Negligible Heat Loss Research Articles

Multidimensional Interactive Cascading Nanochips for Detection of Multiple Liver Diseases via Precise Metabolite Profiling.

It is challenging to detect and differentiate multiple diseases with high complexity/similarity from the same organ. Metabolic analysis based on nanomatrix-assisted laser desorption/ionization mass spectrometry (NMALDI-MS) is a promising platform for disease diagnosis, while the enhanced property of its core nanomatrix materials has plenty of room for improvement. Herein, a multidimensional interactive cascade nanochip composed of iron oxide nanoparticles (FeNPs)/MXene/gold nanoparticles (AuNPs), IMG, is reported for serum metabolic profiling to achieve high-throughput detection of multiple liver diseases. MXene serves as a multi-binding site and an electron-hole source for ionization during NMALDI-MS analysis. Introduction of AuNPs with surface plasmon resonance (SPR) properties facilitates surface charge accumulation and rapid energy conversion. FeNPs are integrated into the MXene/Au nanocomposite to sharply reduce the thermal conductivity of the nanochip with negligible heat loss for strong thermally-driven desorption, and construct a multi-interaction proton transport pathway with MXene and AuNPs for strong ionization. Analysis of these enhanced serum fingerprint signals detected from the IMG nanochip through a neural network model results in differentiation of multiple liver diseases via a single pass and revelation of potential metabolic biomarkers. The promising method can rapidly and accurately screen various liver diseases, thus allowing timely treatment of liver diseases.

Preparation and thermal properties of zeolite/MgSO4 composite sorption material for heat storage

Thermochemical sorption heat storage based on salt hydrates offers the potential advantages such as high energy density, negligible heat loss, small volume change and flexible working modes. Magnesium sulphate (MgSO4) is a high energy density hydrated salt available for the thermochemical sorption heat storage. In this work, different types of zeolites (including 3A, 5A and 13X zeolites) have been selected as mass-transfer-enhancing and structural stabilizing materials, and a series of zeolite/MgSO4 composites have been fabricated. To investigate the thermal energy storage performance of zeolite/MgSO4 composites, the properties of the composites, such as micro-morphology, pore structure, chemical composition and sorption-desorption behavior, have been characterized and analyzed. Results indicated that the mass transfer performance of the composite materials is significantly better than that of the pure zeolites. As the mass fraction of MgSO4 in the composite sorbents increases, the specific surface area and porosity of the composite sorbent decreases, and the sorption performance has been enhanced. Compared with 3A zeolite-based and 5A zeolite-based composites, 13X zeolite/MgSO4 composite materials show the best heat storage performance. At the condition of 25 °C and 60% RH, the 13XM20 has the highest sorption capacity of 0.21 g/g, which is 24% higher than that of pure zeolite 13X. Accordingly, the maximum heat storage density is 438.4 kJ/kg, which exhibits the superior heat storage performance among of the hydrated salt sorbents. The potential of 13X zeolite/MgSO4 as sorption heat storage material in efficient utilization of solar heat and low-grade industrial waste heat has been revealed.

Simulation-based analysis of thermochemical heat storage feasibility in third-generation district heating systems: Case study of Enschede, Netherlands

In this article a dual heat storage system comprising thermochemical heat storage (TCS) and hot water storage for managing the mismatch between heat generation and demand in district heating systems (DHs) is evaluated. TCS is known as technology suitable for long-term heat storage due to its high energy density and negligible heat losses over a longer period. However, the integration of TCS in DHs is significantly influenced by the operating conditions of DHs. Here we evaluate the feasibility of integrating TCS into DHs in the Enschede region of the Netherlands. DHs models are established to simulate heat generation, demand, and storage, and a control strategy is designed to manage storage coordination. The obtained results show that the dual storage system outperforms the single hot water storage system in reducing peak load generation. Depending on the TCS's operational condition, annual energy generation from peak load in dual storage systems could drop by 30–60 % compared to the single hot water storage system. It is achieved mainly by managing the energy capacity remaining in the storage system. The technical feasibility and benefits of implementing a TCS system in DHs with a dual storage system are shown to be more energy efficient.

