Nitrogen Co-doped Porous Carbon Research Articles

In-situ doped and activated N, S co-doped porous carbon derived from organic salt for application in high-performance potassium-ion batteries

Owing to its abundance in nature and low cost, potassium has attracted considerable attention as a substitute for lithium in the manufacture of secondary-ion batteries. However, developing amorphous carbon materials that show fast K+ ion kinetics for application in high-performance potassium-ion battery (PIB) anodes remains challenging. In this study, we designed and synthesized a 3-D hierarchical nitrogen and sulfur co-doped porous carbon electrode via in-situ doping and activation using acesulfame potassium. Owing to its prominent structural advantages, the as-prepared N, S co-doped electrode showed a high reversible capacity (459.8 mAh g−1 at 0.05 A g−1) and long-term cycle stability (205 mAh g−1 after 1000 cycles at 0.5 A g−1). Further, the results of ex-situ Raman spectroscopy and X-ray photoelectron spectroscopy verified the advantages of N and S co-doping with respect to K+ ion intercalation and adsorption/desorption properties within the carbon matrix. Therefore, our findings enhance understanding regarding the advantages of the dual-doped system with respect to K+ ion storage and highlight an efficient strategy for developing high-performance and durable carbon anode materials for PIBs.

ZIF-8-Based Nitrogen and Monoatomic Metal Co-Doped Pyrolytic Porous Carbon for High-Performance Supercapacitor Applications.

Metal-organic frameworks (MOFs) receive wide attention owing to their high specific surface area, porosity, and structural designability. In this paper, ZC-Ru and ZC-Cu electrodes loaded with monatomic Ru and Cu doped with nitrogen were prepared by pyrolysis, ion impregnation, and carbonization process using ZIF-8 synthesized by static precipitation as a precursor. ZC-Cu has a high specific surface area of 859.78 m2 g-1 and abundant heteroatoms O (10.04%) and N (13.9%), showing the specific capacitance of 222.21 F g-1 at 0.1 A g-1 in three-electrode system, and low equivalent series resistance (Rct: 0.13 Ω), indicating excellent energy storage capacity and electrical conductivity. After 10,000 cycles at 1 A g-1 in 6 M KOH electrolyte, it still has an outstanding capacitance retention of 99.42%. Notably, symmetric supercapacitors ZC-Cu//ZC-Cu achieved the maximum power density and energy density of 485.12 W·kg-1 and 1.61 Wh·kg-1, respectively, positioning ZC-Cu among the forefront of previously known MOF-based electrode materials. This work demonstrates the enormous potential of ZC-Cu in the supercapacitor industry and provides a facile approach to the treatment of transition metal.

Nitrogen and Sulfur Co-doped Biomass-Derived Porous Carbon Electrodes for Ultra-High-Performance All-Aqueous Thermally Regenerative Flow Batteries.

Developing high-performance electrodes for the all-aqueous thermally regenerative ammonia battery (ATRB) system, serving as superior substitutes for commercial carbon cloth electrodes, is anticipated to enhance performance, yet it lacks effective guidance and research. In this work, theoretical analysis is initially used to evaluate the effective conversion and adsorption capacity of nitrogen and sulfur co-doped carbon with respect to copper ion by density functional theory calculation. On the basis of this concept, the nitrogen and sulfur co-doped biomass-derived porous carbon electrode (DGC) is prepared using natural porous carbon materials and thiourea. Compared with commercial carbon cloth electrodes, ATRB with DGC achieves a significant improvement in maximum power density of 49.2%. Via optimization of the doping conditions, the active sites can be effectively regulated to boost charge transfer at the reaction interface. Furthermore, the rapid charge transfer can match the excellent mass transfer performance, generating an impressive net power density of 847.5 W/m2.

