Non-local Thermodynamic Equilibrium Conditions Research Articles

Quantum rotational dynamics of linear C5 at low interstellar temperatures for H2 collision.

The quantum dynamics of carbon chains through H2 and He collisions in the interstellar medium (ISM) is an important step toward accurate modeling of their abundance in non-local thermodynamic equilibrium conditions. The C5(Σg+1) molecule is the longest pure carbon chain detected in the ISM to date. While He collisions are computationally easy to perform, the collision with much more abundant H2 is both complicated and computationally demanding. Using templates for approximating p-H2 collisional rates, such as scaling He rates and using a reduced 4D → 2D potential energy surface (PES), has limited applicability. On the other hand, any such approximation does not exist for o-H2. Therefore, a full rotational dynamics of C5 with both p- and o-H2 is performed considering both molecules as rigid-rotors. The PES is calculated using CCSD(T)-F12a/AVTZ, and a neural network fitting model has been carefully chosen to strictly obey spectroscopic accuracy and augment the PES. The augmented PES is then expanded into radial terms using the bispherical harmonics function, and close coupling calculations have been done to get the cross sections and, subsequently, rate coefficients for various rotational transitions of C5.

NLTE Analysis of High-Resolution H-Band Spectra, V: Neutral Sodium

In order to derive sodium abundances and investigate the effects of non-local thermodynamic equilibrium (NLTE) on the formation of H-band Na I lines, we update the sodium atomic model by incorporating collision rates with hydrogen from new quantum-mechanical calculations. The differential Na abundances for 13 sample stars are obtained by analyzing high-resolution H-band spectra from the Apache Point Observatory Galactic Evolution Experiment (APOGEE) and optical spectra under both local thermodynamic equilibrium (LTE) and NLTE conditions. Consistent abundances from both bands suggest that our updated atomic model is valid for studying the formation of H-band Na I lines. Our calculations show that, in our stellar parameter space, NLTE effects are negative and can result in corrections larger than −0.4 dex on optical lines. The corrections on H-band Na I lines are typically small, within about 0.05 dex, but not negligible if accurate sodium abundance is desired. We note that the [Na/Fe] ratios favor the theoretical galactic chemical model.

Modeling the Chromosphere and Transition Region of Planet-hosting Star GJ 436

Abstract Ahead of upcoming space missions intending to conduct observations of low-mass stars in the ultraviolet (UV) spectral region it becomes imperative to simultaneously conduct atmospheric modeling from the UV to the visible (VIS) and near-infrared (NIR). Investigations on extended spectral regions will help to improve the overall understanding of the diversity of spectral lines arising from very different atmospheric temperature regions. Here we investigate atmosphere models with a chromosphere and transition region for the M2.5V star GJ 436, which hosts a close-in Hot Neptune. The atmosphere models are guided by observed spectral features from the UV to the VIS/NIR originating in the chromosphere and transition region of GJ 436. High-resolution observations from the Hubble Space Telescope and Calar Alto high-Resolution search for M dwarfs with Exo-earths with Near-infrared and optical Echelle Spectrographs (CARMENES) are used to obtain an appropriate model spectrum for the investigated M dwarf. We use a large set of atomic species considered in nonlocal thermodynamic equilibrium conditions within our PHOENIX model computations to approximate the physics within the low-density atmospheric regions. In order to obtain an overall match for the nonsimultaneous observations, it is necessary to apply a linear combination of two model spectra, where one of them better reproduces the UV lines while the other better represents the lines from the VIS/NIR range. This is needed to adequately handle different activity states across the observations.

Non-LTE formation of the Fe I 6173 Å line in the solar atmosphere

The current analysis is dedicated to a detailed investigation of the non-local thermodynamic equilibrium (NLTE) effects influencing the formation of the Fe I 6173 Å line, which is widely used by many instruments, including the Helioseismic and Magnetic Imager (HMI) on board the Solar Dynamics Observatory (SDO) and the Polarimetric and Helioseismic Imager on board the Solar Orbiter. We synthesize the Stokes profiles in a snapshot of a three-dimensional magnetohydrodynamic simulation of the solar photosphere under both LTE and NLTE conditions. The simulation cube contains a sunspot and a plage region around it. The LTE and NLTE Stokes profiles formed in different features are compared and analysed. NLTE effects are evident in both intensity and polarization profiles. For the 6173 Å line, UV overionization is the dominant NLTE mechanism, and scattering effects are much less important. In addition to Fe, an NLTE treatment of Si, Mg, and Al is necessary to set the right photon density in the UV. This is found to further enhance the LTE departures compared to the case where Fe alone is treated in NLTE. These effects in the Stokes profiles survive even when the profiles are averaged spatially or sampled on a coarse wavelength grid such as that used by the SDO/HMI and other magnetographs. The deviations from the LTE profiles are stronger in the Fe I 6173 Å compared to the 6301 Å–6302 Å lines because in the latter case, line scattering compensates the effect of UV overionization. Based on the nature of departures from LTE, treating the 6173 Å line in LTE will likely result in an overestimation of temperature and an underestimation of the magnetic field strength.