Energy and exergy analysis with cost-efficiency comparison of modified phase change material (PCM) integrated with solar panel thermal system

This study investigates the efficiency and cost-effectiveness of integrating Phase Change Materials (PCMs) into solar panels to optimize power output and power conversion efficiency under varying temperature conditions. By applying PCMs, temperature fluctuations can be reduced, maintaining solar panels at an optimal temperature for power generation. The research employs modeling and simulation techniques, focusing on energy and exergy analysis of solar energy storage systems based on pure and modified PCMs such as Paraffin wax, Sodium acetate trihydrate, Sodium sulfate decahydrate, etc. Temperature and light intensity data are collected in the Wangchan district, Rayong province, using a light intensity sensor and a thermocouple. The study analyzes each layer of the solar panel, employing numerical methods and matrix solutions to solve the system of non-algebraic equations, yielding temperature values for each component layer. The thermodynamic properties of the modified PCMs are calculated theoretically, and their cost-efficiency is analyzed by comparing the solar panel’s increased power area density generation after applying specific PCMs to the cost of the PCM. The simulation results demonstrate that the solar panel integrated with PCM generates up to 11.1% more power than a regular solar panel, assuming negligible heat loss from the sides of the solar panel and an average temperature during the melting and solidification processes for the PCMs. Moreover, the best cost-efficiency of the modified PCM is achieved, with an increase of up to 637.7%, using a combination of paraffin wax and polyethylene glycol.

Experimental investigation on a thermochemical seasonal sorption energy storage battery utilizing MgSO4-H2O.

Thermochemical sorption energy storage (TSES) is the most recent thermal energy storage technology and has been proposed as a promising solution to reduce the mismatch between the energy supply and demand by storing energy for months in form of chemical bonds and restore it in form of synthesis chemical reaction. Compared with sensible/latent thermal energy processes, TSES system has major advantages, including a high energy storage capacity/density and the possibility of long-term energy retention with negligible heat loss. Therefore, a solid-gas thermochemical sorption battery is established and investigated utilizing a composite working pair of MgSO4-H2O based on room temperature expanded graphite (RTEG), treated with sulfuric acid (H2SO4) and ammonium persulfate ((NH4)2S2O8) as a porous additive. The experimental results showed that energy storage density and sorption efficiency increase with the increment of charging temperature or decreasing of discharging temperature at a certain ambient temperature. Under experimental conditions, energy density ranged from 31.7 to 908.8 kJ/kg (corresponding to volume energy density from 11.7 to 335.8 MJ/m3), while sorption energy efficiency ranged from 28.3 to 79.1%. The highest values were obtained when charging, condensation, and discharging temperatures were 95, 20, and 15 °C, respectively. The maximum thermal efficiency was 21.1% at charging/discharging temperature of 95/15 °C with sensible to sorption heat ratio of 3:1.

A design optimization method for solar-driven thermochemical storage systems based on building performance simulation

The challenge of the temporal mismatch between energy supply and demand in buildings is growing with the increasing share of renewable energy in total energy consumption. Among all the state-of-the-art energy storage solutions, thermochemical heat storage shows a unique potential thanks to its considerable energy density, acceptable cost, and negligible heat loss. For this reason, it becomes a promising alternative to common sensible heat storage solutions for building applications. The integration of such a novel technology in buildings necessitates a method for the assessment of its potential impact and benefit, the comparison to common alternatives, and the optimization of the system design. This work proposes a method based on modeling and simulation of the interaction between the thermochemical heat storage system and the building using a data-driven surrogate model of the storage system in combination with a building performance simulation engine. The data-driven model was developed and validated based on laboratory measurements of a novel closed-loop thermochemical heat storage system, the heat battery (HB). The method was demonstrated in a case study to identify the optimal size of the HB in a solar-driven configuration based on a residential building use case. The results show that the heat battery can digest the thermal energy transferred from the solar thermal collector to reduce the original electricity consumption for heating the detached house (0.7 MWh to 1.0 MWh in considered cases) without any obvious sacrifice in thermal comfort and that the small-scale HB (with a storage volume below 160 l) shows efficient usage of the designed storage capacity.