Phosphorus and Nitrogen Codoped Porous Carbon Nanosheets for Energy Storage and Gas Adsorption

Phosphorus and Nitrogen Codoped Porous Carbon Nanosheets for Energy Storage and Gas Adsorption

Biomass carbon aerogels by polyatomic synergistic modification and synchronous activation for supercapacitors

The regulation and modification of carbon aerogel are essential for the construction of supercapacitors electrode with high energy density. Heteroatom doping has also been used in the modification of carbon aerogels to further improve the properties of materials. In this work, nitrogen and sulfur co-doped porous biomass carbon aerogels (NSPCs) for high-performance supercapacitors were innovatively synthesized by a straightforward and highly efficient one-step gel and synchronous activation strategy. Such a covalently interconnected hierarchical porous structure with co-doped nitrogen and sulfur greatly improves the pore structure and wettability of the materials and forms functional groups to provide additional pseudocapacitance. Owing to these structural advantages and the component synergy, the NSPCs exhibit high electrolyte ion storage ability, unhindered ion channels, and excellent electrochemical performance, and display a specific capacitance of 344.3 F g−1, and a capacitance retention rate of 91.5 % after 10,000 cycles. Additionally, the NSPCs-based symmetric supercapacitor showed a high energy density of 12.82 Wh kg−1.

Insights into the activation of peroxymonosulfate by ZIF-L@ZIF-67 derived CoCN catalyst for highly effective removal of phenol in the presence of chloride ions

A novel catalyst with cobalt and nitrogen-codoped porous carbon matrix (CoCN-900) was successfully prepared, characterized and applied for activating peroxymonosulfate (PMS) to remove phenol in aqueous solution. The CoCN-900 material exhibited superior performance in activating PMS for phenol degradation and could completely remove phenol within 60 min. Radical quenching tests and electron paramagnetic resonance (EPR) analysis showed that 1O2 and SO4•– played a major role in the phenol removal process over the CoCN-900/PMS system. In addition, the influences of catalyst/PMS dose, initial phenol concentration, reaction temperature, natural organic matter and coexisting anions on phenol degradation were systematically investigated. Particularly, it was found that the chloride ions (Cl–) had a significant accelerative effect, increasing the phenol degradation rate from 0.142 to 0.600 min−1. In the presence of Cl–, the phenol degradation efficiency was primarily ascribed to the effects of 1O2 and O2•–, which were significantly different from those in the absence of Cl–. Meanwhile, Cl– could also accelerate the deactivation of the catalyst. Findings in this study provided new insight for the fabrication of high-performance zeolitic imidazolate frameworks (ZIFs)-derived carbon materials and evaluating the influences of anions on the degradation of phenolic contaminants in PMS-based advanced oxidation processes (AOPs).

Unraveling the Ion Uptake Capacitive Deionization of Sea- and Highly Saline-Water by Sulfur and Nitrogen Co-Doped Porous Carbon Modified with Molybdenum Sulfide.

In parallel to the depletion of potable water reservoirs, novel technologies have been developed for seawater softening, as it is the most abundant source for generating deionized water. Although salt removal at subosmotic pressures and ambient temperatures by applying low-operating potentials with high energy efficiency made capacitive deionization (CDI) an advantageous water-softening process, its practical application is limited by insufficient ion removal capacity and low concentration influent. The performance of a CDI system is in progress with engineering the electrode active materials, also facilitating the advance design in highly saline- and seawater study. Herein, an innovative strategy was developed to provide high-performance CDI systems based on efficient and electrochemical ion-uptake active materials with a simple initial preparation. Nitrogen-doped porous carbons (N-pCs) received benefits from a high specific surface area and good surface wettability. The N-pCs were modified with molybdenum oxide/sulfide intercalative array and developed as CDI electrode active materials for desalination of both low/medium saline- and seawater. The MoS2/S,N-pC electrode materials exhibited perfect optimized salt adsorption capacity (SACs) of 47.9 mg g-1 when compared to N-pC (37.9 mg g-1) and MoO3/N-pC (39.6 mg g-1) counterparts at 1.4 V in a 750 ppm NaCl solution. In addition, the assembled CDI cells exhibited reasonable cycle stability and retained 96.7% of their initial SAC in continuous CDI cycles for 128,000 s. The fabricated CDI cell rendered an excellent salt removal efficiency (SRE, %) of 13.34% from the real seawater sample at 1.2 V. In detail, the SRE % of the NaCl, KCl, MgCl2, and CaCl2 soluble salts with respect to seawater sample exhibited a remarkable SRE % of 30.8%, 36%, 32.6%, and 19.3%, respectively. These SRE % values (>13.34%) provide convincing evidence on the reasonable ion uptake capability of the fabricated CDI cells for removing Na+, K+, Mg2+, and Ca2+ ions compared to other soluble component. The advanced cell design parallel to the promising outcomes provided herein makes these CDI systems immensely propitious for efficient water softening.