Numerical solutions to linear transfer problems of polarized radiation

Context. The polarization signals produced by the scattering of anistropic radiation in strong resonance lines encode important information about the elusive magnetic fields in the outer layers of the solar atmosphere. An accurate modeling of these signals is a very challenging problem from the computational point of view, in particular when partial frequency redistribution (PRD) effects in scattering processes are accounted for with a general angle-dependent treatment. Aims. We aim at solving the radiative transfer problem for polarized radiation in nonlocal thermodynamic equilibrium conditions, taking angle-dependent PRD effects into account. The problem is formulated for a two-level atomic model in the presence of arbitrary magnetic and bulk velocity fields. The polarization produced by scattering processes and the Zeeman effect is considered. Methods. The proposed solution strategy is based on an algebraic formulation of the problem and relies on a convenient physical assumption, which allows its linearization. We applied a nested matrix-free GMRES iterative method. Effective preconditioning is obtained in a multifidelity framework by considering the light-weight description of scattering processes in the limit of complete frequency redistribution (CRD). Results. Numerical experiments for a one-dimensional (1D) atmospheric model show near optimal strong and weak scaling of the proposed CRD-preconditioned GMRES method, which converges in few iterations, independently of the discretization parameters. A suitable parallelization strategy and high-performance computing tools lead to competitive run times, providing accurate solutions in a few minutes. Conclusions. The proposed solution strategy allows the fast systematic modeling of the scattering polarization signals of strong resonance lines, taking angle-dependent PRD effects into account together with the impact of arbitrary magnetic and bulk velocity fields. Almost optimal strong and weak scaling results suggest that this strategy is applicable to realistic 3D models. Moreover, the proposed strategy is general, and applications to more complex atomic models are possible.

Partition sums for non-local thermodynamic equilibrium conditions for nine molecules of importance in planetary atmospheres

Internal vibrational and rotational partition functions are calculated for nine molecules that are abundant in the terrestrial atmosphere and some are also observed in planetary and exoplanet atmospheres. These molecules are often observed in non-local thermodynamic equilibrium (NLTE) conditions. Calculations are made for all isotopologues of these molecules for which data are available, generally for the temperature range T = 1–5000 K. The methods of calculation of the vibrational and rotational partition functions, Qv and Qr, respectively, the convergence, and the uncertainties for each isotopologue are discussed. Finally, a FORTRAN program, NLTE_TIPS_2021.FOR, to recall the NLTE partition sums is discussed.

The polarization angle in the wings of Ca I 4227: A new observable for diagnosing unresolved photospheric magnetic fields

Context. When observed in quiet regions close to the solar limb, many strong resonance lines show conspicuous linear polarization signals, produced by scattering processes (i.e., scattering polarization), with extended wing lobes. Recent studies indicate that, contrary to what was previously believed, the wing lobes are sensitive to the presence of relatively weak longitudinal magnetic fields through magneto-optical (MO) effects. Aims. We theoretically investigate the sensitivity of the scattering polarization wings of the Ca I 4227 Å line to the MO effects, and we explore its diagnostic potential for inferring information on the longitudinal component of the photospheric magnetic field. Methods. We calculate the intensity and polarization profiles of the Ca I 4227 Å line by numerically solving the problem of the generation and transfer of polarized radiation under non-local thermodynamic equilibrium conditions in one-dimensional semi-empirical models of the solar atmosphere, taking into account the joint action of the Hanle, Zeeman, and MO effects. We consider volume-filling magnetic fields as well as magnetic fields occupying a fraction of the resolution element. Results. In contrast to the circular polarization signals produced by the Zeeman effect, we find that the linear polarization angle in the scattering polarization wings of Ca I 4227 presents a clear sensitivity, through MO effects, not only to the flux of the photospheric magnetic field, but also to the fraction of the resolution element that the magnetic field occupies. Conclusions. We identify the linear polarization angle in the wings of strong resonance lines as a valuable observable for diagnosing unresolved magnetic fields. Used in combination with observables that encode information on the magnetic flux and other properties of the observed atmospheric region (e.g., temperature and density), it can provide constraints on the filling factor of the magnetic field.

