Nano Glass Research Articles

Radiation and mechanical performance of cementitious materials containing ecofriendly nano laboratory waste glass

This study helps in managing waste glass and greening the environment by incorporating laboratory waste glass into mortar production to make an eco-friendly shielding material against gamma rays. The efficiency of using waste glass powder as a cement replacement or addition in mortar production was studied by using two waste glass sizes: micro glass (particle size range from 10.09 to 24.73 μm) and nano glass (particle size range from 10.57 to 26.42 nm) to design different mortar specimens with varying percentages of fine glass powder from 0 to 30%. Compressive strength and flexure strength were evaluated to determine mechanical properties. The results indicated that adding WGP to mortar positively affects the characteristics of cementitious composites. The linear and mass attenuation coefficients of the samples were experimentally determined using a NaI detector and various radioactive sources (Am-241, Ba-133, Eu-152, Cs-137, and Co-60) with gamma energies ranging from 59.53 to 1332 keV. The obtained coefficients were then compared to the theoretical values of the composites using XCOM software to verify their accuracy. Additionally, the half-value layer, tenth-value layer, mean free path, and effective atomic number were computed. Furthermore, the results revealed that the mortar sample with 30% nano additive glass was the most effective in reducing gamma radiation.

Evaluation of microhardness, degree of conversion, and abrasion resistance of nanoglass and multiwalled carbon nanotubes reinforced three-dimensionally printed denture base resins.

To assess the effect of nanoglass (NG) particles and multiwalled carbon nanotubes' (MWCNTs) addition on Vickers hardness (VH), degree of conversion (DC), and abrasion resistance of 3D-printed denture base resin. 3D-printed denture base resin was reinforced using silanized NG and MWCNTs to obtain four groups: Control, 0.25 wt% NG reinforced resin, 0.25 wt% MWCNTs reinforced resin, and a combination group of 0.25 wt% of both fillers. All specimens (N = 176) were tested before and after thermal aging (600 cycles) for VH (n = 22), DC, and abrasion resistance (n = 22). Abrasion resistance specimens were subjected to 60,000 brushing strokes, and then assessed for surface roughness (Ra) and weight loss. Specimens were then scanned with a benchtop scanner before and after abrasion to produce a color map of topographical changes from superimposed images. Data were analyzed using ANOVA tests followed by Tukey post hoc test. Kruskal-Wallis test was used to compare percent change among groups, followed by Dunn post hoc test (α = 0.05). The interaction between nanofiller content and thermal cycling displayed a significant effect on VH and DC. The 0.25% NG expressed the highest VH before aging but revealed the highest percent decrease after aging. Nanofiller content, thermal aging, and brushing displayed a significant interaction impact on the Ra values. The addition of nanofillers resulted in an overall improvement in resin microhardness and abrasion resistance. The 0.25% MWCNTs group revealed the lowest Ra with the least percent change in VH and DC, while the combination one displayed the least change in weight.

Impact of Bi2O3 on prepared nano (SiO2-Na2O-CaO-B2O3) glass as radiation shielding material

Melt quenching technique was used to create Bismuth Boro-Silicate nano glasses with compositions of 45SiO2-10CaO- 25Na2O- xBi2O3- (20-x) B2O3 (where x is 0, 5, 10, 15, and 20 mol %). Standard point sources AM-241, Ba-133, Co-60, Cs-137, and Eu-152 were used in the radiation experiment to evaluate the attenuation coefficients spanning the energy range of 59.51 keV to 1048.01 keV. The findings show that adding Bi2O3 in place of B2O3 increases the following: radiation protection efficiency (RPE%), transmission factor (TF%), absorption buildup factor values (ABF), exposure buildup factor values (EBF), mass attenuation coefficients (MACs), linear attenuation coefficients (LACs), and radiation protection efficiency (RPE%). In comparison to lead glass, these findings demonstrate the potential of nano Bismuth Boro-Silicate glass as a radiation shielding material.

Biaxial flexural strength of nanoglass and multiwalled carbon nanotubes reinforced 3D-printed denture base resins and their shear bond strength to 3D-printed and acrylic denture teeth

