Fiber Network Research Articles

Bacterial Cellulose/Graphene Oxide/Hydroxyapatite Biocomposite: A Scaffold from Sustainable Sources for Bone Tissue Engineering.

Bone tissue engineering demands advanced biomaterials with tailored properties. In this regard, composite scaffolds offer a strategy to integrate the desired functionalities. These scaffolds are expected to provide sufficient cellular activities while maintaining the required strength necessary for the bone repair for which they are intended. Hence, attempts to obtain efficient composites are growing. However, in most cases, the conventional production methods of scaffolds are energy-intensive and leave an impact on the environment. This work aims to develop a biocomposite scaffold integrating bacterial cellulose (BC), hydroxyapatite (HAp), and graphene oxide (GO), designated as "BC/HAp/GO". All components are sourced primarily from agricultural and food waste as alternative means. BC, known for its biocompatibility, fine fiber network, and high porosity, serves as an ideal scaffold material. HAp, a naturally occurring bone component, contributes osteoconductive properties, while GO provides mechanical strength and biofunctionalization capabilities. The biomaterials were analyzed and characterized using a scanning electron microscope, a X-ray diffractometer, and a Fourier transform infrared spectrometer. The produced biocomposite scaffolds were tested for thermal stability, mechanical strength, and biocompatibility. The results showed a nanofibrous, porous network of BC, highly crystalline HAp particles, and well-oxygenated GO flakes with slight structural deformities. The synthesized biocomposite demonstrated promising characteristics, such as increased tensile strength due to added GO particles and higher bioactivity through the introduction of HAp. These inexpensively synthesized materials, marked by suitable surface morphology and cell adhesion properties, open potential applications in bone repair and regeneration.

Aerosol Assisted Chemical Vapour Deposition (AACVD) of Zinc dichalcogenoimidodiphosphinate Complexes for the Deposition of Zinc Selenide Thin Films.

Dichalcogenoimidodiphosphinate complexes of zinc [Zn{(EPiPr2)2N}2], [E=Se,Se; S,Se] were synthesized through metathetical reactions from the dichalcogenoimidodiphosphinate ligands [(EE'PiPr2NH)] (E, E'=Se, Se; S, Se). These complexes were characterized and used as single-source precursors through Aerosol-Assisted Chemical Vapour Deposition (AACVD) for the deposition of cubic zinc selenide (ZnSe) films on glass substrates. The deposition temperature occurred at 500 and 525 °C, while the flow rates of the carrier gas was 160 and 240 standard cubic centimetre (sccm). The morphology of the deposited films ranged between dense fibrous network and woven fibres. X-ray photoelectron spectroscopy (XPS) confirmed the presence of the constituent elements in zinc selenide.

Morphological Characteristics of Interatrial Septum and Its Clinical Relevance

ABSTRACTBackgroundThe development of new trans‐septal transcatheter interventions for patients with structural heart disease necessitates a precise and comprehensive understanding of the anatomy of the interatrial septum (IAS). The scarcity of gross anatomical studies has triggered our interest in exploring the morphometry and morphology of IAS.AimsTo study the morphology, morphometry and variations of the interatrial septum in autopsied human hearts.MethodsThe study was conducted on 97 autopsied fresh human hearts, in which we observed the position and shape of fossa ovalis (FOv), along with prominence of the limbus and its location. The diameter of FOv, thickness of its floor, redundancy and any variation in the IAS were noted.ResultsIn most cases (72.9%), the FOv was situated toward the inferior vena cava and was oval shaped (69.8%), with mean horizontal and vertical diameters of 17.21 ± 4.11 mm and 12.74 ± 3.78 mm, respectively. The limbus was prominent in 72.2% specimens, most commonly prominent all around (36.6%), followed by antero‐superior (28.2%), antero‐inferior (16.9%) and anterior (8.5%) prominence. The mean thickness of the floor of FOv was 0.71 ± 0.98 mm, and redundancy was observed in 47% of samples. Probe patency was seen only in 10.3% specimens. The right surface of the IAS showed more variations (71.1%) compared to the left (44.3%), in form of recesses, atrial septal pouches, fibrous strands, retinacular‐type fibrous networks and combination of more than one type.ConclusionVariations in the location of FOv, the prominence of limbus and the common occurrence of anatomical variants of the IAS mandate the preprocedural imaging of the region to reduce the failure rate and complications.

