The ignition process of a hypergolic hybrid rocket fuel presents a significant challenge due to its complex and interconnected nature. However, understanding its underlying physics is crucial for accurately estimating the delay time and ignition performance. In this study, we employed an approximate analytical method to directly address the transient conduction problem with nonlinear surface heat generation. By using the Arrhenius equation and considering dual heat flux directions in both the liquid and solid domains, we propose a model for determining the delay time of heterogeneous hypergolic ignition. Our solution is straightforward and computationally efficient. Notably, when subjected to identical initial conditions and property settings, our results exhibit similarity with the solutions derived from other models. Moreover, we advance our approach by developing a particle packing model through the utilization of a well-established algorithm. By simulating the particle arrangement within the pellet, the surface layer properties and the thermal time constant of certain fuel designs can be modeled. This simulation serves the purpose of incorporating the particle size effect of the fuel pellet into our ignition model. The results generated by our heterogeneous hypergolic ignition model, in conjunction with the particle packing model, demonstrated impressive agreement with the experimental data derived from droplet tests. Novelty and significance statementThis study utilized a novel solving method to address a transient conduction problem with non-linear heat generation on the surface during a heterogeneous hypergolic ignition process. The study successfully derived an analytical solution, providing a simpler method for calculating ignition delay times. A scenario involving different initial temperatures was also examined. Additionally, the research integrated particle packing model data and thermal time constants to assess the effect of particle size. The model results were in agreement with the experimental data, confirming its accuracy and offering a reliable method for estimating the heterogeneous hypergolic ignition delay time.