NH3 Atmosphere Research Articles

Electrocatalytic oxygen reduction on nitrogen-doped porous carbon spheres prepared with resorcinol–phenolsulfonic acid–formaldehyde mixed resins

Abstract The resorcinol–phenolsulfonic acid–formaldehyde (RxPS1–xF) mixed resin spheres were prepared by the high-temperature hydrothermal synthesis. Pyrolysis of the resin spheres under NH3 atmosphere produced small, porous, conductive N-doped carbon spheres. These carbon spheres promoted electrocatalytic oxygen reduction reaction (ORR) with almost 100% four-electron reduction selectivity, and their performance was comparable to that of the state-of-the-art Pt/C catalyst.

Cu- and S-Doped Heteropolyacid Co2Mo10 as Electrocatalysts for Efficient Hydrogen Evolution.

This study employed polyoxometalate Co2Mo10 as a precursor and a two-step method to prepare carbon cloth-supported CuxS-CoS2-MoS2 materials. The morphology and structure of the materials were characterized using XRD, XPS, SEM, TEM, and other techniques. Interestingly, changes in the reducing gas during the calcination process could adjust the product morphology, thereby altering catalytic activity. Electrochemical results indicated that the CuxS-CoS2-MoS2 nanomaterials prepared under an NH3 atmosphere exhibited unique morphology and structural advantages. They demonstrated significant electrocatalytic activity for the hydrogen evolution reaction (HER) in alkaline and acidic electrolytes (overpotentials of 108 and 196 mV at a current density of 10 mA cm-2, lower than the overpotentials of 143 and 226 mV obtained under a H2-Ar atmosphere during calcination) and excellent long-term durability. These findings provide insights and methods for synthesizing multicomponent electrocatalysts with enhanced catalytic performance.

Pt‐Mo₂N Catalyst Formed by Inverse Sintering for the Reverse Water‐Gas Shift Reaction

AbstractThe reverse water‐gas shift (RWGS) reaction is significant for the resource utilization of CO2. However, this reaction requires high temperatures and metal catalysts are prone to agglomeration, leading to loss of activity. In this work, a Pt catalyst supported on Mo₂N formed via phase transition and metal reverse sintering under a high‐temperature NH₃ atmosphere is developed. This catalyst exhibits excellent RWGS activity, achieving a CO production rate of 294.8 mmolgcat−1 h−1 at 623 K, with CO selectivity maintained at 93%. Moreover, under continuous testing conditions for 100 h, the catalyst's activity shows no significant decline. Notably, further investigation reveals that the surface reaction mechanism at 623 K differs from the previously reported associative mechanism, instead following a redox mechanism in the presence of H₂. This research not only provides a deeper theoretical understanding of the mechanism of CO2 hydrogenation but also offers valuable insights for developing novel and efficient metal catalyst regeneration technologies.

N-doped titanium oxide/carbon composite as supports for platinum catalysts in highly efficient methanol oxidation

The commercialization of direct methanol fuel cells (DMFCs) faces significant challenges due to the susceptibility of conventional platinum-based catalysts to poisoning by intermediates such as CO and HCOO− generated during the methanol oxidation reaction (MOR). This study details the synthesis of a highly porous titanium dioxide/carbon composite (TCC) using NH2-MIL-125(Ti) (MIL = Matérial Institut Lavoisier) as a precursor. To enhance the conductivity and catalytic properties of TCC, a nitriding reaction is conducted in an NH3 atmosphere, producing a nitrogen-doped titanium oxide/carbon composite (N-TCC). The resulting N-TCC is employed as a support for a platinum catalyst to improve MOR performance in DMFCs. The Pt/N-TCC catalyst demonstrates high catalytic performance, achieving a mass activity of 537 mA mg−1 for the MOR, marking a 39 % increase over the commercial Pt/C catalyst. Furthermore, the Pt/N-TCC catalyst exhibits a low onset potential for CO oxidation, a higher If/Ib ratio, and greater stability in chronoamperometry test, indicating high resistance to CO poisoning and enhanced chemical stability. Therefore, N-TCC can be used as a promising support for Pt-based catalysts in DMFC applications.

Kinetics of Iron Nitride Layer Growth during the Nitriding of AISI 1085 Non-Alloy Steel and AISI 52100 Alloy Steel.

