Near-infrared Component Research Articles

Phosphorescent cyclometalated Ir(III) complexes with fluoranthene unit and their near-infrared (NIR) OLEDs showing NIR% higher than 99 %

With the aim to design and synthesize cyclometalated Ir(III) complexes with near-infrared (NIR) emission, a series of ppy-type ligands with fluoranthene unit have been synthesized bearing different aromatic nitrogen heterocycles of isoquinoline, quinoline, pyridine and benzo [d]thiazole. With these organic ligands, four [Ir (ppy)2 (acac)] complexes are prepared named as IrFTIQ, IrFTQL, IrFTPY and IrFTBZ. In solution, IrFTIQ can emit NIR phosphorescence at 738 nm, while IrFTQL (ca. 692 nm), IrFTPY (ca. 670 nm) and IrFTBZ (ca. 690 nm) are typical deep-red emitters. It should be noted that all these fluoranthene-based cyclometalated Ir(III) complexes show good electrochemical stability indicated by their reversible redox procedures. When doped in the emission layer of OLEDs, IrFTIQ and IrFTBZ can furnish NIR electroluminescence (EL) at 748 nm and 700 nm, respectively, while the devices with IrFTPY as emitter can furnish deep-red EL. Critically, the optimized OLED doped with IrFTIQ can achieve maximum external quantum efficiency (EQE) as high as 5.01 % and a radiance up to 6284 mW Sr−1 m−2. Critically, the NIR OLEDs based on IrFTIQ can furnish EL with NIR component (NIR%) of a total spectrum > 99 %. All these encouraging results definitely demonstrate the effectiveness of our molecular design strategy for the new-type Ir(III) NIR phosphorescent complexes and the great potential of the fluoranthene group in developing high-performance Ir-based NIR phosphors for OLEDs.

Efficient red and broadband near‐infrared luminescence in Mn2+/Yb3+‐doped phosphate phosphor

AbstractIn this work, we report a novel phosphor LSPO:Mn2+ that exhibits red emission at about 616 nm and pleasant broad near‐infrared (NIR) emission at about 800 nm with a full width at half maximum (fwhm) of 112 nm. The structure and spectra show that the doped manganese ions occupy two kinds of Sc sites forming Mn1 and Mn2 emission centers, which are responsible for red and NIR emission, respectively. The XPS and low‐temperature fluorescence spectra reveal that both red and NIR emissions come from the Mn2+ ions. Besides, NIR luminescence is improved by doping Yb3+ in LSPO:Mn2+, leading to the broadened NIR emission range (700‐1100 nm) and enhanced luminescent thermal stability. Our results suggest that the prepared LSPO:Mn2+ and LSPO:Mn2+,Yb3+ phosphors offer the potential applications as red and NIR components in phosphor‐converted white‐light‐emitting diodes (pc‐WLED) and broadband NIR pc‐LED. Meanwhile, this work provides a new way to design novel broadband NIR phosphors.

Multispectrum Indocyanine Green Videography for Visualizing Brain Vascular Pathology

Currently, neurosurgical vascular surgery frequently uses indocyanine green (ICG)-videography (VG) to evaluate the blood flow in brain vessels. Although ICG-VG delineates intravascular ICG fluorescence as a high-intensity signal in gray-scale with dark background, it is hard to identify anatomical structures, including vasculature or surgical devices simultaneously. This report developed combination of a near-infrared (NIR) camera with particular sensitivity and an optical filter to observe the blood-flow conditions and anatomical structures. To overcome the specific issues of ICG-VG, we applied a high-sensitivity camera with a 980-nm NIR component to delineate anatomical and fluorescence images, detecting signals between 830 and 1000 nm simultaneously during operation. We used a diluted ICG phantom to evaluate fluorescence signal changes by changing wavelength of the emission light. For clinical use, we used a high-sensitivity NIR camera with a high-pass filter on a surgical microscope. The new NIR system detected signals between 770 and 1000 nm, and the lighting system illuminated objects mainly at 980-nm wavelength. Both images with the blood flow and anatomical structures were projected to the smart glasses in real time. In the phantom experiment, we found that the emission light with wide band widths (575-800 nm) evoked various intensities of ICG fluorescence. This new NIR system allowed us to observe ICG fluorescence and anatomical structures without image fusion or time-delay. The both information of anatomy and fluorescence was projected on wearable smart glasses. Furthermore, the new NIR system detected ICG-fluorescence signals for a longer duration than the original camera, which allowed us to achieve careful and detailed observation of more vasculature and fine vessels. This study proposes a new NIR system and emphasizes simultaneous observation of anatomy and fluorescence signals during operation. It paves the way for further possibilities in the development of optical systems. To understand the natural phenomena and combination of different scientific and clinical fields, it might be important to understand and combine not only fluorescence, but also natural science, optics, and background pathology. This simple system would be available for neuroendoscope and robotic surgery.

