain the CO2 fluxes. The five domains are (A) the northern SCS shelf, (B) the northern SCS slope, (C) the SCS basin, (D) West of the Luzon Strait, and (E) the western SCS. We found a large spatial variability in sea surface pCO2 in the SCS, except during winter when values remained in a narrow range of 300 to 360 μatm. In general, seasonal variability was evident in surface water pCO2 values from the northern SCS (Domains A, B and D), with lower values during the cold seasons and higher values during the warm seasons, except in the Pearl River plume (150–650 μatm) and the area off northwest Luzon where winter upwelling occurred (370–470 μatm). In the SCS basin and the western SCS (Domains C and E), pCO2 in surface waters was generally higher than in the atmosphere (380–420 μatm). We also revealed large intra-seasonal variations in the northern SCS during monsoonal transitions in both spring and fall. In spring, pCO2 increased with temperature in the northern SCS, which was a CO2 sink in March but became a CO2 source in May with April as a transitional month. Fall is also a transitional season for the northern SCS, where it changes from a CO2 source back to a CO2 sink. The area-weighted CO2 fluxes across the entire SCS were −1.1 ± 2.2 mmol m−2 d−1 in winter, 0.9 ± 0.9 mmol m−2 d−1 in spring, 2.5 ± 1.4 mmol m−2 d−1 in summer and 1.9 ± 1.1 mmol m−2 d−1 in fall. Nevertheless, on an annual basis, the average CO2 flux from the SCS was 1.2 ± 1.7 mmol m−2 d−1. Enhanced carbon sink on the northern SCS shelf was observed in winter. The annual average CO2 flux was significantly lower than the previous estimate, which can largely be attributed to the addition of new datasets in the previously under-sampled seasons and regions.

Source-to-sink processes of fluvial sediments in the northern South China Sea: Constraints from river sediments in the coastal region of South China

The fine-grained fractions (<63 μm) of nine fluvial sediments from South China coastal rivers (SCCR) and fourteen surface sediments from the continental shelf of the northern South China Sea (NSCS) are analyzed to determine the major and trace elements and Sr-Nd isotope compositions and differentiate the sediment sources and factors that control the distribution of geochemical compositions on the NSCS shelf. The results reveal that the geochemical compositions of sediments from the SCCR differ from each other and can be utilized to identify the sediment provenance in the study area. These river sediments are mostly deposited on the continental shelf of the NSCS, and their influence is different in various locations. Sediments on the eastern and western sides of the Pearl River mouth have different εNd values and 87Sr/86Sr ratios, indicating that the weathering intensity varies greatly from the eastern side to the western side. The main sediment sources in the NSCS shelf contain fluvial sediments discharged by the eastern and western coastal rivers of South China and the coastal rivers of western Taiwan and relict sediments on the continental shelf.

Numerical modeling of the seasonal circulation in the coastal ocean of the Northern South China Sea

The Finite Volume Community Ocean Model (FVCOM) was adapted to the Northern South China Sea (NSCS) to investigate the seasonality of coastal circulation, as well as along-shelf and cross-shelf transport. In fall and winter, southwestward current dominates the NSCS shelf, while the current’s direction shifts to northeast in summer. The circulation pattern in spring is more complicated: both southwestward and northeastward currents are detected on the NSCS shelf. The mean shelf circulation pattern in winter does not show the permanent counter-wind South China Sea Warm Current (SCSWC) along the 100–200 m isobaths. Meanwhile, the model results indicate a northeastward current flowing along 50–100 m isobaths in spring. Southwestward along-shelf transport varies from 0.30–1.93 Sv in fall and winter, and it redirects to northeast in summer ranging from 0.44–1.09 Sv. Onshore transport is mainly through the shelf break segment southeast of the Pearl River Estuary.

Progress on shelf and slope circulation in the northern South China Sea

Influenced by the seasonally reversed monsoons, water exchange through straits, and topography, the shelf and slope circulation in the northern South China Sea (NSCS) is complex and changeable. The typical current system in the NSCS consists of the slope current, South China Sea warm current (SCSWC), coastal current, and associated upwelling (in summer) and downwelling (in winter). This paper reviews recent advances in the study of NSCS shelf and slope circulation since the 1990s, and summarizes the roles of Kuroshio intrusion, the monsoons, topography, and the buoyancy effect of the Pearl River plume in the shelf and slope current system of the NSCS. We also point out some potential scientific issues that require further study, such as the dynamic connection between the internal basin and shelf areas of the NSCS, the persistence of the SCSWC in winter, the temporo-spatial characteristics of downwelling during winter in the NSCS, and its material and energy transport.