Digital Shear Printing of Mechanically Robust Liquid Metal Circuits with Hierarchical Embedded Structure for Paper Electronics

The seamless integration of recyclable and deformable liquid metal (LM) conductors into paper is attractive to developing flexible, breathable, and green electronics. However, the weak adhesion between paper and LM complicates the patterning. In addition, the low damage endurance of LM, an open problem for on‐surface conductors, restricts the practical applications. Here, a simple yet efficient approach of shear printing is reported to directly pattern hierarchical embedded LM circuits with erasure resistance onto paper. This is achieved by digitally applying the shear force to the solid gallium film to induce its adhesive wear with the paper, allowing the gallium to be embedded into the paper's fiber networks. Meanwhile, the pressure‐induced formation of microgrooves on paper allows the LM circuits to be surface‐embedded onto paper. The hierarchical embedded structure endows the LM circuits with enhanced mechanical damage endurance that they can even withstand eraser rubbing and tape peeling. Applications of the hierarchical embedded, mechanically robust, and breathable LM‐enabled paper electronics in enhanced humidity sensing, electrophysiology monitoring, and digital droplet microfluidics are also shown. This work opens doors to developing sustainable yet robust paper electronics by rationally utilizing the solid properties of low‐melting‐point metals.

Enhanced chitosan fibres for skin regeneration: solution blow spinning and incorporation with platelet lysate and tannic acid

Abstract In this study, we developed and characterised enhanced chitosan/polyethylene oxide (PEO) nanofibre scaffolds using solution blow spinning (SBS) for potential application in skin tissue engineering. SBS enabled the efficient and scalable production of fibre matrices with precise morphology control, facilitating the integration of PEO to improve spinnability, 100X the speed of electron spinning. Following fabrication, fibres were subjected to potassium carbonate neutralisation to reduce PEO content, improving chitosan stability in aqueous environments. Characterisation by scanning electron microscopy (SEM) and attenuated total reflectance Fourier-transform infrared spectroscopy (ATR-FTIR) confirmed structural integrity post-neutralisation and the successful incorporation with bioactive additives. Platelet lysate (PL) was incorporated to introduce growth factors, and tannic acid (TA) was added for antibacterial properties and enhanced mechanical stability through potential crosslinking. Mechanical testing showed that the optimised PL- and TA-enriched scaffolds exhibited the highest mechanical performance, with Young’s modulus of 7.0 ± 0.6 MPa, an ultimate tensile strength of 26.4 ± 2.3 MPa, elongation at break of 16.5 ± 1.7%, and toughness of 3.0 ± 0.3 MJ m−3 which is within the range of human skin. At the same time, SEM and ATR-FTIR analyses confirmed the stability and distribution of these functional agents within the fibre network. Biocompatibility tests with normal human dermal fibroblasts (NHDF) indicated low cytotoxicity, appropriate cell adhesion and proliferation over 14 days in culture, suggesting these scaffolds as promising candidates for wound healing and skin regeneration applications.

Enhanced Electromagnetic Interference Shielding in Cement Composites Utilizing Carbon Fiber Clustered Networks with Dual Different Lengths

Electromagnetic interference (EMI) shielding is crucial for radio frequency ranges, particularly around 1 GHz, to ensure the functionality and security of electronic devices and wireless communications especially within building materials. The inherent properties of typical metallic materials, such as their heavy weight and high cost, make them less suitable for mass production, particularly in the construction applications. Herein, we present a novel approach to improve EMI shielding efficiency of cement composites by incorporating two types of carbon fibers with distinct lengths as fillers and optimizing the clustering network among these fillers. By precisely controlling the length and proportion of long (mother) and short (anchor) carbon fibers, we demonstrate that a 7:3 ratio of 6 mm mother fibers to 2 mm anchor fibers yields optimal shielding efficiencies, delivering 65.3 dB at a low radio frequency (1 GHz) and 44.5 dB in the high X-band frequency range (8.2 – 12.4 GHz). Significantly, two-dimensional matrix simulations corroborate the geometric modifications occurring between fillers as the length and ratio of carbon fibers are altered, showing excellent agreement with our experimental results. Combined with an intriguing approach to fine-tune the clustered network of carbon fibers, this study highlights the critical role of filler geometry within the matrix in developing high-performance EMI shielding materials, offering new insights for the design of advanced EMI shielding solutions.