Controllable ultra‐broadband visible and near‐infrared photoemissions in Bi‐doped germanium‐borate glasses

AbstractThe design of functional materials with tunable broadband luminescence performance is still of great interest in the fields of lighting, solar cells, tunable lasers, and optical amplifiers. Here, via a melt‐quenching method, a series of bismuth (Bi)‐doped germanium‐borate glasses with composition of 40GeO2–25B2O3–25Gd2O3–10La2O3–xBi2O3 have been prepared, in which multiple Bi active centers can be stabilized simultaneously. Dual‐modulating modes of visible (380‐750 nm) and near‐infrared (NIR) (1000‐1600 nm) broadband photoemissions were effectively controlled under flexible excitation scheme. Photoluminescence (PL) spectra at low temperature 10‐298 K were appropriately employed to interpret such an unusual wide visible emission band. To further illustrate the origin of NIR component, transmission electron microscopy (TEM) measurement was carried out. It is demonstrated experimentally that the visible emission mainly originates from the collective contribution of the 3P1/3P01S0 transitions of Bi3+, while the broadband NIR luminescence should be related to the formation of low valent Bi+ and (or) Bi0 centers. This work may help to enhance the knowledge of the complex luminescence mechanism for the Bi species and it also enables such transparent glass materials to be a promising candidate for the multifunctional tunable light source.

THE NUCLEUS OF THE PLANETARY NEBULA EGB 6 AS A POST-MIRA BINARY*

ABSTRACT EGB 6 is a faint, large, ancient planetary nebula (PN). Its central star, a hot DAOZ white dwarf (WD), is a prototype of a rare class of PN nuclei associated with dense, compact emission-line knots. The central star also shows excess fluxes in both the near-infrared (NIR) and mid-infrared (MIR). In a 2013 paper, we used Hubble Space Telescope (HST) images to show that the compact nebula is a point-like source, located 0.″16 (∼118 AU) from the WD. We attributed the NIR excess to an M dwarf companion star, which appeared to coincide with the dense emission knot. We now present new ground-based NIR spectroscopy, showing that the companion is actually a much cooler source with a continuous spectrum, apparently a dust-enshrouded low-luminosity star. New HST images confirm common proper motion of the emission knot and red source with the WD. The I-band, NIR, and MIR fluxes are variable, possibly on timescales as short as days. We can fit the spectral energy distribution (SED) with four blackbodies (the WD, a ∼1850 K NIR component, and MIR dust at 385 and 175 K). Alternatively, we show that the NIR/MIR SED is very similar to that of Class 0/I young stellar objects. We suggest a scenario in which the EGB 6 nucleus is descended from a wide binary similar to the Mira system, in which a portion of the wind from an AGB star was captured into an accretion disk around a companion star; a remnant of this disk has survived to the present time and is surrounded by gas photoionized by UV radiation from the WD.

Color Restoration of RGBN Multispectral Filter Array Sensor Images Based on Spectral Decomposition.

