Normal Mid-ocean Ridge Basalt Research Articles

Magnesium isotope behavior in oceanic magmatic systems: Constraints from mid-ocean ridge lavas from the East Pacific Rise

The magnesium (Mg) isotope composition of oceanic basalts has provided useful constraints on the evolution of the upper mantle and crust-mantle interactions. However, the behavior of Mg isotopes during oceanic magma differentiation is still unclear because of the small range in Mg isotope values in typical normal mid-ocean ridge basalts (N-MORB). Here, we present high-precision Mg isotope data on a well-characterized suite of mid-ocean ridge (MOR) lavas from the 9–10°N segment of the East Pacific Rise. These samples range from relatively primitive basalt to evolved dacite with MgO contents decreasing from 8.62 to 0.80 wt.%, and display a resolvable variation in δ26Mg from -0.27 to -0.17‰. The less-evolved samples (MgO > 7.0 wt.%) that have experienced olivine and plagioclase fractional crystallization have δ26Mg values ranging from -0.23 to -0.17‰ that are negatively correlated with MgO content. Samples containing MgO of 3.5–7.0 wt.%, that have experienced significant crystallization of clinopyroxene, together with plagioclase, show a limited variation of δ26Mg (-0.20 to -0.18‰). For those highly evolved samples (MgO < 3.5 wt.%) saturated with Fe–Ti oxides, the δ26Mg vary from -0.27 to -0.20‰ and are positively correlated with MgO content. The variation of δ26Mg in the MOR lavas is consistent with three stages of magma differentiation, beginning with fractional crystallization of olivine and plagioclase followed by increasing amounts of clinopyroxene and finally joined by Fe-Ti oxides. Quantitative modeling of the Mg isotopic variation in EPR samples, shows that the variation of δ26Mg in MOR lavas is primarily a consequence of fractional crystallization of the Mg-bearing minerals when Δ26MgOl-melt ∼ -0.10‰, Δ26MgCpx-melt ∼ 0.00‰, and Δ26MgTi−Mgt-melt ∼ 0.20‰. This study provides evidence that shallow level crystal fractionation can produce significant and predicable variations in Mg isotopic compositions of MOR lavas and that this process should be carefully considered when using evolved lavas to trace mantle source compositions.

Coupled Geodynamical‐Geochemical Perspectives on the Generation and Composition of Mid‐Ocean Ridge Basalts

AbstractOwing to their abundance and relative availability on Earth's seafloor, mid‐ocean ridge basalts (MORBs) have a well‐defined chemical element budget, reflected by the low standard deviation associated with typical normal MORB (N‐MORB) composition. However, the exact mechanisms leading to magma differentiation and MORB generation remain debated, which hinders our ability to evaluate MORB parental magma composition. In this study, we leverage the predictive power of the BDD21 numerical framework to obtain a representative trace element budget of parental MORB magma and assess its ability to fractionate into the N‐MORB composition. Utilizing revised parameterizations for mineralogy, melting, and partitioning, we couple BDD21 with numerical simulations of a MOR system driven by seafloor spreading in which we track the evolution of partial melting, mineral modal abundances, and concentrations of incompatible elements. Parental magma compositions are determined once simulations reach a steady state, and magma chamber replenishment models are employed to predict the trace element budget of the erupted liquid. We explore a range of geophysical and geochemical parameters to evaluate their effect on computed trace element concentrations. Previous magma chamber replenishment models are extended to account for multiple crystallization events and melt‐crystal interaction. Modeling outcomes suggest that petrologically constrained fractionation of parental magma compositions obtained through BDD21 yields glass compositions compatible with the N‐MORB budget. Nevertheless, our results show a systematic underestimation of Sr concentration, indicating the presence of recycled oceanic crust in the MORB source region.

Geology of the Mutis Complex, Miomaffo, West Timor

Mesozoic forearc assemblages are widespread across Indonesia, and these are also exposed in the overthrust terranes on Timor. The oldest rocks in the allochthonous Mutis Complex, West Timor are Mesozoic basaltic volcaniclastic rocks and melange containing blocks of normal mid-ocean ridge basalt (N-MORB) basalt (194 ± 5 Ma), amphibolite (metamorphism at 184 ± 6 Ma), garnet and actinolite-bearing schists, arkosic sandstone and volcanogenic sedimentary rocks. Based on the large component of Jurassic material, these rocks were probably derived from the Woyla terrane. The eastern part of the Miomaffo massif is complexly deformed with a dominant foliation overprinted by several fold and fault events including late normal cataclastic zones. This sequence is intruded by calc-alkaline andesitic dykes (possibly in the Eocene). The Central Sector of the massif is a block of high-strain greenschist facies rocks where the primary texture can no longer be recognised, but the bulk composition is the same as the volcaniclastic rocks in the east. Further west is an amphibolite facies metamorphic province. Amphibolite from the Western Sector have the same N-MORB composition as the basalt in the east, but the gneissic rocks have a higher proportion of arc-sourced protoliths. The peak metamorphic conditions were 650 °C and 0.9 GPa. This metamorphic event occurred at 37 Ma, reflecting subduction on the southeast margin of Sundaland, whereas the low-grade Mesozoic metamorphism of the Eastern Sector of the massif occurred in the accretionary prism along the Woyla Arc. The Mutis Complex at Miomaffo demonstrates the complex geological history of Mesozoic rocks in eastern Indonesia.

