Natural Aquifer Research Articles

Variscan Gornjane granitoid as an alternative cold-water reservoir in the ore-baring and mining area of eastern Serbia: Quantitative-qualitative characterization (Carpathian-Balkan belt, Getic unit)

The diminishing high-quality groundwater reservoirs have sparked significant interest in hard-rock aquifers, especially in active mining and raw material exploration areas. This paper aims to forecast the quantity and quality of alternative water resources in the area, thus facilitating the planning and design of the existing water resource systems. The focal point is the groundwater accommodated within basement-type alternative igneous aquifers nestled within an active mining and exploration province belonging to the Carpathian-Balkan fold-and-thrust belt (Banat-Timok Province/Banatitic Belt, sector in eastern Serbia). Despite their lower water-bearing capacity, we underscore the significant hydrogeological potential of natural water igneous-type aquifers, such as the Variscan Gornjane massif.For the first time, this research identifies different reservoirs across the granite massif, providing a fresh perspective on the regional water resource systems. By categorizing reservoirs based on porosity type, flow rates, depth of reservoir rocks (in the depth range of 50 m), and distribution, this study significantly enhances the forecasting of the new water resource system, underlining the importance of this research in the field of water resources and mining. In addition to faulted sections of granite, aquifers are formed in the area characterized by weathered and decomposed granite fragments, often referred to as gruss deposits. The gruss layer has a flow rate reaching up to 0.01 l/s. In terms of the water quality, the groundwaters of the Gornjane granite massif mostly do not contain elements that are above the maximum permitted concentrations for drinking water. However, the occurrence of the elements Fe Mn in some water samples and the presence of Al Pb in one sample, as well as Se, As, Cu, Zn, Ag, Cd, Ga, and Bi, suggest the contact of water with sulfide mineralization detected in granite rocks of Rudna Glava-Tanda-Luka area, raising concerns about potential water quality issues.

Speciation Controls the Kinetics of Iron Hydroxide Precipitation and Transformation at Alkaline pH.

The formation of energetically favorable and metastable mineral phases within the Fe-H2O system controls the long-term mobility of iron complexes in natural aquifers and other environmentally and industrially relevant systems. The fundamental mechanism controlling the formation of these phases has remained enigmatic. We develop a general partial equilibrium model, leveraging recent synchrotron-based data on the time evolution of solid Fe(III) hydroxides along with aqueous complexes. We combine thermodynamic considerations and particle-morphology-dependent kinetic rate equations under full consideration of the aqueous phase in disequilibrium with one or more of the forming minerals. The new model predicts the rate of amorphous 2-line ferrihydrite precipitation, dissolution, and overall transformation to crystalline goethite. It is found that the precipitation of goethite (i) occurs from solution and (ii) is limited by the comparatively slow dissolution of the first forming amorphous phase 2-line ferrihydrite. A generalized transformation mechanism further illustrates that differences in the kinetics of Fe(III) precipitation are controlled by the coordination environment of the predominant Fe(III) hydrolysis product. The framework allows modeling of other iron(bearing) phases across a broad range of aqueous phase compositions.

Transformation of iron-minerals from natural aquifer media by sulfate-reducing bacteria: Behavior, mechanism, and Cr(VI) removal

Sulfate-reducing bacteria (SRB) and iron minerals are widespread in subsurface environments, where their mediated Fe and S transformations are crucial for contaminant immobilization. However, the mechanism mediated by SRB to transform natural iron minerals into reduced iron–sulfur compounds and the contaminant removal capacity of the transformation products remain unclear. Herein, the mechanism of native SRB-mediated transformation of iron-minerals from natural aquifer media into biogenic ferrous sulfide (FeS) was revealed and the Cr(VI) removal performance of the transformation product was evaluated. The results showed that Fe2+ production, sulfate reduction, and sulfide production occurred sequentially (rather than simultaneously) in the liquid phase. This suggests new processes and mechanisms for iron-mineral transformation: first, iron minerals dissolve to produce Fe2+ under enzymatic action rather than sulfide reduction; then, the generated Fe2+ accelerates sulfate reduction by SRB, producing sulfide in large amounts; finally, sulfide combines rapidly with Fe2+ to produce FeS. Elevated temperatures markedly shortened the required transformation time to start: maximum Fe production occurred at 18–24 days, 6–12 days, and 0–6 days at 10 °C, 20 °C, and 35 °C, respectively. Ambient temperature strongly affected SRB community composition, with Desulfosporosinus dominant at 10 °C and 20 °C and Desulfotomaculales prevalent at 35 °C. Sequential extraction, scanning electron microscopy, X-ray photoelectron spectroscopy, and X-ray diffraction analyses confirmed FeS as the main transformation product, which exhibited a highly efficient Cr(VI) removal capacity. Extending transformation time or increasing transformation temperature enhanced the Cr(VI) removal capacity of the transformation product. In column experiments, in-situ stimulation of SRB growth in aquifer media is able to form FeS, the Cr(VI) removal capacity of FeS reached up to 90.1 mg(Cr(VI))/kg(media). These findings suggest that biostimulation of SRB to mediate the in-situ transformation of iron-minerals to FeS has great potential for remediation of contaminated groundwater.

