Near-infrared Laser Beam Research Articles

Femtosecond optical vortex-induced flower-shaped surface relief structures in an azo-polymer film

We study the formation of surface relief structures in azo-polymers generated via two-photon induced photoisomerization using a femtosecond near-infrared optical vortex laser beam. These structures exhibit exotic flower-like shapes with petals along the azimuthal direction, and they are formed from spatial mode instability, which is associated with third-order nonlinear effects in the azo-polymer. This process is a unique and exotic interaction between light and matter, which may be applied to the development of advanced optical data storage technologies. Here, an additional degree of freedom is offered by the number of formed petals, which themselves are a function of the topological charge of the optical vortex beam.

Superparamagnetic Fe3O4 nanoparticles capped with silver induce apoptosis of colon cancer cells via damaging DNA@increasing ROS

A sol-gel approach was used to create magnetite nanoparticles (Fe3O4 NPs) as a core and silver (Ag) as a shell. Ag-Fe3O4 NPs were identified by x-ray diffraction (XRD) and energy dispersive x-ray (EDX), scanning electron microscope (SEM), Fourier transform infrared (FTIR) spectroscopy, and vibrating sample magnetometer (VSM) techniques. The capabilities of Ag-Fe3O4 NPs to induce apoptosis were investigated utilizing the Acridine orange/Ethidium bromide stain. The activity of NPs against (HT-29) cancer cells was further evaluated in and out of the existence of near-infrared (NIR) laser beam and alternating magnetic field (AMF). The exposed laser enhanced the cytotoxicity effect against (HT-29) cells. However, greatly elevated cytotoxic activity was seen with using the AMF.

LIPSS formation on Ni surface using mixed near-infrared laser beam harmonics

Generation of laser-induced periodic surface structures (LIPSS) is investigated with femtosecond laser pulses with 1030nm wavelength and its second and its harmonics. The second (λ2ω = 515nm) and third harmonics (λ3ω = 343nm) beams in addition to their combination were utilized to control the period of the LIPSS on a Ni surface. The resulting periodicity of the formed structures was ∼ 0.42μm, 0.22μm, and 0.33μm respectively for the second harmonic beam, third harmonic beam, and their combination. This method demonstrates a direct way to control the periodicities on a metal target by employing an individual laser beam wavelength to induce a variable range of LIPSS periods.

Enhancement of skin tumor laser hyperthermia with Ytterbium nanoparticles: numerical simulation

Laser hyperthermia therapy (HT) has emerged as a well-established method for treating cancer, yet it poses unique challenges in comprehending heat transfer dynamics within both healthy and cancerous tissues due to their intricate nature. This study investigates laser HT therapy as a promising avenue for addressing skin cancer. Employing two distinct near-infrared (NIR) laser beams at 980 nm, we analyze temperature variations within tumors, employing Pennes’ bioheat transfer equation as our fundamental investigative framework. Furthermore, our study delves into the influence of Ytterbium nanoparticles (YbNPs) on predicting temperature distributions in healthy and cancerous skin tissues. Our findings reveal that the application of YbNPs using a Gaussian beam shape results in a notable maximum temperature increase of 5 °C within the tumor compared to nanoparticle-free heating. Similarly, utilizing a flat top beam alongside YbNPs induces a temperature rise of 3 °C. While this research provides valuable insights into utilizing YbNPs with a Gaussian laser beam configuration for skin cancer treatment, a more thorough understanding could be attained through additional details on experimental parameters such as setup, exposure duration, and specific implications for skin cancer therapy.

In Situ Synchrotron Investigations of Beam Diameter Influence on Vapor Capillary Formation during Laser Beam Welding of Copper Alloy with a Blue Laser Beam Source

