New Type Of Material Research Articles

Chiral nanoenzymes: synthesis and applications.

Chiral nanoenzymes are a new type of material that possesses both chiral nanostructures and enzymatic catalytic activity. These materials exhibit selectivity in their catalytic activity towards organisms due to the introduction of chiral features in nanomaterials and have inherent chiral discrimination in organisms. As synthetic enzymes, chiral nanoenzymes offer significant advantages over natural enzymes. Due to their unique chiral structure and distinctive physicochemical properties, chiral nanoenzymes play an important role in various fields, including biology, medicine, and environmental protection. Their strong stereospecificity and biocompatibility make them useful in disease therapy, biosensing, and chiral catalysis, setting them apart from conventional and natural enzymes. In recent years, the design of synthetic methods and biological applications of chiral nanoenzymes has received significant attention and extensive research among scientists. This paper provides a systematic review of the research progress in the discovery, development, and application of chiral nanoenzymes in the last decade. Additionally, it presents various applications of chiral nanoenzymes, such as disease therapy, biosensing, and chiral catalysis. Finally, the challenges and future prospects of chiral nanoenzymes are discussed.

State primary special standard of impulse current unit in the range from 1.0 to 1.0·105 A GET 202-2024

Metrological assurance of immunity tests to impulse currents of natural and artificial origin is an urgent task in the development and production of aviation, rocket and space equipment and telecommunication equipment. The State primary special standard of lightning discharge impulse current unit GET 202-2012 provided the unity of measurements of impulse current parameters in the amplitude range from 1 to 100 kA and the time range from hundreds of nanoseconds to units of milliseconds. In order to provide metrological support for measuring instruments for impulse currents of electrostatic discharges and switching currents (rise time of the transient response of at least 1 ns, measurement range from 1 to 200 A), GET 202-2012 underwent a modernization cycle in 2020–2023. As a result of the modernization, the State Primary Special Standard of the unit of pulse current in the range from 1.0 to 1.0·105 A GET 202-2024 was approved, the lower limit of the range of reproduction of the unit of pulse current of which was 1 A with a pulse front duration of no more than 1 ns. Thus, the problem of ensuring the uniformity of measurements of electrostatic discharges and power switching impulse currents parameters was solved. To achieve the specified characteristics, GET 202-2024 includes devices for reproducing current pulses based on semiconductor keys and reference current shunts with a short rise time. The composition, structural diagram, technical and metrological characteristics of GET 202-2024 are given. GET 202-2024 ensures the uniformity of measurements of the parameters of pulse currents of electrostatic discharges, partial lightning discharges, as well as pulse currents generated by switching processes when solving problems of electromagnetic compatibility, creating new types of materials and coatings, in geophysical and meteorological research and observations, in healthcare.

Gradient Mo1−xWxSe2 monolayer Alloys: Synthesis and multifunctional applications

With the continuous and rapid development of electronic information technology, the demand for new materials with miniaturization, high integration, high performance, and multifunction is becoming increasingly urgent. However, it is difficult for existing photodetectors based on a single material to achieve multi-functionality while maintaining excellent performance, and the devices based on heterostructures are faced with complex preparation and compatibility problems. In this work, gradient Mo1−xWxSe2 monolayer alloys with high crystal quality have been synthesized by an evaporation-assisted chemical vapor deposition method. The composition of the synthesized Mo1−xWxSe2 monolayer alloys varies gradually with x ranging from 0 to 1. The Mo1−xWxSe2 based photodetector shows superior photoresponse performance in the visible wavelength with maximum responsivity of 26 A/W and external quantum efficiency up to 6320 % under 520 nm laser irradiation. Besides, the Mo1−xWxSe2 device is capable of high-resolution imaging, which can be used as image sensor. Moreover, nonvolatile memory function has also been realized in the device because the band gap of Mo1−xWxSe2 can be effectively adjusted by the gradient distribution of the component and the deep energy levels caused by Se vacancies can be modulated to shallow energy levels. A thrilling discovery is that the gradient Mo1−xWxSe2 alloy device can simulate the biological synapses successfully, including paired-pulse facilitation, short-term plasticity, long-term plasticity and learning process. The realization of high-performance photodetection, visualization, nonvolatile memory and synaptic simulation based on a single gradient crystal offers a new type of material to develop advanced optoelectronic devices with multiple functions.