ZnO quantum dots @ nitrogen and sulfur Co-doped porous carbon nanosheets for the detection of lung cancer biomarkers in exhaled breath

The development of non-selective sensors as an e-nose system for breath analysis application generates unique breath prints delineating the fundamental body metabolism aiding early diagnosis of lung cancer. In this work, size dependent ZnO quantum dots (QDs) were controlled by pH and finely dispersed on nitrogen and sulfur co-doped porous carbon nanosheet (CNS) for exploration of their chemi-resistive gas sensing property. Application of these nanocomposites to different lung cancer biomarkers (toluene, isoprene acetone and benzene) depicts unique responses to each at different operating temperatures. Particularly, the composite with lower ZnO QDs size on sulfur rich porous carbon nanosheet (SC-SQD) exhibited 2.5 times of the response to toluene compared to the composite with higher QDs size and sulfur poor porous carbon nanosheet (NC-LQD) in the concentration range between 1 ppm and 5 ppm. It was demonstrated that for 5 ppm of toluene, a response of 31.4 was observed with a response and recovery time of 18 s and 58 s, respectively. The sensor exhibited an estimated lower limit of detection of 800 ppb. Besides, the sensor exhibited a gradual decrease (∼9.55%) in response to 5 ppm toluene at 90% humidity. This superior performance can be explained by the density of defect states, reactive oxygen species (ROS) and oxidation states of functionalization.

Synthesis of three-dimensional (3D) hierarchically porous iron–nickel nanoparticles encapsulated in boron and nitrogen-codoped porous carbon nanosheets for accelerated water splitting

Designing two-dimensional (2D) porous carbon nanosheets is a promising strategy for enhancing the water-splitting activities of non-noble metal catalysts. In this study, we developed a novel method for synthesizing the novel three-dimensional (3D) hierarchically porous iron–nickel (FeNi) nanoparticles encapsulated in boron (B) and nitrogen (N)-codoped porous carbon nanosheets (denoted as FeNi@BNPCNS). Owing to the advantages of morphology and structure of B and N, 10.31 atom % of B/N active centers were successfully doped into the optimal FeNi@BNPCNS-800 nanosheets. FeNi@BNPCNS-800 exhibited better hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) electrocatalytic activities than control catalysts in an alkaline solution. However, the HER and OER electrocatalytic activities of FeNi@BNPCNS-800 were slightly lower than 20 wt% Pt/C and RuO2. The FeNi@BNPCNS-800||FeNi@BNPCNS-800 electrolyzer achieved 10 mA cm−2 at 1.514 V, which was 73 mV lower than that of 20 wt% Pt/C||RuO2 electrolyzer (1.587 V). The perfect 3D honeycomb-like architectures, abundant mesopores/defects, and abundant electrocatalytic active sites were attributed to the outstanding water-splitting performances of FeNi@BNPCNS-800 nanosheets. This study provides an efficient strategy for the large-scale, rapid, and low-cost fabrication of 2D porous carbon nanosheets without using any template, surfactant, or expensive raw material, thus presenting a simple approach to design advanced non-noble metal electrocatalysts for water splitting.

Phosphorus-Mediated Local Charge Distribution of N-Configuration Adsorption Sites with Enhanced Zincophilicity and Hydrophilicity for High-Energy-Density Zn-Ion Hybrid Supercapacitors.

Tailor-made carbonaceous-based cathodes with zincophilicity and hydrophilicity are highly desirable for Zn-ion storage applications, but it remains a great challenge to achieve both advantages in the synthesis. In this work, a template electrospinning strategy is developed to synthesize nitrogen and phosphorous co-doped hollow porous carbon nanofibers (N, P-HPCNFs), which deliver a high capacity of 230.7 mAh g-1 at 0.2 A g-1 , superior rate capability of 131.0 mAh g-1 at 20 A g-1 , and a maximum energy density of 196.10Wh kg-1 at the power density of 155.53W kg-1 . Density functional theory calculations (DFT)reveal that the introduced P dopants regulate the distribution of local charge density of carbon materials and therefore facilitate the adsorption of Zn ions due to the increased electronegativity of pyridinic-N. Ab initio molecular dynamics (AIMD)simulations indicate that the doped P species induce a series of polar sites and create a hydrophilic microenvironment, which decreases the impedance between the electrode and the electrolyte and therefore accelerates the reaction kinetics. The marriage of ex situ/in situ experimental analyses and theoretical simulations uncovers the origin of the enhanced zincophilicity and hydrophilicity of N, P-HPCNFs for energy storage, which accounts for the faster ion migration and electrochemical processes.

