Non-local Thermodynamic Equilibrium Abundances Research Articles

The Pristine Inner Galaxy Survey (PIGS) VII: a discovery of the first inner Galaxy CEMP-r/s star

ABSTRACT Well-studied very metal-poor (VMP, [Fe/H] <−2) stars in the inner Galaxy are few in number, and they are of special interest because they are expected to be among the oldest stars in the Milky Way. We present high-resolution spectroscopic follow-up of the carbon-enhanced metal-poor (CEMP) star Pristine_184237.56-260624.5 (hereafter Pr184237) identified in the Pristine Inner Galaxy Survey. This star has an apocentre of ∼2.6 kpc. Its atmospheric parameters (Teff = 5100 K, log g = 2.0, and [Fe/H] = −2.60) were derived based on the non-local thermodynamic equilibrium (NLTE) line formation. We determined abundances for 32 elements, including 15 heavy elements beyond the iron group. The NLTE abundances were calculated for 13 elements from Na to Pb. Pr184237 is strongly enhanced in C, N, and O, and both s- and r-process elements from Ba to Pb; it reveals a low carbon isotope ratio of 12C/13C = 7. The element abundance pattern in the Na–Zn range is typical of halo stars. With [Ba/Eu] = 0.32, Pr184237 is the first star of the CEMP-r/s subclass identified in the inner Galaxy. Variations in radial velocity suggest binarity. We tested whether a pollution by the s- or i-process material produced in the more massive and evolved companion can form the observed abundance pattern and find that an i-process in the asymptotic giant branch star with a progenitor mass of 1.0–2.0 $\, {\rm M}_{\odot }$ can be the solution.

The formation of the milky way halo and its dwarf satellites: a NLTE-1D abundance analysis. IV. Segue 1, Triangulum ii, and Coma Berenices UFDs

ABSTRACT We present atmospheric parameters and abundances for chemical elements from carbon to barium in metal-poor stars in Segue 1 (seven stars), Coma Berenices (three stars), and Triangulum ii (one star) ultrafaint dwarf galaxies (UFDs). The effective temperatures rely on new photometric observations in the visible and infra-red bands, obtained with the 2.5 m telescope of the SAI MSU Caucasian observatory. Abundances of up to fourteen chemical elements were derived under the non-local thermodynamic equilibrium (NLTE) line formation, and LTE abundances were obtained for up to five more elements. For the first time, we present abundance of oxygen in Seg 1 S1 and S4, silicon in ComaBer S2 and Tri ii S40, potassium in Seg 1 S1−S6 and ComaBer S1−S3, and barium in Seg 1 S7. Three stars in Segue 1, two stars in Coma Berenices, and Triangulum ii star have very low [Na/Mg] of −1.08 to −1.67 dex, which is usually attributed in the literature to an odd–even effect produced by nucleosynthesis in massive metal-free stars. We interpret this chemical property as a footprint of first stars, which is not blurred due to a small number of nucleosynthesis events that contributed to chemical abundance patterns of the sample stars. Our NLTE abundances of Sr and Ba in Coma Berenices, Segue 1, and Triangulum ii report on lower [Sr/Ba] abundance ratio in the UFDs compared to that in classical dwarf spheroidal galaxies and the Milky Way halo. However, in UFDs, just as in massive galaxies, [Sr/Ba] is not constant and it can be higher than the pure r-process ratio. We suggest a hypothesis of Sr production in metal-poor binaries at the earliest epoch of galactic evolution.

The Gaia-ESO survey: 3D NLTE abundances in the open cluster NGC 2420 suggest atomic diffusion and turbulent mixing are at the origin of chemical abundance variations