Experimental investigation on a strontium chloride/ammonia sorption heat storage system

• A thermochemical sorption heat storage system has been established. • The total highest heat storage density is 1871.03 kJ/kg SrCl 2 composite sorbent. • The total highest heat storage efficiency of the sorption system is 92.74%. Thermochemical sorption heat storage based on solid-gas interaction is considered as a cutting-edge technology for harvesting solar energy and industrial waste heat due to the significant advantages of high heat storage density, flexible working modes and long-term storage capacity with negligible heat loss. As a vital technology to enhance energy infrastructures, the thermochemical sorption heat storage has aroused extensive interest in the past decade. In this work, a solid-gas thermochemical sorption system was established and investigated for recovering the thermal energy. Working pair of strontium chloride/ammonia was selected, and strontium chloride composite sorbents were synthesized using the expanded graphite as matrix. The heat storage performances of strontium chloride/ammonia sorption system at the different temperatures were experimentally investigated. Under the condition of 92 °C charging temperature, 40 °C discharging temperature and -5 ℃ condensation/evaporation temperature, the highest sorption heat storage density of the sorption system obtained is up to 1630.78 kJ/kg SrCl 2 (or 1386.16 kJ/kg composite sorbent), and the total heat storage density can reach 2201.21 kJ/kg SrCl 2 (or 1871.03 kJ/kg composite sorbent). The total energy efficiency of the sorption system increases from 74.71% to 92.74% with the heat storage temperature rising from 68 ℃ to 92 ℃. Results indicated that strontium chloride and its composites are promising heat storage materials, and revealed great potentials of thermochemical sorption heat storage technology for rational and efficient utilization of thermal energy.

Heat Confinement Aerogel Enables Supramagnetothermal Effect for Triggering Nitric Oxide Generation.

Reducing heat dissipation plays an indispensable role in boosting the magnetothermal effect but has received scant attention. Herein, a magnetothermal aerogel (MA) combining an efficient magnetothermal convertor for heat generation and a highly porous aerogel for reducing heat dissipation is developed. Such a heat confinement MA shows a large thermal resistance and high infrared absorption that can effectively confine the heat by regulating interior thermal conduction and radiation, exhibiting a supramagnetothermal effect. In addition, a waterproof beeswax coated MA achieves negligible heat loss and a supramagnetothermal effect even in high-thermal-diffusion aqueous media. As a proof of concept, a synthesized heat-triggered nitric oxide (NO) precursor is integrated into an MA, and the rapid NO generation (∼22 μM/min) resulting in an antibacterial effect further verifies the supramagnetothermal effect of the MA. This work provides an efficient strategy to promote the magnetothermal effect and offers inspiration for building a heat-triggering system.

Numerical simulation of the calcium hydroxide/calcium oxide system dehydration reaction in a shell-tube reactor

The Ca(OH)2/CaO system is a promising candidate for thermochemical energy storage because of its high energy density, low cost and negligible heat loss. Coupling mechanisms of multiple physiochemical processes still need further investigation and the system performance should be further improved. In this work, for the first time, a three-dimensional numerical model is developed to study the thermochemical energy storage process by Ca(OH)2 dehydration reaction in a shell-tube reactor. The turbulent heat transfer fluid flow in the shell side, and the steam flow, heat transfer and dehydration reaction in the tube side are comprehensively taken into account. Effects of operation conditions and reactor geometry parameters on the dehydration process are also investigated in detail. Five indicators are proposed to comprehensively evaluate the reactor performance, including reaction time, energy storage density, heat exchange power, heat exchange efficiency and energy storage efficiency. The results reveal that higher inlet temperature and inlet velocity of heat transfer fluid can enhance the heat transfer and accelerate the reaction. Lower porosity, although increases the energy storage density, leads to higher flow resistance and impedes the reaction. With deep understanding of the physiochemical processes, 16 more tubes are properly added in the by-pass flow region, leading to shorter reaction time and higher energy storage amount. The low values of heat exchange efficiency and energy storage efficiency reveal that the input heat cannot be efficiently transferred to the tube side. To improve the energy conversion performance of reactor, additional schemes are discussed including regenerative HTF, optimization of reactor geometry, increase of reactant thermal conductivity, reducing tube-side flow resistance and extending HTF residence time. The numerical model and simulation results in the present work could be helpful for optimizing the shell-tube Ca(OH)2/CaO reactor and improving the thermochemical energy storage performance.