High-pressure single-crystal elasticity of corundum: Implication for multiple seismic structure of 660-km discontinuity

The complex multi-discontinuity structure at 660‐800 km depth is likely attributable to lateral mantle composition heterogeneities, which are closely related to the mid-ocean ridge basalts (MORB). To decipher the impact of varying composition on the seismic properties of MORB, detailed knowledge of the elasticity of candidate minerals is thus important. Here we employed Brillouin scattering coupled with diamond anvil cells to determine the single-crystal elasticity of corundum up to 14 GPa and 300 K. Using third-order finite strain equation of state, we calculate the pressure derivatives of adiabatic bulk modulus and shear modulus of corundum, which yields KS0’ = 3.8(1), G0’ = 1.8(1) with KS0 = 256(1) GPa and G0 = 163(1) GPa and ρ0 = 3.987(1) g/cm3. Combined with previous high-temperature data, the velocity and anisotropy of corundum have been calculated at 300 K or along normal geotherm. Our results are applied to model the density and velocity profiles of normal and alkali-depleted MORB. Our modeling demonstrates that varying the alkali content and temperature of MORB can significantly impact the discontinuity depth and velocity jump at 660–800 km depth. For normal MORB, reducing the temperature by 300 K from normal mantle geotherm results in a shift of the velocity jump from 670–710 to 650–710 km depth but hardly affects the magnitude of the velocity jump (5.8–6.8(3)% for VP and 10.0–10.8(5)% for VS). By contrast, in alkali-depleted MORB, the discontinuity will occur at a greater depth from 705–730 to 720–745 km depending on temperature with a VP jump of 3.8–4.6(2)% and VS jump of 6.3–7.4(4)%.

Calcium isotopic variability in hotspot lavas controlled by partial melting and source lithological heterogeneity

Crustal recycling can induce significant chemical and lithological heterogeneity of the mantle. Ocean island basalts (OIBs) are the surface expressions of rising mantle plumes from the Earth's deep interior and thus can be a probe of the compositional heterogeneity in the deep mantle. Endmember OIBs sampled the most isotopically extreme mantle components including EM1 (Enriched mantle 1), EM2 (Enriched mantle 2), HIMU (high μ; μ =238U/204Pb), and FOZO (Focus zone), but the lithological properties of their source regions are still not well understood. Here we explore the potential of stable calcium (Ca) isotopes in identifying mantle source lithology by investigating OIBs from the type localities for the several mantle components. We find that the δ44/40Ca values of classic HIMU OIBs (0.77 ± 0.09‰; 2SD, N = 15) and Louisville FOZO OIBs (0.78 ± 0.06‰; 2SD, N = 4) are indistinguishable from the average MORB (mid-ocean ridge basalt) value (0.84 ± 0.09‰; 2SD, N = 31), while the δ44/40Ca values of the Pitcairn EM1 (0.65–0.72‰) and the Samoan (Tutuila) EM2 OIBs (0.61–0.71‰) are distinctly lower than those of MORBs. Such Ca isotopic distinction cannot be attributed to magmatic differentiation because the EM1 and EM2 OIBs have obviously lower δ44/40Ca values than the HIMU and FOZO OIBs even at a same MgO content. Equilibrium fractionation during partial melting of garnet peridotite with bulk silicate Earth (BSE) δ44/40Ca (0.94 ± 0.05‰) can explain the Ca isotopic compositions of the HIMU and FOZO OIBs but is unable to reproduce the Ca isotopic variation of all OIBs in this study. Quantitative modeling suggests that the coupling of low δ44/40Ca (< 0.7‰) and high Gd/Yb (> 3.5) ratios in the EM1 and EM2 OIBs most likely points to an eclogitic source component with MORB-like or even lower δ44/40Ca (e.g., < 0.8‰), possibly reflecting contributions from recycled oceanic crust and sediments. A negative correlation between average δ44/40Ca and δ57Fe values (a useful proxy for mantle source lithology) of all endmember OIBs further confirms this proposal and highlights the significant contribution of distinct source lithologies to the Ca isotopic variations in these basalts. Therefore, our study indicates that Ca isotopes of basalts can be another promising tracer of lithological heterogeneity in the mantle.