Context. Atomic diffusion and mixing processes in stellar interiors influence the structure and the surface composition of stars. Some of these processes cannot yet be modelled from the first principles, and they require calibrations. This limits their applicability in stellar models used for studies of stellar populations and Galactic evolution. Aims. Our main goal is to put constraints on the stellar structure and evolution models using new refined measurements of the chemical composition in stars of a Galactic open cluster. Methods. We used medium-resolution, 19 200 ≤ R ≤ 21 500, optical spectra of stars in the open cluster NGC 2420 obtained within the Gaia-ESO survey. The sample covers all evolutionary stages from the main sequence to the red giant branch. Stellar parameters were derived using a combined Bayesian analysis of spectra, 2MASS photometry, and astrometric data from Gaia DR2. The abundances of Mg, Ca, Fe, and Li were determined from non-local thermodynamic equilibrium (NLTE) synthetic spectra, which were computed using one-dimensional (1D) and averaged three-dimensional (3D) model atmospheres. We compare our results with a grid of Code d’Evolution Stellaire Adaptatif et Modulaire (CESTAM) stellar evolution models, which include atomic diffusion, turbulent, and rotational mixing. Results. We find prominent evolutionary trends in the abundances of Fe, Ca, Mg, and Li with the mass of the stars in the cluster. Furthermore, Fe, Mg, and Ca show a depletion at the cluster turn-off, but the abundances gradually increase and flatten near the base of the red giant branch. The abundance trend for Li displays a signature of rotational mixing on the main sequence and abrupt depletion on the sub-giant branch, which is caused by advection of Li-poor material to the surface. The analysis of abundances combined with the CESTAM model predictions allows us to place limits on the parameter space of the models and to constrain the zone in the stellar interior, where turbulent mixing takes place.

3D NLTE spectral line formation of lithium in late-type stars.

Accurately known stellar lithium abundances may be used to shed light on a variety of astrophysical phenomena such as big bang nucleosynthesis, radial migration, ages of stars and stellar clusters, and planet engulfment events. We present a grid of synthetic lithium spectra that are computed in non-local thermodynamic equilibrium (NLTE) across the stagger grid of three-dimensional (3D) hydrodynamic stellar atmosphere models. This grid covers three Li lines at 610.4, 670.8, and 812.6 nm for stellar parameters representative of FGK-type dwarfs and giants, spanning T eff = 4000-7000 K, log g = 1.5-5.0, [Formula: see text]-0.5, and A(Li) = -0.5-4.0. We find that our abundance corrections are up to 0.15 dex more negative than in previous work, due to a previously overlooked NLTE effect of blocking of UV lithium lines by background opacities, which has important implications for a wide range of science cases. We derive a new 3D NLTE solar abundance of A(Li) = 0.96±0.05, which is 0.09 dex lower than the commonly used value. We make our grids of synthetic spectra and abundance corrections publicly available through the breidablik package. This package includes methods for accurately interpolating our grid to arbitrary stellar parameters through methods based on Kriging (Gaussian process regression) for line profiles, and multilayer perceptrons (a class of fully connected feedforward neural networks) for NLTE corrections and 3D NLTE abundances from equivalent widths, achieving interpolation errors of the order of 0.01 dex.

Cobalt-Hydrogen Atomic and Ionic Collisional Data

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Non-local thermodynamic equilibrium line formation for Si i–ii–iii in A–B stars and the origin of Si ii emission lines in ι Her

ABSTRACT A comprehensive model atom was developed for Si i–ii–iii using the most up-to-date atomic data available so far. Based on non-local thermodynamic equilibrium (NLTE) line formation for Si i, Si ii and Si iii and high-resolution observed spectra, we determined the NLTE abundances for a sample of nine unevolved A9–B3 type stars with well-determined atmospheric parameters. For each star, NLTE reduces the line-to-line scatter for Si ii substantially compared with the LTE case and leads to consistent mean abundances from lines of different ionization stages. In the hottest star of our sample, ι Her, Si ii is subject to overionization that drives emission in the lines arising from the high-excitation doublet levels. Our NLTE calculations reproduced 10 emission lines of Si ii observed in ι Her. The same overionization effect leads to greatly weakened Si ii lines, which are observed in absorption in ι Her. Large positive NLTE abundance corrections (up to 0.98 dex for 5055 Å) were useful for achieving consistent mean abundances from lines of the two ionization stages, Si ii and Si iii. It was found that NLTE effects are overestimated for the Si ii 6347, 6371 Å doublet in ι Her, while the new model atom works well for cooler stars. At this stage, we failed to understand this problem. We computed a grid of the NLTE abundance corrections for lines of Si i, Si ii and Si iii in model atmospheres with effective temperatures and surface gravities characteristic of unevolved A–B type stars.