Molecular characteristics of dissolved organic matter regulate the binding and migration of tungsten in porous media

Tungsten (W) is an emerging contaminant that poses potential risks to both the environment and human health. While dissolved organic matter (DOM) can significantly influence the W's environmental behavior in natural aquifers, the mechanisms by which DOM's molecular structure and functional group diversity impact W binding and migration remain unclear. Using molecular weight-fractionated soil and sediment DOM (<1 kDa, 1–100 kDa, and 100 kDa–0.45 μm), this study systematically investigated the relationship between DOM molecular characteristics and tungstate (WO42−) binding properties using multiple spectroscopic methods, including FTIR, fluorescence spectroscopy and XPS. The migration behavior of WO42− in porous media was also investigated through quartz sand column experiments. Results revealed that approximately 75 % of W was controlled by DOM, with over 50 % binding to low molecular weight DOM (<1 kDa). Tungsten bound to medium-high molecular weight DOM (1–100 kDa, >100 kDa) showed a greater propensity for retention, with the >100 kDa fractions demonstrating stronger selective binding to W, exhibiting distribution coefficients (Kmd) of 6.11 L/g and 10.69 L/g, respectively. Further analysis indicated that W primarily binds with aromatic rings, phenolic hydroxyls, polysaccharides, and carboxyl groups in DOM, potentially affecting DOM structural stability and consequently influencing W migration characteristics. Free W migration in quartz sand was primarily controlled by Langmuir monolayer adsorption, leading to local enrichment (Da = 6.83, Rd = 86.98). When bound to DOM, W's migration ability significantly increased (Rd = 8–10), with adsorption shifting to a Freundlich multilayer model, primarily controlled by convective transport (Npe = 27–62> > 1.96), while adsorption effects weakened (Da ≈ 1). This study, for the first time, systematically reveals the regulatory mechanisms of DOM molecular characteristics on tungsten's environmental behavior. It offers crucial parameter support for constructing tungsten migration models and provides important guidance for tungsten pollution risk assessment and remediation strategies.

Density-driven free convection in heterogeneous aquifers with connectivity features

Free convection usually happens in variable-density groundwater flow systems, and it favors contaminant transport by enlarging length scales and shortening timescales compared to advection and diffusion/dispersion alone. Previous studies have demonstrated that heterogeneity with multi-variate Gaussian distribution for logarithmic permeabilities (log10k) plays an important role in the onset, growth, and/or decay of instability during the density-driven convective process. Nevertheless, the connectivity features (i.e., connected structures of extremely high/low-k values), which are common in natural aquifers, have received little attention. In this study, the classical problem of transient free convection has been modified and numerically simulated by Monte Carlo approach to investigate the effects of connectivity features in heterogeneity on the unstable convective processes. Results show that free convection is promoted by the connected high-k structures and retarded by the connected low-k structures during mainly the early-stage mass loading. The impacts of connectivity features tend to be amplified by higher variation in log10k distributions, and can be secondarily influenced by correlation lengths and anisotropy. Under the multi-variate Gaussian assumption, the existence of connected high-k structures leads to underestimation of density-driven instability, in which the risk differs based on the statistics of permeability fields, metrics of interest and timeframe. This study highlights the importance of understanding connectivity features in heterogeneous geological media when assessing density-dependent solute transport in groundwater systems.