ObjectiveEvaluation of biaxial flexural strength (BFS) of nanoglass (NG) and multiwalled carbon nanotubes (MWCNTs) reinforced 3D-printed denture base resins and their shear bond strength (SBS) to 3D-printed and acrylic denture teeth. MethodsSilanized NG and MWCNTs were added to 3D-printed denture base resin to obtain four groups: Control, 0.25 wt% NG, 0.25 wt% MWCNTs, and a combination group with 0.25 wt% of both fillers. All specimens were tested before and after 600 cycles of thermal aging. BFS (n = 88) was tested using disk-shaped specimens (12 ×2 mm) centralized on an O ring in a universal testing machine. Weibull analysis was conducted to assess predictability of failure. SBS (n = 176) was tested for acrylic and 3D-printed denture teeth attached to bar-shaped specimens in a universal testing machine followed by failure mode analysis using stereomicroscope. Two and three-way ANOVA tests followed by Tukey post hoc test were conducted for BFS and SBS. Kruskal-Wallis test compared percent change among groups with subsequent Dunn post hoc test with Bonferroni correction (α = 0.05). ResultsBFS was affected significantly by filler content (P < 0.001) and thermal cycling (P < 0.001), with thermal cycling displaying the uppermost effect (Ƞp2 =0.551). A significant interaction between filler content, thermal cycling, and teeth type was displayed by SBS results (P < 0.001, F=10.340, Ƞp2 =0.162). The highest BFS values belonged to 0.25 % MWCNTs while the highest SBS to printed teeth was displayed by the combination. SignificanceThe combination group displayed higher BFS and SBS to printed teeth compared to control which allows 3D-printed materials to have a long-term clinical success.

Effect of nanoglass grain size investigated by a mesoscale variable characteristic strain model

Severe shear localization in metallic glasses (MGs) significantly limits their mechanical performance. Nanoglass (NG), composed of heterogeneous glassy domains created by introducing interfaces into MGs at the nanoscale, could be a promising strategy against severe shear localization, as demonstrated by numerous atomistic simulations. This study introduces a novel mesoscale kinetic Monte Carlo (kMC) model with a variable characteristic strain (VCS) to investigate the grain size effect in NGs. This model captures the complex evolution of shear bands during deformation, revealing a surprising transition from inhomogeneous to homogeneous deformation as the NG grain size decreases to approximately 10 nm. This transition is attributed to the impediment of shear band formation by the small grain size, facilitated by softer interfaces guiding early shear transformation zone (STZ) activities across the entire sample. Furthermore, a progressive reduction of elastic constants simulates the failure response observed in experiments. Our model predicts a critical grain size for the transition in agreement with molecular dynamics simulations and experiments, highlighting its potential for designing NGs with enhanced shear resistance. This mesoscale model enables the investigation of NG deformation with microstructural features on an experimentally-relevant spatial-temporal scale. This paves the way for tailoring NG microstructures to achieve enhanced mechanical performance, and opens new avenues for exploring the influence of interfaces in controlling shear localization.

Enhancement of the Properties of Nano Glass Fibre Composites – A Review of Some Significant Trends

The article provides some significant insights on the properties of nano glass fibre composites. Fiber reinforced polymer (FRP) composites plays an important role in many industries; because weight to strength ratio is extremely high when compared to monolithic metals.

Preparation and Characterization of Nano Glass–ceramics from CeO2-doped Li2O-SiO2 System for Dental Applications

Glasses based on the basic composition of lithium disilicate (Li2O.2SiO2) together with derived samples containing increasing CeO2 replacing Li2O (0.1, 0.2, 0.5, 1 Mol %) were prepared by melting – annealing method, samples from the prepared parent glasses were thermally heat treated through two-step regime (450° C /10 h – followed by 650° C / 6 h) to convert them to their glass – ceramics derivatives. The main purpose of this study is to find out the main properties of the prepared glass – ceramics to be applied as dental candidates. The optical, FTIR, and thermal expansion properties of the parent glasses were examined to identify the main structural groups which are defined as tetrahedral stronger SiO2 building groups. The detailed separated crystalline phases within the prepared glass–ceramics were identified together with their textural features. The Vickers microhardness data for both the parent glasses and their glass -ceramics derivatives were evaluated. SEM and EDAX measurements indicate the ability of the prepared samples to form hydroxyapatite upon immersion in SBF solution.

Crystallization behavior and Photoluminescence of cerium doped ZAS glasses and nano glass ceramics with different Li2O content and without added nucleating agents

In this research, ZnO-Al2O3-SiO2 glass-ceramics were prepared with various contents of Li2O (1–5 mol.%). No nucleating agent was used. The prepared glasses were converted into glass-ceramics through nucleation and crystal growth processes. The physical parameters and crystallization behavior of the samples were assessed through differential thermal analysis (DTA), dilatometry, x-ray diffraction (XRD), field-emission scanning electron microscopy (FESEM), and Fourier transform infrared spectroscopy (FTIR). The incorporation of Li2O declined the Tg level from 820 °C to 768 °C. Gahnite and eucryptite were the dominant phases in the glass-ceramics. A rise in the Li2O content to 5 mol% led to an opaque glass-ceramic. Results showed that the addition of the lithium oxide led to the formation of a eucryptite phase alongside the primary gahnite phase. The dimension of the crystals was in the range of 20 nm through controlling the nucleation temperature and growth of the glass-ceramics. In order to induce photoluminescence (PL) property into the glasses, cerium oxide was added to all samples at 2 wt.%. The PL behavior was then investigated with the help of PL spectrum. TGC-Li3 sample exhibited up to 10 times higher PL intensities than the corresponding glass.