Non-LTE chemical abundances in Galactic open and globular clusters

Aims. We study the effects of non-local thermodynamic equilibrium (NLTE) on the determination of stellar parameters and abundances of Fe, Mg, and Ti from the medium-resolution spectra of FGK stars. Methods. We extended the Payne fitting approach to draw on NLTE and LTE spectral models. These were used to analyse the spectra of the Gaia-ESO benchmark stars and the spectra of 742 stars in 13 open and globular clusters in the Milky Way: NGC 3532, NGC 5927, NGC 2243, NGC 104, NGC 1851, NGC 2808, NGC 362, M 2, NGC 6752, NGC 1904, NGC 4833, NGC 4372, and M15. Results. Our approach accurately recovers effective temperatures, surface gravities, and abundances of the benchmark stars and clusters members. The differences between NLTE and LTE are significant in the metal-poor regime, [Fe/H] ≲ −1. The NLTE [Fe/H] values are systematically higher, whereas the average NLTE [Mg/Fe] abundance ratios are ∼0.15 dex lower, compared to LTE. Our LTE measurements of metallicities and abundances of stars in Galactic clusters are in a good agreement with the literature. Though, for most clusters, our study yields the first estimates of NLTE abundances of Fe, Mg, and Ti. Conclusion. All clusters investigated in this work are homogeneous in Fe and Ti, with the intra-cluster abundance variations of less then 0.04 dex. NGC 2808, NGC 4833, M 2, and M 15 show significant dispersions in [Mg/Fe]. Contrary to common assumptions, the NLTE analysis changes the mean abundance ratios in the clusters, but it does not influence the intra-cluster abundance dispersions.

NLTE modelling of integrated light spectra

Aims.We study the effects of non-local thermodynamic equilibrium (NLTE) on the abundance analysis of barium, magnesium, and manganese from integrated light spectroscopy, as typically applied to the analysis of extra-galactic star clusters and galaxies. In this paper, our reference object is a synthetic simple stellar population (SSP) representing a mono-metallicα-enhanced globular cluster with the metallicity [Fe/H] = −2.0 and the age of 11 Gyr.Methods.We used the MULTI2.3 program to compute LTE and NLTE equivalent widths of spectral lines of Mg I, Mn I, and Ba II ions, which are commonly used in abundance analyses of extra-galactic stellar populations. We used ATLAS12 model atmospheres for stellar parameters sampled from a model isochrone to represent individual stars in the model SSP. The NLTE and LTE equivalent widths calculated for the individual stars were combined to calculate the SSP NLTE corrections.Results.We find that the NLTE abundance corrections for the integrated light spectra of the metal-poor globular cluster are significant in many cases, and often exceed 0.1 dex. In particular, LTE abundances of Mn are consistently under-estimated by 0.3 dex for all optical lines of Mn I studied in this work. On the other hand, Ba II, and Mg I lines show a strong differential effect: the NLTE abundance corrections for the individual stars and integrated light spectra are close to zero for the low-excitation lines, but they amount to − 0.15 dex for the strong high-excitation lines. Our results emphasise the need to take NLTE effects into account in the analysis of spectra of individual stars and integrated light spectra of stellar populations.

Ultra metal-poor stars: improved atmospheric parameters and NLTE abundances of magnesium and calcium

Abstract The most metal-poor stars are the oldest objects, they provide a unique opportunity to study the earliest epoch of the Galaxy formation and individual nucleosynthesis events. These stars should be investigated with a scrupulous care, taking into account all available photometric, spectroscopic, and astrometric informations. We determined atmospheric parameters for 17 ultra metal-poor (UMP) stars, using an extensive method based on colour-Teff calibrations, isochrones, Gaia DR2 trigonometric parallaxes, and non-local thermodynamic equilibrium (NLTE) analysis of the Ca i/Ca ii ionization equilibrium and the Balmer line wings. We updated the model atom of Ca i- ii by including recent quantum-mechanical rate coefficients for the Ca i + H i and Ca ii + H i inelastic collisions. For any line of Ca i and Ca ii in our sample stars, the changes in collisional data result in a shift of smaller than 0.05 dex in the NLTE abundance. We determined magnesium and calcium NLTE and LTE abundances of our sample stars. For 10 stars, we found close-to-solar [Ca/Mg] NLTE abundance ratios. In the remaining stars, magnesium and calcium abundances do not follow each other, such that [Ca/Mg] varies between −3.15 and + 0.36, suggesting a contribution to stellar Mg and Ca abundances from a small number of supernova explosions with different properties. The obtained atmospheric parameters will be used in the forthcoming paper to determine NLTE abundances of chemical elements observed in spectra of the UMP stars.

