Abstract Solar wind measurements in the heliosphere predominantly comprise protons, alphas, and minor elements in a highly ionized state. The majority of low-charge states, such as He+, measured in situ are often attributed to pick-up ions of nonsolar origin. However, through inspection of the velocity distribution functions of near-Earth measurements, we find a small but significant population of He+ ions in the normal solar wind whose properties indicate that it originated from the Sun and has evolved as part of the normal solar wind. Current ionization models, largely governed by electron impact and radiative ionization and recombination processes, underestimate this population by several orders of magnitude. Therefore, to reconcile the singly ionized He observed, we investigate the recombination of solar He2+ through charge exchange with neutrals from circumsolar dust as a possible formation mechanism of solar He+. We present an empirical profile of neutrals necessary for charge exchange to become an effective vehicle to recombine He2+ to He+ such that it meets observational He+ values. We find that the formation of He+ is not only sensitive to the density of neutrals but also to the inner boundary of the neutral distribution encountered along the solar wind path. However, further observational constraints are necessary to confirm that the interaction between solar α particles and dust neutrals is the primary source of the He+ observations.