Fabrication and characterization of transparent nanocomposite films based on poly (lactic acid)/polyethylene glycol reinforced with nano glass flake

Developing new biodegradable packaging with superior properties and advanced functionalities is one of the most emerging research areas of interest in food packaging. In this study, PLA/PEG-based nanocomposite films incorporated with different amounts of nano glass flake (NGF) (0, 0.5, 1, and 2 phr) were fabricated via casting solution for applications in food packaging. The ATR-FTIR displayed no chemical interaction between the PLA/PEG-based matrix and NGF particles. The scanning electron microscopy (SEM) observations exhibited a relatively smooth and homogeneous surface without defects. Incorporation of the NGF into the PLA/PEG-based matrix did not affect the color and opacity of the fabricated films. The prepared nanocomposite films were highly transparent and exhibited superior properties such as increased hydrophobicity, appreciable oxygen barrier properties, and enhanced thermal stability. Dynamic mechanical thermal analysis (DMTA) and differential scanning calorimetry (DSC) analysis confirmed the existence of a single glass-transition temperature (Tg) as evidence of miscibility. According to the research results, the PLA/PEG/NGF1 nanocomposite film significantly offered the best overall performance. This work has developed new insight into the potential application of nano glass flakes in food packaging.

Preparation and Characterization of Nano-waste glass powder

This experimental study investigates top-down grinding to turn used waste glass into nano-glass powder. The study explores a new instrument locally manufactured to synthesize nano-glass powder. The high-energy ball mill was manufactured based on design, material, assembly, testing, optimization, and quality control. Two milling environments were examined: wet with water as a surfactant liquid and dry with varying grinding times. In addition, this study compared the output of nano glass created from mechanical and chemical grinding processes. Blaine's method for surface area measurement results of nanoscale powder samples produced by the wet grinding method showed a steady increase commensurate with the grinding duration, as the 12-h grinding specimen was the highest in surface area. In contrast, dry grinding samples showed anomalies in some instances due to the agglomerate phenomenon, such as 8- and 10-h grinding samples. Moreover, FE-SEM showed that the 12-h grinding specimen has the smallest particle size. But the AFM illustrated accurately with the 2D measurement that these particles have cortical shapes, which may describe the secret beyond the high surface area. X-ray diffraction (XRD) and AFM tests showed that in the case of nanoscale glass particles, regardless of their morphology status, the shape of the particle itself is the deciding factor in giving the Nano powder the highest particle surface area. The specimen milled with 4 h of dry grinding is best suited for civil engineering research applications, while other applications that need a small amount of nano glass are recommended to use chemical methods despite their dangerous processes.

Investigation of Adding Microscopic Slide Glass Nano Particles on the Metallurgical Characterization and Mechanical Properties of Cast Aluminum 7075 Composites

Investigation of Adding Microscopic Slide Glass Nano Particles on the Metallurgical Characterization and Mechanical Properties of Cast Aluminum 7075 Composites

Nanomaterials in geopolymer composites: A review

Nanomaterials (NMs) are being used to enhance the properties of construction materials. This review focuses on the use of NMs to improve the characteristics of fresh and hardened Geopolymer Composites (GC). Over 335 research publications are reviewed to detail the benefits and drawbacks of the integration of NMs in GC. More specifically, this review outlines the effects of numerous NMs such as Nano Silica (NS), Nano Alumina (NA), Nano Titanium dioxide (NT), Carbon Nano Tubes (CNT), Multiwall Carbon Nano Tubes (MCNT), Nano Calcium Carbonate (NCC), Nano Zinc oxide (NZ), Graphene Oxide (GO), Nano Metakaolin (NMK), Nano Fly Ash (NFA), Nano Glass Powder (NGP) and Nano-clay(NC) on Geo-polymer Paste (GPP), Geo-polymer Mortar (GPM) and Geo-polymer Concrete (GPC). The presence of NMs was found to enhance the geo-polymerization reaction and result in a denser matrix. The presence of NMs also enhances the durability of GC by preventing micro-pores interconnectivity. In hindsight, our review indicates that the addition of NMs is directly tied to producing high-performance GC, which the construction industry can effectively readily adopt. Additional insights, challenges, and future research directions are identified and discussed toward the end of this review.

