Nonclassical Behavior Research Articles

Hybrid lattice Boltzmann method for turbulent nonideal compressible fluid dynamics

The development and application of a compressible hybrid lattice Boltzmann method to high Mach number supercritical and dense gas flows are presented. Dense gases, especially in Organic Rankine Cycle turbines, exhibit nonclassical phenomena that offer the possibility of enhancing turbine efficiency by reducing friction drag and boundary layer separation. The proposed numerical framework addresses the limitations of conventional lattice Boltzmann method in handling highly compressible flows by integrating a finite-volume scheme for the total energy alongside a nonideal gas equation of state supplemented by a transport coefficient model. Validations are performed using a shock tube and a three-dimensional Taylor–Green vortex flow. The capability to capture nonclassical shock behaviors and compressible turbulence is demonstrated. Our study gives the first analysis of a turbulent Taylor–Green vortex flow in a dense Bethe–Zel'dovich–Thompson gas and provides comparisons with perfect gas flow at equivalent Mach numbers. The results highlight differences associated with dense gas effects and contribute to a broader understanding of nonideal fluid dynamics in engineering applications.

Non-Classical Heat Transfer and Recent Progress

Abstract Heat transfer in solids has traditionally been described by Fourier's law, which assumes local equilibrium and a diffusive transport regime. However, advancements in nanotechnology and the development of novel materials have revealed non-classical heat transfer phenomena that extend beyond this traditional framework. These phenomena, which can be broadly categorized into those governed by kinetic theory and those extending beyond it, include ballistic transport, phonon hydrodynamics, coherent phonon transport, Anderson localization, and glass-like heat transfer, among others. Recent theoretical and experimental studies have focused on characterizing these non-classical behaviors using methods such as the Boltzmann transport equation, molecular dynamics, and advanced spectroscopy techniques. In particular, the dual nature of phonons, exhibiting both particle-like and wave-like characteristics, is fundamental to understanding these phenomena. This review summarizes state-of-the-art findings in the field, highlighting the importance of integrating both particle and wave models to fully capture the complexities of heat transfer in modern materials. The emergence of new research areas, such as chiral and topological phonons, further underscores the potential for advancing phonon engineering. These developments open up exciting opportunities for designing materials with tailored thermal properties and new device mechanisms, potentially leading to applications in thermal management, energy technologies, and quantum science.

Observation of micropolar modes in the transmission of acoustic waves at oblique incidence by polystyrene plates.

This study investigates micropolar plates through the analysis of transmitted acoustic waves at various incident angles. Using a combined theoretical and experimental approach, we explore the non-classical elasto-dynamic behavior of these materials. Theoretical transmission coefficients are tailored to highlight generalized Lamb modes and a new type of vibration mode called micropolar modes, considering the constant thickness of the plate and the effects of material micropolarity on linear elasticity. Overlaying diverse transmission coefficients for different angles provides insight into micropolar behavior, aiding in the understanding of mode evolution in the frequency domain and the estimation of the critical angle. We employ two types of low-density closed-cell foams made from polystyrene (expanded in one case, extruded in the other), covering a frequency range from 4 to 60 kHz using a tweeter loudspeaker and a microphone integrated with a National Instruments acquisition system. Identification of the first vibration mode of the plates is facilitated by the frequency range rich in low frequencies. Additionally, all responses exhibit supersonic velocities with substantial attenuations. The originality of this paper is twofold: it provides theoretical predictions of micropolar modes, along with their experimental observations above a critical angle of incidence. Consequently, this research enriches our understanding of micropolar materials and their potential contribution to effective noise reduction strategies in acoustic engineering.