Assessment of Potential Aquifer Recharge Zones in the Locumba Basin, Arid Region of the Atacama Desert Using Integration of Two MCDM Methods: Fuzzy AHP and TOPSIS

Natural aquifers used for human consumption are among the most important resources in the world. The Locumba basin faces significant challenges due to its limited water availability for the local population. In this way, the search for possible aquifer recharge zones is crucial work for urban development in areas that have water scarcity. To evaluate this problem, this research proposes the use of the hybrid Fuzzy AHP methodology in conjunction with the TOPSIS algorithm to obtain a potential aquifer recharge map. Ten factors that influence productivity and capacity in an aquifer were implemented, which were subjected to Fuzzy AHP to obtain their weighting. Using the TOPSIS algorithm, the delineation of the most favorable areas with high recharge potential was established. The result shows that the most influential factors for recharge are precipitation, permeability, and slopes, which obtained the highest weights of 0.22, 0.19, and 0.17, respectively. In parallel, the TOPSIS result highlights the potential recharge zones distributed in the Locumba basin, which were classified into five categories: very high (13%), high (28%), moderate (15%), low (28%), and very low (16%). The adapted methodology in this research seeks to be the first step toward effective water resource management in the study area.

OH radical initiated oxidative degradation of imidacloprid in the environment: An assessment of breakdown kinetics and environmental hazards

Imidacloprid (IMI) is a common neonicotinoid pesticide that acts via a similar mechanism of action to nicotine, a naturally occurring insecticide. It is therefore important to understand its chemical fate in the environment. Hydroxyl radicals (HO) are significant oxidizing species in natural aquifers due to their strong reactivity towards organic substrates. Therefore, principal photo-oxidation products are expected to form with the involvement of HO in the self-cleaning process of water in nature. Here quantum chemical calculations are used to examine the reaction of IMI with HO in the atmosphere and aqueous environments. It was found that the principal mechanism of the HO + IMI reaction is the hydrogen transfer that, in a two-step process, produces stable cations in the gas phase. Within the atmospheric temperature range of 253–323 K, the overall rate constants for the HO + IMI reaction decreased from 4.35 × 1010 to 2.13 × 1010 M−1 s−1. Consequently, IMI can undergo rapid gaseous degradation within a comparatively brief period of 2.81 × 10−4 – 5.75 × 10−4 years. However, differences in environmental temperature and pH in aqueous environments influence the processes, rate constants, and products of IMI breakdown by the HO radical. The data indicate that IMI breakdown by OH radicals is strongly temperature and pH-dependent, resulting in the generation of different reaction products. The results imply that at all pH levels, the interaction between IMI and the ambient HO radical in water produces toxic chemical species. According to the computed data, it appears that IMI and the vast majority of degradation products present potentially carcinogenic and/or mutagenic hazards, and they also lack downstream biodegradability.

Integrated experiments and numerical simulations for chromium (VI) surface complexation in natural unconsolidated sediments

This study focuses on the adsorption and transport of Cr (VI) on natural sediments from Qiqihar, China. Through batch and column experiments, we assessed the adsorption capacities influenced by factors such as contact time, initial concentration, pH, ionic strength, solid-to-solution ratio, coexisting ions in groundwater, sediment characteristics and flow rate. The adsorption kinetics of Cr (VI) follow the pseudo-first-order model well, while the isotherms of all three sediments are accurately represented by the Freundlich model. The adsorption edges reveal a strong pH dependence in Cr (VI) adsorption: the stronger the acidity, the more favorable it is for adsorption. The adsorption capacity decreases with an increasing solid-to-solution ratio, stabilizing at higher ratios. Coexisting ions in groundwater reduce Cr (VI) adsorption in loam under neutral pH. Additionally, Fourier transform infrared spectroscopy (FTIR) results indicate that the hydroxyl group is the primary reactive functional group in all three sediments. X-ray photoelectron spectroscopy (XPS) results further show partial adsorbed Cr (VI) was reduced to Cr (III) by organic matters. However, surface complexation reactions dominate the removal of Cr (VI). On the base above, we introduced a surface complexation model, optimizing equilibrium complexation constants by fitting adsorption edges. Subsequently, reactive transport models incorporating both surface complexation and reduction processes for Cr (VI) were established to simulate column experiments. As the flow rate decreases, the adsorption capacity and the amount of reduction reaction for Cr (VI) increase, while the reduction rate decreases. Specifically, the reduction for Cr (VI) was found to be more significant in loam compared to sand, correlating with the organic matter content. The results emphasize the existence of surface complexation reactions and the role of organic matters in electron transfer. Our study provides significant information for understanding Cr (VI) adsorption and transport behavior in natural aquifer sediments.

