Gaining insight into groundwater chemistry and its evolution in irrigation areas is essential for optimizing irrigation strategies. This study explores the origins and influencing variables of groundwater chemistry across both irrigated and non-irrigated areas of the Guanzhong Plain, aiming to elucidate how irrigation practices impact hydrochemical changes. Hydrochemical data, isotopic data, multivariate statistical techniques and hydrochemical methods were used in this study. The findings underscored that groundwater in non-irrigation areas had low total dissolved solids, with 90% of the groundwater samples exhibiting the HCO3-Ca•Mg type. In comparison, groundwater from irrigation areas showed elevated total dissolved solids levels and diverse hydrochemical types, including HCO3-Ca•Mg, HCO3-Na, and SO4•Cl-Ca•Mg types. These categories collectively represented 88% of the water samples from irrigation areas. Isotopic and hydrochemical analyses revealed that groundwater in irrigation areas experienced more intense evaporation and cation exchange. Furthermore, anthropogenic activities like sewage and manure had a more pronounced effect on groundwater chemistry in irrigation areas. Groundwater suitability for irrigation deteriorated from the western irrigation area to the eastern irrigation area. This research offers a robust scientific foundation for the careful management and conservation of groundwater resources in the region.
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