This paper presents a comparison of two-component ammonia-based inlet atmospheres diluted with either hydrogen (NH3/H2) or nitrogen (NH3/N2). Taking advantage of the features of inlet atmospheres diluted with nitrogen and hydrogen, four two-stage processes were designed and carried out, which were juxtaposed with two single-stage processes carried out only in an NH3 atmosphere. A common parameter of the processes carried out was the same value of nitrogen availability in each process stage. The gas nitriding process was carried out on ASIS 1085 non-alloy steel and ASIS 52100 alloy steel. It was found that the chemical composition of the steels studied, for the adopted nitriding process parameters, did not affect the kinetics of the growth in the mass of nitrided samples as a function of the nitriding time. However, the additions of alloying elements present in the steels studied significantly affected the nitrogen distribution between the resulting iron nitride layer and the diffusion zone in the nitrided substrate. Because of the presence of chromium in AISI 52100 steel, a larger mass of nitrogen accumulated in the nitriding zone in the solution compared with unalloyed AISI 1085 steel. As a result, with the same increase in the mass of nitrided steel, a thicker layer of iron nitrides formed on AISI 1085 steel than on AISI 52100 steel.

Enhancement of Wear and Corrosion Resistance of Ti6Al4V Alloy through Hollow Cathode Discharge-Assisted Plasma Nitriding.

In order to improve the wear and corrosion resistance of Ti6Al4V alloy, a Ti-N compound layer was formed on the alloy by plasma nitriding at a relatively low temperature (750 °C) and within an economical processing duration (4 h), in a mixture of NH3 and N2 gases with varying ratios. The influence of the gas mixture on the microstructure, phase composition, and properties of the Ti-N layer was investigated. The results indicated that the thickness of the nitrided layer achieved in a mixed atmosphere with optimal proportions of NH3 and N2 (with a ratio of 1:2) was substantially greater than that obtained in an atmosphere of pure NH3. This suggests that appropriately increasing the proportion of N2 in the nitriding atmosphere is beneficial for the growth of the nitrided layer. The experiments demonstrated that the formation of the surface nitrided layer significantly enhances the corrosion and wear resistance of the titanium alloys.

Facile and scalable synthesis of N-doped carbon based Ni electrocatalyst for efficient CO2 reduction to CO

Electrochemical reduction of CO2 into valuable chemical products could be realized by reasonable design of effective electrocatalysts with atomically dispersed active sites, but the task presents challenges for chemistry because of the lack of facile and scalable synthetic route. Therefore nitrogen-doped porous carbon supported Ni electrocatalyst is presented via a facile synthetic method. In the first step, commercial carbon black was oxidized by HNO3 to generate organic group followed by absorption of Ni ions. Secondly, calcination under NH3 atmosphere led to N doped carbon based Ni catalyst which exhibited excellent catalytic performance with approximate 95 % Faradaic efficiency for CO, which is helpful for chemists to reasonable design and scalable preparation of economical and efficient catalysts.

Co, N co-doping controlled preparation of FeS/FeS2 heterojunction for efficient overall water splitting

The low electrical conductivity and catalytic activity of transition metal sulfides have been identified as the primary factors limiting their application in the field of electrocatalytic water splitting. In this study, FeS2 and Co-FeSx were initially synthesized through a hydrothermal method, followed by further annealing in an NH3 atmosphere to obtain Co,N-FeSx. The introduction of Co led to adjustments in the electronic structure, resulting in the formation of FeS2/FeS (FeSx) heterojunctions that facilitated accelerated charge transfer. Simultaneously, Co element doping increased the electrochemical active surface area, providing more active sites for the reactions. N element doping, on the other hand, introduced sulfur vacancies, thereby enhancing electrical conductivity and improving charge transfer efficiency. As a result, Co,N-FeSx exhibited significantly higher activities for the oxygen evolution reaction (OER) and overall water splitting compared to FeS2, with overpotentials of 290 mV and 330 mV, respectively, at a current density of 10 mA cm−2. Furthermore, the catalyst demonstrated excellent stability. The designed structure of the catalyst provides theoretical support for the study of Fe-based catalysts in OER and overall water splitting.