Highly efficient and salt rejecting solar evaporation via a wick-free confined water layer

Recent advances in thermally localized solar evaporation hold significant promise for vapor generation, seawater desalination, wastewater treatment, and medical sterilization. However, salt accumulation is one of the key bottlenecks for reliable adoption. Here, we demonstrate highly efficient (>80% solar-to-vapor conversion efficiency) and salt rejecting (20 weight % salinity) solar evaporation by engineering the fluidic flow in a wick-free confined water layer. With mechanistic modeling and experimental characterization of salt transport, we show that natural convection can be triggered in the confined water. More notably, there exists a regime enabling simultaneous thermal localization and salt rejection, i.e., natural convection significantly accelerates salt rejection while inducing negligible additional heat loss. Furthermore, we show the broad applicability by integrating this confined water layer with a recently developed contactless solar evaporator and report an improved efficiency. This work elucidates the fundamentals of salt transport and offers a low-cost strategy for high-performance solar evaporation.

Estimating the state of charge in a latent thermal energy storage heat exchanger based on inlet/outlet and surface measurements

• Estimators for the total and partial stored energy are developed and validated. • The estimator for the heat transfer fluid energy is generally applicable. • A finite volume latent thermal energy storage model is developed and fitted. The performance of latent thermal energy storage (LTES) heat exchangers is related to the stored energy (i.e. state of charge) during the (dis)charging of the energy storage system. Therefore, measuring the stored energy is crucial to understand the behavior of LTES systems. However, technical considerations often oppose the measurability of the stored energy. The present article presents a case where only measurements at the in- and outlet of the heat transfer fluid and on the outer surface of the heat exchanger were possible. Based on this sparse set of measurements, estimators for the stored energy are developed. To test these estimators, a finite volume model of the LTES heat exchanger is made. The finite volume model is fitted by comparing the predicted heat transfer fluid outlet temperature for 36 experiments. The energy estimators are compared to simulation results. The estimators for the stored energy in the heat transfer fluid, metal and phase change material obtain an average deviation of respectively 0.5 %, 3.9 % and 0.6 % with the stored energy predicted by the finite volume model. The estimator for the stored energy in the heat transfer fluid should be applicable to all LTES heat exchangers while the applicability of the estimators for stored energy in the metal and phase change material depend on small temperature differences between surface and interior of the metal and negligible heat losses.

Discharging behavior of a shell-and-tube based thermochemical reactor for thermal energy storage: Modeling and experimental validation

Thermochemical energy storage (TCES) has attracted significant attention in recent years due to some unique features of the technology such as very high energy density and negligible heat loss during storage. The TCES, however, is still at its early stage of development currently at a technology readiness level of 1–3. Major technical challenges of the TCES include materials stability, charge/discharge kinetics and limited temperature lift. Here we firstly studied the application of shell-and-tube thermochemical reactor with silica gels as heat storage material in open TCES system by experimental method. And then validated model (the maximum root mean square percentage error of 13.62% between the modeling and experiments) of single tube reactor containing 0.29 kg silica-gel was established to numerically investigate the discharging behavior of the thermochemical reactor under different operating conditions and flow directions of air and water. The numerical simulation results showed inverse heat transfer occurred for a counter-flow of air-water. The problem could be solved by changing the counter-flow of air and water to the parallel-flow. Thus, the water outlet maximum temperature limit was broken through. The total heat uptake increased by at least 24.14% when water flow rate was less than 0.36 kg/h and 11.93% when air flow rate was more than 1.07 kg/h, respectively. By increasing the inlet temperature of air and water from 23 °C to 38 °C, the maximum temperature lift could be significantly increased by 79.94% for air and 80.81% for water, respectively. Meanwhile, the total heat uptake increased by 107.44%. For a completely charging and discharging process, the discharging rate of parallel-flow was faster than that of counter-flow.