Atomistic simulations of nanoindentation on nanoglasses: Effects of grain size and gradient microstructure on the mechanical properties

The use of nanoglass (NG) microstructures has been shown as an effective strategy to improve the ductility of rather brittle metallic glass alloys. To evaluate the effects of grain size and gradient design on the mechanical properties of NGs, we perform molecular dynamics simulations of nanoindentation on Cu64Zr36 NGs. We consider samples with uniform 3 and 7 nm grain sizes as well as gradient microstructures with gradient grain sizes varying from 3 to 7 nm. The results show that the deformation mechanism in NGs with small grain sizes is dominated by the activation and evolution of multiple shear transformation zones. Increasing grain sizes enhances the elastic modulus and hardness at the cost of reduced abrasion resistance. Though the average grain size at the indentation surface plays a crucial role in the deformation behavior of gradient NG models, their strain localization and plastic deformation states are affected by the grain sizes far from the indenter. Desired combinations of mechanical properties can be realized by different NG microstructure designs.

Influence of Nano-glass Powder on the Characteristics Properties as Well as Stability Against Firing for Geopolymer Composites

Influence of nano-glass powder on physico-mechanical properties of geopolymer composite materials has been studied, in addition to studying their firing stability against high temperature from 500 up to 1000 °C. For increasing mechanical, physical as well as firing stability for metakaolin composites; Nano-glass powder was used. Alumino-silicate materials are kaolin, fired kaolin (metakaolin) and limestone all pass 75 µm. Materials prepared at water/binder ratios in a range of 0.40; whereas the used activator 5 M sodium hydroxide with equal volume of liquid sodium silicate. Nano-glass powder added as a partial replacement for metakaolin material in the ratio of 1 up to 9%. Results indicated that compressive strengths of geopolymer mixes incorporating Nano glass powder were obviously higher than those of control one and increased up to 7% followed by slight decrease of on using 9%. Firing of hardened geopolymer results in high thermal resistance up to 500 °C then exposed to decrease up to 800 then increased again at 1000 °C for specimens incorporated 7 and 9% nano-glass powder. However, no micro-cracks were noticed up to 800 °C for all samples as recorded by visual examination of the fired samples.

Role of indenter geometry on the deformation behavior in a Pd-Si based metallic and nanoglass

Nanoindentation experiments are performed on a binary Pd-Si metallic glass (MG) and nanoglass (NG) using Berkovich and cube-corner indenters to investigate the effect of indenter geometry on the deformation behavior. A large number of pop-ins in the load vs. displacement curves and a higher pile-up of material around the indenter are observed for sharper cube-corner indenter compared to the Berkovich indenter. In case of both the indenters, NG displays lower hardness than the MG due to the presence of higher free volume and lack of any clusters in the glassy grains or interfaces. Further, the hardness is observed to decrease with indentation load signifying the indentation size effect (ISE) in hardness. The discrete plasticity ratio, Ψ defined as the ratio of pop-in displacement, ∆hdis to the total displacement, htot is used to estimate the influence of serrations on total plastic deformation and characterize the nature of the plastic flow. The Ψ indicates that the deformation mode is independent of indenter geometry for both the glasses.

The Influence of Hybrid Fibers and Nanomaterials (Nano Glass with Nano Slag) on the Behavior of Reactive Powder Concrete

The new production ofReactive Powder Concrete (RPC) has become an interesting topic due to the dramatic properties that such materials can give. Thus, this study has been prepared to observe the properties of RPC mixes reinforced with micro steel fibers (MSF) by the order of 2% volumetric fractions (vol.). As well, hybrid fibers from MSF, sisal fiber (SIF), and also human hair fibers (HHF) have been included in the RPC mix in the order of 1.5% MSF plus 0.5% SIF, 1.5% MSF plus 0.5% HHF, and 1.5% MSF plus 0.25% SIF plus 0.25% HHF, respectively. Besides, the inclusion of two different nanomaterials combination by 2.5% Nano glass powder (NG) and 2.5% Nano Iron slag powder (NS) was performed into that reinforced RPC. The preparation of these different RPC mixes was followed by testing them to investigate the performance of such RPC based on the properties of flowability, compressive strength, tensile strength, flexural strength, flexural toughness, and static modulus of elasticity. The results showed that the incorporation of 2%MSF increases the compressive strength, tensile strength, and flexural strength by 6.76%, 12.45%, and 14.34%, respectively, at 90 days. Whereas, the reinforcing of RPC by 1.5% micro steel fibers (MSF) with 0.25% sisal fibers (SIF) and 0.25% human hair fibers (HHF) rises the values of compressive strength, tensile strength, and flexural strength by 5.38%, 11.59%, and 14.05%, respectively, at age of 90 days. Moreover, the uses of nanoparticles as 2.5%NG with 2.5%NS in addition to 2%MSF increase the compressive strength, tensile strength, and flexural strength by 33.09%, 36.05%, and 43.68% at age of 90 days, respectively. The use of 1.5% MSF plus 0.25% SIF plus 0.25% HHF with the mentioned nanoparticles (2.5%NG and 2.5% NS) boosts the best performance by converting such concrete from brittle material to ductile material.