Recognizing different types of ocean plate stratigraphy in the southeastern South Qilian Accretionary Belt, northeastern Tibet Plateau

Dissection of relicts of ocean plate stratigraphy (OPS) in orogens could provide important insights into oceanic evolution, orogenic formation and continental growth. Here we describe a study of petrology, geochronology, geochemistry and Sr–Nd isotopes for OPS in the South Qilian Accretionary Belt with the aim of providing new constraints on the evolution of the Proto-Tethys Ocean (PTO). Three types of OPS units were recognized by their differing petrological, geochemical and isotopic features. Type 1 OPS, representing relicts of ocean islands or seamounts, comprises ocean island basalt and gabbro ( t  = 525 ± 4 Ma, ( 87 Sr/ 86 Sr) i  = 0.7035–0.7039 and ε Nd ( t ) = +3.63 to +4.16) and (siliceous) carbonate rocks. Type 2 OPS, representing fragments of normal oceanic crust, consists of normal mid-ocean ridge basalt (N-MORB) and basaltic andesite (( 87 Sr/ 86 Sr) i  = 0.7059–0.7063 and ε Nd ( t ) = +6.33 to +7.44), chert and siliceous mudstone. Type 3 OPS could be oceanic plateau-derived and comprises enriched (E)-MORB and dolerite (( 87 Sr/ 86 Sr) i  = 0.7051–0.7064 and ε Nd ( t ) = +4.81 to +6.24), carbonate–siliceous mudstone and carbonate rock. These OPS units witnessed evolution of the PTO. Using available studies on regional arc-type magmatism and U–Pb geochronological data for detrital zircon in this study, a model of ‘trench jam accompanying subduction flip induced by accretion of the OPS’ is put forward. Supplementary material : Zircon U–Pb data, whole-rock major and trace element data and a supplementary figure are available at https://doi.org/10.6084/m9.figshare.c.6764637 Thematic collection: This article is part of the Ophiolites, melanges and blueschists collection available at: https://www.lyellcollection.org/topic/collections/ophiolites-melanges-and-blueschists

Identification of recycled oceanic crust in the mantle source of sulfide-bearing lower crust of the Gangdese magmatic arc, Southern Tibet: Constraints from Sr–Nd–Li isotopes

Post-collisional porphyry copper deposit (PCD) is a new genetic type of PCDs discovered in the Himalayan–Tibetan orogenic belt. It is believed that the formation of ore-forming magmas results from the re-melting of a sulfide-bearing, thickened, juvenile mafic lower crust in a magmatic arc associated with the oceanic plate subduction. However, the material contribution of subduction processes to the formation of this particular arc magma remains unclear. In this paper, we attempted to present a study that includes petrology, mineral geochemistry, whole rock Sr–Nd–Li isotopes, of Late Cretaceous Lilong ultramafic igneous rocks, south Lhasa sub-terrane, Tibet. The target ultramafic igneous rocks are sulfide-bearing cumulates. They show relative depletion in whole rock Nd isotopic compositions, slightly elevated (87Sr/86Sr)i ratios (0.7043–0.7059), and variable δ7Li values (2.8–9.0‰). Simulation results showed that trace element of melts in equilibrium with cumulus hornblende grains exhibit typical arc-like trace element distribution patterns, indicating that these ultramafic igneous rocks crystallized from arc magma. Additionally, the modeled melts showed enrichment in melt-mobile elements such as Ba, Pb, Sr, Th, and light rare earth elements (LREE), and higher Th/Yb ratios, as compared with normal mid-ocean ridge basalt (MORB). These geochemical properties can be explained by the metasomatism of depleted MORB mantle peridotites by hydrous melts derived from subducted seafloor sediments. Whole rock Sr isotopes show correlations with Ba/Nb and Th/La ratios for the modeled melts, showing that fluids from the basaltic igneous crust, in addition to hydrous melts from the seafloor sediments, contribute to their mantle source. In addition, the heterogeneity of whole rock δ7Li values for ultramafic igneous rocks also indicates that their mantle sources have been metasomatized by terrigenous sediment- and altered oceanic crust-derived fluids. Depleted MORB mantle peridotites react with the mixed fluids at sub-arc depths to produce ultramafic metasomatites, and model calculations for trace element contents and Sr–Nd–Li isotopic compositions further validate that the geochemical compositions of the Lilong ultramafic rocks can be clarified by this process. The results show that the deeply subducted oceanic crust may have played an important role in the formation of sulfide-bearing juvenile mafic lower crust of this magmatic arc.

Fate of an oceanic plate in the Neo-Tethys intra-oceanic subduction system: Evidence from elemental and Rb/Sr – Sm/Nd isotopic systematics