An empirical recipe for inelastic hydrogen-atom collisions in non-LTE calculations

Context. Determination of high-precision abundances of late-type stars has been and always will be an important goal of spectroscopic studies, which requires accurate modeling of their stellar spectra with non-local thermodynamic equilibrium (NLTE) radiative transfer methods. This entails using up-to-date atomic data of the elements under study, which are still subject to large uncertainties.Aims. We investigate the role of hydrogen collisions in NLTE spectral line synthesis, and introduce a new general empirical recipe to determine inelastic charge transfer (CT) and bound-bound hydrogen collisional rates. This recipe is based on fitting the energy functional dependence of published quantum collisional rate coefficients of several neutral elements (BeI, Na I, Mg I, Al I, Si Iand Ca I) using simple polynomial equations.Methods. We perform thorough NLTE abundance calculation tests using our method for four different atoms, Na, Mg, Al and Si, for a broad range of stellar parameters. We then compare the results to calculations computed using the published quantum rates for all the corresponding elements. We also compare to results computed using excitation collisional rates via the commonly used Drawin equation for different fudge factors,SMH, applied.Results. We demonstrate that our proposed method is able to reproduce the NLTE abundance corrections performed with the quantum rates for different spectral types and metallicities for representative Na Iand Al Ilines to within ≤0.05 dex and ≤0.03 dex, respectively. For Mg Iand Si Ilines, the method performs better for the cool giants and dwarfs, while larger discrepancies up to 0.2 dex could be obtained for some lines for the subgiants and warm dwarfs. We obtained larger NLTE correction differences between models incorporating Drawin rates relative to the quantum models by up to 0.4 dex. These large discrepancies are potentially due to ignoring either or both CT and ionization collisional processes by hydrogen in our Drawin models.Conclusions. Our general empirical fitting method (EFM) for estimating hydrogen collision rates performs well in its ability to reproduce, within narrow uncertainties, the abundance corrections computed with models incorporating quantum collisional rates. It performs generally best for the cool and warm dwarfs, with slightly larger discrepancies obtained for the giants and subgiants. It could possibly be extended in the future to transitions of the same elements for which quantum calculations do not exist, or, in the absence of published quantum calculations, to other elements as well.

NLTE Analysis of Copper Lines in Different Stellar Populations∗

Abstract The copper abundances of 29 metal-poor stars are determined based on the high-resolution, high-signal-to-noise ratio spectra from the UVES spectrograph at the ESO VLT telescope. Our sample consists of the stars of the Galactic halo, thick- and thin-disk, with [Fe/H] ranging from ∼−3.2 to ∼0.0 dex. The non-local thermodynamic equilibrium (NLTE) effects of Cu i lines are investigated, and line formation calculations are presented for an atomic model of copper including 97 terms and 1089 line transitions. We adopted the recently calculated photoionization cross sections of Cu i, and investigated the hydrogen collision by comparing the theoretical and observed line profiles of our sample stars. The copper abundances are derived for both local thermodynamic equilibrium (LTE) and NLTE based on the spectrum synthesis methods. Our results show that the NLTE effects for Cu i lines are important for metal-poor stars, in particular for very metal-poor stars, and these effects depend on the metallicity. For very metal-poor stars, the NLTE abundance correction reaches as large as ∼+0.5 dex compared to standard LTE calculations. Our results indicate that [Cu/Fe] is under-abundant for metal-poor stars (∼−0.5 dex) when the NLTE effects are included.