Water/Ethanol and 13X Zeolite Pairs for Long-Term Thermal Energy Storage at Ambient Pressure

Thermal energy storage is a key technology to increase the global energy share of renewables - by matching energy availability and demand - and to improve the fuel economy of energy systems - by recovery and reutilization of waste heat. In particular, the negligible heat losses of sorption technologies during the storing period make them ideal for applications where long-term storage is required. Current technologies are typically based on the sorption of vapour sorbates on solid sorbents, requiring cumbersome reactors and components operating at below ambient pressure. In this work, we report the experimental characterization of working pairs made of various liquid sorbates (distilled water, ethanol and their mixture) and a 13X zeolite sorbent at ambient pressure. The sorbent hydration by liquid sorbates shows lower heat storage performance than vapour hydration; yet, it provides similar heat storage density to that obtainable by latent heat storage (40-50 kWh/m^3) at comparable costs, robustness and simplicity of the system, while gaining the long-term storage capabilities of sorption-based technologies. As a representative application example of long-term storage, we verify the feasibility of a sorption heat storage system with liquid sorbate, which could be used to improve the cold-start of stand-by generators driven by internal combustion engines. This example shows that liquid hydration may be adopted as a simple and low-cost alternative to more efficient - yet more expensive - techniques for long-term energy storage.

Combined neural networks and predictive control for heat exchanger networks operation

Optimal operation of integrated heat exchangers is a challenging task in the field of process control due to system nonlinearities, disturbances and adequate model identification. This paper describes the design of an advanced neural network predictive control (NNPC) applied to a heat exchanger network. A case study with two hot and one cold streams, through three counter-current heat exchangers is used to test the proposed strategy. A lumped dynamic model is built based on the concept of multi-cells topology (mixed tanks), where the hot and cold cells are connected by a wall element throughout the heat exchanger length. Each cell is assumed perfectly mixed and all physical properties are constant. A distributed behavior is achieved by increasing the number of cells. The main assumptions of the lumped model are constant temperature in each cell, heat exchanger volume and area equally distributed between cells and negligible heat loss to the environment. The predictive controller relies on a neural-based model of the plant that is used to identify the system and to predict future performance over a predefined horizon. Results were compared to a traditional controller, and the control performance was improved when compared to the Ziegler-Nichols tuning method.

Lifetime of Plasma Etched Copper Lines

The electromigration failure process of the plasma etched Cu line has been studied. The surface color changed due to joule heating that caused surface oxidation for the case of the uncapped copper line or the diffusion of copper into the TiW capping layer for the case of the capped copper line. The line temperature was estimated based on the assumption of the negligible heat loss to the glass substrate. The resistance of the copper line also changed with the stress time. Therefore, the copper line failure process can be predicted from the observation of changes of the surface color and line resistance.

Experimental Investigation of hot Water Generation from Small CaO/Ca(OH)2 Thermochemical Energy Storage System

Thermochemical energy storage (TCS) is a very promising method for energy applications, storage, transport and thermal generation because of its high energy density and negligible heat loss. Several storage materials are being explored, in which CaO/Ca(OH)2 is among the most attractive systems for further investigations. In this work, a small Ca based TCS system was developed, built and tested for hot water generation. Hydration and dehydration reactions involving CaO and Ca(OH)2 powders were performed. Performance in terms of temperature rise in heat transfer fluid and its efficiency during successive discharging/charging cycles was evaluated and discussed.

