This work considers a guest Lithium atom (Li@C n ) in an endohedral fullerene, embedded in a quantum plasma modeled by the more general exponential cosine screened Coulomb (MGECSC) potential, under the influence of a spherical confinement and laser radiation field. The system is examined in nonrelativistic form and the related wave equation is solved using the tridiagonal matrix method (TMM), thus obtaining the discrete-continuum spectrum and related wave functions. The numerical values of the relevant parameters in this process are physically accessible values. The effects of the plasma, laser field and endohedral cavity on the photoionization cross section (PCS) are analysed in detail. The shielding effect of the plasma medium and the pulsating effect of the laser field modify the effective potential energy of the system, affecting the localizations of the 2s and continuum states, causing various overlapping cases. Considering different values of the endohedral encompassement parameters, which means that different types of fullerenes are taken into account, overlapping cases occur for different spectra and wave functions. Scrutinising these overlappings, the confinement and Cooper resonances of the PCSs are analysed. This analysis provides many details for the radiative dynamics of an artificial system Li@C n . The relevant ranges and critical values of plasma, laser field, and endohedral encapsulation parameters in the formation process of these resonances and PCSs are explained, as well as the cross-section curves, resonance positions, effective photoelectron energy range, and general PCS behavior, which can be important for potential experiments in addition to other theoretical investigations.
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