Almost majority of petroleum produce is utilized for transportation, generation of heat and electricity, and balance used as a raw material in chemical industry. With increasing energy demand, limited fossil fuel sources, study is directed towards alternate renewable fuels. Biodiesel extracted from Vegetable Oil, is becoming a popular alternative propulsion fuel. Experiments were conducted using different blends from Mustard Oil biodiesel mixed with diesel in concentration of 10%, 20%, 30%, 40%, 50%, to determine the properties of these biodiesel blends and evaluate the performance as well as emission characteristics of a CRDI Engine. The trials were conducted for various load conditions viz. 0 kg, 3 kg, 6 kg, 9 kg and 12 kg, for two different compression ratios 16 and 18. The performance assessments indicators like brake power, brake specific fuel consumption, brake thermal efficiency, mechanical efficiency, air-fuel ratio were examined. The highest magnitude of mechanical efficiency observed is 59.14% for Mustard Oil Biodiesel 10% Blend (MuB10) for 12 kg, engine load and compression ratio 16. The emission indicating parameters oxides of nitrogen, hydrocarbon, carbon dioxide, carbon monoxide, and smoke were scrutinized throughout trials. The result of this investigation exposed that blend B10 has given favorable outcomes as compared to pure diesel for CRDI engine performance indicating parameters and has fewer emissions as compared to that of pure diesel.