Laser beam welding as a reliable tool for high-precision joining of batteries or microelectronics is more and more the choice for achieving reproducible results in production processes. In addition to a high automation capability, the precise control of the energy deposition into the material plays an important role, especially when highly reflective materials, such as copper or aluminum, must be welded together. Alongside the use of highly brilliant fiber lasers in the near-infrared range with a focal diameter of a few tens of micrometers, diode lasers in the wavelength range of 445 nm are increasingly being used. Here, beam diameters of a few hundred micrometers can be achieved. With a wavelength of 445 nm, the absorptivity in copper can be increased by more than a factor of 10 compared to a near-infrared laser beam sources in solid state at room temperature. This paper presents the in situ X-ray observation of laser welding processes on CuSn6 with a laser beam source with a wavelength of 445 nm using synchrotron radiation at DESY Petra III Beamline P07 EH4 in Hamburg, Germany. For the experiments, the laser radiation was focused via two separate optics to focal diameters of 362 µm and 609 µm. To characterize the dynamics of the vapor capillaries depending on the different focal diameters dF, the parameters were varied with respect to laser power PL and feed rate v. For the investigations, a synchrotron beam of 2 × 2 mm2 in size with a photon energy of 89 keV was used, and the material samples were analyzed by means of phase-contrast videography to show the boundaries between solid, liquid, and gaseous material phases. The results of this paper show the welding depths achieved and how the geometry of the vapor capillary behaves by changing the focal diameter, laser power and feed rate.

Deep penetration welding of brass with subsequent wire filling process by laser beam with combined core and ring beam

Brass is an important copper alloy and plays a crucial role in component production. Laser welding of brass offers promise for high-quality seams and productivity. Challenges include irregular surfaces, pores, and spatters due to melt pool and keyhole instabilities, intensified by zinc evaporation. Smooth surfaces are crucial for aesthetic applications, requiring solutions to address welding challenges and ensure optimal outcomes in various industrial contexts. Recent advancements in high-brilliance near-infrared laser beams with adjustable profiles aim to stabilize welding processes.This study focuses on the welding of CuZn37 (508L) brass alloy using a 6000 W laser beam with a core and ring profile. High-quality deep penetration welds are for 2 mm thickness are shown with a subsequent wire filling process to address underfills. By feeding a brass wire into the seam and melting it with the laser beam, parameters are identified to produce smooth, pore-free welds with reinforcement and strong bonding.

Optical trapping of nanoclusters formed in a temperature-responsive ionic liquid aqueous solution under focused near-infrared laser irradiation.

Confining molecules and ions at a specific position in a solution enables the control of chemical reactions and analysis of tiny amounts of substances. Here, we demonstrate local condensation of a temperature responsive ionic liquid using optical tweezers. Two kinds of microdroplets are prepared through phase separation or nanocluster formation under irradiation of a near-infrared laser beam. The droplet formation mechanism is discussed in view of the evolution of an optical potential well and the local temperature distribution.

Terahertz Generation through Coherent Excitation of Slow Surface Waves in an Array of Carbon Nanotubes

In this paper, we present a scheme for generating terahertz (THz) radiation using an array of parallel double-walled carbon nanotubes (DWCNTs) subjected to a direct current (DC). The longitudinal surface plasmon polaritons (SPPs) in the DWCNTs are coherently excited by two near-infrared laser beams with slightly different frequencies. Through numerical methods, we investigate the spectral characteristics of the SPPs in the presence of a DC current in the nanotubes. We identify high-quality plasmonic modes with a slowdown factor exceeding 300 in the terahertz frequency region. The amplification of these slow SPP modes is facilitated by the DC current in the DWCNTs, fulfilling a synchronism condition. This condition ensures that the phase velocity of the SPPs is closely matched to the drift velocity of the charge carriers, allowing for an efficient energy exchange between the current and the surface electromagnetic wave. The high-frequency currents on the nanotube walls in the DWCNT array enable the emission of THz radiation into the far field, owing to an antenna effect.

Optothermal crystallization of hard spheres in an effective bidimensional geometry.

Using colloids effectively confined in two dimensions by a cell with a thickness comparable to the particle size, we investigate the nucleation and growth of crystallites induced by locally heating the solvent with a near-infrared laser beam. The particles, which are "thermophilic," move towards the laser spot solely because of thermophoresis with no convection effects, forming dense clusters whose structure is monitored using two order parameters that gauge the local density and the orientational ordering. We find that ordering takes place when the cluster reaches an average surface density that is still below the upper equilibrium limit for the fluid phase of hard disks, meaning that we do not detect any signof a proper "two-stage" nucleation from a glass or a polymorphic crystal structure. The crystal obtained at late growth stage displays a remarkable uniformity with a negligible amount of defects, arguably because the incoming particles diffuse, bounce, and displace other particles before settling at the crystal interface. This "fluidization" of the outer crystal edge may resemble the surface enhanced mobility giving rise to ultra-stable glasses by physical vapor deposition.

