Negative Pulse Research Articles

Effect of Pulse Electrodeposition Mode on Microstructures and Properties of Ni-TiN Composite Coatings

Mild steel is a kind of material commonly used in the chemical industry and to manufacture machinery, farm tools, and other parts in order to improve the surface performance of the parts and prolong their service life. The Ni-TiN composite coating was fabricated through ultrasonic electroplating using a Ni-based sulfamic acid bath with added nano-TiN particles. The effects of three distinct current modes, direct current (DC), positive pulse current (PC), and positive–negative pulse current (PNPC), on various aspects of the coating, including surface morphology, TiN content and distribution, interface bonding strength, microhardness, friction and wear properties, as well as corrosion resistance, were investigated. The findings demonstrated that, in comparison to DC electroplating, PC electrodeposited Ni-TiN composite coatings yielded finer grains, smoother surfaces, reduced surface cracks, increased interface bonding strength, and enhanced corrosion resistance. Furthermore, PNPC electrodeposited Ni-TiN composite coatings showed higher interface bonding strength than those of PC electrodeposited Ni-TiN coatings and had the densest structure, leading to the best corrosion resistance. Pulse current electroplating enhanced the incorporation of nano-TiN particles, with a higher deposition rate observed in positive–negative pulse current electroplating compared to positive pulse current electroplating. Furthermore, the PNPC electrodeposited coating displayed improved microhardness and demonstrated the best friction and wear properties, while the DC electroplated coating displayed the least favorable performance in these aspects.

Synaptic Properties of an Interfacial Memristor Based on a Ga2O3/Nb:SrTiO3 Heterojunction.

Memristors have been extensively studied for tremendous potential for future neuromorphic computing hardware applications because of their ability to imitate biological synaptic processes. Herein, we report an interfacial memristor based on a Ga2O3/Nb:SrTiO3 heterojunction that shows stable bipolar resistive switching behavior, long retention time, and high switching ratio. The conductance of the Au/Ga2O3/Nb:SrTiO3/In memristor can be gradually modulated under the voltage sweep mode as well as positive and negative pulse voltage stimulations, respectively, thus realizing the long-term potentiation/depression characteristics of the simulated biological synapse. A neural network based on the prepared memristor was built to recognize the handwritten picture data set with a recognition accuracy of 92.78% by using the NeuroSimV3.0 platform. Our work indicates that the Ga2O3/Nb:SrTiO3 heterojunction memristor has significant potential in a neuromorphic computing system.

Filament Formation Mechanism for a Nanosecond Surface Barrier Discharge. Part 2. The Local-Energy Approximation

The development of a surface barrier discharge driven by a negative steplike voltage pulse with an amplitude of V = –8 kV in air at the atmospheric pressure and a pulse with an amplitude of V = –15 kV in nitrogen at a pressure of 6 atm is simulated numerically. Calculations for V = –8 kV were carried out using the local-electric-field and the local-electron-energy approximations. It is demonstrated that both approximations yield similar results on the dynamics of discharge development as a whole, the cathode-layer structure, and the field distribution at the front of the discharge. Substantial differences are observed in parameters of the discharge layer adjacent to the dielectric surface, which allowed to simulate an effect similar to filamentation of the discharge in nitrogen at a pressure of 6 atm and voltage of V = –15 kV in the local-energy approximation.

