Neritic Carbonate Research Articles

High-latitude platform carbonate deposition constitutes a climate conundrum at the terminal Mesoproterozoic

During the Mesoproterozoic Era, 1600 to 1000 million years ago, global climate was warm with very little evidence of glaciation. Substantial greenhouse warming would have been required to sustain this ice-free state given 5-18% lower solar luminosity. Paleomagnetic data reported here place voluminous ca. 1.2 Ga shallow marine carbonate deposits from India at an unexpectedly high latitude of around 70° from the equator. Previous studies noted high latitudes, but their implication was never considered. Here, we evaluate the temporal-latitudinal distribution of neritic carbonate deposits across the Proterozoic and identify similar deposits from North China that together with those from India are seemingly unique to the late Mesoproterozoic. A uniformitarian interpretation implies that this is cold-water carbonate deposition, but facies similarity with low-latitude neritic deposits rather suggests a hotter climate and elevated polar ocean temperatures of 15–20° or higher. This interpretation represents a climate conundrum that would require much greater greenhouse warming than documented for the Mesoproterozoic.

A comparative approach employing microCT for the analysis of Cenozoic foraminifera from the Brazilian carbonate equatorial platform

Worldwide, some of the largest hydrocarbon reservoirs are located in tropical neritic carbonate deposits. Biostratigraphic and paleoenvironmental analyzes of these sedimentary records are often based on the study of foraminiferal assemblage. Foraminifera-based biozones are widely employed in the oil industry to support drilling processes that, alongside petrophysical prospecting, define interval favorable for exploiting hydrocarbon resources. Both scientific research and the petroleum industry, however, usually apply traditional petrographical and paleontological methods to analyze microfossil assemblages, especially for large benthic foraminifera. New, faster, and more accurate methods based on microCT analyzes have emerged as a valuable high-output tool to obtain high-resolution microfossil records for biostratigraphy and paleoenvironmental reconstructions. This method is also useful for the development of digital databases for artificial intelligence applications. MicroCT analyzes, therefore, lead to faster identification of foraminifera assemblage and support digital access to international foraminifera repositories and reference collections, introducing a new dimension in micropaleontological research.

Availability and type of energy regulate the global distribution of neritic carbonates

The study of carbonate rocks is primarily reliant on microfacies analysis, which is strongly based on the comparison with modern allochem assemblages. Despite the existence of several models aimed at comprehensively explaining, on the bases of abiotic factors, the distribution of carbonate-producing organisms, a global, quantitative and standardized overview of the composition of shallow-water carbonate sediments is still missing. Aiming to address this gap in knowledge, the current study provides a global database of the available quantitative data on neritic carbonate sediments. This is paired with satellite-based observations for the abiotic parameters. The results highlight a non-linear, multi-variable, dependence in the distribution of allochems and suggest that depth, temperature, and trophic state are, to a certain extent, interchangeable. The implication of which is a level of non-uniqueness for paleoenvironmental interpretation. The resulting distribution is rather continuous and stretches along an energy gradient. A gradient extending from solar energy, with autotrophs and symbiont-bearing organisms to chemical energy with heterotrophs. Further, quantitative data from modern oceans are still required to disentangle the remaining elements of uncertainty.

Eocene-Oligocene large-scale circulation of the East Asian summer monsoon recorded in neritic carbonates of the proto-South China Sea

When the modern features of large-scale Asian monsoonal circulation were set-up is poorly constrained and pre-Neogene monsoonal archives are rare. This study investigates the temporal evolution of neritic carbonates in the proto-South China Sea to reconstruct East Asian monsoonal currents and winds during the middle to late Paleogene. Analysis of three-dimensional seismic and well core data from the North-West Palawan block reveals the occurrence of a set of thick (>125 m), aggrading Halimeda bioherms, early Oligocene in age. By analogy with Holocene green algal buildup counterparts, they are interpreted to form in nutrient-rich areas subject to upwelling currents and reflect the early presence of a strong coastal jet in the Proto-South China Sea, as seen today during the summer monsoonal season. The analysis of the underlying mixed carbonate–siliciclastic ramp shows that mesotrophic conditions already prevailed during the late Eocene, thus suggesting that modern-like summer East Asian Monsoon large-scale circulation was possibly active as early as the late Eocene in the Proto-South China Sea. Evidence for upwelling currents vanishes in late early Oligocene carbonate-producing biota, that are characterized by the significant development of euphotic hermatypic coral communities reflecting lower nutrient concentrations. This turnover coincides with the opening of the modern South China Sea and is interpreted to result from the southward drift of the North-West Palawan block which placed the area away from the Chinese margin and the coastal jet. Our results highlight therefore that many of the features of the summer East Asian Monsoon large-scale circulation are rooted in the middle Paleogene.