We report the coexistence of normal mid-ocean ridge basalt (NMORB)-type and alkaline ocean island basalt (OIB)-type mafic volcanics from the Zildat Ophiolitic Mélange (ZOM), Indus Suture Zone (ISZ), eastern Ladakh Himalaya. Trace element modeling portrays chemically heterogeneous mantle sources, wherein blueschists and sub-alkaline mafic volcanics depict almost flat REE-patterns [(La/Sm)N = 1.04–2.9] and respectively <20 % and >20 % degrees of partial melting from a depleted spinel-lherzolite mantle source. In contrast, alkaline mafic volcanics depict enriched LREE-patterns [(La/Yb)N = 35–48] with <5 % degrees of partial melting from a transitional garnet-spinel lherzolite enriched mantle source. Since the prevalent hypothesis considers seamounts and island arc rocks of the subducting oceanic plate within the Neo-Tethys Ocean to be the protolith for the contemporaneous Shergol Ophiolitic Melange (SOM) blueschists. In contrast, ZOM blueschists depict different protolith signatures. The εNd(t = 140 Ma) values for ZOM blueschists (+3.7 to +7.4) and sub-alkaline mafic volcanics (+9.2 to +9.3) are analogous to present-day Indian Ocean NMORB, while for OIB-type mafic volcanics (+3.7 to +4.3) are comparatively lower and analogous to Hawaii and Kerguelen OIB. Therefore, the observed protolith decoupling in the contemporaneous blueschists suggest the involvement of different protolith contenders, which were partially off-scraped from of the subducting plate during prolonged deep subduction followed by exhumation along the ISZ.

Evidence of South American lithosphere mantle beneath the Chile mid-ocean ridge

Numerous geochemical studies on mid-ocean ridge basalts have established the presence of both compositional and lithological heterogeneities in the upper mantle. These studies have successfully constrained the composition and age of the chemical heterogeneities within the Earth's upper mantle. However, the origin of those heterogeneities remains highly debated. The Chile Mid-Ocean Ridge in the southeast Pacific Ocean, located far away from any hotspot, is colliding and subducting under the South America plate promoting the formation of a slab window. Comprehensive geochemical data (major, trace, volatile element contents and Sr, Nd, Hf and Pb isotope ratios) on Chile Ridge submarine glasses collected over the 1000 km ridge length demonstrate significant mantle compositional variability. Four main mantle components have been recognized: the typical Pacific MORB mantle, an enriched mantle (e.g., EM-1), a Subduction Modified mantle, and an anciently depleted mantle with unusually high Hf isotope ratios. Surprisingly, despite the large compositional variability, all glasses – including those with a subduction signature – have volatile-refractory element ratios within the range of the Pacific normal MORB. We propose that the Patagonia sub-continental lithospheric mantle, variably metasomatized since the Early Paleozoic, is eroded and incorporated into an asthenosphere with a south Atlantic MORB mantle composition that is flowing westward across the slab window from South America to the Chile Ridge. This scenario contrasts with a well-accepted geodynamic model that predicts the opposite direction of mantle flow. We speculate that the westward mantle flow across the slab window might be a counter-flow response to the opening of the Drake passage and the eastward movement of Pacific mantle since ∼30 Ma ago.

Formation of Archean greenstone belts: Insights from an assemblage-scale study in the western Superior craton

Archean greenstone belts contain the oldest volcanic rocks on Earth and can provide critical insights into Earth’s early evolution. This study chooses the Sturgeon Lake greenstone belt in the easternmost Western Wabigoon terrane (WWT) of the Superior craton to illustrate an option for better understanding the formation of Archean greenstone belts. Our dataset includes outcrop observations, bulk compositions of 77 mafic to felsic volcanic samples, and in-situ U-Pb, Lu-Hf, and trace elements of zircon from 14 intermediate to felsic volcanic samples. The results revealed that this greenstone belt had broadly continuous volcanism from ca. 2780 to 2725 Ma, followed by a tectonic quiescence prior to a ca. 2707–2703 Ma volcanism at the terrane boundary. The intermediate volcanic rocks are characterized by variable Th/Nb and highly depleted Hf (zircon ƐHf(i) = +3 to + 6), interpreted to be derived from mantle sources ranging from those of normal mid-ocean ridge basalts (N-MORB) to those of enriched MORB (E-MORB), which commonly assimilated various felsic crustal components. The mafic volcanic rocks are dominated by low La/Sm basalts with negligible Nb, Ta anomalies and limited range of Th/Nb, forming a mantle array on the Th/Yb-Nb/Yb plot and consistent with oceanic crust of N-MORB to enriched N-MORB affinities. Some basalts from the ca. 2738–2725 Ma assemblages, however, gave high La/Sm, negative Nb and Ta anomalies, and limited range of Th/Nb plotting above and parallel to the mantle array. These basalts might be associated with passive subcretion and rollback of oceanic crust of the stagnant-lids tectonics or subduction of oceanic lithosphere as in modern-style plate tectonics, both of which are supported by trace element compositions of zircon that indicate hydrous, oxidized, large-ion lithophile element-enriched, and medium- to high-pressure magmas. Identification of three magma-series would not be possible if the data were lumped together, which is commonly seen in terrane- or craton-scale studies that sometimes propose contrasting interpretations of rock origins and Archean geodynamic processes. This detailed approach of distinguishing rock types and zooming into the subunits of a greenstone belt offers a practical solution to more accurately characterize Archean volcanic rocks and to better understand the early Earth.

Earth's evolving geodynamic regime recorded by titanium isotopes.

