Near-field Radiative Heat Transfer Research Articles

Near-Field Radiative Heat Transfer between Layered β-GeSe Slabs: First-Principles Approach.

The group-IV monochalcogenide monolayers, GeSe, are interesting and novel two-dimensional (2D) semiconductor materials due to their highly anisotropic physical properties. Monolayers of the different GeSe polymorphs have already had their physical properties and potential applications extensively investigated. However, few-layer homostructures, which can also be approximated as 2D systems in many cases, have not received the same attention. For this reason, in this work, we investigate the optical properties of a free-standing few-layer β-GeSe system and use this information to investigate their performance in the near-field radiative heat transfer (NFRHT). The required optical conductivity of the few-layer 2D material is calculated by using density functional theory (DFT), including spin-orbit coupling. The band structure is investigated for up to five layers, and the effective electron masses are calculated correspondingly. Using this information, both the intraband transitions due to the presence of free electrons introduced by doping and the interband transitions are considered. The contribution of the ionic vibrations is also included in calculating the optical properties because of its relevance to NFRHT through the resulting active optical phonons. With all these contributions included, more realistic predictions of the NFRHT between the layered 2D β-GeSe materials can be obtained. It is found that the heat transfer attainable with the layered system is similar to that of a single layer of β-GeSe we have obtained previously.

Active control of nonreciprocal near-field radiative heat transfer with a drift-current biased graphene/α-MoO3 heterostructure.

The interaction between the drift-current biased graphene plasmonics and the hyperbolic phonon polaritons of α-MoO3 provides a promising way to manipulate near-field radiation heat transfer (NFRHT). Through examination of the drift biased graphene/α-MoO3 heterostructure, it has been discovered that drift-current applied to the graphene effectively enhances photon tunneling. Consequently, they dynamically modulate the coupling effect of the two excitations, thereby offering a reliable pathway for the modulation of NFRHT. Furthermore, the influencing mechanism of vacuum gaps on nonreciprocal NFRHT with different drift-current rates is revealed, and it is discovered that the vacuum gaps can filter the nonreciprocal surface plasmon polaritons with high nonreciprocity. Our findings make it possible to manipulate nanoscale thermal rectification and noncontact thermal modulation.

Time-modulated near-field radiative heat transfer

Near-field radiative heat transfer has recently attracted increasing interests for its applications in energy technologies, such as thermophotovoltaics. Existing works, however, are restricted to time-independent systems. Here, we explore near-field radiative heat transfer between two bodies under time modulation by developing a rigorous fluctuational electrodynamics formalism. We demonstrate that time modulation can result in the enhancement, suppression, elimination, or reversal of radiative heat flow between the two bodies, and can be used to create a radiative thermal diode with an infinite contrast ratio, as well as a near-field radiative heat engine that pumps heat from the cold to the hot bodies. The formalism reveals a fundamental symmetry relation in the radiative heat transfer coefficients that underlies these effects. Our results indicate the significant capabilities of time modulation for managing nanoscale radiative heat flow.

Corner- and edge-mode enhancement of near-field radiative heat transfer.

It is well established that near-field radiative heat transfer (NFRHT) can exceed Planck's blackbody limit1 by orders of magnitude owing to the tunnelling of evanescent electromagnetic frustrated and surface modes2-4, as has been demonstrated experimentally for NFRHT between two large parallel surfaces5-7 and between two subwavelength membranes8,9. However, although nanostructures can also sustain a much richer variety of localized electromagnetic modes at their corners and edges10,11, the contributions of such additional modes to further enhancing NFRHT remain unexplored. Here we demonstrate both theoretically and experimentally a physical mechanism of NFRHT mediated by the corner and edge modes, and show that it can dominate the NFRHT in the 'dual nanoscale regime' in which both the thickness of the emitter and receiver, and their gap spacing, are much smaller than the thermal photon wavelengths. For two coplanar 20-nm-thick silicon carbide membranes separated by a 100-nm vacuum gap, the NFRHT coefficient at room temperature is both predicted and measured to be 830W m-2 K-1, which is 5.5 times larger than that for two infinite silicon carbide surfaces separated by the same gap, and 1,400 times larger than the corresponding blackbody limit accounting for the geometric view factor between two coplanar membranes. This enhancement is dominated by the electromagnetic corner and edge modes, which account for 81% of the NFRHT between the silicon carbide membranes. These findings are important for future NFRHT applications in thermal management and energy conversion.

