Natural Groundwater Research Articles

Modelling hazards impacting the flow regime in the Hranice Karst due to the proposed Skalička Dam

Abstract. This study examines the hydrogeological hazard associated with the construction of the proposed Skalička Dam in the vicinity of the Hranice Karst. Prompted by the catastrophic regional floods in 1997 and 2010, the design of the dam aims to mitigate floods along the Bečva River downstream of the reservoir. However, concerns have been raised regarding the potential disturbance of the natural groundwater regime in the Hranice Karst and the source of mineral waters for the Teplice spa. This is due in particular to the dam's location in an area with limestone outcrops potentially susceptible to surface-water infiltration. Previous studies have also highlighted the strong correlation between the water level in the Bečva River and the water level in karst formations such as the Hranice Abyss, Zbrašov Aragonite Caves, and other caves in the locality. To address these concerns, a nonlinear reservoir-pipe groundwater flow model was employed to simulate the behaviour of the Hranice Karst aquifer and specifically the effects of the dam reservoir's impoundment. The study concluded that the lateral variant of the dam would have a practically negligible impact on the karst water system, with the rise in water level being only a few centimetres. The through-flow variant was found to have a more significant potential impact on water levels and the outflow of mineral water to the spa, with a piezometric rise of about 1 m and an increase in the karst water discharge to the Bečva River of more than 50 %. Based on these results, recommendations for further investigations concerning the design of the dam and its eventual construction have been formulated to reduce geological uncertainties and to minimize the potential impact of the hydraulic scheme on the hydrogeology of the karstic system.

Ecohydrological role of groundwater outflows in the functioning of the ecotone zone in Lake Jaczno, Poland

The research determined the influence of natural groundwater outflows from the spring peat bog on the water supply and its quality in Lake Jaczno. Lake Jaczno is located in the Suwalski Landscape Park (SLP) in the Podlaskie Voivodeship, north-east Poland. The research was conducted from April 2009 to October 2010 and from September 2022 to September 2023. Water samples were collected from spring areas, shallow groundwater, and from Lake Jaczno. Fieldwork involved measuring flow, temperature, water electrolytic conductivity (EC), dissolved oxygen (DO) concentration, water oxygen saturation (WS), and water reaction (pH). Chemical analyses of water samples were carried out in the laboratory. Findings indicate that groundwater, spring water, and lake water in the SLP maintain high quality, with no significant changes in chemical composition over the past decades. Additionally, the physical water parameters display low temporal variability. The EC in the tested waters oscillates around 500 μS∙cm–1. Both spring and lake waters are well oxygenated (97–100%). Biogenic element concentrations exhibit higher variability, influenced by flora development in areas with natural groundwater outflows. High oxygenation of water contributes to increased concentrations of nitrates. The analysed waters exhibited similarity in the concentration and structure of phosphorus forms. Additionally, sediment chemical parameters at Lake Jaczno suggests a buffering capacity in the transitional zones between water and land. Despite similarities in chemical composition, sediment granulometry suggests low permeability, potentially restricting exchange between groundwater and surface waters. Monitoring springs in these environments is important due to their impact on quantity and quality of water in the analysed areas.

Hydrographic and hydrochemical characteristics of selected groundwater outflows in desert and semi-desert areas

The presence of natural groundwater outflows depends on many factors, such as lithology, geological structure, and climate. Areas with particularly poor crenological recognition are arid and semi-arid regions, primarily due to rarity of groundwater outflows in these locations. The article presents the hydrographic and hydrochemical characteristics of selected groundwater outflows in arid and semi-arid areas. In addition to hydrographic mapping, basic physical parameters of water were measured in selected springs, such as temperature (T, °C), electrolytic conductivity (EC, μS∙cm–1), and reaction (pH, –). Laboratory analyses determined the major cations and anions in water: Ca2+, Mg2+, Na+, K+, NH4+, SO42−, Cl−, NO3−, Br−, PO43−,. The analyses were performed using an ion chromatograph Metrohm 850 Professional IC. Twenty-four natural groundwater outflows in South America, Africa, and Asia were selected for research. It was found that the vast majority of outflows are transit sources. Their supply area may be far from discharge points. The supply source is rainwater or meltwater from high mountain massifs. Other types of outflow are springs of alluvial fans and braided rivers. They are fed by waters from glacial rivers, which infiltrate alluvial deposits and flow back to the surface. Hydrochemical analysis has shown that the physicochemical properties of water in dry areas vary significantly. Still in the hydrochemical type, there is a predominance of sulphate, chloride, and sodium ions. This distinguishes the spring waters from these areas in temperate latitudes, which are dominated by bicarbonate and calcium ions.