Earth's mantle has a two-layered structure, with the upper and lower mantle domains separated by a seismic discontinuity at about 660 km (refs. 1,2). The extent of mass transfer between these mantle domains throughout Earth's history is, however, poorly understood. Continental crust extraction results in Ti-stable isotopic fractionation, producing isotopically light melting residues3-7. Mantle recycling of these components can impart Ti isotope variability that is trackable in deep time. We report ultrahigh-precision 49Ti/47Ti ratios for chondrites, ancient terrestrial mantle-derived lavas ranging from 3.8 to 2.0 billion years ago (Ga) and modern ocean island basalts (OIBs). Our new Ti bulk silicate Earth (BSE) estimate based on chondrites is 0.052 ± 0.006‰ heavier than the modern upper mantle sampled by normal mid-ocean ridge basalts (N-MORBs). The 49Ti/47Ti ratio of Earth's upper mantle was chondritic before 3.5 Ga and evolved to a N-MORB-like composition between approximately 3.5 and 2.7 Ga, establishing that more continental crust was extracted during this epoch. The +0.052 ± 0.006‰ offset between BSE and N-MORBs requires that <30% of Earth's mantle equilibrated with recycled crustal material, implying limited mass exchange between the upper and lower mantle and, therefore, preservation of a primordial lower-mantle reservoir for most of Earth's geologic history. Modern OIBs record variable 49Ti/47Ti ratios ranging from chondritic to N-MORBs compositions, indicating continuing disruption of Earth's primordial mantle. Thus, modern-style plate tectonics with high mass transfer between the upper and lower mantle only represents a recent feature of Earth's history.

Constraints on near-ridge magmatism using 40Ar/39Ar geochronology of enriched MORB from the 8°20' N seamount chain

Our understanding of the spatial-temporal-compositional relationships between off-axis magmatism and mid-ocean ridge spreading centers is limited. Determining the 40Ar/39Ar ages of mid-ocean ridge basalt (MORB) lavas erupting near mid-ocean ridges (MOR) has been a challenge due to the characteristically low K2O contents in incompatible element-depleted normal MORB (NMORB). High-precision 40Ar/39Ar geochronology is used here to determine ages of young, basaltic lavas erupted along the 8°20' N seamount chain west of the East Pacific Rise (EPR) axis that have a range of incompatible element enrichments (EMORB) suitable for 40Ar/39Ar geochronology (e.g., K2O contents > 0.3 wt%). 40Ar/39Ar ages were determined in 29 well-characterized basalts sampled using HOV Alvin and dredging. Detailed geochronology and geochemical analyses provide important constraints on the timing, distribution, and origins of lavas that constructed this extensive volcanic lineament relative to magmatism beneath the adjacent EPR axis. Seamount eruption ages are up to ∼1.6 Ma younger than the underlying lithosphere, supporting a model of prolonged off-axis magmatism for at least 2 Myrs at distances as great as ∼90 km from the ridge axis. Increasing geochemical heterogeneity with eruption distance reflects the diminishing effect of sub-ridge melt focusing. The range of geochemically distinct lavas erupted at given distances from the ridge highlights the dynamic nature of the near-ridge magmatic environment over Myr timescales. Linear ridge-like (EPR-parallel) morphotectonic features erupt the youngest and most incompatible element-enriched lavas of the entire seamount chain, indicating there is a recent change in the influence of mantle heterogeneity and off-axis melt metasomatism on the near-ridge lithospheric mantle. Changes in seamount morphologies are attributed to counter-clockwise rotation and southward migration of the nearby Siqueiros transform over the last few million years.

Multiple ridge subduction processes in the southern Altaids: Implications from clinopyroxene chemistry and Sr–Nd–Hf isotopes of late carboniferous Nb-enriched, magnesian diorite-andesites in West Junggar, NW China

Magnesian (Mg# > 45) and/or Nb-rich (Nb > 6 ppm) dioritic-andesitic rocks have been identified in the Mayile area of southern West Junggar, Northwest China. A systematic petrological, geochronological, whole-rock geochemical, Sr–Nd–Hf isotope, and clinopyroxene chemistry study was conducted to constrain the petrogenesis, mantle source, and P–T conditions of magmas as well as the tectonomagmatic processes in the southern Paleo-Asian Ocean subduction zone. Mayile dioritic-andesitic rocks generated in the Late Carboniferous (306–312 Ma) have a high SiO2 content (52.3–63.2 wt%) and high Mg# (46–66) as well as sanukitic-like low LaN/YbN and Sr/Y ratios. They have high Nb contents (6.27–11.6 ppm) and Nb/U (9–18) ratios and are Nb-enriched sanukitic high-Mg andesites (HMAs). Clinopyroxene thermobarometry indicates that the parental magma of the Mayile HMAs experienced a high-temperature (1137–1199 °C) and shallow-level (0.8–0.17 GPa) partial melting in a mantle wedge. They have εNd(t) (+5.14 to +6.42), εHf(t) (+8.8 to +14.4), and zircon εHf(t) (+9.4 to +15.8) values and a slightly high (87Sr/86Sr)t ratio ranging from 0.703214 to 0.704140 relative to normal mid-ocean ridge basalt (N-MORB). The results suggest that West Junggar was dominated by continuous records of sanukitic rocks hinting at multiple ridge subduction processes in the southern Altaids. We reconstructed the subduction history of the Junggar Ocean in the Carboniferous-Permian from these particular observations in West Junggar, and gained insight into the gradual evolution of the tectonic setting, which transitioned from normal intraoceanic subduction to hot subduction of the young oceanic lithosphere from the Early to Late Carboniferous, with subsequent ridge subduction occurring mainly in the Late Carboniferous.