First-principle study origin of ferromagnetism in non-magnetic perovskite BaSnO3 doped with 2p-X (X=C, N)

In this study, our goal is to analyze the origin of magnetization in non magnetic cubic structure perovskite BaSnO3 doped with 2p-X (X=C, N) using the full potential linearized augmented plane wave (FP-LAPW) method based on density functional theory (DFT). For the exchange and correlation potential we have applied the generalized gradient approximation (GGA) and the GGA plus-modified Becke-Johnson potential (mBJ-GGA). The results show that BaSnO3 doped with C then with N and finally with C and N exhibit half-metallic ferromagnetism behavior with the integer magnetic moment of 1, 2 and 3 μB per cell respectively. The origin of the ferromagnetism that occurs within these compounds is mainly caused by the p-p hybridization between 2p-impurities and its neighboring oxygen atoms. These results allowed to conclude that doped perovskite could provide a new type of materials, called half-metallic for future spintronic devices.

Flexible MXene/CuNWs/Tartaric Acid composite fabrics constructed by stacking assembly for Electromagnetic Interference Shielding

With the rapid development of modern communication technology, the exploration of flexible wearable shielding fabrics with exceptional electromagnetic interference (EMI) shielding performance has emerged as an utmost priority to safeguard both human beings and electronic devices from the detrimental effects of electromagnetic radiation. Herein, a scalable multilayer stacking assembly method is proposed to prepare uniform MXene/CuNWs/Tartaric Acid (TA) composites-coated fabrics. MXene, as a new type of material, can achieve higher electron and ion transfer rates. However, it is prone to oxidation in air, leading to poor stability. Benefiting from the synergistic effect of tartaric acid, the MXene/CuNWs/TA-coated fabrics exhibit certain oxidation stability and corrosion resistance, while retaining the inherent flexibility and breathability of natural polymer textiles. Furthermore, the multilayer stacking structure works perfectly with the MXene/CuNWs conductive network, enabling multiple reflections and absorptions of electromagnetic waves internally, thus effectively diminishing energy transmission. The modified fabrics exhibit a low sheet resistance of 3.25 ± 0.12 Ω/sq and a good EMI shielding performance of 41.2 dB at X-band. Therefore, MXene/CuNWs/TA fabrics with high shielding performance are expected to reach their potential in wearable electronic products.

Water‒soil-air‒plant mutual feedback mechanism under the application of red bed composite polymers.

Red bed composite polymers composed of weathered red bed soil, adhesive materials, and water-retaining materials have been applied as a new type of material for environmental restoration. However, the promotion and application of this material has been limited by a lack of understanding of its action mechanism in environmental restoration. The objective of this study is to innovatively propose a water‒soil-air‒plant mutual feedback mechanism based on this material. Therefore, water‒soil-air‒plant mutual feedback tests were conducted in this study under 3 initial water contents and 10 red bed composite polymers ratios. Key parameters, namely, water content, soil conductivity, pH, temperature, O2 and CO2 contents, pigeon pea (Cajanus cajan) germination number and plant height were monitored and analyzed. As the results, a mutual feedback mechanism driving water retention, soil consolidation, air retention, and plant rooting was revealed under the application of red bed composite polymers. And, suitable environments and optimal compositions for this material are proposed. The study results provide a theoretical basis for the large-scale application of red bed composite polymers.