Mitigating Scattering in a Quantum System Using Only an Integrating Sphere

Strong quantum correlated sources are essential but delicate resources for quantum information science and engineering protocols. Decoherence and loss are the two main disruptive processes that lead to the loss of nonclassical behavior in quantum correlations. In quantum systems, scattering can contribute to both decoherence and loss. In this work, we present an experimental scheme capable of significantly mitigating the adverse impact of scattering in quantum systems. Our quantum system is composed of a two-mode squeezed light generated with the four-wave-mixing process in hot rubidium vapor and a scatterer is introduced to one of the two modes. An integrating sphere is then placed after the scatterer to recollect the scattered photons. We use mutual information between the two modes as the measure of quantum correlations and demonstrate a 47.5% mutual information recovery from scattering, despite an enormous photon loss of greater than 85%. Our scheme is the very first step toward recovering quantum correlations from disruptive random processes and thus has the potential to bridge the gap between proof-of-principle demonstrations and practical real-world implementations of quantum protocols. Published by the American Physical Society 2024

Probing quantum discord and coherence dynamics in the discrete-time quantum walk under generalized amplitude damping noise channel

We investigate the behaviour of one-dimensional dissipative Hadamard discrete-time quantum walk (DTQW) in the generalized amplitude damping channel. By manipulating the noise intensity, we uncover intriguing dynamics in the coherence of the coin state such as rebounding and freezing phenomena. The entanglement between the quantum walker’ states diminishes at lower dissipation rates despite the pronounced coherence. The non-classical characters of the dissipative DTQW becomes evident through the manifestation of quantum discord. Our study shows that even under maximum dissipation stemming from both zero and finite-temperature environment, the quantum walker retains rudimentary non-classical behaviours. It is shown that fine-tuning the parameter governing the coin rotation angle optimizes the quantum discord of the walker. These results are useful for optimizing quantum walks in the presence of noisy channels.

Stable acceptance for mighty knowledge

Drawing on the puzzling behavior of ordinary knowledge ascriptions that embed an epistemic (im)possibility claim, we tentatively conclude that it is untenable to jointly endorse (i) an unfettered classical logic for epistemic language, (ii) the general veridicality of knowledge ascription, and (iii) an intuitive ‘negative transparency’ thesis that reduces knowledge of a simple negated ‘might’ claim to an epistemic claim without modal content. We motivate a strategic trade-off: preserve veridicality and (generalized) negative transparency, while abandoning the general validity of contraposition. We criticize various approaches to incorporating veridicality into domain semantics, a paradigmatic ‘information-sensitive’ framework for capturing negative transparency and, more generally, the non-classical behavior of sentences with epistemic modals. We then present a novel information-sensitive semantics that successfully executes our favored strategy: stable acceptance semantics, extending a vanilla bilateral state-based semantics for epistemic modals with a knowledge operator loosely inspired by the defeasibility theory of knowledge.

Structural pathway for nucleation and growth of topologically close-packed phase from parent hexagonal crystal

The solid diffusive phase transformation involving the nucleation and growth of new phase particles is universal and frequently employed but has not yet been fully understood at the atomic level. Here, our first-principles calculations reveal a structural formation pathway of a series of topologically close-packed (TCP) phases within the hexagonally close-packed (hcp) matrix. The results show that the nucleation follows a nonclassical nucleation process, and apart from atomic diffusion, the entire hcp→TCP transformation only involves shuffle-based displacements, with a specific 3-layer unstable hcp-ordering serving as the basic structural transformation unit (BSTU). The thickening of plate-like TCP phases relies on the formation of these unstable hcp-orderings at their coherent TCP/matrix interface to nucleate a ledge, but the ledge lacks the dislocation characteristics which is commonly considered in the conventional view. Additionally, the atomic structure of the critical nucleus for the Mg2Ca and MgZn2 Laves phases was predicted in terms of Classical Nucleation Theory (CNT). The formation of polytypes and off-stoichiometry in TCP precipitates is found to be related to the nonclassical nucleation behavior. These insights contribute to a deeper understanding of solid diffusive phase transformations at the atomic level and provide a foundation for investigating other technologically significant transformations.

Signatures of Topological States in Conjugated Macrocycles.

Single-molecule electrical junctions possess a molecular core connected to source and drain electrodes via anchor groups, which feed and extract electricity from specific atoms within the core. As the distance between electrodes increases, the electrical conductance typically decreases, which is a feature shared by classical Ohmic conductors. Here we analyze the electrical conductance of cycloparaphenylene (CPP) macrocycles and demonstrate that they can exhibit a highly nonclassical increase in their electrical conductance as the distance between electrodes increases. We demonstrate that this is due to the topological nature of the de Broglie wave created by electrons injected into the macrocycle from the source. Although such topological states do not exist in isolated macrocycles, they are created when the molecule is in contact with the source. They are predicted to be a generic feature of conjugated macrocycles and open a new avenue to implementing highly nonclassical transport behavior in molecular junctions.