Sediment dynamics and geomorphology of a submarine carbonate platform canyon system situated in an arid climate setting

ABSTRACTChanges in neritic carbonate production and sediment transport off platforms are related to climate variations, sea‐level fluctuations and tectonic processes. Canyon systems marking the platform slopes represent critical source‐to‐sink pathways transporting shallow‐water sediments basinward. However, these export systems and related processes are primarily studied on platform slopes in humid to tropical climate settings. A newly discovered canyon system on the leeward margin of the Al Wajh platform (north‐east Red Sea) represents the ideal laboratory to investigate source‐to‐sink pathway dynamics in an arid climate that prevailed since the Late Pleistocene. A high‐resolution bathymetry map was established to characterize the slope morphology. The system displays a U‐shaped, 10 km long main channel dominantly sourced by the north‐west/south‐east running outer channel and two smaller 2 to 3 km long canyons. The latter are positioned perpendicular to the main canyon. A 4 km wide head scarp at the reef edge and dozens of amphitheatre‐shaped scarps along the mid to lower slope suggest significant slope failures over time. The analysis of four sediment cores collected on a profile down the canyon revealed sedimentation rates of 26 cm/ka at the mid‐slope to 9.4 cm/ka in the basin. Three main sediment‐export processes were identified: (i) sandy and neritic component‐poor turbidites; (ii) winnowing of strontium‐rich carbonate fines through surface currents; and (iii) remobilized carbonate fines on the upper slope. As of the Last Glacial, turbidites are predominantly deposited during times of significant sea‐level instability, both rises and falls, whereas their flat‐topped‐tropical counterparts show a higher turbidite frequency during highstands. Strontium‐rich carbonate fines are exported similarly through time in both climate settings. Overall, sediment export is controlled by: (i) the platform morphology (flat‐topped versus rimmed lagoon); (ii) variations in sediment production; (iii) sea‐level variations (exposure or flooding of sediment production areas); and (iv) the interaction between the sedimentary system and atmospheric changes (sediment production and delivery).

Relative sea level response to mixed carbonate-siliciclastic sediment loading along the Great Barrier Reef margin

The continental shelf along northeastern Australia is the world's largest mixed carbonate-siliciclastic passive margin and the location of the Great Barrier Reef (GBR). Following sea-level transgression during the last deglaciation, extensive sediment was deposited along the GBR due to neritic carbonate deposition (including shelf edge reefs, Holocene reefs and Halimeda bioherms) and fluvial discharge of terrigenous siliciclastic sediments. Such sediment loading can alter local relative sea level (RSL) by several metres through the sediment isostatic adjustment (SIA) process, a signal that is poorly constrained at the GBR. In this study, we used a glacial isostatic adjustment (GIA) model to develop an ensemble-based sediment loading history for the GBR since Marine Isotope Stage 2 (MIS 2). A Bayesian style framework is adopted to calibrate the sediment history ensemble and GIA model parameters using a sea-level database. According to our results, 1853.7 Gt (1613.1-2078.7 Gt, 95% confidence interval) of sediment have been deposited across the GBR since MIS 2 (28 ka BP), causing spatially variable relative sea-level change with the highest magnitude (0.9-1.1 m) found in the outer shelf of the southern central GBR (18.4-21.6∘ S). Because the SIA-induced RSL rise is unrelated to ice mass loss, failing to correct for this signal will lead to systematic overestimation of grounded ice volume by up to ∼4.3 × 105 km3 during the Last Glacial Maximum. Additionally, we found that spatial variation in sediment loading and coastal environment may explain the different RSL history documented by published fossil coral reef records from Noggin Pass and Hydrographer's Passage. These results highlight the importance of considering SIA for any postglacial sea-level studies adjacent to large sediment systems. Lastly, by quantifying both the GIA and SIA signals, we provide a spatially and temporally complete RSL reconstruction that is well-suited to be used as a boundary condition to study the evolution of the GBR shelf and slope sedimentary system.