Basic and microwave modification processes to produce new activated carbon adsorbents based on Pistacia atlantica Kurdica nuts as carbonaceous raw material; A comparative study on the adsorption and elimination of acid blue 113

The nutshell of the pistachio tree was used as a precursor for producing new activated carbon (AC) adsorbent. The raw material was rinsed in H3PO4 (85 % w/w) and heated in a cylindrical furnace at 350 °C/90 min to 700 °C/60 min in a He and NH3 atmosphere. To change the surface chemistry, basic modification of AC was done under the NH3 atmosphere at 700 °C. The FT-IR spectrum showed apparent changes. The microwave, as second modification method, led to significant changes in the porosity properties of AC, especially in the surface area. The SEM images showed the differences in the morphology of the modified and unmodified samples. In the next step, an improved adsorption process was implemented to remove acid blue 113 (AB113). Basic and microwave-modified AC (BMM-AC) showed an enhanced removal efficiency of more than 97.54 % compared to AC, 60.32 %, microwave-modified AC (MM-AC), 73.08 %, and basic modified AC (BM-AC) 88.72 %, which revealed the positive role of the modification methods. Increasing the SBET from 238.8 to 368.6 m2/g using microwaves and changing the surface chemistry by basic modification were significant results of the study. These changes led to the construction of an improved removal process using BMM-AC to eliminate AB113.

Experimental study and correlation analysis for the effect of hydrogen pressure on biomass fluidized hydropyrolysis under N2-H2 mixed atmosphere

The utilization of fluidized bed reactors for the biomass hydropyrolysis vapor upgrading is essential in the conversion of biomass into liquid fuels. Conducting pyrolysis experiments in fluidized bed reactors with a N2-H2 mixed atmosphere is advantageous for system operation as it allows for lower minimum operating velocities, enhances pyrolysis efficiency, and reduces heat loss. This research examines the impact of hydrogen pressure in a bubbling fluidized bed reactor using a N2-H2 mixed carrier gas, with poplar wood as the feedstock and Ni-Moγ/Al2O3 as the catalyst. Through experimental and correlation analyses, significant relationships are observed between hydrogen pressure and the production of liquid and gas-phase products, with varying effects attributed to changes in hydrogen ratio and reaction pressure. Elevated hydrogen ratios facilitate secondary reactions such as the CO2 hydrogenation, resulting in a decline in CO2 production and an elevation in the yields of light hydrocarbons and aqueous phase products. Augmenting the reaction pressure to enhance hydrogen pressure aids in promoting hydrogen saturation and cracking, and amplifying the hydrogen pressure through an increase in the reaction pressure at a specific hydrogen ratio proves more efficacious in enhancing both the quantity and quality of bio-oil produced. In the context of poplar hydropyrolysis vapor upgrading utilizing a Ni-Moγ/Al2O3 catalyst, a hydrogen ratio of 50 % at a reaction pressure of 1.5 MPa emerged as the preferred option for achieving a 12 % bio-oil yield with a moderate average bio-oil carbon number and satisfactory hydrogenation levels. This comprehensive investigation examines the influence of hydrogen pressure on biomass hydropyrolysis, highlighting variations in the impacts of changes in hydrogen ratio and reaction pressure on pyrolysis results. These results offer a theoretical framework for discerning distinctions between hydropyrolysis investigations carried out in pure hydrogen atmospheres versus mixed N2-H2 atmospheres.

The effect of SO2 on NH3-SCR reaction synergistic CO oxidation over a Mn-Co-Ti catalyst

Mn–Co–TiO2 prepared using an impregnation method was applied to synergistic NH3-based selective catalytic reduction (NH3-SCR) and CO oxidation in a simulated flue gas. The NO conversion, NO oxidation, and CO oxidation were substantially enhanced after adding 15% Co3O4 to the 20MnTi catalyst. In an NO or NO + NH3 atmosphere, CO oxidation over the Mn–Co–TiO2 catalyst was mainly restrained by the competitive adsorption and formation of sulfate species. In contrast, the NH3-SCR reaction progressed almost unimpeded in a CO atmosphere. A SO2 atmosphere drastically reduced the NO conversion of the catalyst at lower temperatures and almost completely suppressed the oxidation activities toward NO and CO. The amount of remaining NO oxidation (approximately 10%) was primarily contributed by gas-phase oxidation of NO by O2. Next, fresh and SO2-poisoned Mn–Co–TiO2 were characterized using various methods. Results indicated that no conspicuous change occurred in the crystal structure of the samples after SO2 poisoning, but numerous sulfate products were deposited on the catalyst surface. The deposition of sulfate-species byproducts decreased the specific surface area and pore volume of the catalyst and shifted the surface acid sites to a higher temperature range, further reducing the CO oxidation performance. Moreover, the catalytic reaction of CO and NO followed the Eley–Rideal mechanism. Furthermore, the mechanisms through which multicomponent flue gases influence the synergistic NH3-SCR and CO oxidation performance were proposed.