Toward local Madelung mechanics in spacetime

It has recently been shown that relativistic quantum theory leads to a local interpretation of quantum mechanics wherein the universal wavefunction in configuration space is entirely replaced with an ensemble of local fluid equations in spacetime. For want of a fully relativistic quantum fluid treatment, we develop a model using the nonrelativistic Madelung equations, and obtain conditions for them to be local in spacetime. Every particle in the Madelung fluid is equally real, and has a definite position, momentum, kinetic energy, and potential energy. These are obtained by defining quantum momentum and kinetic energy densities for the fluid and separating the momentum into average and symmetric parts, and kinetic energy into classical kinetic and quantum potential parts. The two types of momentum naturally give rise to a single classical kinetic energy density, which contains the expected kinetic energy, even for stationary states, and we define the reduced quantum potential as the remaining part of the quantum kinetic energy density. We treat the quantum potential as a novel mode of internal energy storage within the fluid particles, which explains most of the nonclassical behavior of the Madelung fluid. For example, we show that in tunneling phenomena, the quantum potential negates the barrier so that nothing prevents the fluid from flowing through. We show how energy flows and transforms in this model, and that enabling local conservation of energy requires defining a quantum potential energy current that flows through the fluid rather than only flowing with it. The nonrelativistic treatment generally contains singularities in the velocity field, which undermines the goal of local dynamics, but we expect a proper relativistic treatment will bound the fluid particle velocities at c.

New angular momentum coherent states via the nonlinear Bose SU(2) generators and their nonclassical behaviors

I theoretically construct a kind of new angular momentum coherent states by virtue of the nonlinear Bose SU(2) generators, and investigate their nonclassicality by analyzing the sub-Poissonian distributions, photon number distributions, entanglement entropy and Wigner phase-space distributions. The results show that the new states always have the sub-Poissonian distributions for all of the photon number sum [Formula: see text] of two modes, the photon number distributions are subjected to the parameter q, and the entanglement always increases quickly and then decreases slowly with increasing [Formula: see text], and the new states for odd q possess more stronger nonclassicality than for even q.

Nonclassical symmetries, optimal classification, and dynamical behavior of similarity solutions of (3+1)-dimensional Burgers equation

This paper is devoted to the study of symmetry group classification, and optimal subalgebras of the three-dimensional Burgers equation, which describes nonlinear wave motion exhibits nonlinear effects and enhanced dispersion in the context of nonlinear dynamics. The equation undergoes a Painlevé analysis to assess its integrability properties to verify the possibility that it passes the Painlevé test, followed by the derivation of nonclassical symmetries. Utilizing the invariance property of Lie groups, desirable infinitesimal symmetries of Lie algebra have been outlined for the equation. Relying on the invariance characteristic of adjoint transformation along with the newly generated similarity variables, an intensive and systematically organized approach is employed to achieve a one-dimensional optimal system. The entire set of group invariant solutions for each of the associated subalgebras has been established. The dynamical behavior of derived exact solutions is examined using numerical simulations, and numerous intriguing occurrences are discovered, such as flat sheet, periodic wave, doubly soliton, multisoliton, bright-dark soliton, breather soliton, line soliton type, which offer valuable insights into the dynamics of the system and can predict the behavior of waves in real-world scenarios.

Slow dynamics and the role of moisture

The elastic behavior of rocks and other composite materials cannot be entirely captured by the traditional theory of nonlinear elasticity, where the stress field is related to powers of the strain field. Rather, these materials display non-classical nonlinear elastic behavior, such as hysteresis, end-point memory, fast dynamics, and slow dynamics. Slow dynamics (SD) is characterized by a drop in material stiffness due to a minor mechanical conditioning, followed by a slow recovery back to the original macroscopic elastic state. SD has drawn particular attention because the recovery, often logarithmic in time, has been observed in a wide variety of materials, on lengths scales from the laboratory to the seismic, and on time scales from milliseconds to years. The universal character suggests a simple, fundamental mechanism for the SD recovery. This talk will present recent experiments that seek to test proposed SD mechanisms. In particular, the role of moisture will be investigated. The main experimental venue is the simplified structure introduced in previous work—a single bead confined between two slabs of a similar material. The main benefit of this structure over more commonly studied SD materials (sandstones and concrete) is the ability to control the environment around the contact points.