Record of a dense succession of drowning phases in the Alpstein mountains, northeastern Switzerland: Part II—the Lower Cretaceous Schrattenkalk Formation (late Barremian)

The Schrattenkalk Formation represents a complete succession of Lower Cretaceous shallow-water carbonate platform series cropping out in the Alpstein massif of north-eastern Switzerland. The Schrattenkalk Formation is traditionally divided into two sedimentary units, the “Lower” and the “Upper” Schrattenkalk, separated by the more marly Rawil Member. The “Lower” Schrattenkalk is habitually dated to the late Barremian, while the Rawil Member and the “Upper” Schrattenkalk are dated to the early Aptian. New field observations, however, call the lithostratigraphic dichotomy of the Schrattenkalk into question, as the neritic carbonates are disrupted by several key surfaces associated with karstic episodes and/or transgressive sediments, corresponding to ammonite-rich hemipelagic deposits on the distal shelf. A large number of ammonites were collected in the Drusberg Member as well as rare ammonites from the Schrattenkalk Formation. These ammonites as well as the neritic macrofauna from the Schrattenkalk Formation allow a precise dating of the onset of the Schrattenkalk Formation across the Alpstein massif and its successive phases of progradation. Three successive carbonate bodies and a fourth sedimentary intermediate rock body at the top of the Schrattenkalk platform are defined, based on new biostratigraphic data and updated interpretations of the sequence stratigraphy and geochemical data. The data shows a progressive onset of the Schrattenkalk carbonate platform along the studied transect, following a SE progradation over time. The oldest deposits refer to the upper Barremian T. vandenheckii Zone and the youngest carbonates to the uppermost Barremian M. sarasini Subzone. The new dating of the discontinuity surfaces and key-beds highlight three successive flooding events. The first drowning phase, which correlates with the "Sartousiana" event, dates from the middle late Barremian (upper T. vandenheckii—lower G. sartousiana Zone). The second phase, represented by the Rawil Member, is an incipient drowning, which seems to coincide with the latest Barremian Taxy event (usually reported to the I. giraudi and lowermost M. sarasini zones) according to rare ammonite discoveries. The final demise of the Schrattenkalk platform, situated close to the Barremian-Aptian boundary, is related to an exposure and consecutive drowning event.

More gaps than record! A new look at the Pliensbachian/Toarcian boundary event guided by coupled chemo-sequence stratigraphy

The Pliensbachian/Toarcian boundary (Pl/To) event precedes by ca. 1 Myr the onset of the Toarcian Oceanic Anoxic Event. It corresponds to a second order mass extinction associated with an outstanding collapse of shallow marine ecosystems at global scale. Yet, our knowledge about its exact driver(s) and unfolding is relatively ambiguous due to the numerous hiatuses present in the sedimentary record during this critical time interval. In this study, an integrated carbon isotope chemostratigraphy and sequence stratigraphy approach is applied to two case studies (the upper Pliensbachian in South-East France and the Pliensbachian–Toarcian transition in Morocco) to demonstrate how the major changes in sea-level and sedimentation supply accompanying the Pl/To event led to the formation of ubiquitous, often cryptic hiatal surfaces in the sedimentary record. Hence, as a consequence of strongly progradational stacking pattern during the latest Pliensbachian related to a global sea-level lowstand associated with cold greenhouse climate, proximal settings were characterized by bypass and/or erosion, inducing an incomplete record of the Spinatum chronozone in localities situated in the outer part of sedimentary basins. In the earliest Toarcian, the collapse of the neritic carbonate factory led to a halt of carbonate mud export into the basin, resulting in sediment starvation in most basins characterized by a carbonate-dominated sedimentation regime before the environmental perturbation. Only localities where vigorous siliciclastic sediment supply took over are likely to have a more complete sedimentary record of the immediate aftermath of the carbonate production collapse. This combination of causes explains the ubiquitous incompleteness of the record of the Pliensbachian/Toarcian transition in numerous European localities where the bulk of our current understanding about the Pl/To event derives from. A comparison between the two known most expanded and complete records of the Pliensbachian–Toarcian transition of the Llanbedr (Mochras Farm) core in Wales and Bou Oumardoul n'Imazighn section in Morocco shows that the onset of the environmental perturbations is associated with a positive carbon isotope excursion spanning the Pliensbachian/Toarcian boundary. This is followed by a negative carbon isotope excursion during the earliest Toarcian that coincides with the global collapse of neritic carbonate factory and an ample sea-level fall.

Darriwilian–Sandbian (Middle–Late Ordovician) shallow warm-water deposits in the Upper Yangtze region, South China: A case study from the Qiaojia area, northeastern Yunnan Province