Plasma potential and ion energy characteristics in BP-HiPIMS discharge with double layer

Abstract As an emerging ion acceleration plasma source, the bipolar-pulse high power impulse magnetron sputtering (BP-HiPIMS) discharge has been widely studied by academia and industry due to its ability to adjust the ion kinetic energy. Formation of the double layer (DL) potential structure during the BP-HiPIMS positive pulse is vital for accelerating ions, but its structural characteristics are still unclear. In this work, to understand the DL characteristics affected by various discharge parameters, the evolution of plasma potential V p and ion energy in BP-HiPIMS discharge with copper target has been investigated systematically using an emissive probe and mass spectrometer together. Spatial plasma potential measurements show that the DL is established in front of the target during the positive pulse, whose boundary potential drop U DL to accelerate ions can be increased to ∼60 V at a lower operating gas pressure (p= 0.6 Pa) and a higher applied positive pulse voltage (U + = 200 V). The ignition onset time of DL after applying the positive pulse can be shortened to ∼25 μs by decreasing the gas pressure and increasing the positive pulse voltage or negative pulse duration. After DL ignition, a group of high-energy copper ions with energy higher than the surrounding plasma potential can be recognized in the ion energy distribution function curves in the downstream plasma. This result illustrates that the copper ions can be ionized in the high-potential plasma region and be accelerated by the DL boundary potential drop. In addition, a global current balance model of the DL in BP-HiPIMS is developed, which suggests that the U DL can be well adjusted by increasing the positive pulse voltage U + especially for U + > 200 V as verified by the experimental potential measurements. All results suggest that the copper particles play an important role in the formation of DL and the DL plays an important role in accelerating copper ions.

Reduction of the deceleration phase to mitigate the negative effect of hydrodynamic instabilities in direct-drive ICF implosions

In the deceleration phase of an Inertial Confinement Fusion capsule implosion Rayleigh–Taylor hydrodynamic instability can affect or even quench the ignition and thermonuclear burn wave propagation. This instability tends to mix the inner hot plasma with the cold and dense plasma shell providing a mixing layer where nuclear fusion reactions are inhibited. The 1D hydrodynamics code Multi-IFE has been used to simulate the implosion of a direct-drive high-gain laser-capsule design and the temporal evolution of the average radius and thickness of the mixing layer have been estimated. To mimic the effect of the reduced reaction rate, the fuel reactivity in the mixing layer is artificially set to zero thus inhibiting the burn wave propagation throughout it nullifying the energy gain. In order to overcome this negative effect, secondary short and powerful laser pulse is added, shortening this way the deceleration phase, which in turn reduces the thickness of the mixing layer. A study has been carried out to identify the optimal secondary laser pulse that recovers the high energy gain.

Studying of Filamentation Mechanism for Nanosecond Surface Dielectric Barrier Discharge. Part 1. Local Field Approximation

The goal of this work is to check numerically whether or not the previously proposed mechanism for surface barrier discharge filamentation in nitrogen in the case of positive polarity nanosecond voltage pulse is applicable for similar process in nitrogen and air in the case of negative voltage polarity pulse. The results have shown, that in this case some signs of successful filamentation modeling are present both in nitrogen and air, but the whole dynamics of discharge development is qualitatively different from that one observed in experiment. It is assumed, that the failure of simulation is due to the usage of local field approximation, which is too rough inside a region with steep electron density gradient relevant to filamentation zone.

WS2 Nanotube Transistor for Photodetection and Optoelectronic Memory Applications.

Nanotube and nanowire transistors hold great promises for future electronic and optoelectronic devices owing to their downscaling possibilities. In this work, a single multi-walled tungsten disulfide (WS2) nanotube is utilized as the channel of a back-gated field-effect transistor. The device exhibits a p-type behavior in ambient conditions, with a hole mobility µp ≈ 1.4 cm2V-1s-1 and a subthreshold swing SS ≈ 10 V dec-1. Current-voltage characterization at different temperatures reveals that the device presents two slightly different asymmetric Schottky barriers at drain and source contacts. Self-powered photoconduction driven by the photovoltaic effect is demonstrated, and a photoresponsivity R ≈ 10 mAW-1 at 2V drain bias and room temperature. Moreover, the transistor is tested for data storage applications. A two-state memory is reported, where positive and negative gate pulses drive the switching between two different current states, separated by a window of 130%. Finally, gate and light pulses are combined to demonstrate an optoelectronic memory with four well-separated states. The results herein presented are promising for data storage, Boolean logic, and neural network applications.