Modeling the scattering polarization of the solar Ca I 4227 Å line with angle-dependent partial frequency redistribution

Context. The correct modeling of the scattering polarization signals observed in several strong resonance lines requires taking partial frequency redistribution (PRD) phenomena into account. Modeling scattering polarization with PRD effects is very computationally demanding and the simplifying angle-averaged (AA) approximation is therefore commonly applied. Aims. This work aims to assess the impact and the range of validity of the AA approximation with respect to the general angle-dependent (AD) treatment of PRD effects in the modeling of scattering polarization in strong resonance lines, with a focus on the solar Ca I 4227 Å line. Methods. Spectral line polarization was modeled by solving the radiative transfer problem for polarized radiation, under nonlocal thermodynamic equilibrium conditions, taking PRD effects into account in static one-dimensional semi-empirical atmospheric models presenting arbitrary magnetic fields. The problem was solved through a two-step approach. In step 1, the problem was solved for the intensity only, considering a multilevel atom. In step 2, the problem was solved including polarization, considering a two-level atom with an unpolarized and infinitely sharp lower level, and fixing the lower level population calculated at step 1. Results. The results for the Ca I 4227 Å line show a good agreement between the AA and AD calculations for the Q/I and U/I wings’ signals. However, AA calculations reveal an artificial trough in the line-core peak of the linear polarization profiles, whereas AD calculations show a sharper peak in agreement with the observations. Conclusions. An AD treatment of PRD effects is essential to correctly model the line-core peak of the scattering polarization signal of the Ca I 4227 Å line. By contrast, in the considered static case, the AA approximation seems to be suitable to model the wing scattering polarization lobes and their magnetic sensitivity through magneto-optical effects.

Detection and assignment of ozone bands near 95% of the dissociation threshold: Ultrasensitive experiments for probing potential energy function and vibrational dynamics

Ozone formation and depletion play a key role in various physical and chemical atmospheric processes which remain to be understood in more detail. The modeling of such phenomena based on ozone dynamics calculations requires a detailed knowledge of quantum states, transition probabilities, and ozone potential energy surface (PES) near the dissociation threshold ${D}_{0}$. Knowledge of highly excited rovibrational states with energies approaching ${D}_{0}$ is necessary for a reliable interpretation of satellite measurements of the ozone absorption or emission in the upper atmosphere in nonlocal thermodynamic equilibrium conditions. In addition, these states provide an ideal probe of PESs computed by ab initio methods but their detection by absorption spectroscopy is particularly challenging due to the sharp decrease of the intensity with the energy of the corresponding vibrational combination and overtone bands. In this work, two very high-energy vibrational bands are detected by high sensitivity cavity ring-down spectroscopy providing a noise equivalent absorption ${\ensuremath{\alpha}}_{\mathrm{min}}$ on the order of a few ${10}^{\ensuremath{-}11}\phantom{\rule{0.16em}{0ex}}\mathrm{c}{\mathrm{m}}^{\ensuremath{-}1}$. The corresponding cold bands, assigned as ${\ensuremath{\nu}}_{1}+6{\ensuremath{\nu}}_{2}+3{\ensuremath{\nu}}_{3}$ and $6{\ensuremath{\nu}}_{1}+{\ensuremath{\nu}}_{2}+{\ensuremath{\nu}}_{3}$ centered at 7969 and $7993\phantom{\rule{0.16em}{0ex}}\mathrm{c}{\mathrm{m}}^{\ensuremath{-}1}$, respectively, are about nine orders of magnitude less intense than the well-known ${\ensuremath{\nu}}_{3}$ fundamental band near 10 \textmu{}m. The spectrum analysis allowed for the experimental determination of 240 rovibrational energy levels of the upper vibrational states. The corresponding rotational patterns, located between 93.1% and 96.7% of the dissociation threshold, are the most excited ones measured so far by absorption spectroscopy. The values of the band centers and rotational constants derived from the spectrum analysis provide further confirmation of the absence of an activation barrier on the minimum-energy path towards the dissociation threshold [Tyuterev et al., Phys. Rev. Lett. 113, 143002 (2014)]. The vibrational dynamics is discussed in the context of the radiative transition probabilities and related Einstein coefficients for the observed bands. Another important question in the context of the nuclear dynamics concerns the interaction among the three identical potential wells of the ozone molecule in the ground electronic state, which appears to be due to the Jahn-Teller effect. Recent theoretical results accounting for the three potential wells in a full symmetry approach predicted that vibration states should exhibit deviations from the conventional one-potential-well ab initio calculations, near the dissociation threshold. In the present work, we observe a better agreement of the experimentally determined energy value with the three-wells prediction for the (1,6,3) vibrational state involving a large simultaneous excitation of both bending (${\ensuremath{\upsilon}}_{2}=6$) and asymmetric stretch (${\ensuremath{\upsilon}}_{3}=3$) vibrations pointing towards a nearby well. This could be tentatively interpreted as a manifestation of the three-wells effect.