A NLTE line formation for neutral and singly ionized calcium in model atmospheres of B-F stars

We present non-local thermodynamic equilibrium (NLTE) line formation calculations for Ca I and Ca II in B-F stars. The sign and the magnitude of NLTE abundance corrections depend on line and stellar parameters. We determine calcium abundances for nine stars with reliable stellar parameters. For all stars, where the lines of both species could be measured, the NLTE abundances are found to be consistent within the error bars. We obtain consistent NLTE abundances from Ca II lines in the visible and near infra-red (IR, 8912-27, 9890 A) spectrum range, in contrast with LTE, where the discrepancy between the two groups of lines ranges from -0.5 dex to 0.6 dex for different stars. Our NLTE method reproduces the Ca II 8912-27, 9890 A lines observed in emission in the late B-type star HD 160762 with the classical plane-parallel and LTE model atmosphere. NLTE abundance corrections for lines of Ca I and Ca II were calculated in a grid of model atmospheres with 7000 K < Teff < 13000 K, 3.2 < log g < 5.0, -0.5 < [Fe/H] < 0.5, Vt = 2.0 km/s. Our NLTE results can be applied for calcium NLTE abundance determination from Gaia spectra, given that accurate continuum normalisation and proper treatment of the hydrogen Paschen lines are provided. The NLTE method can be useful to refine calcium underabundances in Am stars and to provide accurate observational constraints on the models of diffusion.

Ultra-metal-poor Stars: Spectroscopic Determination of Stellar Atmospheric Parameters Using Iron Non-LTE Line Abundances

Abstract We present new ultra-metal-poor stars parameters with [Fe/H] &lt; −4.0 based on line-by-line non-local thermodynamic equilibrium (NLTE) abundances using an up-to-date iron model atom with a new recipe for non-elastic hydrogen collision rates. We study the departures from LTE in their atmospheric parameters and show that they can grow up to ∼1.00 dex in [Fe/H], ∼150 K in and ∼0.5 dex in log g toward the lowest metallicities. Accurate NLTE atmospheric stellar parameters, in particular [Fe/H] being significantly higher, are the first step to eventually providing full NLTE abundance patterns that can be compared with Population III supernova nucleosynthesis yields to derive properties of the first stars. Overall, this maximizes the potential of these likely second-generation stars to investigate the early universe and how the chemical elements were formed.

Influence of inelastic collisions with hydrogen atoms on the non-LTE modelling of Ca i and Ca ii lines in late-type stars

We perform the non-local thermodynamic equilibrium (NLTE) calculations for Ca I-II with the updated model atom that includes new quantum-mechanical rate coefficients for Ca I + H I collisions from two recent studies, that is, by Barklem and by Mitrushchenkov, Guitou, Belyaev, Yakovleva, Spielfiedel, and Feautrier, and investigate the accuracy of calcium abundance determinations using the Sun, Procyon, and five metal-poor (MP) stars with well-determined stellar parameters. We show that both collisional recipes lead to very similar NLTE results. When using the subordinate lines of Ca I and the high-excitation lines of Ca II, NLTE provides the smaller line-to-line scatter compared with the LTE case for each star. For Procyon, NLTE removes a steep trend with line strength among strong Ca I lines seen in LTE and leads to consistent [Ca/H] abundances from the two ionisation stages. In the MP stars, the NLTE abundance from Ca II 8498 A agrees well with that from the Ca I subordinate lines. NLTE largely removes abundance discrepancies between the high-excitation lines of Ca I and Ca II 8498 A obtained for our four [Fe/H] < -2 stars under the LTE assumption. We investigate the formation of the Ca I resonance line in the [Fe/H] < -2 stars. Consistent NLTE abundances from the Ca I resonance line and the Ca II lines are found for two hyper metal-poor stars HE0107-5240 and HE1327-2326. We provide the NLTE abundance corrections for 28 lines of Ca I in a grid of model atmospheres suitable for abundance analysis of FGK-type dwarfs and subgiants.

The formation of the Milky Way halo and its dwarf satellites; a NLTE-1D abundance analysis

We present a homogeneous set of accurate atmospheric parameters for a complete sample of very and extremely metal-poor stars in the dwarf spheroidal galaxies (dSphs) Sculptor, Ursa Minor, Sextans, Fornax, Bo\"otes I, Ursa Major II, and Leo IV. We also deliver a Milky Way (MW) comparison sample of giant stars covering the -4 < [Fe/H] < -1.7 metallicity range. We show that, in the [Fe/H] > -3.5 regime, the non-local thermodynamic equilibrium (NLTE) calculations with non-spectroscopic effective temperature (Teff) and surface gravity (log~g) based on the photometric methods and known distance provide consistent abundances of the Fe I and Fe II lines. This justifies the Fe I/Fe II ionisation equilibrium method to determine log g for the MW halo giants with unknown distance. The atmospheric parameters of the dSphs and MW stars were checked with independent methods. In the [Fe/H] > -3.5 regime, the Ti I/Ti II ionisation equilibrium is fulfilled in the NLTE calculations. In the log~g - Teff plane, all the stars sit on the giant branch of the evolutionary tracks corresponding to [Fe/H] = -2 to -4, in line with their metallicities. For some of the most metal-poor stars of our sample, we hardly achieve consistent NLTE abundances from the two ionisation stages for both iron and titanium. We suggest that this is a consequence of the uncertainty in the Teff-colour relation at those metallicities. The results of these work provide the base for a detailed abundance analysis presented in a companion paper.