NONCLASSICAL PROPERTIES OF TWO-MODE DISPLACED FOCK STATE

In this paper, we investigate a variety of nonclassical properties of a two-mode displaced Fock state (TMDFS). Nonclassical properties such as sum squeezing, difference squeezing, antibunching effect, and the Cauchy-Schwarz inequality will be discussed analytically for the TMDFS. The results show that by changing the Fock state parameters between modes and the displacement parameter, the TMDFS exhibits enhanced nonclassical behaviors and makes a valuable contribution to quantum optics.

Quantum dynamics of excited state proton transfer in green fluorescent protein.

Photoexcitation of green fluorescent protein (GFP) triggers long-range proton transfer along a "wire" of neighboring protein residues, which, in turn, activates its characteristic green fluorescence. The GFP proton wire is one of the simplest, most well-characterized models of biological proton transfer but remains challenging to simulate due to the sensitivity of its energetics to the surrounding protein conformation and the possibility of non-classical behavior associated with the movement of lightweight protons. Using a direct dynamics variational multiconfigurational Gaussian wavepacket method to provide a fully quantum description of both electrons and nuclei, we explore the mechanism of excited state proton transfer in a high-dimensional model of the GFP chromophore cluster over the first two picoseconds following excitation. During our simulation, we observe the sequential starts of two of the three proton transfers along the wire, confirming the predictions of previous studies that the overall process starts from the end of the wire furthest from the fluorescent chromophore and proceeds in a concerted but asynchronous manner. Furthermore, by comparing the full quantum dynamics to a set of classical trajectories, we provide unambiguous evidence that tunneling plays a critical role in facilitating the leading proton transfer.

Implementation of a modified Graham-Walles viscosity function within a Chaboche viscoplastic constitutive model

This work provides a numerical framework for the accurate prediction of operational life of metallic components exhibiting a non-classical creep behavior under constant loadings and very high temperature. A modified Graham-Walles type analytical viscoplastic function is implemented into a Chaboche unified viscoplastic constitutive model. The numerical model is integrated into the finite element software Lagamine following a fully-implicit two-step radial return mapping algorithm. The non-linear system of equations is solved using a robust Newton-Raphson method. The computational efficiency of the model is enhanced by implementing a sub-step routine, thereby decreasing the average number of iterations of the finite element software. The validation of the model is performed using experimental data available in the literature on the non-classical creep behavior of Incoloy 800H, a Ni-superalloy exhibiting a two-step creep strain rate minima attributed to multiple complex dislocation-precipitate interactions.

Preparation of non-Gaussian states based on three-photon quantum scissors

We investigate the properties of non-Gaussian quantum states generated by a three-photon quantum scissor (3-QS). Three different types of inputs to the 3-QS are considered: coherent state (CS), squeezed vacuum state (SVS), and optical field thermal state (TS). We discuss both the detection probability and fidelity of the output states. Our results demonstrate that when the input states have a smaller mean photon number, the output non-Gaussian state can exhibit high detection probability and high fidelity by selecting an appropriate transmissivity. Additionally, we calculate the Wigner functions for the various output states and analyze the non-classical properties by comparing the negative volume of the Wigner functions. The results indicate that the output non-Gaussian states display significant non-classical behavior, particularly when the transmissivity is high, with SVS as the input state showing the strongest effect. Moreover, we compare the performance of the 3-QS with that of the two-photon quantum scissors (2-QS). The findings demonstrate that the non-Gaussian states prepared by the 3-QS possess stronger non-classical characteristics. These results have potential implications for advancing the practical application of the 3-QS in quantum information technology.

