Municipal Waste Incineration Bottom Ash Research Articles

Impact of Municipal Solid Waste Incineration Bottom Ash as Cement Substitution

Impact of Municipal Solid Waste Incineration Bottom Ash as Cement Substitution

Assessment of mechanical and heavy metal leaching behavior of engineered cementitious composites incorporating ultra-high-volume municipal waste incineration bottom ash

This study aimed to explore the feasibility of incorporating 100% municipal solid waste incineration bottom ash (MSWIBA) as a replacement for fine aggregates in engineered cementitious composites (ECCs). To improve mechanical properties, three types of polymer fibers (PVA, PP, and PE) were used at dosages of 0-2% by volume. The impact of fiber content on compressive strength, elastic modulus, and other key performance indicators such as peak strain, ultimate strain, damage modulus, and toughness index was systematically investigated. Results showed that while the elastic modulus and peak stress slightly decreased with increasing fiber content due to fiber agglomeration and increased macro-porosity, fibers significantly enhanced the deformation capacity and toughness. For instance, the MSWIBA-ECCs with 2% PP fibers exhibited the highest compressive damage energy of 205.47 J, a 79.48% increase over the control group, demonstrating superior toughness. Additionally, the study developed a new constitutive model that accurately predicted stress-strain behavior considering fiber characteristics. Environmental assessment revealed that MSWIBA-ECCs effectively immobilized hazardous heavy metals (Cu, Ni, Pb, Zn), with a solidification efficiency of 97%, ensuring compliance with Chinese environmental standards. These findings suggest that MSWIBA-ECCs, combined with optimized fiber content, offer a sustainable and high-performance alternative for construction applications.

Optimization of Sustainable Alkali Activated Municipal Solid Waste Incinerator Bottom Ash Materials with High Performance

Optimization of Sustainable Alkali Activated Municipal Solid Waste Incinerator Bottom Ash Materials with High Performance

A novel use of incineration bottom ash for H2 aeration in the production of artificial lightweight aggregates

Cold bonding is an energy-efficient method for producing artificial aggregate (AA). However, the relatively high density of AA restricts its use in lightweight concrete products. This study aims to fully upcycle aluminum (Al) content in municipal solid waste incineration bottom ash (IBA) for H2 aeration in the production of lightweight artificial aggregate through alkali activation. To achieve this, the glass particles (GP) in IBA were ground into powder and used as the precursor for NaOH, while the remaining IBA (RIBA), rich in Al, served as the foaming agent. The results showed that RIBA particles (<300 μm) can be used to produce lightweight AA with a loose bulk density ranging from 780 to 840 kg/m3, comparable to sintered fly ash aggregates, and a wide pore size distribution ranging from 0.02 mm to over 1 mm. The inclusion of finer RIBA particles (<75 μm) enhanced the homogeneity of the pore structure, resulting in aggregate strengths of 0.4–0.6 MPa. Moreover, increasing the GP content in IBA up to 40% further boosted the aggregate strength to 1.1 MPa by refining the pore structure and promoting more (C)-N-A-S-H gels with Q4 structures. To ensure sufficient geopolymerization reactions and achieve high strength in the AAs, the alkali concentration should be kept above 3 mol/L. The proposed strategy for lightweight AA production reduced the global warming potential by about 20% compared to the conventional sintered method, offering a more environmentally friendly approach.

Utilization of Multiple Recycled Materials in Asphalt Concrete: Mechanical Characterization and Cost-Benefit Analysis.

This study examines the strategic incorporation of various recycled materials into asphalt concrete, specifically focusing on municipal solid waste incineration bottom ash (MSWI BA), recycled asphalt shingle (RAS), and recycled concrete aggregate (RCA). Due to the high porosity of MSWI BA and RCA, and the significant asphalt binder content (30-40%) found in RAS, there is a need to increase the amount of liquid asphalt used. RAS is posited as an efficient substitute for the asphalt binder, helping to counterbalance the high absorption characteristics of MSWI BA and RCA. The research objective is to quantitatively evaluate the effect of the combined use of RAS, MSWI BA, and RCA in Hot Mix Asphalt (HMA). This study encompasses several laboratory evaluations (i.e., rutting and tensile strength tests) and a cost-benefit analysis, which is a life cycle cost analysis. The results indicate that the combined use of these materials results in a higher tensile strength and rut resistance when compared with the control (with virgin aggregate). According to the cost-benefit analysis result, when the three recycled materials are used for an HMA overlay over an existing aged pavement, it could be 60-80% more cost-effective compared to a conventional HMA overlay, thereby offering significant economical savings each year in the field of road construction.