One-step synthesis of nitrogen and sulfur co-doped hierarchical porous carbon derived from acesulfame potassium as a dual-function agent for supercapacitors and lithium‑sulfur batteries

Acesulfame potassium (AK) is an artificial sweetener that contains N and S functional groups in its organic moiety and is suitable as porous carbon precursor. In this study, AK derived carbon (AKC) was obtained via direct carbonization and in situ doping without additives under the dual conditions of inert gas protection and high temperatures. The obtained AKCs exhibited high porosity structure with a specific surface area of 2043 m2 g−1 and 3.22 wt% N and 8.61 wt% S dual heteroatom doping. When applied to the supercapacitor electrode, the AKC ensured a high capacitance of 264 F g−1 at 0.5 A g−1, which maintained 86.1 % of the initial capacitance after 5000 cycles at 5 A g−1, and an ultra-high energy density of 16.3 Wh kg−1 in a full cell device. By analyzing its application in the lithium‑sulfur battery cathode, the S-loaded AKC exhibited a high capacity of 1075 mAh g−1 at 0.1C, and 490.5 mAh g−1 after 150 cycles with 66.5 % of capacity retention. The excellent performance of AKC can be attributed to its high specific surface area, pore structure, and sulfur and nitrogen co-doping combine effect. Overall, AKCs exhibited excellent electrochemical performances, thereby proposing a new synthetic strategy of preparing dual heteroatom doped porous carbon for high-performance electrode materials through a single precursor and low-cost perspective.

Nitrogen and sulfur co-doped porous carbon derived from polypyrrole-polythiophene for efficient peroxydisulfate activation towards degradation of aniline

To enhance the catalytic activity of carbon materials and streamline their synthesis process, it is necessary to optimize the doping of heteroatoms and reduce the dependence on organic solvents. This can be achieved by utilizing carbonized Polypyrrole-Polythiophene (C(Ppy-Pth)), which is obtained through simultaneous and in-situ co-doping of N and S. This material can serve as an effective activator of peroxydisulfate (PDS) for the degradation of aniline (AN). The results showed that Ppy-Pth could be efficiently synthesized by using cetyltrimethyl ammonium bromide, pyrrole, thiophene, FeCl3, and H2O2 in water. Based on the price, self-decomposition and oxidation efficiency, the performance of PDS activated by C(Ppy-Pth) was superior to that of peroxymonosulfate (PMS) in degrading AN. The optimum conditions for catalyzing PDS and degrading 30 mg/L AN by C(Ppy-Pth) were 0.10 g/L C(Ppy-Pth)-1000-1/1, 2.10 mM PDS, and pH0 = 3.00, which resulted in 86.69% AN removal in 30 min. Carbonation temperature, N/S ratio and pyridine N content are the key factors affecting the catalytic activity of C(Ppy-Pth). Quenching, probe, and electrochemical experiment revealed that in the catalytic PDS system with C(Ppy-Pth)-1000-1/1 (pH0 = 3.00), the oxidation of AN mainly occurred through the generation of hydroxyl radical (·OH), superoxide anion (O2·-), and electron transfer on the C(Ppy-Pth)-1000-1/1 surface. The steady-state concentration of ·OH and O2·- were 2.65 × 10−14 M and 1.97 × 10−13 M, respectively, and the contribution rate of ·OH oxidation was 31.28%. The oxidation of AN by sulfate radical (SO4·-) and singlet oxygen (1O2) could be neglected. This study provides a promising strategy for the construction of PDS catalyst and wastewater treatment.