Methodology for creating a Map of the Vulnerability of the Quantity of Natural Groundwater Resources to Drought for the Czech Republic

Methodology for creating a Map of the Vulnerability of the Quantity of Natural Groundwater Resources to Drought for the Czech Republic

Infiltration of secondary treated wastewater into an oxic aquifer: Hydrochemical insights from a large-scale sand tank experiment

To mitigate groundwater level decline, managed aquifer recharge (MAR) with secondary treated wastewater (STWW) is increasingly considered and implemented. However, the effectiveness and potential risks of such systems need evaluation prior to implementation. In this study, we present a large-scale sand tank experiment to analyse processes related to the infiltration of real STWW through the vadose zone and subsequent mixing with oxic native groundwater. The varying composition of STWW from 15 infiltration cycles over six months of operation and the retention times were the main drivers of the observed processes, which were characterized by a wide range of analytical techniques such as in situ high-resolution oxidation–reduction potential (ORP) measurements, closed mass balances of solutes, characterization of dissolved organic carbon (DOC), stable nitrate isotopes analysis, as well as numerical flow and transport modelling. Depending on the composition and infiltration rates of the STWW, both nitrification and denitrification could be observed, even simultaneously at different locations in the tank. Furthermore, due to the variability of the real STWW we observed enhanced arsenic mobilisation during times of elevated phosphate concentrations of the infiltrating STWW. Additionally, uranium was mobilised in our experimental system via carbonate mineral dissolution caused by the infiltrating STWW which was undersaturated of calcite for all infiltration cycles. Overall, our results showed the importance of conducting studies with waters of complex matrix, such as real STWW, and considering mixing with groundwater to assess the full range of possible processes encountered at MAR field sites.

Radiocarbon dating of the natural groundwater in the Ob-Zaisan folded region (Russia)

Groundwater in the Ob-Zaisan folded region (Russia) has significant differences in the stable isotope composition of oxygen and hydrogen, which cannot be explained by the geographical and relief features of the region. A probable reason for these differences could be climatic changes in the study area over the past tens of thousands of years. The method of the radiocarbon dating can be perfectly suited in order to determine such small geological ages. The dating of waters using 14C data gives an understanding of their residence time. It will make it possible to differentiate periods of recharge and accumulation of water in aquifers and track the changes of the water stable isotope composition over time. The estimated water age ranges from 650 to 19,000 years. The enrichment of δD and δ18O values with the decreasing of the water age indicates a gradual warming of the Novosibirsk region climate. These results logically complement the meteorological observations over the last century and may be useful for paleoclimate reconstructions of the region.

Efficient arsenic removal from water using iron-impregnated low-temperature biochar derived from henequen fibers: performance, mechanism, and LCA analysis

The present study aims to investigate the low-energy consumption and high-efficiency removal of arsenic from aqueous solutions. The designed adsorbent Fe/TBC was synthesized by impregnating iron on torrefaction henequen fibers. Isothermal adsorption experiments indicated maximum adsorption capacities of 7.30 mg/g and 8.98 mg/g for arsenic(V) at 25.0 °C and 40.0 °C, respectively. The interference testing showed that elevated levels of pH, HCO3− concentration, and humic acid content in the solution could inhibit the adsorption of arsenic by Fe/TBC. Characterization of the adsorbent before and after adsorption using FTIR and SEM–EDS techniques confirmed arsenic adsorption mechanisms, including pore filling, electrostatic interaction, surface complexation, and H-bond adhesion. Column experiments were conducted to treat arsenic-spiked water and natural groundwater, with effective treatment volumes of 550 mL and 8792 mL, respectively. Lastly, the life cycle assessment (LCA) using OpenLCA 2.0.3 software was performed to treat 1 m3 of natural groundwater as the functional unit. The results indicated relatively significant environmental impacts during the Fe/TBC synthesis stage. The global warming potential resulting from the entire life cycle process was determined to be 0.8 kg CO2-eq. The results from batch and column experiments, regeneration studies, and LCA analysis indicate that Fe/TBC could be a promising adsorbent for arsenic(V).