NLTE abundances of C, O, Ca, Ti, and Fe in the reference BAF-type stars

AbstractWe present accurate methods of abundance determination based on the non-local thermodynamic equilibrium (NLTE) line formation for carbon, oxygen, calcium, titanium, and iron in the atmospheres of BAF-type stars. For C I-II, O I, Ca I-II, and Ti I-II, their comprehensive model atoms were described in our previous papers. A fairly complete model atom of Fe I-II is first applied in this study. We determine the NLTE abundances of the nine BAF-type stars with well-determined atmospheric parameters, using high-resolution and high signal-to-noise ratio spectral observations in the broad wavelength range, from the UV to the IR. For C, Ca, Ti, and Fe, NLTE leads to consistent abundances from the lines of the two ionisation stages. The C I, Ca II, and Fe II emission lines were detected in the near IR spectrum of the late B-type subgiant star HD 160762. They are well reproduced in the classical hydrostatic model atmosphere, when applying our NLTE methods.

NLTE carbon abundance determination in selected A- and B-type stars and the interpretation of C i emission lines

We constructed a comprehensive model atom for C\ione\ -- C\ii\ using the most up-to-date atomic data available and evaluated the non-local thermodynamic equilibrium (NLTE) line formation for C\ione\ and C\ii\ in classical 1D models representing the atmospheres of A and late B-type stars. Our NLTE calculations predict the emission that appears at effective temperature of 9250 to 10\,500~K depending on log~$g$ in the C\ione\ 8335, 9405\,\AA\ singlet lines and at \Teff~$>$~15\,000~K (log~$g$ = 4) in the C\ione\ 9061 -- 9111\,\AA\,, 9603 -- 9658\,\AA\, triplet lines. A prerequisite of the emission phenomenon is the overionization-recombination mechanism resulting in a depopulation of the lower levels of C\ione\ to a greater extent than the upper levels. Extra depopulation of the lower levels of the transitions corresponding to the near-infrared lines, is caused by photon loss in the UV lines C\ione\ 2479, 1930, and 1657\,\AA. We analysed the lines of C\ione\ and C\ii\ in Vega, HD~73666, Sirius, 21~Peg, $\pi$~Cet, HD~22136, and $\iota$ Her taking advantage of their observed high-resolution spectra. The C\ione\ emission lines were detected in the four hottest stars, and they were well reproduced in our NLTE calculations. For each star, the mean NLTE abundances from lines of the two ionization stages, C\ione\ and C\ii, including the C\ione\ emission lines, were found to be consistent. We show that the predicted C\ione\ emission phenomenon depends strongly on whether accurate or approximate electron-impact excitation rates are applied.

Grid of theoretical NLTE equivalent widths of four Ba ii lines and barium abundance in cool stars

We present a grid of computed non-local thermodynamic equilibrium (NLTE) equivalent widths (EW) and NLTE abundance corrections for four Ba II lines: 4554, 5853, 6141, and 6496 A. The grid can be useful in deriving the NLTE barium abundance in stars having parameters in the following ranges: effective temperature from 4000 K to 6500 K, surface gravity log g from 0 to 5, microturbulent velocity 0 km s^-1 to 3 km s^-1, metallicity [Fe/H] from -2 to +0.5, and [Ba/Fe] from -0.4 to +0.6. The NLTE abundance can be either derived by EW interpolation (using the observed Ba II line EW) or by using the NLTE correction applied to a previously determined LTE abundance. Ba II line equivalent widths and the NLTE corrections were calculated using the updated MULTI code and the Ba II atomic model that was previously applied to determine the NLTE barium abundance in different types of stars. The grid is available on-line through the web, and we find that the grid Ba NLTE corrections are almost as accurate as direct NLTE profile fitting (to within 0.05-0.08 dex). For the weakest Ba II line (5853 A) the LTE abundances almost agree with the NLTE abundances, whereas the other three Ba II lines, 4554, 6141, and 6496 A, need NLTE corrections even at the highest metallicities tested here. The 4554 A line is extremely strong and should not be used for abundance analysis above [Fe/H]= -1. Furthermore, we tested the impact of different model atmospheres and spectrum synthesis codes and found average differences of 0.06 dex and 0.09 dex, respectively, for all four lines. At these metallicities we find an average Delta NLTE of +/-0.1 dex for the three useful Ba lines for subsolar cool dwarfs.