Behavior of uranium(VI) in the presence of a geomaterial: an aquifer sediment

Sediments from aquatic environments can be contaminated with uranium from natural and anthropogenic sources; the behavior of U(VI) was investigated in two natural (SPT and DS) and gamma-irradiated (SPT-I) aquifer sediments in batch systems. Sediments were characterized, and quartz, albite, and kaolinite were mainly found in both sediments by X-ray diffraction. The points of zero charge were 5.4, 5.3, and 5.5, and the organic matter percentages were 48.0, 46.0, and 4.7% for SPT, SPT-I, and DS, respectively. Uranyl nitrate solutions were put in contact with each sediment considering different parameters (pH, contact time, initial concentration of uranium, and temperature). DS sediment did not adsorb any quantity of uranium at different pH values; SPT and SPT-I, attained the highest q e values at pH 3.5–4. The results show chemisorption on homogenous materials and endothermic processes. Desorption behavior of U(VI)/SPT showed a hundred percent desorption with nitric acid and humic acid solutions; in the last case, it is due to the high stability constant of the complex of uranium with the humic acids. The results help to understand the contamination and decontamination processes of sediments with uranium, the bioavailability of uranium, the ecological risk of U-contaminated sediments, and remediation. Doses of 1 MGy of Co-60 gamma radiation did not affect the uranyl ions behavior in the aquifer sediment.

Process-Based and Probabilistic Quantification of Co and Ni Mobilization Risks Induced by Managed Aquifer Recharge.

Managed aquifer recharge (MAR) is an increasingly used water management technique that enhances water availability while commonly generating water quality benefits. However, MAR activities may also trigger adverse geochemical reactions, especially during the injection of oxidant-enriched waters into reducing aquifers. Where this occurs, the environmental risks and the viability of mitigating them must be well understood. Here, we develop a rigorous approach for assessing and managing the risks from MAR-induced metal mobilization. First, we develop a process-based reactive transport model to identify and quantify the main hydrogeochemical drivers that control the release of metals and their mobility. We then apply a probabilistic framework to interrogate the inherent uncertainty associated with adjustable model parameters and consider this uncertainty (i) in long-term predictions of groundwater quality changes and (ii) in scenarios that investigate the effectiveness of modifications in the water treatment process to mitigate metal release and mobility. The results suggested that Co, Ni, Zn, and Mn were comobilized during pyrite oxidation and that metal mobility was controlled (i) by the sediment pH buffering capacity and (ii) by the sorption capacity of the native aquifer sediments. Both tested mitigation strategies were shown to be effective at reducing the risk of elevated metal concentrations.

Activation of iron oxide minerals in an aquifer by humic acid to promote adsorption of organic molecules

In aquifers, the sequestration and transformation of organic carbon are closely associated with soil iron oxides and can facilitate the release of iron ions from iron oxide minerals. There is a strong interaction between dissolved organic matter (DOM) and iron oxide minerals in aquifers, but the extent to which iron is activated by DOM exposure to active iron minerals in natural aquifers, the microscopic distribution of minerals on the surface, and the mechanisms involved in DOM molecular transformation are currently unclear. This study investigated the nonbiological reduction transformation and coupled adsorption of iron oxide minerals in aquifers containing DOM from both macro- and micro perspectives. The results of macroscopic dynamics experiments indicate that DOM can mediate soluble iron release during the reduction of iron oxide minerals, that pH strongly affects DOM removal, and that DOM is more efficiently degraded at low rather than high pH values, suggesting that a low pH is conducive to DOM adsorption and oxidation. Spherical aberration-corrected scanning transmission electron microscopy (SACTS) indicates that the reacted mineral surfaces are covered with large amounts of carbon and that dynamic agglomeration of iron, carbon, and oxygen occurs. At the nanoscale, three forms of DOM are found in the mineral surface agglomerates (on the surfaces, inside the surface agglomerates, and in the polymer pores). The microscopic organic carbon and iron mineral reaction patterns can form through oxidation reactions and selective adsorption effects. Fourier transform ion cyclotron resonance mass spectra indicate that both synergistic and antagonistic reactions occur between DOM and the minerals, that the release of iron is accompanied by DOM decomposition and humification, that large oxygen- and carbon-containing molecules are broken down into smaller oxygen- and carbon-containing compounds and that more molecules are produced through oxidation under acidic rather than alkaline conditions. These molecules provide adsorption sites for sediment, meaning that more iron can be released. Microscopic evidence for the release of iron was acquired. These results improve the understanding of the geochemical processes affecting iron in groundwater, the nonbiological transformation mechanisms that occur at the interfaces between natural iron minerals and organic matter, groundwater pollution control, and the environmental behavior of pollutants.