Surface segregation phenomena encountered during solid carbon active screen plasma nitrocarburizing of AISI 316L

Plasma nitrocarburizing of an austenitic stainless steel AISI 316L was performed in an N2-H2 atmosphere (50 % H2 and 50 % N2) with a carbon-fiber reinforced carbon (CFC) active screen. The experimental concept of a plasma-discharged CFC active screen in conjunction with a substrate holder at floating potential ensures that no charged particles are present on the sample surface and no sputtering occurs. As a result, carbon contaminations are formed on the surface which were studied in detail with a combination of scanning electron microscopy (SEM) and secondary ion mass spectrometry (SIMS). The results indicate that a layer of about 25–50 nm of carbon is formed. At the same time, a strong segregation of Mn, Ni and Cr is observed below the coating within the steel substrate. Both effects progress with treatment time and there exists a clear correlation between the formation of the carbon layer and the segregation effect.

Study on ignition characteristics of single biomass and coal particles in ammonia co-firing

As a potential solution to reduce carbon emissions in thermal power generation, ammonia co-firing needs further investigation on the ignition behavior due to its significant differences from solid fuel combustion. To provide an increased understanding of the potentially synergetic or competing effect between NH3/biomass and NH3/coal, this research designed an ingenious laser synchronization signal trigger system to acquire the ignition characteristics of single biomass and coal particles with NH3 co-firing. The results revealed that NH3 co-firing could significantly shorten the ignition delay time of biomass and coal particles by accelerating the devolatilization process and promoting combustion intensity. The statistical results of ignition delay time were obtained within the range of 6.75–22.17 ms in N2 atmosphere and 4.64–20.04 ms in NH3 atmosphere for the tested biomass and coal particles.

Challenge of fabricating difficult-to-nitride materials: Formation of martensitic phase in (Fe0.8Co0.2)8N foil based on industrially suitable gas-nitriding process

Nitrogen-martensitic phase (Fe0.8Co0.2)8N was successfully synthesized by using an industrially suitable gas-nitriding process of a bulk foil. So far, the nitrogen-martensitic phase of the bulk material has not been synthesized at such a high Co content. We found that this is because the nitride was easily denitrided by elevating temperature. In this work, by exploiting a NH3 gas-nitriding process combined with quenching at a rapid cooling rate (>800 °C/s) in NH3 atmosphere, we found that nitrogen stayed at the surface layer of the foil. By using cross-sectional laser microscopy, the nitride region was observed as a 7-μm-thick layered shape at the surface of the 100-μm-thick foil. An x-ray diffraction technique revealed that the nitride layer was a martensitic phase that was characterized as a body-centered tetragonal structure with c/a = 1.04. These findings can be applied to nitriding and surface treatments for alloy systems in which a nitrogen solid solution is hardly formed. Our developed method is promising because the martensitic phase is expected to be formed in whole bulk by further optimizing parameters clarified in this work.

In Situ Constructing a TiO2/TiN Heterostructure Modified Carbon Interlayer for Balancing the Surface Adsorption and Conversion of Polysulfides in Li–S Batteries

AbstractSevere shuttle effect and sluggish reaction kinetics caused by lithium‐polysulfides have always been the dominant factor to reduce the actual energy density of lithium–sulfur batteries. It's very important to simultaneously balance the surface adsorption and redox conversion of the lithium‐polysulfides. Herein, a TiO2/TiN heterostructure and in situ N‐doping modified multifunctional carbon interlayer is designed and constructed using a melamine foam as the matrix material at a relatively low temperature and without NH3 atmosphere. Interestingly, TiO2 nano‐particles decorated on the N‐enriched melamine carbon foam can be partially in situ transformed into TiN during pyrolysis process. Based on the support of highly conductive and interconnected carbon skeletons, the N heteroatom and TiO2/TiN show good synergetic adsorption and conversion of the soluble lithium‐polysulfides, whilst boosting the electrochemical performance of lithium–sulfur batteries. Consequently, when used the multifunctional carbon interlayer, the Super P/sulfur cathode based lithium–sulfur battery delivers a high initial discharge capacity of 814 mAh g−1 at a high current rate of 2.0 C and maintain the 548 mAh g−1 after 500 cycles. Even with the high sulfur loading of 7.5 mg cm−2 and low E/S ratio of 4.7 µL mg−1, an acceptable areal capacity of 8.2 mAh cm−2 can be obtained.