A high-precision abundance analysis of the nuclear benchmark star HD 20

Metal-poor stars with detailed information available about their chemical inventory pose powerful empirical benchmarks for nuclear astrophysics. Here we present our spectroscopic chemical abundance investigation of the metal-poor ([Fe/H] = −1.60 ± 0.03 dex), r-process-enriched ([Eu/Fe] = 0.73 ± 0.10 dex) halo star HD 20, using novel and archival high-resolution data at outstanding signal-to-noise ratios (up to ∼1000 Å−1). By combining one of the first asteroseismic gravity measurements in the metal-poor regime from a TESS light curve with the spectroscopic analysis of iron lines under non-local thermodynamic equilibrium conditions, we derived a set of highly accurate and precise stellar parameters. These allowed us to delineate a reliable chemical pattern that is comprised of solid detections of 48 elements, including 28 neutron-capture elements. Hence, we establish HD 20 among the few benchmark stars that have nearly complete patterns and low systematic dependencies on the stellar parameters. Our light-element (Z ≤ 30) abundances are representative of other, similarly metal-poor stars in the Galactic halo that exhibit contributions from core-collapse supernovae of type II. In the realm of the neutron-capture elements, our comparison to the scaled solar r-pattern shows that the lighter neutron-capture elements (Z ≲ 60) are poorly matched. In particular, we find imprints of the weak r-process acting at low metallicities. Nonetheless, by comparing our detailed abundances to the observed metal-poor star BD +17 3248, we find a persistent residual pattern involving mainly the elements Sr, Y, Zr, Ba, and La. These are indicative of enrichment contributions from the s-process and we show that mixing with material from predicted yields of massive, rotating AGB stars at low metallicity improves the fit considerably. Based on a solar ratio of heavy- to light-s elements – which is at odds with model predictions for the i-process – and a missing clear residual pattern with respect to other stars with claimed contributions from this process, we refute (strong) contributions from such astrophysical sites providing intermediate neutron densities. Finally, nuclear cosmochronology is used to tie our detection of the radioactive element Th to an age estimate for HD 20 of 11.0 ± 3.8 Gyr.

Spectroscopic line parameters of NO, NO2, and N2O for the HITEMP database

This work describes the update of NO along with the incorporation of NO2 and N2O to the HITEMP database. Where appropriate, the HITRAN line lists for the same molecules have also been updated. This work brings the current number of molecules provided by HITEMP to seven. The initial line lists originating from ab initio and semi-empirical methods for each molecule have been carefully validated against available observations and, where necessary, adjustments have been made to match observations. We anticipate this work will be applied to a variety of high-temperature environments including astronomical applications, combustion monitoring, and non-local thermodynamic equilibrium conditions.

An improved model of radiative transfer for the NLTE problem in the NIR bands of CO2 and CO molecules in the daytime atmosphere of Mars. 1. Input data and calculation method

Advances in attacking the problem of radiative transfer in the near infrared (NIR) bands of CO2 and CO under nonlocal thermodynamic equilibrium (NLTE) conditions depend on the accuracy of taking into account the radiation processes and inelastic collisions of CO2 and CO molecules. The focus of the paper is to substantially improve the physical model of the problem and update the calculation method. It is the first time the surface albedo is introduced into the problem of the molecular emission under NLTE conditions. The values of the rate constants for inelastic molecular collisions and their temperature dependences have been radically updated. In some cases, since laboratory measurements of these constants are lacking, different versions are provided for them. The relative abundance of CO2 and CO isotopologues is based on the ratios of isotope abundances for the elements C and O obtained from the measurements in the atmosphere of Mars. The intensity of extraterrestrial solar NIR radiation is specified on the base of the high-accuracy ground-based measurements. In the method for calculating the populations of vibrational states, we pioneer in completely taking into account the overlapping of spectral lines in the NIR bands of CO2 and CO.