Deep learning and time series signal processing for bending detection in mining environment using optical fiber sensor

Optical fiber sensors are widely used to monitor environmental disturbances that may trigger or affect mining landslides, a complex phenomenon that involves various factors and can cause severe damage. In this study, we propose a method to detect the curvature of a bent optical fiber, which affects the optical signals traveling through it, using deep learning and time series signal processing. We use a Mach-Zehnder interferometer (MZI) sensor and a single-mode fiber (SMF) cable to capture the interference signal caused by different bending angles. We apply a transformation random convolutional kernel (TRANCE) to reduce the signal and extract its mean and standard deviation as features. We train a dense neural network (DNN) with three hidden layers to classify the bending events into four categories: low, medium, high, and extreme. We evaluate our method on a dataset of 400 samples and achieve an average accuracy of 99% in the confusion matrix and the fifty times tenfold validation experiments. Our method outperforms other methods that use multimode fiber (MMF), speckle images, and convolutional neural networks (CNNs) in terms of accuracy, speed, and generalization. Our method also has the advantages of using SMF, which enables integrated sensing and communication, and using 1D signals, which are easier to process than 2D images. Our method is suitable for high-speed signals containing information in dangerous environments.

A simulation platform for slender, semiflexible, and inextensible fibers with Brownian hydrodynamics and steric repulsion

The last few years have witnessed an explosion of new numerical methods for filament hydrodynamics. Aside from their ubiquity in biology, physics, and engineering, filaments present unique challenges from an applied-mathematical point of view. Their slenderness, inextensibility, semiflexibility, and meso-scale nature all require numerical methods that can handle multiple lengthscales in the presence of constraints. Accounting for Brownian motion while keeping the dynamics in detailed balance and on the constraint is difficult, as is including a background solvent, which couples the dynamics of multiple filaments together in a suspension. In this paper, we present a simulation platform for deterministic and Brownian inextensible filament dynamics, which includes nonlocal fluid dynamics and steric repulsion. For nonlocal hydrodynamics, we define the mobility on a single filament using line integrals of Rotne–Prager–Yamakawa regularized singularities and numerically preserve the symmetric positive definite property by using a thicker regularization width for the nonlocal integrals than for the self-term. For steric repulsion, we introduce a soft local repulsive potential defined as a double integral over two filaments, then present a scheme to identify and evaluate the nonzero components of the integrand. Using a temporal integrator developed in previous work, we demonstrate that Langevin dynamics sample from the equilibrium distribution of free filament shapes and that the modeling error in using the thicker regularization is small. We conclude with two examples, sedimenting filaments and cross-linked fiber networks, in which nonlocal hydrodynamics does and does not generate long-range flow fields, respectively. In the latter case, we show that the effect of hydrodynamics can be accounted for through steric repulsion.

Phase demodulation method for stable long-haul frequency transmission based on the Michelson interferometer.

In this Letter, we present a fiber-optic radio frequency (RF) transmission scheme based on phase modulation with an interferometric detection structure. A self-developed Michelson interferometer (MI) is used to demodulate the frequency signal via an electrically controlled optical shifter. The two complementary outputs from the interferometer are detected using a balanced detector, which suppresses the common-mode noise of the fiber link. The structure is tested in the laboratory using a frequency transfer system over a 560 km fiber link. Experimental results show that a stable 2.4 GHz frequency transmission with a fractional frequency instability of 3.9 × 10-14 at 1 s and 6.2 × 10-17 at 10,000 s is achieved. Compared with the frequency transmission system based on intensity modulation and direct detection, the frequency instability is improved from 7.3 × 10-14 to 3.9 × 10-14 at 1 s. We believe that the proposed method will be useful for the construction of time-frequency synchronous fiber networks.

Rupture Mechanics of Blood Clot Fibrin Fibers: A Coarse-Grained Model Study

Thrombosis, when occurring undesirably, disrupts normal blood flow and poses significant medical challenges. As the skeleton of blood clots, fibrin fibers play a vital role in the formation and fragmentation of blood clots. Thus, studying the deformation and fracture characteristics of fibrin fiber networks is the key factor to solve a series of health problems caused by thrombosis. This study employs a coarse-grained model of fibrin fibers to investigate the rupture dynamics of fibrin fiber networks. We propose a new method for generating biomimetic fibrin fiber networks to simulate their spatial geometry in blood clots. We examine the mechanical characteristics and rupture behaviors of fibrin fiber networks under various conditions, including fiber junction density, fiber tortuosity, fiber strength, and the strain limit of single fiber rupture in both tension and simple shear cases. Our findings indicate that the stress-strain relationship of the fibrin fiber network follows a similar pattern to that of individual fibers, characterized by a shortened entropy stretching phase and an extended transition phase. Fiber junction density, fiber strength, and single fiber rupture limit predominantly influence the stress of the network, while fiber tortuosity governs the strain behavior. The availability of more fibers in shear cases to bear the load results in delayed rupture compared to tension cases. With consideration of different factors of fibrin fibers in networks, this work provides a more realistic description of the mechanical deformation process in fibrin fiber networks, offering new insights into their rupture and failure mechanisms. These findings could inspire novel approaches and methodologies for understanding the fracture of fibrin networks during a surgical thrombectomy.