A multispectral filter array (MSFA) image sensor with red, green, blue and near-infrared (NIR) filters is useful for various imaging applications with the advantages that it obtains color information and NIR information simultaneously. Because the MSFA image sensor needs to acquire invisible band information, it is necessary to remove the IR cut-offfilter (IRCF). However, without the IRCF, the color of the image is desaturated by the interference of the additional NIR component of each RGB color channel. To overcome color degradation, a signal processing approach is required to restore natural color by removing the unwanted NIR contribution to the RGB color channels while the additional NIR information remains in the N channel. Thus, in this paper, we propose a color restoration method for an imaging system based on the MSFA image sensor with RGBN filters. To remove the unnecessary NIR component in each RGB color channel, spectral estimation and spectral decomposition are performed based on the spectral characteristics of the MSFA sensor. The proposed color restoration method estimates the spectral intensity in NIR band and recovers hue and color saturation by decomposing the visible band component and the NIR band component in each RGB color channel. The experimental results show that the proposed method effectively restores natural color and minimizes angular errors.

NMF-Based Spectral Reflectance Estimation From Image Pairs Including Near-Infrared Components

In this paper, a novel spectral reflectance estimation method from image pairs including near-infrared (NIR) components based on nonnegative matrix factorization (NMF) is presented. The proposed method enables estimation of spectral reflectance from only two kinds of input images: 1) an image including both visible light components and NIR components and 2) an image including only NIR components. These two images can be easily obtained using a general digital camera without an infrared-cut filter and one with a visible light-cut filter, respectively. Since RGB values of these images are obtained according to spectral sensitivity of the image sensor, the spectrum power distribution of the light source and the spectral reflectance, we have to solve the inverse problem for estimating the spectral reflectance. Therefore, our method approximates spectral reflectance by a linear combination of several bases obtained by applying NMF to a known spectral reflectance data set. Then estimation of the optimal solution to the above problem becomes feasible based on this approximation. In the proposed method, NMF is used for obtaining the bases used in this approximation from a characteristic that the spectral reflectance is a nonnegative component. Furthermore, the proposed method realizes simple approximation of the spectrum power distribution of the light source with direct and scattered light components. Therefore, estimation of spectral reflectance becomes feasible using the spectrum power distribution of the light source in our method. In the last part of this paper, we show some simulation results to verify the performance of the proposed method. The effectiveness of the proposed method is also shown using the method for several applications that are closely related to spectral reflectance estimation. Although our method is based on a simple scheme, it is the first method that realizes the estimation of the spectral reflectance and the spectrum power distribution of the light source from the above two kinds of images taken by general digital cameras and provides breakthroughs to several fundamental applications.

A new gaze estimation method considering external light.

Gaze tracking systems usually utilize near-infrared (NIR) lights and NIR cameras, and the performance of such systems is mainly affected by external light sources that include NIR components. This is ascribed to the production of additional (imposter) corneal specular reflection (SR) caused by the external light, which makes it difficult to discriminate between the correct SR as caused by the NIR illuminator of the gaze tracking system and the imposter SR. To overcome this problem, a new method is proposed for determining the correct SR in the presence of external light based on the relationship between the corneal SR and the pupil movable area with the relative position of the pupil and the corneal SR. The experimental results showed that the proposed method makes the gaze tracking system robust to the existence of external light.

Exploring the spectral diversity of low-redshift Type Ia supernovae using the Palomar Transient Factory

We present an investigation of the optical spectra of 264 low-redshift (z < 0.2) Type Ia supernovae (SNe Ia) discovered by the Palomar Transient Factory, an untargeted transient survey. We focus on velocity and pseudo-equivalent width measurements of the Si II 4130, 5972, and 6355 A lines, as well those of the Ca II near-infrared (NIR) triplet, up to +5 days relative to the SN B-band maximum light. We find that a high-velocity component of the Ca II NIR triplet is needed to explain the spectrum in ~95 per cent of SNe Ia observed before -5 days, decreasing to ~80 per cent at maximum. The average velocity of the Ca II high-velocity component is ~8500 km/s higher than the photospheric component. We confirm previous results that SNe Ia around maximum light with a larger contribution from the high-velocity component relative to the photospheric component in their Ca II NIR feature have, on average, broader light curves and lower Ca II NIR photospheric velocities. We find that these relations are driven by both a stronger high-velocity component and a weaker contribution from the photospheric Ca II NIR component in broader light curve SNe Ia. We identify the presence of C II in very-early-time SN Ia spectra (before -10 days), finding that >40 per cent of SNe Ia observed at these phases show signs of unburnt material in their spectra, and that C II features are more likely to be found in SNe Ia having narrower light curves.