Quantitative Groundwater Modelling under Data Scarcity: The Example of the Wadi El Bey Coastal Aquifer (Tunisia)

The Grombalia aquifer constitutes a complex aquifer system formed by shallow, unconfined, semi-deep, and deep aquifers at different exploitation levels. In this study, we focused on the upper aquifer, the Wadi El Bey coastal aquifer. To assess natural aquifer recharge, we used a novel physiography-based method that uses soil texture-dependent potential infiltration coefficients and monthly rainfall data. The developed transient flow model was then applied to compute the temporal variation in the groundwater level in 34 observation wells from 1973 to 2020, taking into account the time series of spatially variable groundwater recharge, artificial groundwater recharge from 5 surface infiltration basins, pumping rates on 740 wells, and internal prescribed head cells to mimic water exchange between the wadis and aquifer. The quantified deviations in the computed hydraulic heads from measured water levels are acceptable because the database used to construct a scientifically sound and reliable groundwater model was limited. Further work is required to collect field data to quantitatively assess the local inflow and outflow rates between surface water and groundwater. The simulation of 12 climate scenarios highlighted a bi-structured north‒south behaviour in the hydraulic heads: an increase in the north and a depletion in the south. A further increase in the pumping rate would, thus, be severe for the southern part of the Wadi El Bey aquifer.

Groundwater Hydraulics in Increased Spring Discharge following Earthquakes: Some Applications and Considerations

Earthquakes often entail alterations in the groundwater flow regime, in the phreatic level, surges and losses of springs, and the discharge in brooks. A variety of theoretical approaches attempt to elucidate the post-earthquake effects on spring discharge. This study adopts a conceptual approach, primarily presenting diverse methods to estimate water released by earthquakes involving calculations of discharge surpluses in springs. This study delves into refined techniques rooted in groundwater hydraulics, displaying applications of analytical and simulation methodologies to quantify earthquake-induced groundwater discharge in springs. This research investigates springs as natural indicators and applies mathematical precipitation–runoff models, particularly the CREC model, to simulate hydrographs in post-earthquake scenarios. We apply analytical procedures or mathematical simulation techniques employed in groundwater hydraulics for natural aquifer recharge calculations. Firstly, we briefly describe the methods based on the analysis of depletion curves of hydrographs in spring discharge. Additionally, specific mathematical rainfall–runoff models used to simulate hydrographs of karstic springs, along with derived analytical approximations, are adapted for this scenario. These hydraulic calculations involve the depletion coefficient and hydrodynamic volumes of aquifers, parameters that reveal certain aspects of the relation between groundwater and earthquakes. Three main features are: (a) Acknowledging faults as the primary geological structures in transmitting pore pressures due to earthquakes. Thus, for large and deep faults, which connect the ground surface with the Earth’s crust bottom—where earthquakes trigger—the depletion coefficient, α, usually reaches high values (α = 0.1 days−1). Therefore, these faults become more sensitive to pore pressure than other lithologies. (b) Elucidating the mechanisms of permeability enhancement caused by earthquakes. (c) Highlighting the substantial volumes in motion within the Earth’s interior, which, for instance, could constitute a significant source for the origin of mineral deposits. Mathematical calculations enable the determination of the volume of mobilized water that can be discharged by gravity in each earthquake. This, along with its recurrence, justifies the substantial mineralization volumes.

Harnessing Natural Aquifer Filtration for Large-Scale Water Purification: Opportunities and Challenges

The research investigates the potential benefits of utilizing natural aquifer systems as a means of water treatment on an extensive basis. The present study analyzes the mechanisms via which naturally aquifers properly filter water, examining the possibilities to be practical financially effective ways for dealing with the growing demand for safe water. The paper highlights the potential advantages associated with natural aquifers filtration, such as its small environmental impact and its ability to sustain water quality. At the same time, it recognizes the challenges that have to be overcome, including the risk of pollution, the complex nature of laws and regulations, and the necessity of successfully controlling aquifer recharge. This study incorporates many geological, hydrological, and ecological engineering perspectives in order to offer an in-depth study of natural aquifer filter systems. This study aims to examine case studies and present practices in order to provide an in-depth strategy for effective use of these systems in various global environments. It also takes into consideration the significant potential of these mechanisms as well as the obstacles that need to be solved.