The Middle–Late Ordovician Nuoduo and Huadan formations are well exposed at Songliang of northeastern Yunnan Province, representing rare neritic carbonate sediments deposited in the Yangtze region, South China during that time. Detailed sedimentological analyses support the recognition of ten microfacies from the succession, including shale (MF 1), argillaceous mudstone/dolostone (MF 2), mollusk-ostracod wacke-packstone (MF 3), peloidal wacke- to pack-grainstone/dolostone (MF 4), ooid-cortoid-peloid pack-grainstone/dolostone (MF 5), peloidal bindstone (MF 6), bioclastic wacke-packstone (MF 7), green algae mud-wackestone to floatstone (MF 8), bioclast-lithoclast float-rudstone (MF 9) and green algae bindstone (MF 10). Types A, B and C of shallowing-upward sequences are constructed according to vertical associations of MFs. The Nuoduo Formation mainly comprises Type A and Type B, both being characterized by abundant peloids, ooids, cortoids and aggregate grains. MF 5 and MF 6 cap the Type A and Type B sequences, respectively, suggesting an overall restricted marine environment shifting cyclically from lagoon to shoal, or lagoon to tidal flat, respectively. Type C sequences, occurring in the topmost Nuoduo to Huadan formations, contain various green algae indicative of open-sea, euphotic subtidal zones. The transition from A and B to C sequences is marked by ferruginous ooidal intervals, possibly correlated to relative sea-level rise and/or tectonic activities. A continuous neritic, warm-water environment is proposed for this area from late Middle to Late Ordovician, with the Nuoduo Formation filling the absence of warm-water deposits in the tropical or subtropical Yangtze region during Middle Ordovician. The increasing diversity and abundance of green algae in the Huadan Formation might represent a global radiation event of marine flora during the studied interval. Unique fossils and environments distinct from those of the interior Yangtze region are documented here, leading to a better understanding of the Ordovician System regionally and globally.

A new discosorid and some other nautiloids from the Givetian of the Rhenish Massif, Germany

Nautiloids were subordinate inhabitants of Middle Devonian Rhenish reefs and in surrounding neritic carbonate facies. However, a literature review shows the presence of more than 45 orthoconic, cyrtobreviconic, and gyroconic taxa, which are mostly insufficiently known. We report the first discovery of an orthobreviconic representative of the order Discosorida from the initial phase (Binolen Member) of the thick Hagen-Balve Reef Complex in the Hönne Valley (northern Sauerland). It belongs to a new genus and species (Binoleniceras stichlingi n. gen. n. sp.) that is characterised by fast conch expansion, fine longitudinal ribbing, and a marginal siphuncle with short, recumbent cyrtochoanitic (dorsally) and suborthochoanitic (ventrally) septal necks, rounded adapical thickenings (bulletes), strongly thickened connecting rings, and irregular lamellae in the septal opening. It has no described relative in the Middle Devonian of Central or Southern Europe. Other taxa discussed are the oncoceratoid Cranoceras Hyatt, 1884, with the first Rhenish record of Cranoceras subdepressum (Roemer, 1850), and the archiacoceratid Cyrtoceratites, with a possibly new species with very large-sized siphuncle.

Anatomy of a platform margin during a carbonate factory collapse: implications for the sedimentary record and sequence stratigraphic interpretation of poisoning events

Sequence stratigraphic interpretations are limited in their prediction of sedimentary architecture and changes in sea-level when used in systems characterized by marked fluctuations in sediment supply, particularly in carbonate-dominated environments. Pronounced variations in sediment supply occurred during the Pliensbachian–Toarcian transition, when significant perturbations of the carbon cycle and intense environmental disturbances led to a global shutdown of carbonate production. We studied the impact of this event on sedimentation and stratal stacking patterns in the Moroccan central High Atlas. We reconstructed the lateral variations in facies and sedimentary geometries along a carbonate platform margin and slope in the field by tracking six key discontinuity surfaces covering the Pliensbachian–Toarcian transition from the platform margin to the toe-of-slope. This work highlights the difficulties in sequence stratigraphic interpretations in cases of neritic carbonate factory collapse without assessments of shoreline movement because the stacking patterns in open marine environments do not necessary reflect the regional variation in base level in disturbed carbonate systems. This study also emphasizes the uncertainties associated with focusing solely on lower offshore strata to assess the history and causes of palaeoenvironmental perturbations because decreases in the rate of carbonate production dampen neritic carbonate shedding and therefore favour the creation of a hiatus in deep water settings.

Geochemical expression of sequence stratigraphic surfaces: A case from Upper Cretaceous shallow-water carbonates of southeastern Neo-Tethys margin, SW Iran