Petrology, geochemistry and Ar-Ar geochronology of eclogites in Jinshajiang orogenic belt, Gonjo area, eastern Tibet and restriction on Paleo-Tethyan evolution

As one of the important Paleo-Tethys suture zones in eastern Tibet, the Jinshajiang orogenic belt is of great significance to study the tectonic evolution of the main suture zone of Paleo-Tethys. In this paper, eclogites developed in the Jinshajiang suture zone in Gonjo area, eastern Tibet, are selected as specific research objects, and petrological, geochemical and Ar-Ar geochronological analyses are carried out. The major element data of the whole rock reveals that the eclogite samples have the characteristics of picritic basalt-basalt and belong to the oceanic low potassium tholeiites. The results of rare earth elements and trace elements of the samples show that the protoliths of eclogites have characteristics similar to oceanic island basalt (OIB) or normal mid ocean ridge basalt (N-MORB). Muscovite (phengite) from two eclogite samples yield the Ar-Ar plateau ages of 247 ± 2 Ma and 248 ± 2 Ma respectively, representing the peak metamorphic age of eclogite facies and the timing of complete closure of the Jinshajiang Paleo-Tethys Ocean. Muscovite and biotite selected from the hosting rocks of eclogite yield the Ar-Ar plateau ages are 238 ± 2 Ma and 225 ± 2 Ma respectively, reflecting the exhumation age of eclogites and their hosting rocks. Combined with the zircon U-Pb dating data (244 Ma) of eclogites obtained in previous work, it can be concluded that the Jinshajiang Paleo-Tethys ocean was completely closed and arc-continent collision was initiated at about 248–244 Ma (T₂¹). Subsequently, due to the large-scale arc (continent)-collision orogeney between Deqin-Weixi continental margin arc and Zhongza block (T₃¹–T₃²), the eclogites were rapidly uplifted to the shallow crust.

Light stable Cr isotope compositions of mid-ocean ridge basalts: Implications for mantle source composition

Stable isotopes of chromium (Cr) and iron (Fe), both multivalent elements in silicate melts, are valuable proxies of redox conditions in magmatic systems. Partial melting and fractional crystallization have been identified as the dominant fractionation processes for Cr and Fe isotopes in high-temperature reservoirs that can lead to small but detectable isotope variations in igneous rocks. More recently, however, the source mineralogy has been suggested to play an important role, which can ultimately affect the magnitude of Cr and Fe isotopic fractionation during partial melting and thus the Cr and Fe isotopic composition of the originating melt.With the aim to investigate the role of magmatic processes and the source Cr and Fe isotope signatures on the isotope composition of these transition metals in normal mid-ocean ridge basalts (N-MORB), we analyzed 21 well-characterized MORB glasses from the southern East-Pacific Rise, Pacific-Antarctic Ridge and Mid-Atlantic Ridge. The Cr isotope compositions of N-MORB show a narrow range from −0.278 to −0.186 ‰ in δ53/52Cr (i.e., difference of a sample’s 53Cr/52Cr ratio relative to the international reference material NIST SRM979), with an average value of −0.237 ± 0.050 ‰ (2SD; n = 19). As such, the average N-MORB δ53/52Cr value is significantly lower than that of Bulk Silicate Earth of −0.12 ± 0.06 ‰ and the Cr isotope compositions reported for most ocean island basalts ranging from ∼ −0.23 to 0.00 ‰. Iron isotopic compositions of these MORB range from +0.032 to +0.137 ‰ in δ56/54Fe (i.e., difference of a sample’s 56Fe/54Fe ratio relative to the international reference material IRMM014) and are within the range of previously published MORB data. The lack of correlations between N-MORB Cr isotope signatures and indices of magmatic differentiation suggests a negligible control of this process on Cr stable isotopes. Partial melting modeling using pMELTS provides evidence that the significant offset towards lower δ53/52Cr values of N-MORB cannot be produced by decompression partial melting of a lherzolithic source such as the depleted upper mantle alone. Instead, we suggest that the lower δ53/52Cr values of MORB could be linked to intrinsic small-scale 53Cr-depleted pyroxene-rich domains in the upper mantle that influence the melt’s Cr isotopic budget during partial melting.