A tightly coupled non-equilibrium model for inductively coupled radio-frequency plasmas

The objective of the present work is the development of a tightly coupled magneto-hydrodynamic model for inductively coupled radio-frequency plasmas. Non Local Thermodynamic Equilibrium (NLTE) effects are described based on a hybrid State-to-State approach. A multi-temperature formulation is used to account for thermal non-equilibrium between translation of heavy-particles and vibration of molecules. Excited electronic states of atoms are instead treated as separate pseudo-species, allowing for non-Boltzmann distributions of their populations. Free-electrons are assumed Maxwellian at their own temperature. The governing equations for the electro-magnetic field and the gas properties (e.g., chemical composition and temperatures) are written as a coupled system of time-dependent conservation laws. Steady-state solutions are obtained by means of an implicit Finite Volume method. The results obtained in both LTE and NLTE conditions over a broad spectrum of operating conditions demonstrate the robustness of the proposed coupled numerical method. The analysis of chemical composition and temperature distributions along the torch radius shows that: (i) the use of the LTE assumption may lead to an inaccurate prediction of the thermo-chemical state of the gas, and (ii) non-equilibrium phenomena play a significant role close the walls, due to the combined effects of Ohmic heating and macroscopic gradients.

On the quality of MIPAS kinetic temperature in the middle atmosphere

Abstract. The kinetic temperature and line of sight elevation information are retrieved from the MIPAS Middle Atmosphere (MA), Upper Atmosphere (UA) and NoctiLucent-Cloud (NLC) modes of high spectral resolution limb observations of the CO2 15 μm emission using the dedicated IMK/IAA retrieval algorithm, which considers non-local thermodynamic equilibrium conditions. These variables are accurately derived from about 20 km (MA) and 40 km (UA and NLC) to 105 km globally and both at daytime and nighttime. Typical temperature random errors are smaller than 0.5 K below 50 km, 0.5–2 K at 50–70 km, and 2–7 K above. The systematic error is typically 1 K below 70 km, 1–3 K from 70 to 85 km and 3–11 K from 85 to 100 km. The average vertical resolution is typically 4 km below 35 km, 3 km at 35–50 km, 4–6 km at 50–90 km, and 6–10 km above. We compared our MIPAS temperature retrievals from 2005 to 2009 with co-located ground-based measurements from the lidars located at the Table Mountain Facility and Mauna Loa Observatory, the SATI spectrograph in Granada (Spain) and the Davis station spectrometer, and satellite observations from ACE-FTS, Aura-MLS and TIMED-SABER from 20 km to 100 km. We also compared MIPAS temperatures with the high latitudes climatology from falling sphere measurements. The comparisons show very good agreement, with differences smaller than 3 K below 85–90 km in mid-latitudes. Differences over the poles in this altitude range are larger but can be generally explained in terms of known biases of the other instruments. The comparisons above 90 km worsen and MIPAS retrieved temperatures are always larger than other instrument measurements.

Theoretical investigation of thermophysical properties in two-temperature argon-helium thermal plasma

The thermophysical properties of argon-helium thermal plasma have been studied in the temperature range from 5000 to 40 000 K at atmospheric pressure in local thermodynamic equilibrium and non-local thermodynamic equilibrium conditions. Two cases of thermal plasma considered are (i) ground state plasma in which all the atoms and ions are assumed to be in the ground state and (ii) excited state plasma in which atoms and ions are distributed over various possible excited states. The influence of electronic excitation and non-equilibrium parameter θ = Te/Th on thermodynamic properties (composition, degree of ionization, Debye length, enthalpy, and total specific heat) and transport properties (electrical conductivity, electron thermal conductivity, and thermal diffusion ratio) have been studied. Within the framework of Chapman-Enskog method, the higher-order contributions to transport coefficient and their convergence are studied. The influence of different molar compositions of argon-helium plasma mixture on convergence of higher-orders is investigated. Furthermore, the effect of different definitions of Debye length has also been examined for electrical conductivity and it is observed that electrical conductivity with the definition of Debye length (in which only electrons participate in screening) is less than that of the another definition (in which both the electrons and ions participate in screening) and this deviation increases with electron temperature. Finally, the effect of lowering of ionization energy is examined on electron number density, Debye length, and higher-order contribution to electrical conductivity. It is observed that the lowering of the ionization energy affects the electron transport-properties and consequently their higher-order contributions depending upon the value of the non-equilibrium parameter θ.