Providing a chronostratigraphic framework often is problematic in shallow-marine carbonates with poor biostratigraphic resolution. In such cases, an integration of geochemical, sedimentological, and paleontological data can be used to construct a reliable sequence stratigraphic framework. This study focuses on elemental concentrations and isotopic ratios of Cenomanian–Santonian (C–S) neritic carbonates in SW Iran used to construct a sequence stratigraphic framework, asses sequence ages and durations of hiatus. The diagenetic and geochemical expression of two paleoexposure surfaces, representing type-I sequence boundaries (SBs), are discussed. Increase in Fe and Rb concentrations and decrease in Ca content are recorded at and/or below distinct erosional surfaces. Mg content shows a facies-dependent response with former LMC (low magnesium calcite) or aragonitic facies showing increase while HMC (high magnesium calcite) indicates decrease in response to SBs. Mn shows considerable changes apart from sequence surfaces that are strongly facies dependent. Sr concentrations show an increase in HMC and decrease in LMC in samples which experienced semi-closed meteoric diagenesis, far below the SBs. However, in samples characterized by open system diagenesis, directly underlying the SBs, Sr tends to decrease in all components. The Sr/Rb ratio is a reliable tool in detecting erosional SBs, shown as conspicuous negative excursions. C (carbon) and O (oxygen) isotopes show distinct negative excursions at erosional SBs and a slight increase at or around the MFSs. The 87Sr/86Sr ratio shows clear positive excursions at SBs probably due to 87Rb decay in incorporated aluminosilicate detritus, which makes it as the most reliable proxy for the detection of SBs in the studied sections. Two main erosional SBs are marked by 87Sr/86Sr ratios including the CT-ES (Cenomanian–Turonian boundary exposure surface) and mT-ES (middle Turonian exposure surface) with hiatus durations of 0.53 and 2.7 Myr, respectively. These paleoexposure surfaces are correlated with other neritic sections of C–S sequences in SW Iran.

New Facies Model and Carbon Isotope Stratigraphy for an Ediacaran Carbonate Platform From South America (Tamengo Formation—Corumbá Group, SW Brazil)

The Ediacaran is a period characterized by the diversification of early animals and extensive neritic carbonate deposits. These deposits are still not well understood in terms of facies and carbon isotope composition (δ13C). In this study we focus on the Tamengo Formation, in southwestern Brazil, which constitutes one of the most continuous and well-preserved sedimentary record of the late Ediacaran in South America. We present new detailed lithofacies and stable isotopes data from two representative sections (Corcal and Laginha) and revise the paleoenvironmental and stratigraphic interpretation of the Tamengo Formation. The Corcal section consists of neritic deposits including shallow-water limestone beds, alternated with shale and subordinate marl beds. These facies yield specimens of the Ediacaran fossils Cloudina lucianoi and Corumbella werneri. On the other hand, the Laginha section shows more heterogeneous facies, such as impure carbonates, breccias, marls, and subordinate mudstone beds, as well as no evidence of Corumbella werneri. The stable carbon isotope record is also different between the two sections, despite belonging to the same unit. The Corcal section displays higher and more homogeneous δ13C values, consistent with those of Ediacaran successions worldwide. The Laginha section, instead, displays more variable δ13C values, which suggest the influence of local and post depositional processes. The difference between the two sections was attributed to the different distance from the shore. We propose that the difference is due to topographic variations of the continental platform, which, at the Laginha site, was steeper and controlled by extensional faults. Therefore, the Corcal section is a better reference for the Tamengo Formation, whereas the Laginha is more particular and influenced by local factors. Besides, the lithofacies associations of the Tamengo Formation are like those of the Doushantuo and Dengying formatios, in South China, with no significant biogenic carbonate buildups, and different from those of other important Ediacaran units, such as the Nama Group in Nmibia and the Buah Formation in Oman. Our work highlights the complexity and heterogeneity of Ediacaran carbonate platforms and of their carbon isotopic composition. In addition, we characterize the Corcal section as a possible reference for the Ediacaran in South America.

Geology, geochemistry, and genesis of REY minerals of the late Cretaceous karst bauxite deposits, Zagros Simply Folded Belt, SW Iran: Constraints on the ore-forming process