Development of a cambrian back-arc basin in the North Qilian orogenic belt: New constraints from gabbros in Yushigou ophiolite

Introduction: The North Qilian orogenic belt, as the Northern branch of the original Tethys tectonic domain, is important for reconstructing the tectonic evolution of the ancient Tethys. However, the tectonic history of the North Qilian orogenic belt remains controversial. This study addresses this issue from a geochemical perspective.Methods: In this study, a comprehensive analysis of the geochronology, whole-rock geochemistry, clinopyroxene mineral geochemistry, zircon Ti crystallization temperature, and gabbromagma temperature and pressure in the Yushigou ophiolite of the North Qilian orogenic belt was conducted to provide constraints on its tectonic evolution.Results and Discussion: Laser ablation inductively coupled plasma mass spectrometry zircon U-Pb dating results reveal that the gabbros have ages of 519 ± 3 Ma and 495 ± 4 Ma, belonging to the Cambrian period. Most of the studied gabbros exhibited geochemical characteristics of tholeiitic basaltic rocks with normal mid-ocean ridge basalt and island arc tholeiite dual geochemical affinities. The gabbros are interpreted to have formed by a high degree of partial melting of the depleted mantle spinel lherzolite. These results suggest that the back-arc basin of the North Qilian tectonic belt may have evolved to a relatively mature stage from 519 to 495 Ma. Overall, this study contributes to our understanding of the tectonic evolution of the North Qilian orogenic belt through geochemical analyses.

Geochemistry and geochronology of the Bay of Islands metamorphic sole, Newfoundland, Canada: Protoliths and implications for subduction initiation

The Bay of Islands complex, Newfoundland, Canada, represents a fossil subduction system that was obducted onto the Laurentian margin during the Taconic Orogeny. We present whole-rock geochemistry and geochronology for the Bay of Islands metamorphic sole from the Table Mountain and North Arm Mountain massifs. The Bay of Islands metamorphic sole can be subdivided into three units: a high metamorphic-grade Grt-Cpx amphibolite and Grt-Cpx granulite unit, a medium metamorphic-grade common amphibolite unit, and a medium metamorphic-grade metasedimentary-dominated unit. Based on their major and trace element contents, two types of protoliths can be inferred for the Bay of Islands sole metabasites: cumulate gabbroic protoliths with high Mg numbers and depleted trace element contents, and basaltic protoliths with trace element contents defining a normal mid-oceanic-ridge basalt (N-MORB) affinity. Titanite in situ U-Pb analyses of two common amphibolite samples yield dates of 486 ± 7 Ma and 484 ± 4 Ma, which are interpreted as a metamorphic age (ca. 485 Ma). One sample from the metasedimentary unit yields detrital zircon dates that range from Archean to Ordovician, with the youngest dates defining the most dominant peak at ca. 490 Ma. This youngest peak is consistent with an arc-related source that may be linked with arc magmatism of the upper plate during the Taconic Orogeny. These observations suggest that (1) the subduction responsible for the formation of the Bay of Islands complex nucleated in an oceanic domain before ca. 485 Ma; and (2) the sediments that form the metasedimentary unit were partly sourced from the upper plate and were deposited on the lower plate while subduction was active.

Permian to Triassic protolith ages of type locality eclogites in the Eastern Alps: Implications for the opening of the Meliata back-arc basin

Abstract The Austroalpine domain contains the type locality of eclogites, but their protolith age is unknown except for a Permian metagabbro. Therefore, we studied the non-gabbroic eclogites from the Saualpe-Koralpe Complex (SKC) representing meta-basalts within a coherent continental rift fragment subducted during the Cretaceous. Zircon laser ablation–inductively coupled plasma–mass spectrometry (LA-ICP-MS) U-Pb dating revealed protolith ages of 283 ± 5 Ma, 255 ± 3 Ma, 251 ± 3 Ma, and 241 ± 3 Ma. Magmatic zircons exhibit 176Hf/177Hf ratios of 0.282935–0.283090 and juvenile εHf(t) values of +10 to +17.4. Typical normal mid-oceanic ridge basalt (N-MORB) geochemistry is established. The SKC host metasedimentary rocks are interpreted as Variscan continental crust close to the margin of the oceanic Meliata basin and were affected by Permian metamorphism. Metamorphic zircon of one SKC eclogite yields an age of 87–93 Ma. These results combined with previous data are used to present a new model for the tectonic evolution of the distal Austroalpine unit associated with the Meliata Ocean in a Wilson cycle: The SKC represents a distal continental margin during Permian to Middle Triassic rifting, which was intruded by few gabbro bodies and numerous basaltic sills and mostly Permian pegmatites. In contrast, structurally separated thick Triassic sedimentary cover successions of the Austroalpine domain lack any magmatism, excluding SKC as Triassic basement of the sedimentary cover successions. The present eclogite-bearing piece of continental crust adjacent to the Meliata oceanic lithosphere was subducted to mantle depth during Late Cretaceous and then exhumed.