Assessing rainwater quality in Ca Mau Province: Unveiling the potential and viability for domestic usage

The potential for exploiting rainwater in Ca Mau Province is immense due to its average annual rainfall of 1772 to 2500mm. Over a 15-year continuous monitoring period, the analysis of rainwater quality in Ca Mau Province reveals a prevailing alkaline tendency, with an average pH of 5.90, well within the established raw water quality standards. Concurrently, ongoing groundwater exploitation activities pose a significant threat to the natural aquifer reserves in the region. Recognizing this challenge, rainwater harvesting emerges as a pivotal strategy to alleviate the strain on groundwater extraction. The accumulation of freshwater during the rainy season in Ca Mau, facilitated by household rainwater storage tanks, offers a sustainable solution, ensuring a readily available supply for drinking and cooking needs during the dry season when rainfall is scarce. In addition, average tank capacity to meet the domestic water demand of a 5-member household is 10m3 for the whole year while this number increases to 18 20m3 during the dry years. These rainwater stored in tanks should be treated with chlorine or UV rays before use. Our study provides valuable evidence for policy makers and managers, based on the case study at Ca Mau, to develop a sustainable rainwater management plan for improving the livelihoods of millions people lacking freshwater in coastal zones of the Vietnamese Mekong Delta.

On the applicability of carbon steels K55 and L80 for underground hydrogen storage

To evaluate the possibility of hydrogen storage in depleted gas reservoirs, natural gas storage facilities, aquifers and salt caverns, the applicability of ferritic pearlitic K55 and tempered martensitic L80, both very frequently used as casings and tubings, has been investigated. Materials were investigated by means of high-pressure, high-temperature autoclave tests and analyses of the hydrogen uptake. The autoclave tests were performed on tensile specimens loaded with a spring at 90 % of the specified minimum yield strength, additionally the samples were analysed to determine the hydrogen uptake. Different gas compositions were considered (pure hydrogen, with or without the presence of CO2/H2S) under a hydrogen partial pressure of 120 bar. The tests were conducted in dry or wet environments. From the results, it can be seen that the hydrogen uptake is low even under the most severe conditions. However, from the mechanical test conducted in this study, it appears that the ferritic pearlitic K55 steel seems to be a suitable pipe material for underground hydrogen storage, and the higher strength steel L80 steel can be used only in non-sour environments (no significant amount of H2S in the reservoir, which is a priori the case of underground storages).

A decade drought monitoring through enhanced and standardized vegetation index in isolated karst environment: Nusa Penida Island, Bali, Indonesia

Nusa Penida is one of the regions in Indonesia that vunarablely experiences extreme drought. The worst drought occurred in December 2019, coinciding with the Covid-19 pandemic outbreak. At that time, drought caused major crises in many local primary economic aspects, such as clean-water crises and local crop failure. The situation worsened after the global pandemic lockdown was imposed. Many tourism-related hospitalities (i.e., hotels, resorts, and restaurants) also have crashed. Isolated karst islands such as Nusa Penida Island pose significant challenges for water and agricultural land management. Geologically, this area consists of hilly carbonate rock terrain, a lack of proper aquifers, low precipitation, and tend to had high concentrations of dissolved Ca and Mg in its water. These conditions make many areas less preferable for settlements and traditional agriculture. In this study, we assessed the area using geospatial data for drought monitoring. We analyzed weekly-22 years of data (18/02/2000-18/02/2022 or 507 weeks data) to understand the period pattern of seasonal droughts in Nusa Penida over the past decade. This study used compiled satellite raster-images data to compute the Enhanced Vegetation Index (EVI) to express the Standardized Vegetation Index (SVI), which is sensitive to vegetation change during drought. The results showed that the longest droughts in Nusa Penida occurred from December 2000 to October 2001 (20 weeks) and Feb 2002 to Jan 2023 (21 weeks). The worst droughts occurred in December 2019 (SVI: -1.903 to -1.236), 2006 (SVI: -1.872 to -1.374), and 2002 (SVI: up to -0.136). There are patterns in which droughts in Nusa Penida tend to occur towards the end of the year, including at the end of 2022. Additionally, we detected some evergreen areas in Nusa Penida that require further investigation. These areas potentially act as natural permanent aquifers even during droughts. Furthermore, this study provides more insights for other comprehensive research, especially to enhance mitigation policies for near-future drought periods in Nusa Penida.