The present study focuses on the geochemistry and occurrence of REY (rare earth elements and yttrium)-bearing minerals in the Late Cretaceous karst bauxite deposits in the central part of the Zagros Simply Fold Belt (ZSFB), SW Iran. The ore bodies comprise a series of individual pods and/or contiguous lenses that occur as infills of deep karst cavities, depressions, and fractures within the upper neritic carbonates of the Cenomanian–Turonian Sarvak Formation. Karst bauxites from the ZSFB show, overall, the same mineral components, which consists of boehmite, hematite (commonly occurring as Al-rich), anatase, and kaolinite, with lesser amounts of diaspore, goethite, chamosite, rutile, and zircon. Among minor constituents, single crystals rich in rare earth elements (REEs) occur mainly in the form of authigenic REY fluorocarbonate, phosphate, and oxide minerals (bastnasite, parisite, rhabdophane, churchite and cerianite). Some textural features, such as spheroidal concretions, pisoids with cortexes lacking radial and circular fractures, growth of simple cortex around earlier pisoids, and pelitomorphic matrix suggest the ores are mostly autochthonous in origin. R-mode factor analysis revealed several significant interelemental relationships including: (i) significant and positive weightings for TiO2, Al2O3, Cr2O3, Ni, Zr, Nb, Hf, Ta, W, and Th, and a significant, negative weighting for SiO2 represent a later bauxitization stage involving silica depletion under drier conditions, promoting formation and stability of a range of minerals including detrital minerals and Al and Ti oxyhydroxides which also control, through scavenging, cations of first-row transition metals such as Ni2+ and Cr6+; (ii) Supergene conditions, mainly acidic pH, probably played an efficient role in the formation of secondary REE-rich phosphates and Ga-hydroxide; (iii) similar and meaningful weightings for U and V suggest that the redox environment would be most important in controlling the U and V mineral phases; and (iv) the scandium co-variance with Fe2O3 represents the control exerted by iron oxy-hydroxides on the critical metal Sc. In the ZSFB bauxites, the most frequent authigenic REE-bearing minerals are light REE (LREE) fluorocarbonates of the bastnaesite group that forms a solid solution series between end members parisite [CaCe2(CO3)3F2] and bastnäsite (CeCO3F). The mode of occurrence of bastnäsite-Ce and parisite-Ce suggests that cerium as fluoride and/or carbonate–fluoride complexes were readily leached by acidic downward solutions and finally precipitated on the geochemical barrier of the carbonate bedrock under alkaline and reducing conditions. Rhabdophane [(Ce, La) PO4·H2O] as an LREE phosphate mineral appears in two generations with different chemical compositions, an early one as irregular and/or acicular particles within the cavities and a later one along the margin of a goethite microvein that cuts the pelitomorphic matrix. Cerianite (CeO2) occurs mainly as sub-micrometer to micrometer grains in the porous aggregates of the aphanitic matrix and as microdomains or microveins that coexist with Al-oxyhydroxide and goethite. Cerianite precipitation may occur due to the predominance of acidic/oxidizing conditions and the dissolution of Ce-rich fluorocarbonates in the bauxitic profile, respectively. The only heavy REE (HREE) phosphate mineral within the ZFSB bauxite deposits is churchite[Y(PO4)·2(H2O)] that forms as single euhedral crystals at the core of the sub-spheroidal structures under an acidic condition.

Contrasting intensity of aragonite dissolution and dolomite cementation in glacial versus interglacial intervals of a subtropical carbonate succession

AbstractAragonite and high‐Mg calcite are abundant in modern, neritic carbonate systems but almost absent in their fossil counterparts. Dissolution of these metastable mineral phases commonly leaves no visible trace in the sedimentary record, compromising the derivation of palaeoenvironmental information from the rock record. The upper 25 m of Integrated Ocean Drilling Program (IODP) Site U1460 on the outer ramp of the western Australian Shelf were investigated to study shallow burial (tens of metres) marine diagenesis in organic‐carbon poor sediments using microscopic, total organic carbon, biomarkers and mineralogical analysis in combination with porewater geochemistry. Aragonite dissolution is negligible at the seafloor but intensifies ca 5 m below, even though bulk porewaters are supersaturated for aragonite. This apparent contradiction likely results from dissolution in undersaturated microenvironments. Aragonite dissolution below 5 to 6 m is on average more intense in interglacial compared to glacial intervals. The presence of disseminated framboidal pyrite and porewater results indicate that minor sulphate reduction is active at IODP Site U1460. Sulphate reduction is probably limited by the low organic matter content (ca 0.2%). It is well‐known from the literature that incipient sulphate reduction can lead to a drop in pH and consequently to carbonate dissolution. It is therefore assumed that the slightly higher concentration of organic matter in the interglacial intervals allowed increased aragonite dissolution during sulphate reduction compared to glacial beds. Low amounts of dolomite cement (<15%) start to form at the same depth (5 to 6 m) as aragonite dissolution intensifies. Dolomite formation and aragonite dissolution also show covariance on a metre‐scale below 5 to 6 m, indicating that a low carbonate saturation state might enhance dolomite formation. This mechanism provides an indirect link between dolomite formation, aragonite dissolution and orbital cycles. The outcome of this study, therefore, contributes to a better understanding of differential diagenesis in marine carbonates.