Hydrochemical processes and inorganic nitrogen sources of shallow groundwater in the Sanjiang Plain, northeast China.

This study investigates the chemical characteristics, formation, and sources of inorganic nitrogen (IN) of shallow groundwater across the Sanjiang Plain, aiming to enhance drinking water safety management and pollution control. A total of 167 groundwater and 27 surface water samples were collected for constituents and isotopes (H2 and O18). The hydrogeochemical characteristics showed that the major type is HCO3- Ca·Mg, with low total dissolved solids and a neutral to weak alkaline nature. Rock weathering processes govern the hydrochemical composition of groundwater. Hydrogen and oxygen stable isotopes analyses revealed that precipitation serves as the main water source. In alluvial areas, oxidative conditions lead to the enrichment of NO3-N concentrations, with sewage, manure, and fertilizers being the primary IN sources. In lacustrine areas, intensive rice cultivation results in reductive conditions and strong denitrification processes, causing the loss of NO3-N and leaving NH4-N as the dominant IN form. Organic matter mineralization is likely a more significant contributor to NH4-N concentrations than ammonium fertilizers. These findings provide valuable information for further research on natural sources and groundwater pollution in areas with similar hydrogeological conditions. PRACTITIONER POINTS: Rock weathering processes govern the hydrochemical composition of groundwater, and precipitation serves as the main water source. In alluvial areas, oxidative conditions lead to the enrichment of NO3-N. In lacustrine areas, intensive rice cultivation results in reductive conditions and strong denitrification processes. Organic matter mineralization is likely a more significant contributor to NH4-N concentrations than ammonium fertilizers. These findings provide references for water management and information for further research on natural sources and groundwater pollution in areas with similar hydrogeological conditions.

High-efficiency photocatalytic H2-evolution in water/seawater over a novel noble metal free Ni3C/Mn0.5Cd0.5S Schottky junction

Solar-powered seawater production of clean hydrogen fuel is highly prospective. In this work, Ni3C/Mn0.5Cd0.5S (NCMCS) Schottky junctions with excellent visible-light correspondence and photogenerated carrier separation properties are constructed using electrostatic attraction. The material achieves a hydrogen evolution rate of 6472.9 μmol h−1 g−1 in simulated seawater, which is 11 times higher than that of a single Mn0.5Cd0.5S (MCS). More attractively, the composite exhibits excellent hydrogen evolution rates in natural river water, groundwater and tap water, with significantly enhanced practical applicability. The underlying hydrogen evolution mechanism was extrapolated from a combination of experimental and theoretical calculations. The present work provides a low-cost and efficient hydrogen evolution photocatalyst for practical application, which can help promote the efficient conversion of solar-hydrogen energy.

Multi-contamination groundwater risk assessment based on integrated OSPRC framework considering receptor and consequence components

This study evaluates the risks associated with geogenic and anthropogenic contaminants in the Azarshahr aquifer situated in the Lake Urmia watershed in NW Iran, an area critically affected by both natural mineral deposits and intensive agricultural activities. This region, characterized by its significant geological diversity and extensive use of pesticides and fertilizers, presents a unique opportunity to study the interaction between natural and human-induced groundwater contamination. Employing the Origin-Source-Pathway-Receptors-Consequence (OSPRC) framework, the research focuses on the linkage between these contaminants and waterborne diseases, particularly examining the less-studied “Receptor” and “Consequence” components using the Groundwater Quality Index (GQI) and health risk indices. Our approach integrates vulnerability assessments through the DRASTIC and SPECTR methods, enhanced by Sugeno fuzzy logic, to produce a detailed risk map highlighting two critical zones: Risk Cell 1, impacted predominantly by agricultural contaminants including nitrate and chlorpyrifos, and Risk Cell 2, affected by geogenic contaminants such as arsenic, lead, nickel, and chromium. This comprehensive analysis not only maps out the source and migration pathways of these contaminants but also evaluates their impact on human health. The findings underscore a strong correlation between identified risks and health impacts, emphasizing the pressing need for targeted health interventions and improved management of water resources in the region. By advancing the application of the OSPRC framework, this research fills a vital gap in our understanding of aquifer contamination dynamics and sets a new standard for future groundwater risk assessments.