Engineering light-emitting diode surgical light for near-infrared fluorescence image-guided surgical systems.

The near-infrared (NIR) fluorescence signal in the 700 to 900 nm from molecular probes used in fluorescence image-guided surgery (FIGS) is usually weak compared to the NIR component from white light-emitting diode surgical light, which is typically switched off during FIGS to enhance the molecular fluorescence contrast of the image. We propose a simple solution to this critical issue in FIGS by removing NIR light from surgical light with a low cost commercial 3M cool mirror film 330.

On-line predictions of the aspen fibre and birch bark content in unbleached hardwood pulp, using NIR spectroscopy and multivariate data analysis

An on-line fibre-based near-infrared (NIR) spectrometric analyser was adapted for on-site process analysis at an integrated paperboard mill. The analyser uses multivariate techniques for the quantitative predication of the aspen fibre (aspen) and the birch bark contents of sheets of unbleached hardwood pulp. The NIR analyser is a prototype constructed from standard NIR components. The spectroscopic data was processed by using principal component analysis (PCA) and partial least square (PLS) regression. Three sample sets were collected from three experimental designs, each composed of known pulp contents of birch, aspen and birch bark. Sets 1 and 2 were used for model calibration and set 3 was used to validate the models. The PLS model that produced the best predictions gave an error of prediction (RMSEP) of 13% for aspen and less than 2% for birch bark. Eight components resulted in an R 2 X of 99.3%, R 2 Y of 99.6%, and Q 2 of 95.3%. For additional validation of aspen, three unbleached hardwood samples from the mill's production were calculated to lie between − 7% and + 6%, regarding to the PLS model. When vessel cells were counted under a light microscope a value for the aspen content of 4.7% was obtained. The predictive models evaluated were suitable for quality assessments rather than quantitative determination.

Modeling hourly and daily fractions of UV, PAR and NIR to global solar radiation under various sky conditions at Botucatu, Brazil

In this analysis, using available hourly and daily radiometric data performed at Botucatu, Brazil, several empirical models relating ultraviolet (UV), photosynthetically active (PAR) and near infrared (NIR) solar global components with solar global radiation (G) are established. These models are developed and discussed through clearness index K T (ratio of the global-to-extraterrestrial solar radiation). Results obtained reveal that the proposed empirical models predict hourly and daily values accurately. Finally, the overall analysis carried out demonstrates that the sky conditions are more important in developing correlation models between the UV component and the global solar radiation. The linear regression models derived to estimate PAR and NIR components may be obtained without sky condition considerations within a maximum variation of 8%. In the case of UV, not taking into consideration the sky condition may cause a discrepancy of up to 18% for hourly values and 15% for daily values.

Component reflectance scheme for DMSP-derived sea ice reflectances in the Arctic Basin

Abstract A scheme is introduced which in effect 'splits’ Defence Meteorological Satellite Program (DMSP) single broadband sea ice reflectances into weighted visible and near-infrared (NIR) component reflectances. The method is rooted in (1) the fitting of polynomials to observed spectral reflectance curves of sea ice, (2) a weighting scheme and (3) the identification of general sea ice types and their corresponding areal coverage per imaged cell. Previously derived DMSP broadband sea ice reflectances in the Arctic Basin have been spectrally sequestered into visible and NIR component reflectances for May to August for the years 1977, 1979, 1984 and 1985. Comparison of spectrally modified DMSP visible reflectances (0-4-0-9 µm) are in closer agreement with NOAA-5 derived visible sea ice reflectances (0-52-0-72 µm ) than unmodified DMSP visible/NIR reflectances (0-4-1-1 µm ) for July 1977 in the Arctic Basin. It was also found that melt pond and flooding effects were more apparent for spectrally-modified NIR reflectances as compared to spectrally-modified visible reflectances. Possible uses of the scheme and newly created data sets are discussed.