Experimental investigation on a MnCl2[sbnd]CaCl2[sbnd]NH3 resorption system for heat and refrigeration cogeneration

Sorption thermal energy storage (STES) is perceived as one prospective way of thermal energy storage (TES) owing to the advantages of high energy density, negligible heat loss, flexible working modes and long-term storage capability. Based on STES, this paper exhibits an innovative resorption thermal energy storage (RTES) system, and the experimental prototype is established for heat and refrigeration cogeneration. Working pair of MnCl2CaCl2NH3 is chosen, 4.8kg MnCl2 and 3.9kg CaCl2 impregnated in expanded natural graphite treated with sulfuric acid are filled in two sorption beds respectively. Experimental results indicate that the largest energy storage density reaches 1706kJ/kg when charging and discharging temperature are 160°C and 30°C, respectively. The maximum average cooling power achieves 1.07kW during discharging phase and corresponding SCP is 27.33W/kg within the overall cycle period. When charging temperature increases from 135°C to 160°C, the energy efficiency of the resorption system for heat and refrigeration cogeneration augments steadily from 0.72 to 0.87 while the exergy efficiency rises slowly from 0.29 to 0.35.

Direct observation of isolated Damon-Eshbach and backward volume spin-wave packets in ferromagnetic microstripes.

The analysis of isolated spin-wave packets is crucial for the understanding of magnetic transport phenomena and is particularly interesting for applications in spintronic and magnonic devices, where isolated spin-wave packets implement an information processing scheme with negligible residual heat loss. We have captured microscale magnetization dynamics of single spin-wave packets in metallic ferromagnets in space and time. Using an optically driven high-current picosecond pulse source in combination with time-resolved scanning Kerr microscopy probed by femtosecond laser pulses, we demonstrate phase-sensitive real-space observation of spin-wave packets in confined permalloy (Ni80Fe20) microstripes. Impulsive excitation permits extraction of the dynamical parameters, i.e. phase- and group velocities, frequencies and wave vectors. In addition to well-established Damon-Eshbach modes our study reveals waves with counterpropagating group- and phase-velocities. Such unusual spin-wave motion is expected for backward volume modes where the phase fronts approach the excitation volume rather than emerging out of it due to the negative slope of the dispersion relation. These modes are difficult to excite and observe directly but feature analogies to negative refractive index materials, thus enabling model studies of wave propagation inside metamaterials.

A review of salt hydrate-based sorption technologies for long-term thermal energy storage

Thermochemical heat storage appears to be an attractive alternative solution for long-term heat storage, as it offers large energy capacity and negligible heat loss during long-term storage. Salt hydrate-based sorption is a typical thermochemical heat storage technology, and has become a new research hotpot for long-term thermal storage. It is featured by combined beneficial parameters such as low cost, benign environmental impact, high energy density, and safety operation. In this paper, the advances in the salt hydrate-based sorption technology for long-term heat storage are comprehensively reviewed. Special attentions are paid on the research of sorption properties of pure hydrate salts and composite materials, thermal performance of various sorption reactors, numerical investigation and performance evaluation of the sorption reactor and the whole thermochemical storage system. Finally, based on the understanding of the state of the art, characteristics of the salt hydrates-based seasonal thermochemical storage technology are summarized and the future research directions are discussed.

Research progress of solar thermochemical energy storage

Summary Solar thermal power generation technology has great significance to alleviate global energy shortage and improve the environment. Solar energy must be stored to provide a continuous supply because of the intermittent and instability nature of solar energy. Thermochemical storage (TCS) is very attractive for high-temperature heat storage in the solar power generation because of its high energy density and negligible heat loss. To further understand and develop TCS systems, comprehensive analyses and studies are very necessary. The basic principle and main components of a solar TCS system are described in this paper. Besides, recent progress and existing problems of several promising reaction systems are introduced. Further research directions are pointed out considering the technical, economic, and environmental issues that existed in the wide application of TCS. Copyright © 2014 John Wiley & Sons, Ltd.