Silicon‐Nitride‐Integrated Hybrid Optical Fibers: A New Platform for Functional Photonics

AbstractHybrid optical fibers that integrate exotic materials within more traditional silica glass architectures open a route for the development of highly functional all‐fiber photonic systems. Here, a compact hybrid optical fiber platform is reported formed by depositing a silicon nitride (SiNx ‐ nitride‐rich) nanolayer onto the surface of fused‐silica microfibers via plasma‐enhanced chemical vapor deposition. The SiNx thickness can be precisely tuned over a range of tens of nanometers, while maintaining an ultra‐smooth deposition surface, allowing for tunable coupling between the modes guided predominantly in the nanolayer and the fiber core. The effective indices of the hybrid modes display an anti‐crossing behavior under resonant conditions, resulting in a rich dispersion landscape that can be tailored via adjusting the SiNx thickness. By fabricating a SiNx‐silica hybrid microfiber with precise dispersion engineering and a low insertion loss, a flat supercontinuum spectrum spanning >1.5 octaves (−20 dB level) has been generated. The results demonstrate that SiNx‐silica hybrid microfibers can offer a unique combination of broadband transmission and wide tunablity of the mode properties, while still retaining the benefits of robust integration with conventional silica glass fiber networks, providing a rich playground for hybrid fiber‐based photonic systems.

Design and Synthesis of Triazine-Based Hydrogel for Combined Targeted Doxorubicin Delivery and PI3K Inhibition.

Melanoma, an aggressive skin cancer originating from melanocytes, presents substantial challenges due to its high metastatic potential and resistance to conventional therapies. Hydrogels, three-dimensional networks of hydrophilic polymers with high water-retention capacities, offer significant promise for controlled drug delivery applications. In this study, we report the synthesis and characterization of hydrogelators based on the triazine molecular scaffold, which self-assemble into fibrous networks conducive to hydrogel formation. Rheological analysis confirmed their hydrogelation properties, while microscopic techniques including FE-SEM and FEG-TEM provided insights into their morphological networks. The drug delivery capability of these hydrogelators was evaluated using doxorubicin, a widely employed anticancer agent, demonstrating enhanced biocompatibility and reduced side effects compared to free doxorubicin. Additionally, the hydrogelators exhibited inhibitory activity against phosphoinositide 3-kinase (PI3K), a key enzyme frequently mutated in cancer, and also involved in melanoma progression. The dual functionality of this delivery system - controlled drug release and PI3K inhibition - highlights the potential of triazine-based hydrogelators as innovative therapeutic platforms for melanoma treatment.

Field Experiments of Distributed Acoustic Sensing Measurements

Modern, large bridges and tunnels represent important nodes in transportation arteries and have a significant impact on the development of transportation. The health and safety monitoring of these structures has always been a significant concern and is reliant on various types of sensors. Distributed acoustic sensing (DAS) with telecommunication fibers is an emerging technology in the research areas of sensing and communication. DAS provides an effective and low-cost approach for the detection of various resources and seismic activities. In this study, field experiments are elucidated, using DAS for the Hong Kong–Zhuhai–Macao Bridge, and for studying vehicle trajectories, earthquakes, and other activities. The basic signal-processing methods of filtering and normalization are adopted for analyzing the data obtained with DAS. With the proposed DAS technology, the activities on shore, vehicle trajectories on bridges and in tunnels during both day and night, and microseisms within 200 km were successfully detected. Enabled by DAS technology and mass fiber networks, more studies on sensing and communication systems for the monitoring of bridge and tunnel engineering are expected to provide future insights.