Tunable near-field radiative heat transfer with the shear polariton in three-body low-symmetry crystals

Tunable near-field radiative heat transfer with the shear polariton in three-body low-symmetry crystals

Near-field radiative heat transfer between nonpolar epsilon-near-zero dielectric-filled Si gratings

Near-field radiative heat transfer between nonpolar epsilon-near-zero dielectric-filled Si gratings

Numerical study of near-field radiative heat transfer between bio-inspired spiny particles

The spine-like structure appears on some smooth organisms and has a high light absorption cross-section. Inspired by the spiny structure in the nature, this study establishes models of solid and hollow spiny particles. The effects of spine cross-section size, uniform and nonuniform spine distribution, hollow size, gap, and spine dislocation on near-field radiative heat transfer of spiny particles are investigated based on the thermal discrete dipole approximations method. The spectral radiative conductance and volumetric net power distribution are obtained. The results indicate that the coupling of localized surface phonons between two particles is affected by spine cross-section size and spine distribution. Near-field radiative heat transfer of spiny particles is enhanced maximumly when the frequencies are slightly lower than the resonance frequency of smooth particles. The peak of the spectral conductance is red-shifted and decreases with the increase of hollow size. The uniformity of volumetric power absorbed distribution increases and the variation of the relative spectral conductance decreases with increasing gap. The influence of two particles’ spine dislocation on near-field radiative heat transfer and volumetric power absorbed distribution is not obvious.

Generative adversarial networks for data-scarce radiative heat transfer applications

Abstract Generative adversarial networks (GANs) are one of the most robust and versatile techniques in the field of generative artificial intelligence. In this work, we report on an application of GANs in the domain of synthetic spectral data generation for data-scarce radiative heat transfer applications, an area where their use has not been previously reported. We demonstrate the proposed approach by applying it to an illustrative problem within the realm of near-field radiative heat transfer involving a multilayered hyperbolic metamaterial. We find that a successful generation of spectral data requires two modifications to conventional GANs: (i) the introduction of Wasserstein GANs (WGANs) to avoid mode collapse, and, (ii) the conditioning of WGANs to obtain accurate labels for the generated data. We show that a simple feed-forward neural network (FFNN), when augmented with data generated by a CWGAN, enhances significantly its performance under conditions of limited data availability. In addition, we show that CWGANs can act as a surrogate model with improved performance in the low-data regime with respect to simple FFNNs. Overall, this work contributes to highlight the potential of generative machine learning algorithms in scientific applications beyond image generation and optimization.

Coupling of Surface Plasmon Polaritons and Hyperbolic Phonon Polaritons on the Near-Field Radiative Heat Transfer Between Multilayer Graphene/hBN Structures

ABSTRACT Near-field radiative heat transfer (NFRHT) between multilayer graphene/hBN heterostructures has been demonstrated to exceed the blackbody limit due to the coupling mechanism of surface plasmon polaritons and hyperbolic phonon polaritons, opening the door to applications in thermal management, thermophotovoltaics, and nanoscale metrology. Recent studies have shown that adding vacuum layers within multilayer structures can effectively promote surface modes and thus enhance NFRHT. However, the influence of vacuum layers on NFRHT between multilayer graphene/hBN heterostructures has not been investigated. Moreover, the influence of vacuum layers on coupled resonance modes excited in multilayer structures is worth discussing. In this work, we study the NFRHT based on multilayer graphene/vacuum/hBN/vacuum structures. The results show that as the gap distance increases from 20 nm to 100 nm, the NFRHT of three-cell and six-cell configurations is enhanced, while that of unit-cell configuration is suppressed. The potential mechanism can be identified as the excitation of surface plasmon-phonon polaritons (SPPPs) and hyperbolic plasmon-phonon polaritons (HPPPs) in multilayer structures. The enhancement factor of the six-cell configurations is up to 4.82 when the gap distance is 80 nm. Moreover, the influences of the chemical potential of graphene and the layer thickness on the NFRHT are discussed. The interesting results in this work indicate the perspectives for future near-field research involving coupling of SPPPs and HPPPs, and shed new light on high-performance devices introducing vacuum layers based on near-field radiative heat transfer.