Assessing the Suitability of CCME WQI as a Groundwater Quality Monitoring Tool: An Environmental Ergonomics Case Analysis

This study was conducted with the aim of protecting groundwater, which plays a crucial role in ensuring food quality in the market, preserving public health, and safeguarding the ecosystem, as many regions rely on clean natural groundwater for their population’s survival. The objective of this study was to use the Canadian Council of Ministers of the Environment Water Quality Index (CCME WQI) for groundwater at 12 stations in the Okhla Industrial Area, Nangloi, and Karol Bagh in the Delhi Region. CCME WQI is an effective tool for assessing groundwater quality and communicating water conditions to various users. The research methodology involved fieldwork from June to October 2020 for three different periods in the year: pre-monsoon, monsoon, and post-monsoon, to observe variations in water quality and differences in various physicochemical properties of water. The CCME WQI was applied using sixteen water quality parameters, fourteen of which were physicochemical parameters and two of which were microbiological parameters. Among the physicochemical parameters were color, odor, pH, turbidity, nitrate, total hardness, iron, chloride, fluoride, total dissolved solids, calcium, magnesium, sulfate, and alkalinity, while the microbiological parameters included the total coliform and Escherichia coli counts. Based on the results obtained from the water quality index, station A9 scored between 0 and 44, indicating the lowest water quality index due to wastewater discharges and industrial contamination. The water quality at other stations also requires attention to achieve excellent ratings. The study concludes that serious measures should be taken for proper management of the area to protect the population from hazardous diseases. The research results show that stations 1, 2, and 10 were rated as excellent, station 12 as good, stations 4, 5, and 8 as moderate, stations 3, 6, and 11 as marginal, and station 9 as the poorest in terms of water quality in the year 2020 during the pre-monsoon, monsoon, and post-monsoon periods. To improve the parameters and groundwater quality, it would be necessary to reduce the impact of industry, anthropogenic–geogenic activities, and domestic activities.

The influence of earthworks construction on porewater pressures in clays and mudstones of the Lias Group

Monitoring the changes in porewater pressure associated with the construction of earthworks can yield information on the stiffness and permeability of the ground, as well as how the natural groundwater regime might be impacted. This paper presents 3 years of porewater pressure measurements in weathered Lias Group mudstone, obtained from a trial cutting and a trial embankment constructed for the UK's High Speed Two (HS2) railway. The immediate changes in porewater pressure were small in relation to the changes in total stress imposed. This can be explained by the consolidation or swelling during the period of construction, combined with the sensitivity of very stiff clays and mudstones to a very small (0.5%) reduction in the degree of saturation. In the longer term, porewater pressures reduced across the site owing to the reduction in ground level at the trial cutting. Rates of porewater pressure change were accelerated by more permeable limestone within the ground profile reducing drainage path lengths. It was concluded that construction-induced porewater pressure changes may be smaller, and their rate of dissipation more rapid, in weathered clays and mudstones such as those of the Lias Group than in younger, more compressible clay deposits.

Steady-state semi-analytical solutions for assessing the two-dimensional groundwater hydraulic head depletion induced by river dam removal