Study on the Wetting Mechanism between Hot-Melt Nano Glass Powder and Different Substrates.

The wettability of molten glass powder plays an essential role in the encapsulation of microelectromechanical system (MEMS) devices with glass paste as an intermediate layer. In this study, we first investigated the flow process of nano glass powder melted at a high temperature by simulation in COMSOL. Both the influence of the different viscosity of hot-melt glass on its wettability on SiO2 and the comparison of the wettability of hot-melt glass on Au metal lead and SiO2 were investigated by simulation. Then, in the experiment, the hot-melt glass flew and spread along the length of the Au electrode because of a good wettability, resulting in little coverage of the hot-melt glass on the Au electrode, with a height of only 500 nm. In order to reduce the wettability of the glass paste on the Au electrode, a SiO2 isolation layer was grown on the surface of golden lead by chemical vapor deposition. It successfully reduced the wettability, so the thickness of the hot-melt glass was increased to 1.95 μm. This proved once again that the wettability of hot-melt glass on Au was better.

Impact of nano-glass (NG) particles on seed germination and it’s accumulation in plant parts of wheat (Triticum aestivum L.)

Micro/nano-contaminants have been the focal pollutants in environmental science, which includes several nanomaterials, nanocomposites, fibers, glass, plastics etc. Micro/nano size pollutants are more harmful than macro pollutants due to their size. Therefore, there is an urgent need for research on the possible fate of glass particles in the environment, especially in plant and soil systems. Here, the synthesized nano-glass (NG) from the waste windshield and analyzed its uptake and effect on the wheat (Triticum aestivum L.) plant system in a hydroponic solution. The findings provided direct evidence that NG reduced the germination % with increasing NG concentrations as 100, 96, 92, and 92% for 10, 20, 30, and 40 mg L−1. The lowest root and shoot height (15.40 and 22.42 cm) was achieved in the 40 mg L−1 NG treatment. Decrement in fresh and dry wt. with a maximum reduction of chlorophyll a, b and total content (6.19, 4.98, and 11.17 mg g−1 fresh wt.) was obtained at 40 mg L−1 at 21 days. Rhodamine B was used for fluorescence imaging in seedlings to detect NG movement, Results showed that NG moves via xylem tissues of root part to other parts of the plant. Based on the currently limited or no data and uncertainty regarding the actual impact of NG on soil and plant systems, suggested considerations to address key knowledge gaps are delineated. Further studies are required as a flora build-up of NG can have both environmental influence and consequences on agronomic sustainability and food safety.

Processing of the yttria stabilized zirconia-bioactive glass nano composite produced by electrophoretic deposition method

The yttria-stabilized zirconia (YSZ) is added to a bioactive glass coating through the electrophoretic deposition (EPD) method to significantly improve the mechanical properties, in particular the bonding strength of the coating on the Ti substrate. In this study, suspensions of bioactive glass and YSZ powder (at the same ratio, 20 g/l) are prepared in ethanol solvent; and tri-ethanol-amine is used as the stabilizer. The effects of the EPD parameters such as deposition time and voltage are studied. The optimum coating quality is achieved at a voltage of 60 V for 10 min. After coating, sintering is performed at three different temperatures (800, 850, and 900 °C). The XRD is used to identify the structure and phase of yttria-stabilized zirconia powders and the coated samples. FE-SEM is also employed to assess the microstructure of the specimens. The highest adhesion strength (sim 4.38 MPa) is obtained at the sintering temperature of 850 °C.

Investigation on structural and spectral properties of solution-processed GeTeBi chalcogenide glasses

We report structural investigation and optical nonlinearities of optical grade thin films made from Ge20Te75Bi5 chalcogenide glass nano colloidal solutions in this paper. The presence of reverse saturable absorption is demonstrated by the valley-like open aperture z-scan spectra of nano colloids (RSA). Third-order optical nonlinearities in Ge20Te75Bi5 chalcogenide nano colloids were investigated using the z-scan method to enhance the desired features for usage in nonlinear optics.