Seasonal Dynamics of Dissolved Organic Carbon Under Complex Circulation Schemes on a Large Continental Shelf: The Northern South China Sea

AbstractWe examined the distribution and seasonality of dissolved organic carbon (DOC) based on a large data set collected from the northern South China Sea (NSCS) shelf under complex circulation schemes influenced by river plume, coastal upwelling, and downwelling. The highest surface values of ∼117 μmol L−1 were observed nearshore in summer suggesting high DOC supplies from the river inputs, whereas the lowest surface values of ∼62 μmol L−1 were on the outer shelf in winter due to entrainment of DOC‐poor subsurface water under strengthened vertical mixing. While the summer coastal upwelling brought lower DOC from offshore depth to the nearshore surface, the winter coastal downwelling delivered higher surface DOC to the midshelf deep waters from the inner shelf fueled by the China Coastal Current (CCC) transporting relatively high DOC from the East China Sea to the NSCS. The intensified winter downwelling generated a cross‐shelf DOC transport of 3.1 × 1012 g C over a large shelf area, which induced a significant depression of the NSCS DOC inventory in winter relative to in autumn. In addition to the variable physical controls, net biological production of DOC was semiquantified in both the river plume (2.8 ± 3.0 μmol L−1) and coastal upwelling (3.1 ± 1.3 μmol L−1) in summer. We demonstrated that the NSCS shelf had various origins of DOC including riverine inputs, inter‐shelf transport and in situ production. Via cross‐shelf transport, the accumulated DOC would be exported to and stored in the deep ocean, suggesting that continental shelves are a potentially effective carbon sink.

Geochemical characteristics of phosphorus in surface sediments from the continental shelf region of the northern South China Sea

Abstract Forty surface sediment samples were collected from the northern South China Sea (NSCS) during March–April 2014 to study the geochemical forms and characteristics of phosphorus (P), including exchangeable or loosely adsorbed P (Ex-P), Fe-bound P (Fe-P), authigenic P (Ca-P), detrital apatite P (De-P), and organic P (OP), which were separated and quantified through a sequential extraction procedure. Total P (TP) in surface sediments ranged from 5.10 to 18.79 μmol g− 1, and inorganic P (IP) was the dominant form of P. De-P and Ca-P were the main chemical forms of IP in surface sediments. Terrestrial inputs, biological processes, hydrodynamic conditions, Fe oxides, particle size and organic matter degradation were responsible for the geochemical characteristics of different P species in surface sediments of the NSCS. Organic carbon to OP (OC/OP) ratios ranged from 84 to 595 with an average of 151 in surface sediments, which indicates that organic matter deposited on the NSCS shelf can be ascribed to predominantly terrestrial sources. Fe/P ratios indicate that Fe oxides in most surface sediments of the NSCS had elevated capacity for the retention of particulate P. Bioavailable P represented a significant proportion of the sedimentary P pool, and accounted for 17.9–55.7% of TP in surface sediments of the NSCS.

Sources and accumulation of plutonium in a large Western Pacific marginal sea: The South China Sea

In order to examine the sources of plutonium (Pu) and elaborate its scavenging and accumulation processes, 240Pu/239Pu atom ratios and 239+240Pu activities in the water column of the South China Sea (SCS) were determined and compared with our previously reported data for the sediments. Consistently high 240Pu/239Pu atom ratios that ranged from 0.184–0.250 (average=0.228±0.015), indicative of non-global fallout Pu sources were observed both in the surface water and at depth during 2012–2014. The spatial distribution of the 240Pu/239Pu atom ratio in the SCS showed a decreasing trend away from the Luzon Strait, which was very consistent with the introduction pathway of the Kuroshio Current. The Kuroshio had an even heavier Pu isotopic ratio ranging from 0.250–0.263 (average=0.255±0.006), traceable to the non-global fallout Pu signature from the Pacific Proving Grounds (PPG). Using a simple two end-member mixing model, we further revealed that this PPG source contributed 41±17% of the Pu in the SCS water column. The 239+240Pu activities in the SCS surface seawater varied from 1.59 to 2.94mBqm−3, with an average of 2.34±0.38mBqm−3. Such an activity level was ~40% higher than that in the Kuroshio. The distribution of 239+240Pu in the surface seawater further showed a general trend of increase from the Kuroshio to the SCS basin, suggesting significant accumulation of Pu within the SCS. The 239+240Pu inventory of the water column in the SCS basin at the SEATS station with a total depth of ~3840m was estimated to be ~29Bqm−2, which was substantially higher than the sediment core estimates made for the SCS basin (3.75Bqm−2) but much lower than the sediment core estimates made for the shelf of the northern SCS (365.6Bqm−2). Such differences were determined by the lower scavenging efficiency of Pu in the SCS basin compared to the northern SCS shelf.

Sediment provenance and paleoenvironmental changes in the northwestern shelf mud area of the South China Sea since the mid-Holocene

The late Quaternary paleoceanography and paleoenvironment of the South China Sea (SCS) have been well reconstructed over the last decade. In contrast, the provenance of the terrigenous sediments that have accumulated in the northwestern continental shelf mud area remains enigmatic. This study investigated the provenance of these sediments and the paleoenvironmental changes archived in Core X2 via the analysis of geochemical elements, grain size, and accelerator mass spectrometry (AMS) 14C ages. Based on the upper continental crust (UCC)-normalized REE patterns and REE fractionation parameters, southwestern and western Taiwanese rivers and the Pearl River were identified as the main sources of the fine-grained sediment deposited in the northwestern shelf mud area off Hainan Island. This finding further confirms the long-distance transport (> 1000km) of fine-grained sediment from Taiwanese rivers to the northern SCS shelf and slope. Obvious changes in the grain size and Chemical Index of Alteration (CIA) record occurred at approximately 4.0cal kyr BP and were likely caused by increased Hainan Island inputs due to sea level changes.