Enhanced specific surface area and mechanical property of silk nanofibers aerogel for potential hemostasis applications

Biopolymer aerogel is a new type of material with potential applications in the biomedical field. Silk fibroin is of particular interest as a raw material with good biocompatibility and degradable. However, the low mechanical strength and small specific surface area of silk fibroin aerogels limit its further development. Herein, a fast water absorption, highly specific surface area and mechanically strong of aerogels were prepared using low crystal silk fibroin nanofibers (SNF), sol-gel process, solvent exchange and supercritical carbon dioxide (CO2) drying method. The resulting Aero-Sc displayed highly specific surface area (251 m2/g), porosity (97.6 %) and water absorption capacity (1200 %). Furthermore, with rapid water absorption and stronger erythrocyte adhesion, the Aero-Sc showed highly effective hemostasis in vitro. In vivo, animal experiments on rat liver hemorrhage model confirmed that SNF aerogels have a less blood loss (312 ± 29 mg) and faster hemostatic time (92 ± 13 s) than commercially gelatin sponge (p < 0.05). The unique properties of silk fibroin nanofibers aerogel developed in this study has great potential to be a safe and effective hemostatic medical device.

Polar Alternating Cations Intercalated Hybrid Perovskite with Iodine‐Substituted Spacers Toward Efficient Passive X‐Ray Detection

Abstract2D hybrid perovskites, with their high X‐ray absorption and extended carrier transport, present excellent promise for efficient direct X‐ray detection. However, most of the current devices require external bias voltage, which results in the need for significant energy consumption and severe ion migration, therefore, it is urgent to develop new types of materials for achieving efficient passive X‐ray detection. Herein, two novel chiral polar alternating cations intercalation (ACI)‐type hybrid perovskite materials, named (R/S‐PPA)(IEA)PbBr4 (1‐R/S, (R/S)‐PPA = R/S‐1‐phenylpropylamine; IEA = iodoethylamine), are constructed by integrating the chiral aromatic spacer R/S‐PPA and the iodine‐substituted spacer IEA. Various intermolecular interactions, such as I···I, C─H···I, π···π interactions, are introduced due to the introduction of I‐substituted chain amines, which effectively suppresses ion migration and thus lead to improved operational stability. The device constructed along the polar axis displays superior X‐ray detection performance, such as relatively high sensitivity and an ultra‐low limit of detection (LoD) of 3.0 nGy s−1, making it the first chiral ACI‐type perovskite material for realizing efficient passive X‐ray detection. Furthermore, 1‐R also presents low dark current drift and exceptional irradiation stability. This work provides new thought for using novel ACI‐type polar perovskite for high‐performance passive direct X‐ray detection.

Investigation of the Use of Mycelial Filler with Different Cultivation Times for the Filtration of Particulate Airflow

Balanced and sustainable development has challenges in utilizing the best efficiency technologies, using new types of materials with reduced environmental impact, including composite types, reusable materials, and easily recyclable consumer adaptable products. One understudied biologically produced material is mycelium, the scientifically studied and improved cultivation of which produces an environmentally friendly material with unique properties with a wide range of applications. In this work, filtration fillers from mycelia of different cultivation periods and their abilities to filter airflow from solid particles were experimentally studied. Numerical modeling studied the interaction and trapping of particles in the flow with the surface of mycelium filters. The results of the research revealed a high airflow filtration efficiency of more than 91%, as well as differences and advantages in the properties and structure of mycelia of different growth periods, and the need for further study of this biomaterial.

Strong Electronic Interaction in High-Entropy Oxide Enhances Oxygen Evolution Reaction.

High-entropy oxides are a new type of material with significant application potential. However, the lack of a universal HEO preparation method severely limits the property study and application of HEOs. Herein, we report a universal approach of spray pyrolysis for the preparation of various HEOs and study the electrocatalytic performance of HEOs toward the oxygen evolution reaction. FeCoNiMoWOx HEO exhibits an overpotential of 281 mV at 10 mA cm-2 and a Tafel slope of 34.5 mV dec-1, which are far superior to those of the corresponding medium-entropy oxide and low-entropy oxide. It is found that the high entropy of the HEO greatly strengthens the interaction between Fe and Mo/W and produces abundant oxygen vacancies (OVs) around Mo and W. This work not only provides a universal preparation method for HEOs but also deepens our understanding of OER catalytic activity of HEOs.