SYSTEMATIC Non-LTE STUDY OF THE −2.6 ≤ [Fe/H] ≤ 0.2 F AND G DWARFS IN THE SOLAR NEIGHBORHOOD. I. STELLAR ATMOSPHERE PARAMETERS

We present atmospheric parameters for 51 nearby FG dwarfs uniformly distributed over the -2.60 < [Fe/H] < +0.20 metallicity range that is suitable for the Galactic chemical evolution research. Lines of iron, Fe I and Fe II, were used to derive a homogeneous set of effective temperatures, surface gravities, iron abundances, and microturbulence velocities. We used high-resolution (R>60000) Shane/Hamilton and CFHT/ESPaDOnS observed spectra and non-local thermodynamic equilibrium (NLTE) line formation for Fe I and Fe II in the classical 1D model atmospheres. The spectroscopic method was tested with the 20 benchmark stars, for which there are multiple measurements of the infrared flux method (IRFM) Teff and their Hipparcos parallax error is < 10%. We found NLTE abundances from lines of Fe I and Fe II to be consistent within 0.06 dex for every benchmark star, when applying a scaling factor of S_H = 0.5 to the Drawinian rates of inelastic Fe+H collisions. The obtained atmospheric parameters were checked for each program star by comparing its position in the log g-Teff plane with the theoretical evolutionary track in the Yi et al. (2004) grid. Our final effective temperatures lie in between the T_IRFM scales of Alonso et al. (1996) and Casagrande et al. (2011), with a mean difference of +46 K and -51 K, respectively. NLTE leads to higher surface gravity compared with that for LTE. The shift in log g is smaller than 0.1 dex for stars with either [Fe/H] > -0.75, or Teff < 5750 K, or log g > 4.20. NLTE analysis is crucial for the VMP turn-off and subgiant stars, for which the shift in log g between NLTE and LTE can be up to 0.5 dex. The obtained atmospheric parameters will be used in the forthcoming papers to determine NLTE abundances of important astrophysical elements from lithium to europium and to improve observational constraints on the chemo-dynamical models of the Galaxy evolution.

A non-LTE spectral analysis of the3He and4He isotopes in the HgMn starκCancri

We present a pilot study on non-local thermodynamic equilibrium (NLTE) line-formation computations for the isotopes 3He and 4He in the mercury-manganese star kappa Cancri. The impact of NLTE effects on the determination of isotopic abundances and the vertical stratification of helium in the atmosphere is investigated. Modern NLTE line-formation computations were employed to analyse a high-resolution and high signal-to-noise ratio ESO-VLT/UVES spectrum of kap Cnc. The atmospheric parameters were determined from fitting the hydrogen Balmer lines and the spectral energy distribution. Multiple HeI lines were investigated, including HeI 4921A and 6678A, which show the widest isotopic splits. Half of the observed HeI lines in the spectrum of kap Cnc show significant NLTE strengthening, the effects are strongest in the red lines HeI 5875A and HeI 6678A. NLTE abundances from individual HeI lines are up to a factor of about 3 lower than LTE values. Helium is found to be stratified in the atmosphere of kap Cnc. While the LTE analysis indicates a step-like profile of the helium abundance, a gradual decrease with height is indicated by the NLTE analysis. A 3He/4He ratio of about 0.25-0.30 is found. With the available data it cannot be decided whether the two isotopes follow the same stratification profile, or not. This work implies that NLTE effects may be ubiquitous in the atmospheres of HgMn stars and may have a significant impact on abundance determinations and the interpretation of the vertical abundance stratification of elements.