Let $({\mathcal X},d,\mu)$ be a metric measure space satisfying both the geometrically doubling and the upper doubling conditions. Let $\rho\in (1,\infty)$, $0<p\le1\le q\le\infty$, $p\neq q$, $\gamma\in[1,\infty)$ and $\epsilon\in(0,\infty)$. In this article, the authors introduce the atomic Hardy space ${\widetilde H_{\mathrm{atb},\,\rho}^{p,\,q,\,\gamma}(\mu)}$ and the molecular Hardy space ${\widetilde H_{\rm{mb},\,\rho}^{p,\,q,\,\gamma,\,\epsilon}(\mu)}$ via the discrete coefficient $\widetilde{K}^{(\rho),\,p}_{B,\,S}$, and prove that the Calder\'on-Zygmund operator is bounded from ${\widetilde H_{\rm{mb},\,\rho}^{p,\,q,\,\gamma,\,\delta}(\mu)}$ (or ${\widetilde H_{\rm{atb},\,\rho}^{p,\,q,\,\gamma}(\mu)}$) into $L^p(\mu)$, and from ${\widetilde H_{\rm{atb},\,\rho(\rho+1)}^{p,\,q,\,\gamma+1}(\mu)}$ into ${\widetilde H_{\rm{mb},\,\rho}^{p,\,q,\,\gamma,\,\frac12(\delta -\frac{\nu}{p}+\nu)}(\mu)}$ whose genealized fractional versions are also obtained. The authors also introduce the $\rho$-weakly doubling condition, with $\rho\in (1,\infty)$, of the measure $\mu$ and construct a non-doubling measure $\mu$ satisfying this condition. If $\mu$ is $\rho$-weakly doubling, the authors further introduce the Campanato space ${\mathcal E}^{\alpha,\,q}_{\rho,\,\eta,\,\gamma}(\mu)$ and show that ${\mathcal E}^{\alpha,\,q}_{\rho,\,\eta,\,\gamma}(\mu)$ is independent of the choices of $\rho$, $\eta$, $\gamma$ and $q$; the authors then introduce the atomic Hardy space $\widehat H_{\rm{atb},\,\rho}^{p,\,q,\,\gamma}(\mu)$ and the molecular Hardy space $\widehat H_{\rm{mb},\,\rho}^{p,\,q,\,\gamma,\,\epsilon}(\mu)$, which coincide with each other; the authors finally prove that $\widehat{H}_{\rm{atb},\,\rho}^{p,\,q,\,\gamma}(\mu)$ is the predual of ${\mathcal E}^{1/p-1,\,1}_{\rho,\,\rho,\,1}(\mu)$. Moreover, relations of these Hardy spaces are also discussed.
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