Laser beam welding of brass with combined core and ring beam

Brass represents a large part in the production of components within the copper alloy group. Laser beam welding of this alloy offers great potential for many applications in terms of achievable seam quality and productivity. However, there is a very high tendency of the process for irregular seam surfaces and formation of pores as well as spatters. These are due, among other things, to instabilities of the keyhole, which is favored by the evaporation of the alloy component zinc. Furthermore, near-infrared laser beam wavelength can couple poorly into the material due to the low absorption level of brass, whereas absorption jumps during the melt transition. In recent years, high-brilliance near-infrared laser beam sources with adjustable beam profiles have been developed, to contribute to the stabilization of the keyhole. The presented experimental process investigations are on deep penetration welding of different brass alloys (CuZn37 and CuZn39Pb3). A laser beam source with a power of 6000 W and a combined core and ring beam was used for this purpose. It was found that the process parameters, such as energy per unit length, spot size, and process gas supply, have a significant impact on the resulting weld seam. These parameters were systematically varied. The produced seams were analyzed and evaluated using various methods, including micrograph analysis, energy dispersive x-ray spectroscopy, 3D-computed tomography, and 3D-topography imaging. The results were then correlated with the process parameters. Process parameters that produce high-quality bead-on-plate and butt welds for a sheet thicknesses of 2 mm were determined.

Nanoscale local modification of PMMA refractive index by tip-enhanced femtosecond pulsed laser irradiation

Tip-enhanced optical effects have enabled a wide palette of nanoscale investigation techniques and recently they were successfully used to modify and manipulate matter with nanoscale spatial resolution. We contribute to this latter area by reporting a viable method to modify the refractive index of polymethyl methacrylate (PMMA). Local surface changes of the refractive index are accomplished by focusing a femtosecond pulsed near-infrared laser beam on the apex of a metalized nanosized tip, traditionally used in scanning probe microscopy (SPM). The refractive index is changed over a circular area with diameter <200 nm under 790 nm illumination, representing a four-fold increase in resolution compared to the current state-of-the-art. These results are obtained at low laser pulse energies (<0.5 nJ), which represents a two orders of magnitude advantage over previously reported methods. Besides enabling modifications of the refractive index with high lateral resolution, this method can pave the way towards other important applications such the fabrication of photonic crystal lattices and surface waveguides.

Electrolyte Concentration Dependence on Ionic Current Responses of Au Nanoparticles Irradiated with a Near-Infrared Laser Beam

Electrolyte Concentration Dependence on Ionic Current Responses of Au Nanoparticles Irradiated with a Near-Infrared Laser Beam

Laser-imprinting of micro-3D printed protein hydrogels enables real-time independent modification of substrate topography and elastic modulus

Independent control over the Young's modulus and topography of a hydrogel cell culture substrate is necessary to characterize how attributes of its adherent surface affect cellular responses. Arbitrary, real-time manipulation of these parameters at the micron scale would further provide cellular biologists and bioengineers with the tools to study and control numerous highly dynamic behaviors including cellular adhesion, motility, metastasis, and differentiation. Although physical, chemical, thermal, and light-based strategies have been developed to influence Young's modulus and topography of hydrogel substrates, independent control of these physical attributes has remained elusive, spatial resolution is often limited, and features commonly must be pre-patterned. We recently reported a strategy in which biomaterials having specified three-dimensional (3D) morphologies are micro-3D printed in a two-step process: laser-scanning bioprinting of a protein-based hydrogel, followed by biocompatible hydrogel re-scanning to create microscale imprinted features at user-defined times. In this approach, a pulsed near-infrared laser beam is focused within the printed hydrogel to promote matrix contraction through multiphoton crosslinking, where scanning the laser focus projects a user-defined topographical pattern on the surface without subjecting the hydrogel-solution interface to damaging light intensities. Here, we extend this strategy, demonstrating the ability to decouple dynamic topographical changes from changes in hydrogel Young's modulus at the substrate surface by increasing the isolation distance between the surface and re-scanning planes. Using atomic force microscopy, we show that robust topographic changes can be imposed without altering the Young's modulus measured at the substrate surface by scanning at a depth of greater than ∼6 μm. Transmission electron microscopy of hydrogel thin sections reveals changes to hydrogel porosity and density distribution within scanned regions, and that such changes to the hydrogel matrix are highly localized to regions of laser exposure. These results represent valuable new capabilities for deconvolving the effects of substrate dynamic physical attributes on the behavior of adherent cells.