Comparison of aluminum nitride thin films prepared by magnetron sputter epitaxy in nitrogen and ammonia atmosphere

Wurtzite-type aluminum nitride (AlN) thin films exhibiting high thermal conductivity, large grain size, and low surface roughness are desired for both bulk acoustic wave and surface acoustic wave resonators. In this work, we use ammonia (NH3) assisted reactive sputter deposition of AlN to significantly improve these properties. The study shows a systematic change in the structural, thermal, and morphological properties of AlN grown in nitrogen (N2) and N2 + NH3 atmosphere. The study demonstrates that NH3 assisted AlN sputtering facilitates 2D growth. In addition, the study presents a growth model relating the 2D growth to improve the mobility of aluminum (Al) and nitrogen (N) ad-atoms in NH3 atmosphere. Consequently, the thermal conductivity and roughness improve by ≈76%, and ≈35%, while the grain size increases by ≈78%.

The effect of H2 and NH3 on the pyrolysis of coal model compounds based on reactive molecular dynamics simulation

The co-combustion of coal and ammonia (NH3) has been receiving considerable attention due to its potential for mitigating CO2 emissions. Consequently, comprehending the pyrolysis mechanism of coal under the NH3 atmosphere is of paramount significance. Using pyrrole and pyridine, which are crucial model compounds of coal, the pyrolysis mechanisms within N2/H2/NH3 is systematacially investigated with the help of chemical reaction kinetics simulations (ReaxFF MD). The results revealed that pyrrole performs inferior structural stability compared to pyridine, resulting in accelerated and shorter pyrolysis, alongside a lower activation energy for the reaction. As a result, the pyrolysis process of pyrrole is more prone to C-C and C-N bond cleavage, ultimately producing more HCN. Moreover, this investigation revealed that both H2 and NH3 atmospheres promote the pyrolysis of pyrrole and pyridine, with the NH3 atmosphere having a more pronounced influence. The presence of an NH3/H2 atmosphere increased the production of HCN, lowered the activation energy required for the pyrolysis of pyrrole and pyridine, and aided in the cleavage of C-C and C-N bonds. Additionally, this study demonstrated the reaction network of pyrrole and pyridine in N2/H2/NH3 atmospheres, focusing on the observation that NH2 radicals, during the initial phases of the reaction, stimulate the production of low-carbon fragments and assist the fracture process of the model compounds. Furthermore, this study presents the reaction network of pyrrole and pyridine in N2/H2/NH3 atmospheres, with a particular focus on the NH3 atmosphere. The existence of NH3 in the atmosphere facilitates the formation of low-carbon fragments during the cleavage phase of the model compounds. This leads to the production of low-carbon intermediates and an increase in the generation of HCN during the subsequent condensation stage. These findings highlight the significant impact of the ammonia atmosphere on the pyrolysis of the model compounds. The outcomes of this study elucidate the fundamental principles of nitrogen-containing compound pyrolysis at the mechanistic level, providing critical insights for subsequent experimental and computational research.

Insights into the hydrolysis/alcoholysis/ammonolysis mechanisms of ethylene naphthalate dimer using density functional theory (DFT) method

Hydrolysis, alcoholysis and ammonolysis are viable routes for the efficient degradation and recycling of polyethylene naphthalate (PEN) plastic waste. Various possible hydrolysis/alcoholysis/ammonolysis reaction pathways for the degradation mechanism of the ethylene naphthalate dimer were investigated using the density functional theory (DFT) B3P86/6–31++G(d,p). To determine the thermodynamic and kinetic parameters, geometric structure optimization and frequency calculation were performed on a range of intermediates, transition states, and products associated with the reaction. The calculation results show that the highest energy barrier of the main element reaction step in hydrolysis is about 169.0 kJ/mol, the lowest is about 151.0 kJ/mol for ammonolysis, and the second is about 155.0 kJ/mol for alcoholysis. The main hydrolysis products of the ethylene naphthalate dimer are 2,6-naphthalenedicarboxylic acid and ethylene glycol; the main products of alcoholysis are dimethyl naphthalene-2,6-dicarboxylate and ethylene glycol, and the main products of ammonolysis are naphthalene-2,6-dicarboxamide and ethylene glycol. Furthermore, in the process of ethylene naphthalate dimer hydrolysis/alcoholysis/ammonolysis, the decomposition reaction in the NH3 atmosphere is better than that in methanol, and the reaction in CH3OH is better than that in the H2O molecular environment, and the increase in reaction temperature can increase its spontaneity. Our study presents the molecular mechanism of PEN hydrolysis/alcoholysis/ammonolysis and provides a reference for studying the degradation of other plastic wastes.