Dams are pervasive features of the world’s river systems. The reservoir associated with the dam modifies the distribution of the hydraulic head in the aquifer and the natural groundwater flow. However, such modifications must be defined to forecast their environmental, economic and/or social impacts. Based on the method of fundamental solutions (MFS), steady-state semi-analytical solutions are proposed for evaluating the long-term spatial distribution of the rise or decline of the hydraulic head in an aquifer caused by a dam reservoir on a watercourse or its removal. MFS was chosen because of its ability to account for different boundary conditions along the banks of the watercourse. The dam reservoir can have a triangular or rectilinear geometry. The aquifer is assumed unconfined, homogeneous, inclined and finite. The solutions take into account both the reservoir-aquifer interaction and those between the stream and the aquifer up- and downstream of the reservoir. The reservoir-stream system fully penetrates the aquifer, and is separated from the aquifer by semi-pervious banks (Robin condition). Analysis of the semi-analytical solution included sensitivity tests, and assessment of the influence of several parameters: reservoir leakance parameter, width of the reservoir and width of the aquifer. The results show that the reservoir and river leakage parameters up- and downstream of the reservoir, as well as the geometry of the reservoir dam, are the main determining parameters of the extent of the induced groundwater mound. They show that low aquifer-river exchanges in the river upstream and downstream of the reservoir increases the spatial extension of the mound. The degree of error introduced by the method of linearization used to solve the governing partial differential equation is also discussed. A solution has been also developed with a pumping well, particularly to assess what the depletion of the water level at the well location might be if the dam is removed. The proposed solutions were applied at two field sites, giving satisfactory results.These semi-analytical solutions will be useful applications for assessing the long-term spatial impact on the aquifer of the emplacement, removal or leveling of a reservoir dam.

Hydrologic source identification using stable isotope ratios of bottled drinking water in Egypt

A convenient way to understand hydrologic source identification is to make use of a suitable tracer. Isotopes of oxygen and hydrogen provide that opportunity since the isotope ratios of the primary source, precipitation, can be modified by post precipitation processes. This approach has been tested by carrying out a comprehensive isotope ratios investigation of domestic and imported bottled water sourced and distributed across Egypt. Our collection of bottled water includes 33 samples distributed under 27 distinct brands. We compare the isotope ratios of the bottled water with the isotope ratios of the reported natural water source of this water. The bottled water isotope ratios preserve information about the water sources from which they were derived. The measured oxygen and hydrogen ratios of the studied bottled water samples range from −11.51‰ to 2.94‰, with an average value of −1.89‰ for δ18O and from −81.69‰ to 23.94‰, with an average value of −9.54‰ for δ2H. The observed variability of isotope ratios in the bottled water falls within the span of the natural groundwater resources in Egypt, such as shallow and deep groundwater aquifers as well as claimed non-Egyptian sources. In general, the bottled water samples in the data set can be divided into four distinct groups based on their isotope ratios. One group represents imported bottled water brands, and three groups include domestic brands. The first group represents the imported bottled water brands. Their measured isotopic compositions are similar to those of their claimed sources. The second group has the lowest δ18O and δ2H values and likely originated from the Nubian aquifer. The third and fourth groups appear to have been sourced from the Nile Valley and Delta aquifer. The third group isotopic content and d-excess values indicate a higher degree of mixing with evaporated return flow water. The results provided in this study indicate the diverse hydrogeology of the local bottled water brands. This promises extending the approach to several sites globally.

Model-based zero liquid discharge desalination for land-locked arid/semi-arid regions in India

The arid and semiarid regions usually are water-stressed. The available natural groundwater resources in these areas are, at times, saline and unfit for potable use. Desalination of saline water is a possible solution in such cases. However, discharge of concentrated brine is an issue, particularly in land-locked areas. In this regard, a case study has been presented for brackish water desalination in Western Rajasthan, India. As this is a land-locked desert area, zero liquid discharge (ZLD) desalination has been considered, offering a practical and sustainable solution. This study presents a novel approach to the model-based ZLD hybrid desalination system consisting of reverse osmosis and multi-effect distillation (RO-MED) systems producing drinking quality water and common salt. The simultaneous production of common salt has the potential to bring down the cost of drinking water produced by the system. A system design has been carried out for a real case based on the raw water analysis of groundwater in Western Rajasthan. Our hybrid (RO-MED-ZLD) model results indicate that RO reduced TDS from 4419 mg/l to 22 mg/l with a 67 % recovery rate. The proposed ZLD method recovers 93 % of salt crystals from MED brine solutions, potentially reaching 99 % with adjustments.