Production of high-strength eco-conscious ceramics exclusively from municipal solid waste

This research investigated the application of municipal solid waste incineration fly ash (MSWIFA), municipal solid waste incineration bottom ash (MSWIBA), and construction waste residue (CWR) as raw materials for the comprehensive conversion into municipal solid waste ceramics employing the SiO2-Al2O3-CaO-MgO (8 wt%) phase diagram. This study aimed to evaluate the influence of the addition of MSWIFA and sintering temperature on important ceramics properties, including linear shrinkage, water absorption, sintering range, and flexural strength. Additionally, relationships were established among these physical parameters using Pearson's correlation coefficient. The thermal behavior of the mixture was analyzed through automatic slag melting point tester and TG-DSC techniques. Furthermore, characterization of the crystalline phase transition and microstructure of sintered samples was performed by XRD, Factsage, and SEM. The results showed that both the addition of MSWIFA and the sintering temperature significantly influenced the crystal phase composition of the sintered ceramics. Moreover, the addition of MSWIFA and the sintering temperature had a significant influence on the pore structure of the ceramics. These ceramics exhibited exceptional properties, such as the extremely low water absorption rate of 0.08 % and the remarkable flexural strength of 124.78 MPa. Ceramics performance indicators were far higher than the requirements of China's national standard GB/T4100-2015. The sintering range had the capability to attain 30 °C, guaranteeing the feasibility of practical manufacturing processes. Furthermore, leaching concentration tests conducted on additive-free ceramic samples reveal a low risk of heavy metal contamination, as the heavy metals were effectively solidified within the crystalline and amorphous phases of the ceramics. The comprehensive utilization of MSWIFA, MSWIBA, and CWR for the production of fully solid waste ceramics not only yields cost reduction benefits but also promotes efficient utilization, presenting a feasible and highly promising approach to sustainable waste management.

Recovery potential of municipal solid waste incineration bottom ash graded by particle size in an alkali-activated cementitious material system: Curing properties and environmental leaching risk

Currently, municipal solid waste incineration bottom ash (MSWI BA) is considered for use in alkali-activated cementitious materials (AACMs). However, a comparison of relevant studies revealed large differences in the reaction kinetics performance of MSWI BA. This finding presented difficulties in assessing the use of the MSWI BA in AACM. Compositional differences among particle sizes and design bias caused by the content of reactive components are two of the scientific shortcomings. In this work, MSWI BAs were categorized as S1 (0–2 mm), S2 (2–4 mm), S3 (4–8 mm), and S4 (8–16 mm). The reactivities of S1 to S4 were characterized. The mixing proportions of the AACMs were also designed on the basis of the reactivity components. The results showed that more glassy phases and synthetic ceramics in S4, as well as a lower Ca/Si ratio (1.08) in the final product, increased the strength. The maximum value of the 28 d compressive strength was 36.4 MPa. Among the final AACM products, most of the compressive strengths of AS1 and AS2 developed early, with strength increases of 3.1 % and 15.1 %, respectively, over the 7–28 d process. In addition, the Ca/Si ratios of C–S–H in AS1 and AS4 deviated slightly from the design values of 7.3 % and 4.6 %, respectively. The final product exhibited optimized pore distribution and densification, highlighting the physical encapsulation effect on toxic elements. Moreover, the leaching values of heavy metal elements are within the permissible range of Chinese standards.

Study on the Preparation and Performance of Lightweight Wallboards from MSWIBA Foam Concrete.

To reduce land use and avoid further pollution, incineration for power generation has become the main method for municipal solid waste treatment. This research focused on the potential for transforming Municipal Solid Waste Incineration Bottom Ash (MSWIBA) into a finely ground powder. The impact of the powder's fineness and the amount of water used on its effectiveness was analyzed using a method called grey theory. MSWIBA was used as a partial substitute for cement in making MSWIBA foam concrete and lightweight wall panels. By modifying the fineness and water utilization of the recycled micro-powder, its maximum activity index can be increased to 90.1. This study determined the influence of factors including apparent dry density, water-cement ratio, foaming agent dilution ratio, and admixture dosage on the strength of the recycled foam concrete, and established the optimal mix ratio. This study employed a combination of physical experiments and numerical simulations to elucidate the impact of panel material, core layer thickness, and layer sequence on sound insulation performance. The simulation results were in close agreement with the experimental findings.