Impact-induced energy release characteristics of Ti-Zr-Hf-Ta high-entropy alloys by using a temperature-pressure synchronous measurement method

Energetic structural materials (ESMs) are a new type of materials with structural strength and reactivity, and their impact-induced energy release characteristics are greatly influenced by the fragmentation behavior. In this study, the dynamic fragmentation behavior and energy release characteristics of Ti-Zr-Hf-Ta high-entropy alloys (HEAs) with different precipitate content were investigated based on split Hopkinson pressure bars (SHPB) tests. To quantitatively evaluate the reactivity of ESMs, a temperature-pressure synchronous measurement method combined with a modified calculation model for quasi-sealed chamber was proposed. The results showed that the precipitates were distributed at the grain boundaries. As the precipitate content increased, the quasi-static yield strengths increased from 1004 to 1132 MPa, the dynamic yield strengths increased from 1672 to 1874 MPa, while the fracture strains decreased from 0.47 to 0.29, and correspondingly, the released energy increased from 14±2–511±154 J/g. The results demonstrated that the impact-induced energy release characteristics of the materials are closely related to the fracture strain. It can be confirmed that the alloys with lower plasticity are more likely to fracture under impact conditions, and the combustion reaction will be more violent, which is well consistent with the measurement of the energy-release amounts. High-speed infrared temperature measurement and microstructural photography also provided the underlying mechanism: the fragment size of low plasticity materials is smaller and the local hot spots are more dispersed, both of which are conducive to the combustion reaction. By using this method, the relationship among mechanical properties, fragmentation behavior, and energy release characteristics can be established, and the results will provide new insights into the development of ESMs with superior energy release under impact loading and applicable mechanical properties for potential applications.

High-temperature tensile behavior and constitutive model in Co-free Fe40Mn20Cr20Ni20 high-entropy alloy

High-entropy alloys (HEAs) have attracted widespread attention from scholars as a new type of material employed in extreme environments. However, as a main kind of HEAs, many face-centered cubic single-phase HEAs are restricted in industrial applications due to their lower yield strength and high cost when containing expensive elements such as Co. In this study, dispersion strengthening by heat treatment was introduced in low-cost Co-free Fe40Mn20Cr20Ni20 HEA to improve its strength, and its high-temperature tensile behavior and constitutive model were studied to explore its potential application at high temperatures. It is found that when subjected to quasi-static room-temperature stretching, the heat-treated sample exhibits a yield strength of 534 MPa and a tensile plasticity of 26.8%. In addition, the tensile behavior of samples after heat treatment was investigated at high temperature (573–873 K) and low strain rate (10−3–10−1 s−1). The results suggest that the yield strength decreases with increasing temperature and decreasing strain rate. Moreover, at 873 K and 10−3 s−1, the electron backscatter diffraction system and x-ray diffraction results of the deformed sample indicate that the softening curve is driven from the recovery of materials. Finally, the flow stress was predicted using the Arrhenius equation and Artificial Neural Network model (ANN), and the two models were assessed using the average absolute relative error and coefficient of correlation (R). The results showed that the ANN had higher accuracy.

A Biomimetic Multifunctional Scaffold for Infectious Vertical Bone Augmentation.

The regenerative treatment of infectious vertical bone defects remains difficult and challenging today. Current clinical treatments are limited in their ability to control bacteria and infection, which is unfavorable for new bone formation and calls for a new type of material with excellent osteogenic and antibacterial properties. Here a multifunctional scaffold is synthesized that mimics natural bone nanostructures by incorporating silver nanowiresinto a hierarchical, intrafibrillar mineralized collagen matrix (IMC/AgNWs), to achieve the therapeutic goals of inhibiting bacterial activity and promoting infectious alveolar bone augmentation in rats and beagle dogs. An appropriate concentration of 0.5mgmL-1 AgNWs is selected to balance biocompatibility and antibacterial properties. The achieved IMC/AgNWs exhibit a broad spectrum of antimicrobial properties against Gram-negative Porphyromonas gingivalis and Gram-positive Streptococcus mutans. When the IMC/AgNWs are cocultured with periodontal ligament stem cells, it possesses excellent osteoinductive activities under both non-inflammatory and inflammatory conditions. By constructing a rat mandibular infected periodontal defect model, the IMC/AgNWs achieve a near-complete healing through the canonical BMP/Smad signaling. Moreover, the IMC/AgNWs enhance vertical bone height and osseointegration in peri-implantitis in beagle dogs, indicating the clinical translational potential of IMC/AgNWs for infectious vertical bone augmentation.