RAPCAL code: A flexible package to compute radiative properties for optically thin and thick low and high-Z plasmas in a wide range of density and temperature

AbstractRadiative properties are fundamental for plasma diagnostics and hydro-simulations. For this reason, there is a high interest in their determination and they are a current topic of investigation both in astrophysics and inertial fusion confinement research. In this work a flexible computation package for calculating radiative properties for low and high Z optically thin and thick plasmas, both under local thermodynamic equilibrium and non-local thermodynamic equilibrium conditions, named RAPCAL is presented. This code has been developed with the aim of providing accurate radiative properties for low and medium Z plasmas within the context of detailed level accounting approach and for heavy elements under the detailed configuration accounting approach. In order to show the capabilities of the code, there are presented calculations of some radiative properties for carbon, aluminum, krypton and xenon plasmas under local thermodynamic and non-local thermodynamic equilibrium conditions.

Infrared spectral analysis of engine preflame emission

An investigation has been conducted to examine the previously observed infrared emission occurring at the end of an engine's compression period. The infrared preflame spectrum is measured and quantitatively compared with a radiation emission model incorporating wall effects. The likelihood and degree of contributions to the observed emission by intermediate species under non-local thermodynamic equilibrium conditions are examined, and the viability of applying high-speed infrared imaging as a diagnostic technique for observing the distribution of fuel vapour is demonstrated. A Fastie—Ebert-type grating spectrophotometer was constructed to employ a 64×64 pixel platinum-silicide charge-coupled device imager. This instrument was integrated with a four-camera infrared spatial imaging system. The combined apparatus allows the simultaneous recording of the infrared spectra and four spatial images, each recorded through separate narrow-band filters. One filter is centred at 2.47 μm and another centred at 3.43 μm, covering strong H2O and hydrocarbon bands. Images are recorded at a framing rate of 1880 frames/s in 64-frame sequences from consecutive engine cycles and triggered at a chosen crank-angle position determined by a crankshaft-mounted encoder wheel. To interpret the measured spectrum, a line-by-line radiation model was created utilizing the high-resolution transmission (HITRAN) database of molecular parameters. This database includes spectral line data for radical and intermediate species including hydroxyl (OH) and formaldehyde (HCHO), and the alkyl compounds methane (CH4), ethylene (C2H4), and up to ethane (C2H6). The model predicts the spectra of an isothermal, homogeneous gas mixture consisting of fuel, residual gases H2O and CO2 in air at a given temperature, pressure and concentration, and considers the effect of interaction with an emitting combustion chamber wall. Preflame images and spectra were recorded from an optically accessible spark-ignition engine using four fuels representing minimal (CH4, C2H4), marginal (C2H6), and significant (propane, C3H8) cool-flame chemistry. Results show the measured preflame spectra of the four fuels to have similar large-scale features and magnitude, including the propane fuel known for chemiluminescence during low-temperature reactions. The preflame spectrum of the latter fuel mixture is notable for its lack of spectral features expected of HCHO or OH, suggesting that emission by intermediate species produced by low-temperature mechanisms is not readily evident in the infrared preflame spectrum. There is a high degree of correlation between the measured preflame spectra of CH4 and C2H4 mixtures and the spectrum modelled using parameter values reasonably representative of engine conditions. The prominent features of the observed infrared preflame spectra are explained by thermal emission of the species considered. Since reported absorption cross-sections of n-heptane, n-dodecane, and gasoline at 3.39 μm are greater than that of CH4, these fuels are expected to have thermal emissions of similar if not greater magnitude near this wavelength. Infrared images of fuel vapour during a diesel combustion cycle that have been recorded with the four-camera system are presented. Significantly, it has been shown that mid-infrared imaging can be used as a technique for observing in-cylinder fuel vapour distributions.