Scalable simulation of coupled adsorption and transport of methane in confined complex porous media with density preconditioning

The growing significance of shales and tight formations in the transition to less carbon-intensive and clean energy drives the research endeavor to understand the physics of gas flow within these systems. However, shales are composed of massively heterogeneous physical and chemical features. Most nano-sized pores connect to millimeter-scale fractures, leading to multiscale transport. These nano-scale pore throats demonstrate non-classical flow behavior, such as non-negligible slip velocities and adsorbed gas layers at the boundary. As a result, classical computational fluid dynamics models do not capture the physics. In this work, we develop a coupling scheme for the multiple-relaxation-time (MRT) lattice Boltzmann (LB) method that integrates the Peng-Robinson equation of state into a pseudo-potential interaction model to capture the physics of methane flow in irregular networks of channels that represent nano-scale porous media. We use atomistic simulations to calibrate and validate our model in slit nano-channels. We propose a preconditioning scheme to initialize the coupled transport and adsorption simulation of methane in complex porous media. The results of this implementation of LB agree with Direct Simulation Monte Carlo (DSMC) and Molecular Dynamics (MD) simulations. We then scale up the LB implementation through vectorization and indirect addressing. We parallelize it using Message Passing Interface (MPI) and OpenMP frameworks to simulate transport and adsorption in complex media with a million lattices. We analyze the differences between coupled and transport-only simulations in two case studies and show that considering phase behavior, i.e., adsorption, can significantly change the flow behavior. This work constitutes an important step towards bridging the gap between molecular flow and system-scale behavior of complex disordered porous media.

Magnon statistical properties in multiphoton-catalyzed optomagnonics

Generating magnon states with the nonclassical behavior is a key step of implementing quantum magnonic technologies for applications. We proposed a strategy of magnonic state production by using the conditional measurement, derived from the jointed action of a cavity optomagnonics device and a beam splitter. At the case of the quantum catalysis applying to the optical field of optomagnonic system, the characters of yielding catalyzed state rely not only upon the parameters of optomechanic system but also upon the catalysis photon number and the beam splitter angle. We theoretically create a kind of the catalyzed photon–magnon entangled state and examine the statistical properties of the magnon mode of two mode optomagnonic states in the fields of the mean magnon number, the magnon number distribution, the Mandel Q parameter, the second-order autocorrelation function and the Wigner function. We demonstrate that the sub-Poisson distribution, the antibunching effect and the Wigner function negativity in the magnons can be realized via multiphoton catalysis. We also find that the magnon nonclassical statistical feature may be regulated by adjusting parameters of photon catalysis. Our work will provide a good reference for producing magnonic nonclassical state.

Investigating the behavior of the slow dynamic recovery at early times

Slow dynamics (SD), a type of non-classical nonlinear elastic behavior, is characterized by (i) a material softening due a minor mechanical conditioning and (ii) a subsequent slow recovery that approaches the original macroscopic elastic state. Early work in sandstones and other consolidated granular materials—and more recent work in unconsolidated granular materials—have found the recovery to be logarithmic-in-time, at least for seconds to hours after conditioning. However, other recent studies have observed recoveries in consolidated granular materials that deviate from log(time), particularly for early recovery times. This talk will present experimental investigations in to the nature of the SD recovery, especially at early times. The experimental venue will be the single bead system (a single bead confined between two large plates of a similar material) introduced previously. We will measure SD recoveries using multiple methods, such as Dynamic Acoustic Emission Testing (DAET) and Larsen Monitoring, to better compare our experiments with previous work. The effect of different conditioning mechanisms on the early time recovery will also be investigated. The presentation will conclude with some discussion of proposed mechanisms for slow dynamics.

The emergence of quantum energy science

Quantum engineering seeks to create novel technologies based on the exploitation of distinctly nonclassical behaviors such as quantum coherence. The vast majority of currently pursued applications fall into the domain of quantum information science, with quantum computing as the most visible subdomain. However, other applications of quantum engineering are fast emerging. Here, we review the deployment of quantum engineering principles in the fields of solar energy, batteries, and nuclear energy. We identify commonalities across quantum engineering approaches in those apparently disparate fields and draw direct parallels to quantum information science. We find that a shared knowledge base is forming, which de facto corresponds to a new domain that we refer to as ‘quantum energy science’. Quantum energy science bears the promise of substantial performance improvements across energy technologies such as organic solar cells, batteries, and nuclear fusion. The recognition of this emerging domain may be of great relevance to actors concerned with energy innovation. It may also benefit active researchers in this domain by increasing visibility and motivating the deployment of resources and institutional support.