Evolution of the inter-reef Halimeda carbonate factory in response to Holocene sea-level and environmental change in the Great Barrier Reef

The inter-reef Halimeda bioherms of the northern Great Barrier Reef (GBR) have accumulated up to 25 m of positive relief and up to four times greater volume of calcium carbonate sediment than the nearby coral reefs during the Holocene. Covering >6000 km2, the Halimeda bioherms represent a significant contribution to the development of the northeast Australian continental shelf geomorphology, neritic carbonate factory, and sedimentary archive of post-glacial environmental changes. However, the geochronological record of initiation and development of the Halimeda bioherm carbonate factory was poorly constrained and based on very few datapoints. A comprehensive age dataset is presented, comprising sixty-three new AMS radiocarbon measurements of Halimeda and foraminifera grains, mollusc shells and bulk soil from twelve inter-reef sediment cores, and ten previously published Halimeda ages. Facies transitions and environmental changes are recorded from lithological and palynological analyses spanning Last Interglacial Halimeda deposits, Last Glacial Maximum terrestrial palaeosols, transgressive mangrove vegetated shorelines, and the turn-on of the Halimeda bioherm carbonate factory. Mangrove pollen and coral records from the study area provide additional spatial, temporal and environmental context.Halimeda had established by 11.1 cal kyr BP, just 450 years after transgressive shelf inundation and approximately 1000 years earlier than previous inferred estimates. The outer-shelf carbonate factory was initially dominated by benthic foraminifera, then Halimeda was productive for at least 2100 years prior to the turn-on of Holocene coral reefs in the study area at 8.9 cal kyr BP from Boulder Reef (15.4°S, 145.4°E). Inter-reef Halimeda bioherms play a major role in carbon and nutrient cycling and potentially preserve a near-continuous geochemical record of northeast Australian Holocene oceanographic and climatic changes, filling spatial and temporal gaps not covered by coral and other marine sediment proxies.

Microfacies evidence for the evolution of Miocene coral-reef environments in Cyprus

Cyprus is one of the few areas of the Mediterranean where lower and upper Miocene coral-reefs occur in close proximity and is thus well suited to investigate how environmental and geological changes affected the reefs and their associated shallow-marine facies. The prevailing environmental conditions of the lower Miocene Terra Member and of the upper Miocene Koronia Member are reconstructed here, using detailed microfacies comparisons of the skeletal, foraminiferal and calcareous algal assemblages. The lower Miocene reefs are characterised by a higher biodiversity of coralline algae, large benthic foraminifera and corals, and mainly developed in slightly deeper water (20–40 m, lower euphotic zone) than the upper Miocene reefs (< 15 m; upper euphotic zone). The reduced late Miocene biodiversity was probably caused by changes in the Mediterranean marine environment (e.g. increased seasonality), possibly in response to global cooling, increased latitudinal gradients and progressive isolation of the basin. The observed shift of the reef environment towards the upper euphotic zone could be explained as a response to late Miocene physical oceanographic setting, notably temperature changes, which could have made the upper euphotic zone more favourable for certain hermatypic corals. Similarities between the Miocene carbonate facies of Cyprus and the Eratosthenes Seamount directly to the south, and elsewhere in the Mediterranean region (e.g., Corsica; Italy; Spain), suggest that the environmental changes inferred for the Miocene of Cyprus operated on a Mediterranean or even wider scale. • The skeletal assemblages of Miocene neritic carbonates of Cyprus are analysed. • Lower Miocene coral-reefs are highly biodiverse and developed between 20 and 40 m of water depth. • Upper Miocene coral-reefs display a low biodiversity and developed <15 m of water-depth. • Biodiversity decreased in response to less favorable conditions in the late Miocene.

Geochemical characterization of the Sutlegen bauxite deposit, SW Antalya

Purpose.The purpose is to determine geological and geochemical characteristics of the Sutlegen (Antalya, Turkey) bauxites, to identify the elements that played a major role in their formation. Methods. X-ray diffraction (XRD) mineral phase analysis, X-ray fluorescence (XRF) elemental analysis, plasma-mass spectrometry (ICP-MS), the petrographic and mineralogical analyses, and multivariate statistical methods were used. Findings. The major element content of the ore was determined as Al2O3 (60-35.2 wt%), SiO2 (39.5-0.2 wt%), Fe2O3 (48.4-19.5 wt%), TiO2 (36.9-16 wt%), and P2O5 (0.5-0.1 wt%). The Sutlegen region, which shows epirogenetic action with the uplift of the earth's crust, is generally rich in neritic carbonates. It was revealed that the bauxite ores have undergone moderate and strong laterization as a result of the deferruginization in the environment, and they were classified into four groups as lateritic, ferritic, kaolinitic, and bauxite. The increase in the aluminosilicate minerals, which were formed during the formation of bauxite in the environment was found to be directly proportional to the laterization processes. In this context, it was considered that the lateritic material that was firstly formed in the environment filled the cavities and pores of the karst-type limestones and sedimentary units in the region by superficial transfer phenomena. The bivariate diagrams of Log Cr vs. Log Ni revealed that the bauxite that formed in the region had an ultrabasic source. Originality. In literature, no scientific studies have been found on bauxite mineralization in the Sutlegen deposits that have been operated for a long period. Practical implications. In this context, the geochemical characteristics of bauxites revealed that the source of the laterization process in the region was the ultrabasic igneous rocks. The lateritic material moved by superficial transfer was accumulated on sandstone, claystone, siltstone, and limestone and in karstic cavities; then, it formed karstic bauxite (kaolinitic and bauxite) of different classifications due to the effect of metamorphism.