Controlling LIPSS formation on Ni surface using near-infrared laser beam and its low-order harmonics

Ultrafast laser ablation of metal surfaces is a common physical process used to generate periodic surface structures with tuneable multifunctionality for various applications in science and technology. In this work, the formation of femtosecond laser-induced periodic surface structures (LIPSSs) is investigated with 50 kHz repetition rate laser of 40 fs pulse duration and a central wavelength () along with its second () and third ) harmonic components. The variation in the LIPSS periodicity is demonstrated by changing the wavelength of the ablating laser pulses. LIPSS with periodicity ∼0.85 m at the fundamental ablating pulses, ∼0.42 m periodicity at the second harmonic, and ∼0.35 m periodicity at the third harmonic were observed. The third harmonic radiation was generated in an air-filament with minimal temporal delay with respect to the fundamental driving pulses to structure Nickel surfaces at ambient conditions. The approach demonstrates the potential for generating very fine LIPSS on materials’ surfaces using the efficient high-order harmonics of an infrared fundamental laser beam.

Photothermal nanofibrillar membrane based on hyaluronic acid and graphene oxide to treat Staphylococcus aureus and Pseudomonas aeruginosa infected wounds

Here we reported the fabrication of an electrospun membrane based on a hyaluronic acid derivative (HA-EDA) to be used as a bandage for the potential treatment of chronic wounds. The membrane, loaded with graphene oxide (GO) and ciprofloxacin, showed photothermal properties and light-triggered drug release when irradiated with a near-infrared (NIR) laser beam. Free amino groups of HA-EDA derivative allowed autocrosslinking of the electrospun membrane; thus, a substantial enhancement in the hydrolytic resistance of the patch was obtained. In vitro antibacterial activity studies performed on Staphylococcus aureus and Pseudomonas aeruginosa revealed that such electrospun membranes, due to the synergistic effect of the antibiotic and NIR-mediated hyperthermia, reduced the viability of both pathogens. Specific in vitro experiment demonstrated also that is possible to disrupt, through laser irradiation, the biofilms formed onto the membrane.

Near-infrared single-mode optical waveguide fabrication in LiF crystal by carbon ion irradiation

In this study, a carbon-ion beam irradiation method with energy of 6.0 MeV was employed to prepare single-mode optical waveguide structures in LiF single crystal. The results of this study reveal that the visible light and near-infrared laser beams can be well-confined in the irradiated region that is influenced by the irradiation fluences. An end-face coupling system was used to estimate the propagation loss (1.3 dB cm−1) after annealing treatment. The surface damage of the irradiated regions in LiF was analysed based on the displacements per atom calculation using the stopping and range of ions in matter code.

Proximity-effect-related reduction of the minimum element size in thermochemical laser writing

This study is intended to identify patterns in reducing the minimum size of writable elements in a structure as a function of the distance between elements when they are produced successively by direct thermochemical recording on a thin metal film using direct laser thermochemical writing, as a result of natural thermo-optical effects. Subject of study. The change in writable-element size (the proximity effect) studied here occurs because reduced absorption at the periphery of the beam as it passes through films on which elements have previously been written results in containment of the energy. Methods. This effect was studied by obtaining a solution to the quasi-steady-state heat conduction equation in closed form while taking into account the time-dependent, nonuniform spatial distribution of optical properties within the sample, using titanium films oxidized by exposure to laser light in air as an example. The model results are compared against available experimental studies of the optical and geometric properties of structures written on a 10 nm titanium film by a focused near-infrared cw laser beam. Main results. This research led to a means of predicting the widths of successively written tracks as a function of track separation. The upper threshold track separation values where the effect begins and the lower threshold values below which the new track no longer appears were determined. Both the theoretical and experimental results reveal that the resolution of thermochemical laser writing on thin metal films that form optically transparent oxides can be increased. Practical significance. The theoretical model proposed in this paper can be used to determine the laser exposure parameters required to produce various high-resolution photonic components, such as diffractive optical elements, half-tone photomasks, etc.