Chalcogen Atoms Regulate the Organic Solar Cell Performance of B-N-Based Polymer Donors.

Donor polymers play a key role in the development of organic solar cells (OSCs). B-N-based polymer donors, as new types of materials, have attracted a lot of attention due to their special characteristics, such as high E(T1), small ΔEST, and easy synthesis, and they can be processed with real green solvents. However, the relationship between the chemical structure and device performance has not been systematically studied. Herein, chalcogen atoms that regulate the OSCs performance of B-N-based polymer donors were systematically studied. Fortunately, the substitution of a halogen atom did not affect the high E(T1) and small ΔEST character of the B-N-based polymer. The absorption and energy levels of the polymer were systematically regulated by O, S, and Se atom substitution. The PBNT-TAZ:Y6-BO-based OSCs device demonstrated a high power conversion efficiency of 15.36%. Moreover, the layer-by-layer method was applied to further optimize the device performance, and the PBNT-TAZ/Y6-BO-based OSCs device yielded a PCE of 16.34%. Consequently, we have systematically demonstrated how chalcogen atoms modulated the electronic properties of B-N-based polymers. Detailed and systematic structure-performance relationships are important for the development of next-generation B-N-based materials.

Obtaining and Characterizing New Types of Materials Based on Low-Density Polyethylene and Thermoplastic Starch

Significant interest is devoted to the development of new polymer blends by using concepts of the circular economy. Such materials have predetermined properties, are easy to recycle, ecological, and have a low carbon footprint. This research presents obtaining and characterization of polymer blends based on low-density polyethylene (LDPE) and thermoplastic starch (TPS). In the first stage, TPS was obtained through the gelatinization process, and, in the second stage, mixtures of LDPE and TPS were obtained through a melt mixing process at 150 °C for 7 min. The physical–mechanical characteristics of the samples, like hardness, elongation at break, rebound resilience, and tensile strength, were determined. The sample containing maleic anhydride grafted low-density polyethylene (LDPE-g-MA) as a compatibilizer shows improvements in elongation at break and tensile strength (by 6.59% and 40.47%, respectively) compared to the test sample. The FTIR microscopy maps show that samples containing LDPE-g-MA are more homogeneous. The SEM micrographs indicate that TPS-s is homogeneously dispersed as droplets in the LDPE matrix. From the thermal analysis, it was observed that both the degree of crystallinity and the mass loss at high temperature are influenced by the composition of the samples. The melt flow index has adequate values, indicating good processability of the samples by specific methods (such as extrusion or injection).

Design of Titanium Alloy Mixed Sucker Rods Using API Recommendation Method

Titanium alloy, as a new type of material, has many advantages compared to ordinary metal materials: high specific strength, excellent toughness and fatigue resistance, excellent corrosion resistance, etc. Firstly, the wave equation of titanium alloy pumping rods was established. Then, the equivalent stiffness, equivalent bulk density, and equivalent elastic modulus of titanium alloy mixed pumping rods were derived, and the frequency coefficients of different rod column combinations were calculated. Finally, based on the above research, the steps for designing titanium alloy pumping rods using API recommendation method were summarized. Based on this, the design of titanium alloy pumping rods can be completed using API recommendation method through the above formulas and steps.