Formation of diffuse and spark discharges between two needle electrodes with the scattering of particles

The development of a nanosecond discharge in a pin-to-pin gap filled with air at atmospheric pressure has been studied with high temporal and spatial resolutions from a breakdown start to the spark decay. Positive and negative nanosecond voltage pulses with an amplitude of tens of kilovolts were applied. Time-resolved images of the discharge development were taken with a four-channel Intensified Charge Coupled Device (ICCD) camera. The minimum delay between the camera channels could be as short as ≈ 0.1 ns. This made it possible to study the gap breakdown process with subnanosecond resolution. It was observed that a wide-diameter streamer develops from the high-voltage pointed electrode. The ionization processes near the grounded pin electrode started when the streamer crossed half of the gap. After bridging the gap by the streamer, a diffuse discharge was formed. The development of spark leaders from bright spots on the surface of the pointed electrodes was observed at the next stage. It was found that the rate of development of the spark leader is an order of magnitude lower than that of the wide-diameter streamer. Long thin luminous tracks were observed against the background of a discharge plasma glow. It has been established that the tracks are adjacent to brightly glowing spots on the electrodes and are associated with the flight of small particles.

Design and implementation of an innovative single-phase direct AC-AC bipolar voltage buck converter with enhanced control topology

Direct AC–AC converters are strong candidates in the power converting system to regulate grid voltage against the perturbation in the line voltage and to acquire frequency regulation at discrete step levels in variable speed drivers for industrial systems. All such applications require the inverted and non-inverted form of the input voltage across the output with voltage-regulating capabilities. The required value of the output frequency is gained with the proper arrangement of the number of positive and negative pulses of the input voltage across the output terminals. The period of each such pulse for low-frequency operation is almost the same as the half period of the input grid or utility voltage. These output pulses are generated by converting the positive and negative input half cycles in noninverting and inverting forms as per requirement. There is no control complication to generate control signals used to adjust the load frequency as the operating period of the switching devices is normally greater than the period of the source voltage. However, high-frequency pulse width modulated (PWM) control signals are used to regulate the output voltage. The size of the inductor and capacitor is inversely related to the value of the switching frequency. Similarly, the ripple contents of voltage and currents in these filtering components are also inversely linked with PWM frequency. These constraints motivate the circuit designer to select high PWM frequency. However, the alignment of the high-frequency control input with the variation in the input source voltage is a big challenge for a design engineer as the switching period of a high-frequency signal normally lies in the microsecond. It is also required to operate some high-frequency devices for various half cycles of the source voltage, creating control complications as the polarities of the half cycles are continuously changing. This requires at least the generation of two high-frequency signals for different intervals. The interruption of the filtering inductor current is a big source of high voltage surges in circuits where the high-frequency transistors operate in a complementary way. This may be due to internal defects in the switching transistors or some unnecessary inherent delay in their control signals. In this research work, a simplified AC–AC converter is developed that does not need alignment of high-frequency control with the polarity of the source voltage. With this approach, high-frequency signals can be generated with the help of any analog or digital control system. By applying this technique, only one high-frequency control signal is generated and applied in AC circuits, as in a DC converter, without applying a highly sensitive polarity sensing circuit. So, controlling complications is drastically simplified. The circuit and configuration always avoid the current interruption problem of filtering the inductor. The proposed control and circuit topology are tested both in computer-based simulation and practically developed circuits. The results obtained from these platforms endorse the effectiveness and validation of the proposed work.