Estimating natural groundwater recharge taking into consideration temporal and spatial variability for arid unconfined aquifer

ABSTRACT Water scarcity is one of the major critical affecting arid climate countries. In addition, population growth and climate change are threatening the sustainable development of water resources in the upcoming decades. Therefore, managing groundwater can solve water scarcity such that sustainable development is ensured for future generations. Hence, it is crucial to assess the current quantity of groundwater by analyzing groundwater variables. Thus, natural groundwater recharge could be utilized as an indicator to assess groundwater quantity conditions. This study aims to estimate natural groundwater recharge in an arid unconfined aquifer. El-Qaa plain in Sinai, Egypt was chosen as a case study. Recharge was estimated taking into consideration spatial and temporal variability. To accomplish this, the WetSpass (Water and Energy Transfer between Soil, Plants, and Atmosphere under quasi-Steady State) model was applied. The model was run using morphological, landuse – land cover and climate data from 1986 to 2015 with a monthly time step. To calibrate the model, the isotope signature of δ18O and δ2 H of water was analyzed to determine the natural groundwater recharge of the aquifer. The obtained recharge value was utilized as a reference value for the calibration process. The results were validated using a finite-difference groundwater flow model (MODFLOW). The recharge values were imported to MODFLOW followed via a transient run from 2000 to 2011. The validation was conducted by comparing the simulated groundwater level with the observed ones. After validation process, the inter-annual and seasonal variability of recharge were determined, and a relationship between recharge and other hydrological parameters was deduced. In addition, the recharge distribution was mapped to depict the recharge spatial variability. The results show that the current recharge rate ranges from approximately 8.10 to 16.62 mm/yr, with a mean annual recharge rate of nearly 12.36 mm/yr. The study might be useful for hydrogeologists for determining potential recharge in the study area, groundwater modelers for developing a reliable groundwater flow model, and decision-makers for planning appropriate future sustainable development through water resources management.

Response of two dominant woody species to groundwater depth at the transition zone between desert and oasis

Haloxylon species are traditionally considered as dominant desert plants across Central Asia, but recent studies based on stable isotope showed that they are groundwater-dependent, however, their tolerance strategies and limits to groundwater decline remain unknown. Therefore, we adopted the method of spatial-for-temporal, took Haloxylon ammodendron and Haloxylon. persicum in Gurbantunggut Desert as study objects, combined field survey with model estimation exploring their density, growth, age, and biomass characteristics along a natural groundwater gradient, aiming to reveal their responses to groundwater depth changes and predict future development. The results showed that: (1) With the decline of groundwater depth, the population density, and plant height, canopy width, and basal diameter of two species all decreased significantly. （2）When the groundwater depth descended to lower than 12 m, H. persicum replaced H. ammodendron becoming the more dominant species. (3) As the groundwater depth declined, adult individual percentage increased in the population of H. ammodendron, but H. persicum was still dominated by young trees. (4) The above-ground, below-ground and total biomass of two species were all going down with the lowering of groundwater table, H. ammodendron exhibited a greater reduction, while the root-to-shoot ratio of H. persicum increased significantly (p < 0.05). These findings indicated that continuous decline in groundwater depth greatly limited the survival and development of H. ammodendron, the allocation regulation of H. persicum helped to cushion the adverse effects partially. In the long run, decreased accessibility of groundwater would be not conducive to the exertion of their ecological functions. These findings could provide a scientific basis for the protection and management of these valuable species.

Cationic surfactant-assisted foam fractionation enhances the removal of short-chain perfluoroalkyl substances from impacted water

