Ti–6Al–4V alloy has become a crucial raw material in aerospace and other industries owing to its exceptional mechanical properties. However, it is also a typical difficult-to-machine material, and its removal process and mechanism have been widely investigated by scratch testing. Nevertheless, the inherent non-rotational symmetry of the Vickers indenter introduces a crucial parameter, i.e., the angle λ between the indenter edge and the scratch direction, which affects not only the mechanical response of materials but also its surface formation mechanism during scratch. This study systematically characterized the micro/nano scratch characteristics of Ti–6Al–4V alloy under three typical angles λ (0°, 22.5°, 45°) as well as various normal forces and scratch speeds. The coefficient of friction (COF), scratch depth, scratch width, residual scratch morphology, and specific scratch energy were comparatively analyzed. Finite element simulations confirmed that the direction of material flow changed with the change in angle λ. The corresponding deformation mechanisms during scratch were discussed accordingly. The results revealed a significant influence of the angle λ on the scratch behaviors and surface quality of Ti–6Al–4V alloy.
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