Subducted carbonates not required: Deep mantle melting explains stable Ca isotopes in kimberlite magmas

Ca isotope geochemistry has great potential for improving our understanding of magmatic systems and for tracing the deep Earth carbon cycle. There are still many open questions, however, regarding the proper application of this relatively novel proxy to the study of mantle-derived magmas, including (i) the possible effects of pressure on mineral-melt Ca isotope fractionation factors, and (ii) the potential for Ca isotopes to be used as tracers of recycled marine carbonates in mantle-derived magmas. Kimberlites are mantle-derived melts that are highly enriched in CO2 and are the deepest-sourced magmas (>200 km depth) known to erupt at Earth’s surface, providing an excellent opportunity to explore these questions. We present Ca isotope data combined with detailed petrographic observations, bulk-carbonate C-O isotope data, and bulk-rock major element analyses, for a suite of 23 well-characterized kimberlite samples from their type-locality (Kimberley, South Africa). These kimberlites have abundant previous evidence for recycled surface materials in their mantle source, including low S isotope and moderately radiogenic Sr isotope compositions, yet display only limited variations in their Ca isotope compositions (δ44CaBSE of −0.08‰ to −0.27‰), with an average of −0.17 ± 0.02‰ (2SE, n = 21). This composition is indistinguishable from average carbonatites [−0.19 ± 0.03‰ (2SE, n = 106)] and OIB from recent studies [−0.16 ± 0.01‰ (2SE, n = 41)], and slightly lower than average MORB [−0.11 ± 0.02‰ (2SE, n = 31)]. Although our samples display a wide range of emplacement styles, alteration conditions, extents of magmatic differentiation, and degrees of mantle-cargo entrainment (i.e., xenocryst accumulation), we find no correlations between Ca isotopes and any of these factors. Instead, we find that low-degree partial melting of the likely kimberlite source lithology (i.e., carbon-bearing garnet lherzolite) yields modelled melt δ44CaBSE values ranging between −0.12‰ and −0.16‰ (at 1400–1500 °C), in agreement with the measured Ca isotope compositions of the Kimberley kimberlites. This observation, and the lack of heavy carbon isotope signatures in the examined samples, indicates that kimberlites do not require subducted carbonates in their mantle sources, despite their very high CO2 contents. Although several recent studies have suggested that equilibrium mineral-melt Ca isotope fractionation factors (e.g., 1000lnαgrt-melt) could be significantly different at higher pressures (i.e., due to pressure-induced changes in CaO bond lengths and coordinations), our models successfully reproduce the kimberlite data using pressure-independent predictions for mineral-melt fractionations. It remains possible, however, that differences in isotopic fractionation due to the peculiar composition of kimberlite melts (e.g., high CO2, low SiO2) are effectively cancelled out by competing pressure effects, and future work independently targeting these factors will be especially important for our understanding of Ca isotope fractionation in mantle-derived melts and the Ca isotope systematics of Earth’s mantle.

The evolution of Kerguelen mantle plume and breakup of eastern Gondwana: New insights from multistage Cretaceous magmatism in the Tethyan Himalaya

The relationship between the breakup of eastern Gondwana and Kerguelen mantle plume remains extremely controversial. The crucial conundrum is that when and where the Kerguelen mantle plume initially formed and its evolutionary history are unclear. In this paper, we report the oldest Cretaceous bimodal magmatism (144–140 Ma) associated with the Kerguelen mantle plume from the Comei large igneous province in the Tethyan Himalaya. The mafic rocks are dominated by oceanic island basalt (OIB)-like dykes with occasional normal mid-ocean ridge basalt (N-MORB)-like intrusions, while the felsic rocks show A-type granites affinities. Our results suggest that the > 140 Ma bimodal magmatism was clearly a response to early Kerguelen plume activity, and the Kerguelen plume initially formed underneath the Tethyan Himalaya but not the triple junction between Australia, Antarctica, and Greater India. We argue that the Cretaceous magmatism associated with the Kerguelen plume in the Tethyan Himalaya can be divided into three pulses of ca.141 Ma, ca.132 Ma, and ca.117 Ma, which correspond to vertical underplating, continuous ascent, and a southward migration process, respectively. Moreover, we propose that the multistage OIB-like magmas in the Tethyan Himalaya are mainly the products of interactions between the lower crust and mantle plume, while the contribution of the lithospheric mantle is negligible. This proposal implies that the lithosphere was significantly thinned before ca.141 Ma, and the Kerguelen plume had been incubating underneath the Tethyan Himalaya prior to this. Our findings suggest that the Kerguelen plume may not have been the trigger for the initial breakup of eastern Gondwana, but was complementary to the later complete breakup process. We also innovatively consider that the northward dragging and slab-pull forces caused by the Cretaceous intra-oceanic subduction of the Neo-Tethys Ocean may have played an active role in the evolution of the Kerguelen plume and the breakup of eastern Gondwana.