N, S co-doped porous carbon nanosheet foam as MALDI matrix for efficient and direct profiling of biomolecules and environmental contaminants

It is still urgent to develop a powerful method for high-throughput and sensitive analysis of various small biomolecules and environmental contaminants. Herein, a three-dimensional foam consisting of nitrogen and sulfur co-doped porous carbon (N, S-C) nanosheet synthesized was served as an excellent matrix for matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI-TOF MS) efficiently and directly detecting various small biomolecules and pollutant compounds. This N, S-C nanosheet possessed the advantages of carbon foam for resonant chamber, high-contents of N/S heteroatoms co-doping, large surface area, hierarchical pore and good UV absorption. The use of N, S-C matrix could exhibit higher MS intensities, lower background noise, better salt tolerance and higher sensitivity for probing the various analytes, much superior to the traditional CHCA (α-cyano-4-hydroxycinnamic acid) matrix and control materials (C and N-C). The limit of detection (LOD)s of 1-hydroxy-pyrene, 4-nitrocatechol and nitroguaiacol were calculated to be 0.1 μg/mL, 1 μg/mL and 8 μg/mL at a signal-to-noise ratio (S/N) of 3. Moreover, the rapid and precise detections of 4-nitrocatechol, nitroguaiacol, and 1-hydroxy-pyrene in PM2.5 real sample have also been achieved. Through density functional theory (DFT) simulations, we reveal the sensing mechanism of small molecular deprotonation with the N and S co-doping into carbon matrix. This work may be promising to provide an excellent carbon matrix for the analysis of MALDI-TOF MS method in the biological and environmental field.

Biomass-derived nitrogen and sulfur co-doped sheet-like porous carbon for high-performance supercapacitors

Nitrogen and sulfur co-doped porous carbon materials with excellent electrochemical performance were prepared using a one-step carbonization and activation method.

Nitrogen and Sulfur Codoped Porous Carbon Directly Derived from Potassium Citrate and Thiourea for High-Performance Supercapacitors.

By introducing a heteroatom into carbon material, an effective improvement in capacitance can be realized owing to surface oxidation and reduction reactions of pseudocapacitors. Herein, a simple one-pot carbonization activation method was proposed to convert potassium citrate into three-dimensional interconnected porous carbon (PC). Then, an effective double heteroatom doping method by thiourea was used to prepare nitrogen-sulfur-doped PC (N,S-PC). This porous structure facilitates the storage of a large number of ions and reduces their diffusion path. The synthesized N,S-PC nanomaterial has a capacitance of 674 F/g at 1 A/g in a 1 M H2SO4 electrolyte, can retain 94.41% of the initial capacitance after 10 000 cycles at 5 A/g, and has a long cycle life. More importantly, a symmetric supercapacitor assembled with this material can exhibit an energy density of up to 32.6 (W·h)/kg at a high-power density of 750 W/kg. This is due to the high performance of N,S-PC in supercapacitor electrode materials.

Nitrogen and Oxygen Co-doped Porous Carbon Fabric for Efficient Removal of Formaldehyde

Nitrogen and Oxygen Co-doped Porous Carbon Fabric for Efficient Removal of Formaldehyde

Tiny Ni Nanoparticles Embedded in Boron- and Nitrogen-Codoped Porous Carbon Nanowires for High-Efficiency Water Splitting.

The integration of nickel (Ni) nanoparticle (NP)-embedded carbon layers (Ni@C) into the three-dimensional (3D) hierarchically porous carbon architectures, where ultrahigh boron (B) and nitrogen (N) doping is a potential methodology for boosting Ni catalysts' water splitting performances, was achieved. In this study, the novel 3D ultrafine Ni NP-embedded and B- and N-codoped hierarchically porous carbon nanowires (denoted as Ni@BNPCFs) were successfully synthesized via pyrolysis of the corresponding 3D nickel acetate [Ni(AC)2·4H2O]-hydroxybenzeneboronic acid-polyvinylpyrrolidone precursor networks woven by electrospinning. After optimizing the pyrolysis temperatures, various structural and morphological characterization analyses indicate that the optimal Ni@BNPCFs-900 networks own a large surface area, abundant micro/mesopores, and vast carbon edges/defects, which boost doping a large amount of B (5.81 atom %) and N (5.84 atom %) dopants into carbon frameworks with 6.36 atom % of BC3, pyridinic-N (pyridinic-N-Ni), and graphitic-N active sites. Electrochemical measurements demonstrate that Ni@BNPCFs-900 reveals the best hydrogen evolution reaction (HER) and oxygen reduction reaction catalytic activities in an alkaline solution. The HER potential at 10 mA cm-2 [E10 = -164.2 mV vs reversible hydrogen electrode (RHE)] of the optimal Ni@BNPCFs-900 is just 96.2 mV more negative than that of the state-of-the-art 20 wt % Pt/C (E10 = -68 mV vs RHE). In particular, the OER E10 and Tafel slope of the optimal Ni@BNPCFs-900 (1.517 V vs RHE and 19.31 mV dec-1) are much smaller than those of RuO2 (1.557 V vs RHE and 64.03 mV dec-1). For full water splitting, the catalytic current density achieves 10 mA cm-2 at a low cell voltage of 1.584 V for the (-) Ni@BNPCFs-900||Ni@BNPCFs-900 (+) electrolysis cell, which is 10 mV smaller than that of the (-) 20 wt % Pt/C||RuO2 (+) benchmark (1.594 V) under the same conditions. The synergistic effects of 3D hierarchically porous structures, advanced charge transport ability, and abundant active centers [such as Ni@BNC, BC3, pyridinic-N (pyridinic-N-Ni), and graphitic-N] are responsible for the excellent water-splitting catalytic activity of the Ni@BNPCFs-900 networks. Especially, because of the remarkable structural and chemical stabilities of 3D hierarchically porous Ni@BNPCFs-900 networks, the (-) Ni@BNPCFs-900||Ni@BNPCFs-900 (+) water electrolysis cell displays an excellent stability.