Influence of substrate effect on near-field radiative modulator based on biaxial hyperbolic materials

Relative rotation between the emitter and receiver could effectively modulate the near-field radiative heat transfer (NFRHT) in anisotropic media. Due to the strong in-plane anisotropy, natural hyperbolic materials can be used to construct near-field radiative modulators with excellent modulation effects. However, in practical applications, natural hyperbolic materials need to be deposited on the substrate, and the influence of substrate on modulation effect has not been studied yet. In this work, we investigate the influence of substrate effect on near-field radiative modulator based on α-MoO3. The results show that compared to the situation without a substrate, the presence of both lossless and lossy substrate will reduce the modulation contrast (MC) for different film thicknesses. When the real or imaginary component of the substrate permittivity increases, the mismatch of hyperbolic phonon polaritons (HPPs) weakens, resulting in a reduction in MC. By reducing the real and imaginary components of substrate permittivity, the MC can be significantly improved, reaching 4.64 for ε s = 3 at t = 10 nm. This work indicates that choosing a substrate with a smaller permittivity helps to achieve a better modulation effect, and provides guidance for the application of natural hyperbolic materials in the near-field radiative modulator.

Enhanced near-field radiative heat transfer between nanostructure emitter and GaSb absorber by surface plasmon polaritons and hyperbolic modes

Near-field radiative heat transfer (NFRHT) can overcome the blackbody radiation limit and holds great promise in radiative energy conversion devices such as near-field thermophotovoltaics (NF-TPV). However, NF-TPV is not yet ready for practical applications at larger scales due to the challenges of maintaining the nanoscale gap and the lack of optimized NFRHT with nanostructure emitters. Here, we measure the enhanced near-field radiative heat flux between GaSb absorbers and nanostructure emitters that can be applied in NF-TPV systems, with a cm2-scale plate–plate structure and a temperature difference of 100 K at a gap down to 200 nm. It is demonstrated that the radiative heat flux between the bulk W emitter and the absorber at a 400 nm gap is about an order of magnitude larger than that in the far field, and the heat flux can be further enhanced by 1.6 times at a 200 nm gap. Moreover, the enhanced NFRHT from the surface plasmon polaritons supported by a indium tin oxide film and the hyperbolic modes supported by a W/SiO2 multilayer is also experimentally verified and theoretically analyzed.

Modulation of near-field radiative heat transfer between nanoparticles supported by a strained hBN film with graphene covered

Dynamic modulation of near-field radiative heat transfer (NFRHT) requires changing the optical responses of the object, which is expected to be realized with the help of the strain engineering. Based on the electric dipole approximation and the reflection Green's function, in this work, we investigate the effect of the hBN film under uniform in-plane strain on the NFRHT between two graphene/SiC core-shell (GSCS) nanoparticles. By changing the magnitude of the strain on the film, the hyperbolic phonon polaritons (HPPs) can be dynamically tuned to match and deviate from the localized surface resonance (LSR), thus significantly modulating the NFRHT between the nanoparticles. When the two GSCS nanoparticles are placed above a strained hBN film, an amplification of the maximum radiative heat flux by about 6 orders of magnitude can be achieved. In addition, after the introduction of graphene to form graphene/hBN heterostructure, the radiative heat flux can be further enhanced with the help of the hybrid polaritons. Especially at a suitable chemical potential and strain, the NFRHT can be enhanced by 4 more orders of magnitude compared to the bare hBN film. This work provides a new insight into efficient and dynamic thermal management among nanoparticles.