Soil Conservation Service-Curve Number method-based historical analysis of long-term (1936-2016) temporal evolution of city-scale potential natural groundwater recharge from precipitation: case study Algiers (Algeria).

Managing groundwater resources in urban areas requires an adequate understanding and assessment of urban hydrogeological systems (structure, components, connections, and imposed conditions) as a part of a larger, dynamically evolving environment. Urbanization and climate change are amongst the widely recognized signs of such a continuous evolution. Within this context, the present study gives a quantitative assessment of the impact of these two factors threatening water resources in urban environments. The Soil Conservation Service-Curve Number (SCS-CN) method is used to conduct a long-term quantitative analysis of the temporal evolution of the potential natural groundwater recharge from precipitation at the scale of Algiers city for an 80-year-long period (1936-2016). The length of the study period allowed us to account for and analyze important changes in urban settings and climatic conditions within the study zone. Overall, two trend shifts over three distinct periods were found to characterize the temporal evolution of precipitation, several climate change indicators defined for the study, and the potential natural aquifer recharge. A strong, approximately 1:4, linear correlation between the estimated city-scale potential natural aquifer recharge and precipitation was observed for the studied period (R2 = 0.748). Moreover, even though the urban area has known a rapid (2nd order polynomial) increase from 1936 to 2016, climate change (accounted for via the changes in precipitation regime) impacted the city-scale potential natural groundwater recharge with higher magnitudes than urbanization. Finally, the computed climate change indicators show that starting in the mid-1980s, Algiers has started receiving less precipitations, with fewer heavy rain events and longer dry condition periods.

Optimizing the operational efficiency of the underground hydrogen storage scheme in a deep North Sea aquifer through compositional simulations

In this study, we evaluate the technical viability of storing hydrogen in a deep UKCS aquifer formation through a series of numerical simulations utilising the compositional simulator CMG-GEM. Effects of various operational parameters such as injection and production rates, number and length of storage cycles, and shut-in periods on the performance of the underground hydrogen storage (UHS) process are investigated in this study.Results indicate that higher H2 operational rates degrade both the aquifer's working capacity and H2 recovery during the withdrawal phase. This can be attributed to the dominant viscous forces at higher rates which lead to H2 viscous fingering and gas gravity override of the native aquifer water resulting in an unstable displacement of water by the H2 gas. Furthermore, analysis of simulation results shows that longer and less frequent storage cycles lead to higher storage capacity and decreased H2 retrieval. We conclude that UHS in the studied aquifer is technically feasible, however, a thorough evaluation of the operational parameters is necessary to optimise both storage capacity and H2 recovery efficiency.

QMRA of Ralstonia solanacearum in potato cultivation: Risks associated with irrigation water recycled through managed aquifer recharge

Agricultural aquifer storage recovery and transfer (ASTR) stores excess fresh water for later reuse in irrigation. Moreover, water quality improves because chemical pollutants and pathogens will be removed by degradation and attachment to the aquifer material. The source water may contain the bacterial plant pathogen Ralstonia solanacearum which causes plant infections and high yield losses. We used quantitative microbial risk assessment (QMRA) to investigate the removal of R. solanacearum during ASTR to predict infection risks of potato plants after irrigation with the recovered water. Laboratory experiments analyzed the ASTR treatment by investigating the bacterial die-off in the water phase and the removal by attachment to the aquifer sediment. Die-off in the water phase depends on the residence time and ranged between 1.3 and 2.7 log10 after 10 or 60 days water storage, respectively. A subpopulation of the bacteria persisted for a prolonged time at low concentrations which may pose a risk if the water is recovered too early. However, the natural aquifer sand filtration proofed to be highly effective in removing R. solanacearum by attachment which depends on the distance between injection and abstraction well. The high removal by attachment alone (18 log10 after 1 m) would reduce bacterial concentrations to negligible numbers. Upscaling to longer soil passages is discussed in the paper. Infection risks of potato plants were calculated using a dose-response model and ASTR treatment resulted in negligible infection risks of a single plant, but also when simulating the irrigation of a 5 ha potato field. This is the first QMRA that analyzed an agricultural ASTR and the fate of a plant pathogen focusing on plant health. QMRA is a useful (water) management tool to evaluate the treatment steps of water reclamation technologies with the aim to provide safe irrigation water and reduce risks disseminating plant diseases.