Nitrogen and sulfur co-doped porous chitosan hydrogel-derived carbons for supercapacitors

To achieve high-performance supercapacitors, nitrogen and sulfur co-doped porous chitosan hydrogel-derived carbons (CHC-SK) are successfully prepared by one-step carbonization. In the synthesis, two effective strategies of structure design and heteroatom doping are both used to increase capacitance of carbon materials. To control and design of structure, potassium citrate as a novel pore-former is introduced into chitosan hydrogel systems. It plays three roles in pore formation and thereby can be effective to optimize structure and improve surface area of CHC-SK. In addition, thiourea as binary doping of nitrogen and sulfur can effectively maximize the pseudocapacitance of CHC-SK. Therefore, CHC-SK with large surface area (1596.4 m2 g−1) and high heteroatom content (5.43% for nitrogen, 2.62% for sulfur) show excellent electrochemical performances. The specific capacitance of CHC-SK reaches up to 366.8 F g−1 at 0.5 A g−1. Even at the high current density of 10A g−1, its capacitance retention is 97.1% for 10,000 cycles. This simple strategy for the synthesis of nitrogen and sulfur co-doped porous chitosan hydrogel-derived carbons with high specific capacitance has promising applications in the future.

Biomass derived nitrogen and sulfur co-doped porous carbons for efficient CO2 adsorption

• N, S co-doped porous carbons were synthesized from biomass hazelnut shell. • Thiourea acts both N and S agent. • The resultant carbon exhibits high CO 2 uptake, 6.44 mmol/g at 0 °C and 1 bar. • The sorbents also exhibit various other good CO 2 adsorption properties. • Joints effects of narrow microporosity, N and S content decides CO 2 uptake. In this work, novel nitrogen and sulfur co-doped porous carbons were synthesized by thiourea modification of carbonized hazelnut shell, then followed by KOH activation. In current preparation protocol, thiourea acted as both N and S agent, thereby, nitrogen and sulfur were simultaneously doped into the carbon skeleton by a single-step reaction. After KOH activation, the resultant sorbents hold advanced porosity and a certain amount of N and S contents. This series of sorbents possess the highest CO 2 uptake of 4.30 and 6.44 mmol g −1 at 1 bar, 25 °C and 0 °C, respectively. Comprehensive investigations found that the joint effects of narrow microporostiy, N and S content govern the CO 2 uptake of these adsorbents. Moreover, these adsorbents display various exceptional CO 2 adsorption performances such as excellent reversibility, fast CO 2 adsorption kinetics, moderate heat of adsorption, good CO 2 /N 2 selectivity and high dynamic CO 2 capture capacity. Therefore, these hazelnut shell derived N, S co-doped carbons are promising in actual CO 2 capture.

Constructing Sulfur and Nitrogen Codoped Porous Carbon with Optimized Defect-Sites and Electronic Structure Promises High Performance Potassium-Ion Storage

Constructing Sulfur and Nitrogen Codoped Porous Carbon with Optimized Defect-Sites and Electronic Structure Promises High Performance Potassium-Ion Storage