Several studies have demonstrated that air-bubbling and foam fractionation techniques can efficiently remove long-chain PFAS from contaminated water. However, removing short-chain PFAS is challenging due to its lower surface activity and inability to form self-assembly structures at the air-water interface. In this study, we tested various additives, including salts, surfactants, and polymers, to improve short-chain PFAS (e.g., perfluorobutanesulfonic acid (PFBS) and perfluorobutanoic acid (PFBA)) removal in non-foaming solutions using a bench-scale system. We found that in the presence of cetyltrimethylammonium chloride (CTAC) and salt, air-bubbling can significantly remove 0.5 μg L−1 of PFBS and PFBA in deionized water by >99% (15 min) and 81% (60 min), respectively. The decline of surface tension and the formation of thin foam-like layers during bubbling, controlled by the concentration of CTAC, significantly improved the removal of short-chain PFAS. Adding anionic and neutral surfactants showed no removal of short-chain PFAS during bubbling, suggesting the importance of the electrostatic interactions between short-chain PFAS and the cationic CTAC. We observed a 1:1 M ratio between CTAC and PFBS removed from the solution, suggesting the formation of ion pairs in the solution and enhancing the surface activity of the overall neutral (PFAS-CTAC) complex. A mass balance of the system revealed that the primary mechanism by which PFAS was removed from non-foaming waters was through aerosol generation (70−100%). Using the optimized condition, PFAS mixtures (short- and long-chain PFAS, including five recently regulated PFAS by USPEA, 2 nM each) in deionized water and natural groundwater were successfully removed to below detection (>99% removal; <2 ng L−1), except for PFBA (25−73% removal). These results provide an improved understanding of the mechanism by which PFAS is removed during foam fractionation and highlight the need for capturing aerosols enriched with PFAS to prevent secondary contamination.

Self-enhanced oxidation of resistant monocyclic aromatic compounds during ozone treatment: Applicability in groundwater remediation

The Peroxone process—which utilizes a combination of ozone and hydrogen peroxide to generate hydroxyl radicals—is frequently used in groundwater remediation to effectively remove ozone-resistant contaminants. However, some monocyclic aromatic compounds with low ozone reactivity have been found to be removed by ozone solely (without the need for hydrogen peroxide) through a self-enhanced mechanism. This self-enhanced removal occurs when the interaction of ozone with hydroxide ion generates sufficient amount of hydroxyl radicals, initiating a radical reaction that subsequently propagates through the degradation intermediates. This study leverages the self-enhanced degradation mechanism for the treatment of ozone-resistant compounds during groundwater remediation. Key environmental conditions, including water alkalinity and contaminant concentration, were investigated for their effect on the self-enhanced degradation of para-chloro benzoic acid (pCBA), which served as a model for ozone-resistant compounds. High pCBA removal was observed during ozonation in the concentration range of 0.5–5 μM, where the decay kinetics of pCBA and ozone significantly dependent on the initial pCBA concentration. Furthermore, decreased pCBA removal was noted in water matrices with increased alkalinity, largely due to the scavenging of OH radicals by carbonate species. Finally, pCBA removal was investigated in natural groundwater, where co-existing substances acted as ozone/radical scavengers, leading to reduced pCBA removal. Overall, this study highlights the importance of the self-enhanced removal mechanism of monocyclic aromatic contaminants when treating water with high contamination levels and low-to-moderate alkalinities.

Occurrence and Consequences of Matrix Effects in Simultaneous Multi-class LC-MS/MS Determination of Pesticides, Pharmaceuticals and Perfluoroalkylsubstances in Different Types of Groundwater

Matrix effects are a recent remarkable feature in quantitative LC-MS/MS analysis. In this work, the matrix effects of a multiclass mixture of 46 analytes - pesticides, pharmaceuticals and perfluoroalkylsubstances in different types of natural groundwater were studied. Groundwater samples were spiked with different standards from different chemical groups and determined by direct injection and liquid chromatography coupled to tandem mass spectrometry. Matrix effects were assessed by matrix factors calculated using the slope ratio technique. Groundwater samples were sampled in different boreholes in several places in Slovakia. The relationship with the various detected inorganic parameters was investigated and discussed. Most of the studied analytes showed negative matrix effects. Some analytes showed weak negative or positive matrix effects. The results show that average matrix factors obtained from different sampling sites are not a reliable tool and matrix effects need to be monitored depending on the sampling location. Only weak or no correlation of the matrix factors with the determined inorganic parameters was found. Geochemical composition of boreholes samples was determined and the differences in the macrochemical composition of the samples was evaluated. Model samples of ultrapure water enriched with NaCl, Na2CO3 and NaNO3 at various concentration levels were tested and the matrix effects were not observed. Other content of sample than cations Na+ were responsible for the matrix effects. It was found that the most affected compounds are sulfamethoxazole, sulfadiazine, metamitron, chloridazon and also caffeine. The results show that the detailed study is suitable as a tool for a deeper understanding of matrix effects in different types of groundwater. The proper ground water sample must be selected for reliable results of quantitative analysis.Graphical