Multiwavelength observations of southern hot molecular cores traced by methanol masers - I. Ammonia and 24-GHz continuum data

We present observations of the (1,1), (2,2), (4,4) and (5,5) inversion transitions of para-ammonia (NH 3 ) and 24-GHz continuum, taken with the Australia Telescope Compact Array towards 21 southern Galactic hot molecular cores traced by 6.7-GHz methanol maser emission. We detect NH 3 (1,1) emission towards all 21 regions and 24-GHz continuum emission towards 12 of the regions, including six with no reported 8-GHz continuum counterparts. In total, we find the 21 regions contain 41 NH 3 (1,1) cores but around half of the regions only contain a single core. We extract characteristic spectra for every core at each of the NH 3 transitions and present both integrated intensity maps and channel maps for each region. NH 3 (2,2) emission was detected towards all NH 3 (1,1) cores. NH 3 (4,4) emission was detected in 13 of the NH 3 (1,1) cores with NH 3 (5,5) emission coincident with 11 of these. The NH 3 (4,4) and (5,5) emission is always unresolved and found at the methanol maser position. An analysis of the NH 3 (1,1) and (2,2) line ratios suggests that the cores with NH 3 (4,4) and (5,5) emission are warmer than the remaining cores rather than simply containing more ammonia. The coincidence of the maser emission with the higher spatial resolution NH 3 (4,4) and (5,5) emission indicates that the methanol masers are found at the warmest part of the core. In all cores detected at NH 3 (4,4) (with the exception of G12.68-0.18 core 4), the measured linewidth increases with transition energy. The NH 3 (1,1) spectra of several cores show an emission and absorption component slightly offset in velocity but it is unclear whether or not this is due to systematic motion of the gas. We observe large asymmetries in the NH 3 (1,1) hyperfine line profiles and conclude that this is due to non-local thermodynamic equilibrium conditions arising from a number of dense, small clumps within the beam, rather than systematic motions of gas in the cores. Assuming that the 24-GHz continuum emission is optically-thin bremsstrahlung, we derive properties of the ionized gas. The rate of Lyman continuum photons required to ionize the gas of 10 45 -10 48 s -1 suggests that the continuum emission is powered by stars of mass >8 M ⊙ . We investigate the nature of the 24-GHz continuum sources which were not detected at 8 GHz and find that these are always coincident with both ammonia and methanol maser emission. This is in contrast to those detected at both 8 and 24 GHz which are generally offset from the methanol maser emission. We investigate the possibility that these may be hypercompact H II regions. Finally, we separate the cores into five groups, based on their association with NH 3 , methanol maser and continuum emission. From the different physical properties of the cores in the groups, we discuss the possibility that these groups may represent cores at different evolutionary stages of the massive star formation process.

Experimental Benchmark for an Improved Simulation of Absolute Soft-X-Ray Emission from Polystyrene Targets Irradiated with the Nike Laser

Absolutely calibrated, time-resolved spectral intensity measurements of soft-x-ray emission (hnu approximately 0.1-1.0 keV) from laser-irradiated polystyrene targets are compared to radiation-hydrodynamic simulations that include our new postprocessor, Virtual Spectro. This new capability allows a unified, detailed treatment of atomic physics and radiative transfer in nonlocal thermodynamic equilibrium conditions for simple spectra from low-Z materials as well as complex spectra from high-Z materials. The excellent agreement (within a factor of approximately 1.5) demonstrates the powerful predictive capability of the codes for the complex conditions in the ablating plasma. A comparison to data with high spectral resolution (E/deltaE approximately 1000) emphasizes the importance of including radiation coupling in the quantitative simulation of emission spectra.

Nonthermal steady state translational energy distributions of O(1D) atoms in the stratosphere

The steady state translational energy distributions of O(1D) in the stratosphere between 20 and 50 km have been studied by laboratory experiments and Monte Carlo simulations. The results indicate that at all altitudes studied the translational energies of stratospheric O(1D) are distributed at high energies more than the Maxwell–Boltzmann distributions of the local temperatures. The predominant source of stratospheric O(1D) atoms is the solar UV photolysis of ozone, and the nascent O(1D) atoms produced have large translational energies due to the excess energy. The average translational energy of O(1D), for instance, at the altitude of 50 km, is found to be about twice as large as the thermal energy at the temperature of the ambient air. The nonthermal steady state translational energy distributions of O(1D) atoms result from the relatively slow translational energy relaxation process compared with the electronic quenching process (1D → 3P) by collisions with ambient air molecules (N2 and O2). It is suggested that the atmospheric reactions involving O(1D) atoms in the stratosphere proceed under nonlocal thermodynamic equilibrium conditions.