Dependence of Climate and Carbon Cycle Response in Net Zero Emission Pathways on the Magnitude and Duration of Positive and Negative Emission Pulses

Dependence of Climate and Carbon Cycle Response in Net Zero Emission Pathways on the Magnitude and Duration of Positive and Negative Emission Pulses

Numerical study on the effect of actuation parameters on the formation characteristics of metal droplets in magnetohydrodynamic drop-on-demand (DOD) jetting

Numerical simulations have investigated the effects of electromagnetic drive waveform amplitude and pulse width on the state of metal droplet generation during drop-on-demand printing of molten metal aluminum by electromagnetic drive. It indicates that positive and negative pulses of magnetohydrodynamic(MHD) actuation applied to the molten metal in the crucible can form a so-called “push-pull” effect, which is the main mechanism affecting droplet generation and breakup. The positive pressure pulse causes the liquid metal to be extruded outward, and the negative pressure pulse promotes the fluid retraction at the nozzle to promoting the thinning of the liquid bridge and the generation of liquid droplets. With the increase in the amplitude of the applied current, the ejected molten aluminum from the crucible experiences three states: no droplet, single droplet, and droplet with satellite droplets. In the single drop state, the droplet formation time is shortened as the current peak increases and the droplet volume increases with the increase of pulse width. The energy conversion and force changes during droplet formation and falling are analyzed. When the peak kinetic energy of the ejected molten metal exceeds its surface energy, the jet breaks up and generates a single droplet. For the actuation with constant amplitude and duration for positive pulses, extending the duration of negative pulses weakens the "pull" effect, leading to a transition from the generation of a single droplet to multiple droplets. The numerical simulation results provide information on the current amplitude, pulse width, and Weber number range necessary for stable single droplet generation.

Design of positive pulse measurement while drilling system for mine rotary valve mud

Abstract For the drilling of directional wells and horizontal wells, to ensure that the drilling trajectory is drilled in the coal seam in the direction designed before drilling, it is necessary to transmit information without interrupting the drilling process. The drilling fluid pressure pulse is divided into positive pulse, negative pulse, and continuous wave. The positive pulse transmission system with the mechanical structure of the lifting valve is widely used because of its high pulse signal strength and long propagation distance, which can be used in deep wells. With the increase of the information measured in the formation, the lifting valve can not meet the needs of the current information transmission due to the linear motion of the mechanical structure and the low transmission rate. The rotary valve as the pressure signal generation source can improve the pulse generation rate. Therefore, this paper analyzes the working principle and signal generation principle of the rotary valve positive pulse system, and collects the directional data and natural gamma value of the field test.

Effect of Negative Pulse on the Stability of Black Electrolytes for Magnesium Alloy Microarc Oxidation.

The correlation between negative pulse and the black electrolyte properties of magnesium alloy micro-arc oxidation and the treated area was investigated by introducing a negative pulse electric field. The physical phase composition, microstructure, elemental distribution, and content of the coating were analyzed using X-ray diffraction (XRD), scanning electron microscopy (SEM), and energy dispersive spectroscopy (EDS). The results showed that the introduction of negative pulses favored the generation of MgO and MgSiO3 contents in the coatings, and an increase in the MgO phase was found in the coatings formed in the failed electrolytes; the microporous size and microcracks of the coatings were gradually and significantly reduced; the average consumption of Cu ions was 0.0453 g/L·dm2, which is only 26% of that in the unipolar condition; the introduction of the negative pulses significantly improved the "anomalous consumption" of Cu ions. The introduction of negative pulse can significantly improve the "abnormal consumption" of copper ions, which is attributed to the change in the electric field by negative pulse, which makes the cathode-enriched Cu ions migrate to the anode and reduces the reduction and precipitation of Cu ions at the cathode.