Effect of polyphenol-hydrocolloids interaction on protein oxidation, structure and water distribution properties of thermally processed meat

In order to overcome the weakness and instability of polyphenols during thermal processing, the effect of various food additives including hydrocolloids combined with Gallic acids (GA) on structure, water distribution and oxidative properties of roasted meat was investigated. The findings publicized that the combined addition of GA with carrageenan (CAR) and sodium pyrophosphate (SPP) significantly (P < 0.05) decreased cooking loss, surface hydrophobicity, carbonyl formation and prevented the loss of sulfhydryl groups compared to alone GA and control. The fluorescence spectroscopy and FT-IR analysis showed that combination of GA with CAR and/or SPP decreased hydrophobic aggregation, prevented oxidation of side chain amino acids residues and developed GA-CAR/SPP non-fluorescent complexes with proteins. The inhibitory mechanism of G-CAR and G-SPP was predominated by retaining tightly bound water inside the macromolecules and prevented its seepage from the myofibrillar fiber network, which was also evidenced by high adhesiveness and gumminess of those samples. The microstructure endorsed the compact structure of those samples whereas uneven surface and intercellular spaces were noticed in control samples. Finally, correlation and principal component analysis further differentiated the most influential parameters and mechanism of action. These findings suggest that GA alone is not compatible for thermal processing until supported by an effective additive having potential of creating synergism to improve the thermal stability and quality characteristics of meat.

A novel polydopamine-coated bacterial cellulose/g-C3N4 membrane for highly efficient photocatalytic degradation of methylene blue

Photocatalytic oxidation emerges as an eco-friendly approach for chemically degrading water-borne organic pollutants. Establishing a more sustainable process for synthesizing photocatalyst membranes with higher efficiency and reusability is crucial for advancing safe water remediation solutions. In this study, we present a novel photocatalytic membrane incorporating bacterial cellulose (BC), a naturally occurring biopolymer with an intricate fibrous network, and graphitic carbon nitride (g-C3N4), a visible light-responsive non-metal photocatalyst. The composite membrane is augmented with a coating of polydopamine (PDA), an amorphous polymeric layer derived from dopamine to enhance light absorption and reduce photoexcited charge recombination. The BC/g-C3N4/PDA membrane demonstrates a substantial improvement in methylene blue removal efficiency, up to 95.39 % within 150 min of irradiation. Moreover, the PDA-modified membrane exhibits noteworthy recyclability, retaining significant photodegradation ability for up to three cycles. This method offers an accessible and scalable approach to fabricating a highly effective photocatalyst composite membrane suitable for industrial applications.

Performance analysis of cyanoacrylate bonded optical fiber 2 × 2 acoustic couplers for sensing applications

In this paper the behavior of a cyanoacrylate (CA) bonded optical fiber acoustic signal coupler will be studied in detail. A stainless-steel mold was used to create a 2×2 CA coupler that transfers guided waves between two optical fibers. Four FBGs placed at each port were used to assess the repeatability, signal behavior, and performance of the coupler produced. Signal propagation through the network was mapped to determine how the initial acoustic signal traveled and subdivided through the fiber network. To examine the repeatability of the signal coupler interaction, the experiments were performed multiple times. Finally, the acoustic energy transferred through the coupler’s paths was calculated to assess the performance of the 2×2 coupler. The coupler successfully and repeatably transferred an acoustic signal from one optical fiber to another; however, the performance associated with the current coupler design was limited by relatively large excess and return losses. Improvements to the CA coupler design are then proposed from the results.

On exploiting the architecture of annual ring growth for developing a new class of bio-inspired composites

Inspired by several biological structures available in nature, bio-inspired composite structures are evidenced to exhibit a noteworthy enhancement in various mechanical and multi-physical performances as compared to conventional structures. This article proposes to exploit the architecture of annual ring growth of the stems of trees for developing a new class of bio-inspired composites with enhanced static and dynamic performances, including deflections, stresses, strain energy, and vibration. Concentric circular annual-ring geometries are considered where each layer of concentric circular fibers is analogous to the growth per annum of trees. The annual rings are modeled in a finite element-based computational framework by idealizing each layer as a composite of graphite fibers and epoxy matrix under different boundary conditions. The ratio of deflection to weight and frequency to weight of bio-inspired and traditional composites are compared by considering different parameters such as the number of annual rings, layers, and supporting stiffeners. The numerical results reveal that the proposed bio-inspired composites can enhance and modulate the static and dynamic properties to a significant extent, opening new design pathways for developing high-performance fiber network composites.

