The machining technology for tungsten hole faces considerable challenges. Electrical Discharge Machining (EDM), as a non-traditional machining technique, is widely applied due to its capability to process conductive materials. This technique is characterized by high precision metal processing, high material removal rate, and low tool wear rate. Molecular dynamics simulation technology is employed in this study to model the single pulse discharge process, with the aim of elucidating the erosion mechanism of different melting point metal materials in the melt pool during spark discharge and the effect of pressure difference inside and outside the melt pool. Moreover, for the efficient machining of tungsten materials, Electrospark-electrochemical Hybrid Energy Field Machining (ECEM) method is proposed, which is conducted under a certain conductivity salt solution. The simultaneous high-speed electric spark discharge and electrochemical action effectively promote the rapid formation of spark plasma discharge channels. Orthogonal experimental data and images are utilized in this paper to study the machining of tungsten micropores, with the effects of pulse width, pulse interval, peak current, and concentration of NaNO3 being analyzed, and the optimal machining parameters being determined.