Responses of Field‐Aligned Currents and Equatorial Electrojet to Sudden Decrease of Solar Wind Dynamic Pressure During the March 2023 Geomagnetic Storm

AbstractWe present the observations of field‐aligned currents and the equatorial electrojet during the 23 March 2023 magnetic storm, focusing on the effect of the drastic decrease of the solar wind dynamic pressure occurred during the main phase. Our observations show that the negative pressure pulse had significant impact to the magnetosphere‐ionosphere system. It weakened large‐scale field‐aligned currents and paused the progression of the storm main phase for ∼3 hr. Due to the sudden decrease of the plasma convection after the negative pressure pulse, the low‐latitude ionosphere was over‐shielded and experienced a brief period of westward penetration electric field, which reversed the direction of the equatorial electrojet. The counter electrojet was observed both in space and on the ground. A transient, localized enhancement of downward field‐aligned current was observed near dawn, consistent with the mechanism for transmitting MHD disturbances from magnetosphere to the ionosphere after the negative pressure pulse.

In Situ Pulsed Hydrogen Implantation in Atom Probe Tomography.

The investigation of hydrogen in atom probe tomography appears as a relevant challenge due to its low mass, high diffusion coefficient, and presence as a residual gas in vacuum chambers, resulting in multiple complications for atom probe studies. Different solutions were proposed in the literature like ex situ charging coupled with cryotransfer or H charging at high temperature in a separate chamber. Nevertheless, these solutions often faced challenges due to the complex control of specimen temperature during hydrogen charging and subsequent analysis. In this paper, we propose an alternative route for in situ H charging in atom probe derived from a method developed in field ion microscopy. By applying negative voltage nanosecond pulse on the specimen in an atom probe chamber under a low pressure of H2, it is demonstrated that a high dose of H can be implanted in the range 2-20 nm beneath the specimen surface. An atom probe chamber was modified to enable direct negative pulse application with controlled gas pressure, pulse repetition rate, and pulse amplitude. Through electrodynamical simulations, we show that the implantation energy falls within the range 100-1,000 eV and a theoretical depth of implantation was predicted and compared to experiments.

Modeling of a linear ion trap with driving rectangular waveforms.

We consider the operation of a digital linear ion trap with resonant radial ejection. A sequence of rectangular voltage pulses with a dipole resonance signal is applied to the trap electrodes. The periodic waveform is piecewise constant, has zero mean, and is determined by an asymmetry parameter : one value is taken on interval and another on , where is the RF period. Ion mass scanning is performed by varying the asymmetry parameter and amplitude of the negative pulse part with time. The ion oscillation frequencies and acceptance of the linear trap are calculated. The dependence of the ion mass to charge ratio on the parameter is . The maximum value is about kDa for typical parameters of the linear trap: frequency 0.5 MHz, rod radius 4 mm, and negative pulse amplitude 1 kV. The dipolar excitation frequency is 0.125 MHz at which the LIT acceptance is maximal.

Hardness Distribution and Growth Behavior of Micro-Arc Oxide Ceramic Film with Positive and Negative Pulse Coordination.

Micro-arc oxidation (MAO) is a promising technology for enhancing the wear resistance of engine cylinders by growing a high hardness alumina ceramic film on the surface of light aluminum engine cylinders. However, the positive and negative pulse coordination, voltage characteristic signal, hardness distribution characteristics of the ceramic film, and their internal mechanism during the growth process are still unclear. This paper investigates the synergistic effect mechanism of cathodic and anodic current on the growth behaviour of alumina, dynamic voltage signal, and hardness distribution of micro-arc oxidation film. Ceramic film samples were fabricated under various conditions, including current densities of 10, 12, 14, and 16 A/dm2, and current density ratios of cathode and anode of 1.1, 1.2, and 1.3, respectively. Based on the observed characteristics of the process voltage curve and the spark signal changes, the growth of the ceramic film can be divided into five stages. The influence of positive and negative current density parameters on the segmented growth process of the ceramic film is mainly reflected in the transition time, voltage variation rate, and the voltage value of different growth stages. Enhancing the cathode pulse effect or increasing the current density level can effectively shorten the transition time and accelerate the voltage drop rate. The microhardness of the ceramic film cross-section presents a discontinuous soft-hard-soft regional distribution. Multiple thermal cycles lead to a gradient differentiation of the Al2O3 crystal phase transition ratio along the thickness direction of the layer. The layer grown on the outer surface of the initial substrate exhibits the highest hardness, with a small gradient change in hardness, forming a high hardness zone approximately 20-30 μm wide. This high hardness zone extends to both sides, with hardness decreasing rapidly.