Tectonic Influence on Speleogenesis of Sea Caves on Biševo Island (UNESCO Global Geopark Vis Archipelago, Adriatic Sea, Croatia)

A geological and speleological investigation was conducted in the famous Blue Cave (Modra špilja) and the Monk Seal Cave (Medvidina špilja) on Biševo Island (Croatia) to promote the island’s geoheritage through the new Visitor Centre. The island is mainly composed of Cretaceous to Paleogene neritic carbonates, which form the bedrock, whereas parts of the island are covered with thin Quaternary sediments. The caves are of small dimensions and a simple layout, composed of the main channel and few shorter side channels, all positioned in the tidal zone. Thus, the caves are semi-submerged sea caves located along the coastline. The Blue Cave and the Monk Seal Cave developed within the bedrock limestones and dolostones, respectively, within a zone of left-lateral NNE–SSW striking strike-slip faults that belong to the Biševo fault system. Conjugated discontinuities within the carbonate bedrock indicate a specific strike-slip tectonic regime. Additionally, the host rocks were probably also deformed and fractured during the rise of salt diapirs that characterise this part of the Adriatic foreland. Tectonic and bedding discontinuities form the fragments of the host rock, that combined with the impacts of the strong southern waves, significantly influenced the genesis of the caves.

Breakthrough of natural gas exploration in the beach facies porous dolomite reservoir of Middle Permian Maokou Formation in the Sichuan Basin and its implications: A case study of the tridimensional exploration of Well JT1 in the central-northern Sichuan Basin

The neritic carbonate reservoir of Middle Permian Maokou Formation in the Sichuan Basin has been always treated as a fractured and fractured-vuggy reservoir. After realizing the breakthrough of natural gas exploration in the Lower Cambrian Canglangpu Formation in the Taihe gas bearing area of central-northern Sichuan Basin, Well JT1, a wildcat well, recently discovers a beach facies porous dolomite reservoir in the Maokou Formation above the Canglangpu Formation, and the high-yield industrial gas flow of 112.8 × 104 m3/d is obtained during the test. And thus, Well JT1 achieves the breakthrough of tridimensional natural gas exploration in multiple gas bearing series of strata in the vertical direction and realizes the new discovery of reservoir type in the Maokou Formation. In order to further clarify the characteristics and control factors of the beach facies porous dolomite reservoir of Maokou Formation in the Taihe gas bearing area, this paper studied its sedimentary evolution, high-energy beach facies characteristics, reservoir characteristics and following natural gas exploration direction. And the following research results were obtained. First, along the syneclise margin of central-northern Sichuan Basin develops a beach facies porous reservoir of the second Member of Maokou Formation, whose lithology is dominated by residual dolarenite and calcsparite calcarenite and reservoir space is mainly acted by intergranular pores and intercrystalline pores, with the average porosity of 4.9%. Second, in the middle and late stage of Maokou period, Guangyuan-Bazhong paleo faulted depression was developed in the northern Sichuan Basin and intraplatform low was developed in the central-northern Sichuan Basin. In the central and the northern Sichuan Basin, the high-energy beach of Maokou Formation is distributed around the faulted depression and the syneclise margin in a large scale, and the paleogeographic pattern of “one-margin and three-high belt” is presented. Third, under the control of high-energy beach facies, the Maokou Formation porous reservoir in the central-northern Sichuan Basin is distributed along the “one-margin and three-high belt” in a large scale. The high-energy beach facies of “one-margin and three-high belt” covers the area of 6500 km2. In this area, multiple sets of source rocks (Cambrian, Silurian and Permian) are developed vertically, hydrocarbon source fault is developed and carrier system is good, which is favorable for the large-scale hydrocarbon enrichment and accumulation. In conclusion, there are geological conditions for the development of facies controlled porous reservoir in the Maokou Formation of the Sichuan Basin, and the “one-margin and three-high belt” is the favorable area for the exploration of beach facies porous dolomite reservoir. The research results point out the new exploration field and direction for the large-scale increase of natural gas reserves in the Sichuan Basin.