İki Farklı Reçine Kullanılarak Oluşturulan Hibrit Kompozit Malzemelerin Araç Tamponlarında Kullanımının Araştırılması

As efforts to reduce vehicle weight in today's vehicles accelerate, efforts to find new types of materials that can replace traditional materials have accelerated. In this study, carbon fiber was used as a reinforcement element together with glass fiber for lightening in vehicle bumpers. While vinyl ester and polyester were chosen as the matrix material for the piece to be produced, production was made by the hand lay-up method. The produced samples were first subjected to tensile test and their mechanical values were determined. The mechanical test results were introduced to the ANSYS program, and separate analyzes were made for the materials produced on the same bumper design and the results were compared. According to the results of the analysis, there was 2.13 times decrease in total deformations in glass fiber/carbon fiber/Vinyl ester hybrid composites compared to glass fiber/vinyl ester homogeneous composites. In terms of equivalent stresses, 8% reduction was achieved in the carbon fiber /glass fiber/Vinyl ester hybrid composite compared to the carbon/Vinyl ester homogeneous composite. It was concluded that the choice of reinforcement and matrix is important for creating bumper material and improving the mechanical values of the bumper

Method of ensemble modeling for abrasive water jet machinability of metal materials

As a potential machining tool that can cut almost all kinds of materials, abrasive water jet (AWJ) has been widely used in various fields. However, when facing a new type of material, obtaining the machinability number, which has been used to calculate the cutting head traversing speed, is a big challenge in application. Currently, the machinability number can be obtained through a series of experiments. Although this method is feasible, it is time-consuming and involves high experimental costs. In this paper, an ensemble modeling method was investigated to predict the machinability number of metal materials using material properties that are usually published in the public domain. Two data enhancement algorithms, SMOTER and WERCS, and a quadratic polynomial feature enhancement method are used for small sample data pre-processing. Furthermore, two ensemble models, RandomForest and LightGBM, have been built. With these models, the machinability number could be calculated quickly instead of obtaining it through time-consuming experiments. The data pre-processing method and the ensemble modeling method in this paper could also be used in other small sample data scenarios.

An unexpected imidazole-induced porphyrinylphosphonate-based MOF-to-HOF structural transformation leading to the enhancement of proton conductivity.

Post-synthetic modification of proton-conducting metal-organic frameworks (MOFs) by loading small molecules capable of generating protons into pores is an efficient approach for developing a new type of material with improved ionic conductivity. Herein, the synthesis, characterization and proton conductivity of a novel electroneutral MOF based on palladium(II) meso-tetrakis(4-(phosphonatophenyl))porphyrinate, IPCE-1Pd, are reported. The exposure of the obtained framework to imidazole by the diffusion vapor method has surprisingly led to its complete crystal-to-crystal MOF-to-HOF transformation, resulting in the formation of a novel hydrogen-bonded organic framework (HOF) IPCE-1Pd_Im, which is the first example of such kind of structural change among all known MOFs. This modification has led to an almost 25-fold increase in the proton conductivity in comparison with the pristine MOF, reaching up to 6.54 × 10-3 S cm-1 at 85 °C and 95% relative humidity, which is one of the highest values among all known porphyrin-based HOFs.

FREE VIBRATION MODELING IN A FUNCTIONALLY GRADED HOLLOW CYLINDER USING THE LEGENDRE POLYNOMIAL APPROACH

Introduction: The building industry is under increasing pressure to maximize performance while reducing the costs and the environmental impact. To solve this problem, a new type of materials, i.e., functionally graded materials (FGMs), are proposed. These materials have the advantage of being able to withstand harsh environments without losing their properties. Purpose of the study: The paper aims to further extend the understanding of the propagation modes and characteristics of guided waves in FGM cylinders with infinite lengths. In the course of the study, we analyzed a cylindrical shell composed of three annular layers, each separated by a gradient layer across the wall thickness. A modeling tool based on the Legendre orthogonal polynomial method is proposed in the paper. Methods: The method applied results in an eigenvalue/eigenvector problem. The boundary conditions are integrated into the constitutive equations of guided wave propagation. The phase velocity and normalized frequency dispersion curves are calculated. Besides, the displacement distributions and stress field profiles for a functionally graded cylinder with various graded indices in both modes (axisymmetric and symmetric) are calculated and discussed. The results show a constant fluctuation of effective FGM material. Results: It was found that the phase velocity curves of the same mode decrease as the exponents of the power law increase. In addition, the boundary conditions have a greater impact on the normal stresses. The accuracy and effectiveness of the improved orthogonal polynomial method are demonstrated through a comparison of the exact solution obtained by an analytical-numerical method and our numerical results.