Effect of RF power on analog synaptic behavior of sputter-deposited InGaZnO films for neuromorphic computing applications

We demonstrate that an analog synaptic weight update can be achieved using identical pulses via gradual resistance switching of memristors based on sputter-deposited InGaZnO (IGZO) films. When a positive voltage is applied to the IGZO memristor, oxygen vacancies (Vo) are ionized and electrons that serve as dopants are generated. This lowers the Schottky barrier formed at the interface and decreases the resistance. However, a negative voltage provides electrons from the Pd electrode, annihilating the ionized vacancies. As the barrier is reconstructed, the IGZO memristor exhibits a high-resistance state (HRS). As Vo plays a crucial role in switching, the effect of the radio frequency (RF) power on the memristor during the IGZO deposition is examined. A physical analysis reveals that the Vo concentration in the IGZO is proportional to the RF power, inducing a leaky HRS. However, at the expense of a reduced memory window in the IGZO deposited at a higher power of 200 W, the resultant low-resistance state is reliable over time. The strengthened retention allows the synaptic weights to be linearly decreased even by consecutive negative pulses. Hence, when the IGZO memristors are used for synaptic elements to construct neural networks, a higher recognition accuracy for the MNIST dataset is achieved.

Enhanced response of thermospheric cooling emission to negative pressure pulse

Nitric oxide (NO) emission via 5.3 µm wavelength plays dominant role in regulating the thermospheric temperature due to thermostat nature. The response of NO 5.3 mm emission to the negative pressure impulse during November 06–09, 2010 is studied by using Sounding of Atmosphere by Broadband Emission Radiometry (SABER) observations onboard the Thermosphere Ionosphere Mesosphere Energetics and Dynamics (TIMED) satellite and model simulations. The TIMED/SABER satellite observations demonstrate a significant enhancement in the high latitude region. The Open Geospace General Circulation Model (OpenGGCM), Weimer model simulations and Active Magnetosphere and Planetary Electrodynamics Response Experiment measurements exhibit intensification and equatorward expansion of the field-aligned-currents (FACs) post-negative pressure impulse period due to the expansion of the dayside magnetosphere. The enhanced FACs drive precipitation of low energy particle flux and Joule heating rate affecting whole magnetosphere–ionosphere–thermosphere system. Our study based on electric fields and conductivity derived from the EISCAT Tromsø\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$${\\o }$$\\end{document} radar and TIEGCM simulation suggests that the enhanced Joule heating rate and the particle precipitations prompt the increase in NO cooling emission.

Lateral ionic-gated graphene synaptic transistor with transition from paired-pulse facilitation to depression for filtering and image recognition

The transition from paired-pulse facilitation to paired-pulse depression is of significant importance for regulating biologic neural network. Here, we fabricate and investigate a lateral ionic-gated graphene synaptic transistor (GST) with short gate length. We control the channel current via e-field-dependent movement and diffusion of ions for realizing the transition from paired-pulse facilitation to depression. This phenomenon comes from the over-diffusion and trapping of a finite number of ions and the short ion-diffusion length under large negative gate pulse stimuli. This device successfully emulates facilitation and depression synaptic functions, for leveraging the accumulation, migration and diffusion of ions. Moreover, enhanced high-pass filtering and conversion from long-term depression to long-term potentiation are achieved by changing pulses time interval. Our results indicate that our device possesses excellent frequency-dependent synaptic plasticity, making it highly suitable for information filtering up to 33 Hz in neuromorphic systems, and image edge enhancement for neural image processing. In additional, a simulated artificial neural network built on lateral ionic-gated GSTs for handwritten digit recognition can achieve a learning accuracy of 82.4 %.