Strong enhancement of near-field radiative heat transfer between anisotropic magneto-optical gratings by a weak magnetic field

The highly tunable surface magneto-plasmon polaritons supported by magneto-optical materials provide reliable means for active adjusting of near-field radiative heat transfer (NFRHT). In our study, we proposed an anisotropic system consisting of two graphene-covered magneto-optical gratings, and theoretically investigate the NFRHT between them controlled by a weak magnetic field. We find that an external magnetic field open a broad-spectrum photo tunneling channel and modify the energy distribution of surface electromagnetic modes in the wave-vector space. The near-field heat flux between two magneto-optical gratings can achieve a remarkable maximum enhancement of 6 times at the magnetic field H=0.9T compared to that without a magnetic field. Owing to the coupling between highly tunable surface magneto-plasmon polaritons of graphene and surface modes of InSb, the regulation ratio of the heat flux exceeds 10 from 0.5 T to 0.9 T. In addition, the effects of the separation distance, chemical potential of graphene and structural configuration of two gratings are also investigated. We look forward to the proposed system being used as a thermal switch, providing convenience for tuning thermal radiation and improving the efficiency of energy-utilization devices.

Tuning the spectrum of near-field radiative heat transfer using Mie resonance based metamaterials

Tuning the spectrum of near-field radiative heat transfer using Mie resonance based metamaterials

Coupling polaritons in near-field radiative heat transfer between multilayer graphene/vacuum/α-MoO3/vacuum heterostructures.

Both materials and structures can significantly affect radiative heat transfer, which is more pronounced in the near-field regime of two-dimensional and hyperbolic materials, and has promising prospects in thermophotovoltaics, radiative cooling, and nanoscale metrology. Hence, it is important to investigate the near-field radiative heat transfer (NFRHT) in complicated heterostructures consisting of two-dimensional and hyperbolic materials. Recent studies have reported that adding vacuum layers to multilayer structures can effectively enhance the NFRHT. Take the case of multilayer graphene/α-MoO3 heterostructures: the effect of vacuum layers on these heterostructures has not been studied, and hence investigations on adding vacuum layers between graphene and α-MoO3 layers should be emphasized. In this work, we conduct an investigation of the NFRHT between multilayer graphene/vacuum/α-MoO3/vacuum heterostructures. Compared to unit graphene/α-MoO3 heterostructures without vacuum layers, it is found that NFRHT between the heterostructures with vacuum layers can be suppressed to 49.1% when the gap distance is 10 nm, and can be enhanced to 16.3% when the gap distance is 100 nm. These phenomena are thoroughly explained by the coupling of surface plasmon polaritons and hyperbolic phonon polaritons. Energy transmission coefficients and spectral heat flux are analysed during the calculations changing chemical potentials of graphene, thicknesses of vacuum layers, and α-MoO3 layers. This study is expected to provide guidance in implementing the thermal management of reasonable NFRHT devices based on graphene/α-MoO3 heterostructures.

Enhancement of near-field thermal radiation between composite materials with gradient plasmonic nanoparticles.

Near-field radiative heat transfer (NFRHT) with composite materials is of significant technological interest for practical applications. In this study, we investigate the NFRHT occurring between two composite materials composed of gradient plasmonic nanoparticles (GPNs). We delve into the physical mechanism underlying NFRHT, highlighting the strong coupling and enhancement effect from surface plasmon polaritons (SPPs) at the composite/air interface or the localized SPPs (LSPPs) on the surface of nanoparticles. Furthermore, leveraging the red-shift effect caused by the gradient profile, the intensity of NFRHT can be controlled by adjusting the gradient function and volume fraction of GPNs. Notably, we observe the enhancement of NFRHT from composite materials to bulk materials, with the enhancement ratio exhibiting a notable increase at large spacing. This research establishes a theoretical foundation for the development of near-field thermal devices utilizing composite materials containing GPNs.

Transient measurement of near-field thermal radiation between macroscopic objects.