Self-Repairing [MEDTA]2- functionalized poly(ionic liquid)s in the application of NH3 adsorption through reversible NH3 insertion

MOFs have high adsorption performance of ammonia (NH3) because of its porosity and abundant coordination sites, especially MOFs containing carboxylic acid ligands have emerged as effect NH3 adsorbents. But, it’s troublous for reversible ammonia adsorption for the strong metal-NH3 coordination or the collapse of adsorbents. [MEDTA]2- is a very stable and classic carboxylic acid-containing complex, but there was no relevant report. Therefore, this work carried out the design and synthesis of PVIm-R8-MEDTA based on the use of the coordination structure of [MEDTA]2- and the stability of PILs’ skeleton. The characterization indicated the [MEDTA]2- could be introduced into PILs successfully for the hydrogen bonding interactions with the imidazolium cation, and the obtained PVIm-R8-MEDTA presented enhanced NH3 capacity (10.4–14.7 mmol/g) than their precursor PVIm-R8-Br (7.8 mmol/g). The mechanism of NH3 adsorption was proposed by DFT calculation, spectroscopic method, and the calorimetric test, it indicated the NH3 was fixed by imdazolium cation through hydrogen bonding and inserted into two of the carboxylate and metal bonds of [MEDTA]2-. Because of the multi-meshing coordination of [EDTA]4- and metal ions, the disconnected carboxylate ions could easily coordinate with metal ions again and repair the chelating structure of [MEDTA]2-, which caused the ammonia easily be desorbed. In the process of gas adsorption, there was no bonding breakage of the skeleton of PILs, which helped the PVIm-R8-MEDTA be recovered under moisture and NH3 atmosphere. Thanks for the designability of PILs, such as the cationic structure, structure and size of cross-linking agent, the choice of complex anion and so on, it provides a new design idea and theoretical basis for efficient and reversible ammonia adsorption materials.

Preparation of super-hydrophobic BN nanotube mesh and theoretical research of wetting state

In this study, we have fabricated stainless steel mesh with columnar super-hydrophobic boron nitride nanotubes (BNNTs) through the ‘gas-liquid-solid’ mechanism annealing method. We employed iron (Fe) powder as the catalyst and utilized boron (B) and boron oxide (B2O3) as the raw materials. The synthesis took place within a tubular furnace, operating under an NH3 atmosphere at a temperature of 1250C∘. The contact angle of water droplets on the experimental surface measures approximately 150∘, while the sliding angle is approximately 3∘. In the next place, the laboratory carried out a series of experiments on the tensile properties, corrosion resistance, and erosion resistance of the prepared samples. The experimental results showed that the sample material had good mechanical properties and corrosion resistance. In addition, the erosion resistance test results showed that the sample material even at high speed (2800 rpm/min). After washing the sample for 5 min, the surface of the material still has good wettability (contact angle is 136.49∘). Finally, droplet bouncing experiments have demonstrated that the adhesion force on the surface of the boron nitride nanotube stainless steel mesh is notably minimal, indicating its substantial hydrophobic properties. Additionally, we conducted an investigation into the wetting interaction between droplets and the surface of the boron nitride nanotube stainless steel mesh. By applying the Wenzel and Cassie formulas and considering the pertinent geometric parameters of the material surface, we theoretically elucidated that, upon contact, the droplets assume a ‘Cassie’ state on the surface of the super-hydrophobic boron nitride nanotube stainless steel mesh. The research results show that the superhydrophobic boron nitride nanotube stainless steel mesh has broad application prospects in the fields of hydrogen storage, sewage treatment and oil-water separation.