Rheology of Cellulosic Microfiber Suspensions Under Oscillatory and Rotational Shear for Biocomposite Applications

This study investigates the rheological behavior of cellulose microfiber suspensions derived from kahili ginger stems (Hedychium gardnerianum), an invasive species, in two adhesive matrices: a commercial water-based adhesive (Coplaseal®) and a casein-based adhesive made from non-food-grade milk, referred to as K and S samples, respectively. Rheological analyses were performed using oscillatory and rotational shear tests conducted at 25 °C, 50 °C, and 75 °C to assess the materials’ viscoelastic properties more comprehensively. Oscillatory tests across a frequency range of 1–100 rad/s assessed the storage modulus (G′) and loss modulus (G″), while rotational shear tests evaluated apparent viscosity and shear stress across shear rates from 0.1 to 1000 s−1. Fiber-free samples consistently showed lower moduli than fiber-containing samples at all frequencies. The incorporation of fibers increased the dynamic moduli in both K and S samples, with a quasi-plateau observed at lower frequencies, suggesting solid-like behavior. This trend was consistent in all tested temperatures. As frequencies increased, the fiber network was disrupted, transitioning the samples to fluid-like behavior, with a marked increase in G′ and G″. This transition was more pronounced in K samples, especially above 10 rad/s at 25 °C and 50 °C, but less evident at 75 °C. This shift from solid-like to fluid-like behavior reflects the transition from percolation effects at low frequencies to matrix-dominated responses at high frequencies. In contrast, S samples displayed a wider frequency range for the quasi-plateau, with less pronounced moduli changes at higher frequencies. At 75 °C, the moduli of fiber-containing and fiber-free S samples nearly converged at higher frequencies, indicating similar effects of the fiber and matrix components. Both fiber-reinforced and non-reinforced suspensions exhibited pseudoplastic (shear-thinning) behavior. Fiber-containing samples exhibited higher initial viscosity, with K samples displaying greater differences between fiber-reinforced and non-reinforced systems compared to S samples, where the gap was narrower. Interestingly, S samples exhibited overall higher viscosity than K samples, implying a reduced influence of fibers on the viscosity in the S matrix. This preliminary study highlights the complex interactions between cellulosic fiber networks, adhesive matrices, and rheological conditions. The findings provide a foundation for optimizing the development of sustainable biocomposites, particularly in applications requiring precise tuning of rheological properties.

Temperature-Dependent Characterization of Long-Range Conduction in Conductive Protein Fibers of Cable Bacteria.

Multicellular cable bacteria display an exceptional form of biological conduction, channeling electric currents across centimeter distances through a regular network of protein fibers embedded in the cell envelope. The fiber conductivity is among the highest recorded for biomaterials, but the underlying mechanism of electron transport remains elusive. Here, we performed detailed characterization of the conductance from room temperature down to liquid helium temperature to attain insight into the mechanism of long-range conduction. A consistent behavior is seen within and across individual filaments. The conductance near room temperature reveals thermally activated behavior, yet with a low activation energy. At cryogenic temperatures, the conductance at moderate electric fields becomes virtually independent of temperature, suggesting that quantum vibrations couple to the charge transport through nuclear tunneling. Our data support an incoherent multistep hopping model within parallel conduction channels with a low activation energy and high transfer efficiency between hopping sites. This model explains the capacity of cable bacteria to transport electrons across centimeter-scale distances, thus illustrating how electric currents can be guided through extremely long supramolecular protein structures.

Regulating Entanglement Networks of Fibrillatable Binders for Sub-20-µm Thick, Robust, Dry-Processed Solid Electrolyte Membranes in All-Solid-State Batteries.

Despite significant advancements in all-solid-state batteries (ASSBs), the reliance on thick solid electrolyte (SE) membranes hinders their commercial viability. Although the dry process using polytetrafluoroethylene (PTFE) binder is proposed for thin SE membranes, a comprehensive understanding of the correlation between PTFE fibrillation and SE membrane quality remains lacking. Here an important guidance is provided for producing durable SE membranes that can be reduced to sub-20-µm thickness by regulating the entanglement networks of PTFE. While establishing fabrication parameters; shear time and shear temperature, a dominant effect of the number-average molecular weight (Mn) on PTFE fibrillation is revealed for the first time. Moreover, the degree of PTFE fibrillation is quantified using systematic X-ray diffraction (XRD) analysis. The SE membrane utilizing the high-Mn PTFE binder that achieves a maximum fibrillation degree (≈98%) and thus forms highly entangled fibrous PTFE network interweaving SE particles, exhibited superior toughness. Consequently, the 18 µm thick SE membrane with 0.5wt% high-Mn PTFE shows a considerably higher areal conductance. The ASSB using this durable, ultrathin SE membrane outperforms its counterparts that used flimsy SE membranes or pure SE pellets. Finally, uniquely thin ASSBs demonstrate significantly improved cell-level energy densities, showcasing the promising potential for practical ASSB fabrication.