Non-holonomic path planning is to solve the two point boundary value problem under constraints. Since it is offline and open-loop, the path planning cannot compensate for the disturbances and eliminate the errors. To solve the problems, this paper puts forward an iterative learning control algorithm that adjusts the control parameters of the path planner online through the multiple iterative computations of the target configuration error equation, under the initial configuration error and model error, and thus enhancing the accuracy of non-holonomic system path planning. Then, a simulation experiment on path planning was carried out for a chainable three-joint, non-holonomic manipulator. The results show that the iterative learning controller can eliminate the interference of initial configuration error and model error, such that each joint can move to the target configuration.