The involvement of evanescent waves in the near-field regime could greatly enhance spontaneous thermal radiation, offering a unique opportunity to study nanoscale photon-phonon interaction. However, accurately characterizing this subtle phenomenon is very challenging. This paper proposes a transient all-optical method for rapidly characterizing near-field radiative heat transfer (NFRHT) between macroscopic objects, using the first law of thermodynamics. Significantly, a full measurement at a fixed gap distance is completed within tens of seconds. By simplifying the configuration, the transient all-optical method achieves high measurement accuracy and reliable reproducibility. The proposed method can effectively analyze the NFRHT in various material systems, including SiO2, SiC, and Si, which involve different phonon or plasmon polaritons. Experimental observations demonstrate significant super-Planckian radiation, which arises from the near-field coupling of bounded surface modes. Furthermore, the method achieves excellent agreement with theory, with a minimal discrepancy of less than 2.7% across a wide temperature range. This wireless method could accurately characterize the NFRHT for objects with different sizes or optical properties, enabling the exploration of both fundamental interests and practical applications.

Effect of graphene grating coating on near-field radiative heat transfer

In this work, we analyze the near-field radiative heat transfer (NFRHT) between finite-thickness planar fused silica slabs coated with graphene gratings. We go beyond the effective medium approximation by using an exact Fourier modal method equipped with specific local basis functions, and this is needed for realistic experimental analysis. In general, coating a substrate with a full graphene sheet has been shown to decrease the NFRHT at short separations (typically for d < 100 nm) compared to the bare substrates, where the effective medium approximation consistently overestimates the radiative heat flux, with relative errors exceeding 50%. We show that by patterning the graphene sheet into a grating, the topology of the plasmonic graphene mode changes from circular to hyperbolic, allowing to open more channels for the energy transfer between the substrates. We show that at short separations, the NFRHT between slabs coated with graphene gratings is higher than that between full-graphene-sheet coated slabs and also than that between uncoated ones. We also exhibit a significant dependence of the radiative heat transfer on the chemical potential, which can be applied to modulate in situ the scattering properties of the graphene grating without any geometric alterations. Additionally, we compare the exact calculation with an approximate additive one and confirm that this approximation performs quite well for low chemical potentials. This work has the potential to unveil new avenues for harnessing non-additive heat transfer effects in graphene-based nanodevices.

Near-field radiative heat transfer between moving anisotropic surfaces

Radiation heat transfer from two-dimensional anisotropic materials has promising applications in nanodevices, such as non-contact thermal modulators, thermal lithography and thermophotovoltaics. Moving surface is expected to provide more possibilities for the modulation of near-field thermal radiation due to its special properties such as supporting hyperbolic propagation and non-reciprocity. In this study, the near-field radiative heat transfer between moving anisotropic surfaces is investigated in the framework of the fluctuation-dissipation electrodynamics theory combined with the Lorentz transformation. It is found that the movement and rotation of the surface lead to the asymmetry of energy transfer in the wave vector space, which affects the energy transfer coefficient and hence the radiation heat flux. The effect of velocity, separation distance, rotation angle and electron density on the energy transfer coefficient and radiative heat flux between moving anisotropic surfaces is revealed. It is found that the heat flux decreases as the velocity increases, the sensitivity of the heat flux variation with velocity decreases as the velocity increases. This study provides a new idea for the active regulation of near-field radiative heat transfer.

Near-Field Thermal Transistor InSb/WSM/InSb

Near-field radiative heat transfer has attracted increasing attention in recent years in the development and manufacturing of thermal devices analogous to the building blocks of current microelectronics. In this work, we study theoretically a near-field thermal transistor operating at room temperature. The source and drain were assumed as indium antimonide (InSb) plates, whereas the gate as a Weyl semimetal (WSM). Numerical results computed using the fluctuational electrodynamics framework indicate that the modulation and/or amplification of the heat flux in the considered transistor can be achieved by modifying the gate temperature, and by the action of an external magnetic field upon the system. Results obtained in this work make the proposed near-field thermal transistor a suitable candidate for the contactless devices for the heat flux control and thermal management at nanoscale.