Megahertz ultrasonic source induced by femtosecond laser irradiation of graphene foam

The performance of a photo-thermo-acoustic (PTA) ultrasonic source can be significantly improved by utilizing graphene-based materials. Graphene is an excellent PTA material owing to its wide electromagnetic absorption spectrum, low heat capacity per unit area, and high thermal conductivity. In this study, a broadband graphene-foam-based PTA ultrasonic source covering the frequency range of 50 kHz to 1.8 MHz was excited by a near-infrared femtosecond laser beam. The lower and upper frequency limits of the acoustic wave that can be detected in the experiments were determined by the responsivity of the microphone and the attenuation of the acoustic wave in air, respectively. The experimental results show that the sound pressure of this ultrasonic source was independent of the laser polarization and incident angle. The peak-to-peak magnitude of the ultrasonic wave was proportional to laser energy when the single-pulse energy of the femtosecond laser varied from 0.4 to 1.0 mJ. Therefore, the sound intensity of the ultrasonic source could be easily controlled by modulating the laser energy. The experimental results also show that the ultrasonic wave emitted from the graphene foam had a dipole-like acoustic pressure distribution, and its principal emission direction was normal to the sample surface, regardless of the laser incidence angle. This characteristic may benefit future applications in directed message transfer/acquisition and nondestructive testing/imaging.

Azadipyrromethene Dye-Assisted Defect Passivation for Efficient and Stable Perovskite Solar Cells.

Organic-inorganic perovskite solar cells (PSCs) provide one of the most outstanding photovoltaic (PV) technologies, yet their efficiency, stability, and defect passivation engineering still remain challenging. We demonstrate the use of low-cost, eco-friendly, and multi-functional aza-dipyrromethene (Aza-DIPY) dye molecules to promote the power conversion efficiency (PCE) and the operating stability of PSC devices. The Aza-DIPY dye was meticulously synthesized and incorporated into PSC devices via a one-step solution processing approach. The pyrrole, benzene ring, and chlorine functional groups on the dye have intense interactions with perovskite to passivate surface defects and obtain high-quality perovskite absorbers, resulting in the lengthened carrier recombination time and enhanced fill factor of PSCs. Additionally, the hydrophobic phenyl and halogen functional groups on the Aza-DIPY perform as a protecting barrier against moisture and ameliorate the stability of PSCs. As a consequence, the PV performance of PSCs is considerably improved, with the average PCE increased from 16.71% to 19.71%, and the champion device with Aza-DIPY shows a PCE of 20.46%. The unencapsulated PSC devices with multi-functional molecular Aza-DIPY maintains 89.06% of their beginning PCEs after storage in ambient air (25-30 °C, 50-70% relative humidity) under dark conditions for 100 h, exhibiting a significantly enhanced ambient stability compared with the case of the reference cells without the dye. Furthermore, the Aza-DIPY-modified PSC devices exhibit strong and reversible photoresponses, with a high responsivity of 0.739 mA/W to near-infrared (NIR) laser beams. Our results highlight the potential of synthesizing multi-functional Aza-DIPY dyes-incorporated PSC devices with sensitive NIR/visible light responses, high PV efficiency, and stability.

Laser-based coating process of PEEK powder on stainless steel substrates by using a thulium-doped fiber laser

PEEK is an excellent thermoplastic material for functional coatings due to its outstanding material properties (e.g. biocompatibility, temperature stability, corrosion and wear resistance). In order to reduce the heat input into the base material and to enable a high local selectivity of polymer deposition, a laser-based coating process is a promising approach. In this study, the consolidation of PEEK coatings on stainless steel substrates was investigated experimentally for the first time by using a thulium-doped fiber laser with a wavelength of 1.94 µm. As most polymers exhibit characteristic absorption bands at wavelengths above 1.5 µm, a thulium-doped fiber laser is more appropriate for consolidating thermoplastics in comparison to more common near-infrared laser beam sources with wavelengths of around 1 µm. The effect of admixing fumed silica particles on the flow behavior of the PEEK powder was analyzed by degree of coverage tests to improve the powder deposition process via doctor blade. Furthermore, the influence of an additional substrate heating on the resulting coating characteristics was investigated. Optical microscopy analyses were conducted to characterize the coating surfaces and cross-sections in terms of possible defects. As a result, the flow behavior and hence the deposition process were significantly improved by admixing 1.0 wt. % fumed silica. Optical microscopy analyses verify the basic feasibility of a laser-based coating process with a thulium-doped fiber laser for the consolidation of PEEK powder on stainless steel substrates. In this context, a substrate heating is an important prerequisite to enhance the wetting of the stainless steel substrate and to produce dense as well as adherent PEEK coatings.