Evaluating the strength characteristics of mixtures of municipal solid waste incineration bottom ash and reddish laterite clay for sustainable construction

This study examines effects of mixing municipal solid waste incineration bottom ash (MSWI-BA) with reddish laterite clay (RLC), evaluating factors such as vertical stress, mixing ratio, curing period, and the addition of lime. A total of 153 direct shear tests were conducted to thoroughly assess the mixture's strength characteristics. Vertical stress levels of 85.5 kPa, 172.4 kPa, and 259.3 kPa were used to simulate varying stress conditions, while mixing ratios of 40 %, 80 %, 100 %, and 120 % were applied to explore potential applications of recycled MSWI-BA with clayey soils. A fast-curing approach was employed, with curing periods of 24, 48, and 72 h, to investigate the time-dependent strength development under controlled conditions. A three-way ANOVA analysis confirmed that mixing ratio, curing period, and vertical stress significantly impacted both peak and residual shear strength. The 100 % MSWI-BA mixture, with or without 1 % lime, exhibited optimal performance, providing the pronounced shear strengths and dilative behavior. The study found that MSWI-BA significantly improved shear strength ratios compared to the RLC, with improvement ratios ranging from 1.439 to 2.460 across stress levels. Additionally, upper and lower bound equations for peak and residual strength ratios were developed, providing predictive tools for mixture design. Cohesion values in the range of 8.3–128.9 kPa and friction angles from 40.6° to 44.1° were achieved, surpassing or matching those reported in similar research. The study employed Bolton's (1986) dilatancy model, finding α values between 0.61 and 0.71, comparable to those in studies of granular materials. These results highlight the effectiveness of adding MSWI-BA and lime in enhancing reddish laterite soil stabilization through both chemical and mechanical means, making it a sustainable and cost-effective approach for civil engineering projects by improving material strength, reusing local soils, recycling waste, and reducing carbon footprints.

Physical & mechanical properties of pervious concrete incorporating municipal solid waste incineration bottom ash

Municipal solid waste incineration bottom ash (BA) as a cementitious substitute in pervious concrete constitutes a viable strategy for waste recycling and carbon emission mitigation. Nonetheless, the resultant alterations in the cementitious matrix composition and the inter-aggregate macro-porous structure induced by BA incorporation still need to be explored, limiting a thorough understanding of the mechanical behavior and permeability. Macroscopic tests were employed to investigate the impact of BA and compaction densities on the physical and mechanical properties. The effects of BA on the hydration products were analyzed using X-ray diffraction (XRD) and thermogravimetric analysis (TG) methods. The results reveal that at a density of 2190 kg/m³, BA has minimal effect on the interconnected porosity and permeability. However, as the density increases, a higher BA substitution ratio leads to a narrowed pore distribution and a significant reduction in permeability. Furthermore, a power-function relationship exists between the compressive strength and dynamic modulus of elasticity. At a 15 % substitution ratio, a slight decrease in hydration products was observed, resulting in a minor reduction in compressive strength. Concurrently, a linear relationship was established between the proportion of tiny pores (less than two mm2) and the relative compressive strength. Considering both permeability and mechanical performance, pervious concrete with a density of 2310 kg/m3 and containing no more than 10 % BA meets the requirements of the CJJ/T135-2009 standard. These findings provide a scientific basis for the mix design of pervious concrete incorporating BA.

Phase evolution, microstructure and properties of glass-ceramics derived from municipal solid waste incineration bottom ash and molybdenum tailings

Municipal solid waste (MSW) incineration bottom ash (BA) and molybdenum tailings (MTs) are bulk solid wastes that have low added value and is of a serious environmental concern. Hence, it is imperative to develop technology that potentially as convert these wastes into potential products that are safe to handle. In the present work, the goal is to synthesize glass-ceramics from BA and MTs without addition other supplement materials. The study attempts to assess the influences of raw material ratio and sintering temperature on the phase transformation, microstructure and properties of glass-ceramics. The synthesized product shows that diopside ferroan and anorthite were the dominant crystals, and the content of diopside ferroan and anorthite increased with an increase in the proportion of MTs. It was observed that the presence of Fe2O3 and TiO2 inside solid wastes promote nucleation facilitating growth of crystals. Diopside ferroan and anorthite distribute uniformly and are well interweaved, densifying the structure with favorable properties of glass-ceramics. At the optimal processing temperature the presence of Na2O and K2O in the raw materials act as fluxing agents that facilitate formation of liquid phase, that enhance diffusion and rate of crystallization. The optimal mass ratio of BA to MTs was 45:55 and the sintering temperature of 1000 °C, exhibited the best comprehensive properties of the glass ceramics. At the optimal conditions the flexural strength, Vickers hardness, bulk density and water absorption were observed to be 76.00 MPa, 5.77 GPa, 2.69 g/cm3 and 0.32 %, respectively. The leaching test proved stability of the glass ceramics, and hence can serve to be a potential way of utilizing the waste into a valuable product benefiting the environment and promoting sustainable growth.

Characteristics and release potential of microplastics in municipal solid waste incineration bottom ash

Incineration is an effective method for reducing and safely treating municipal solid waste. However, microplastics (MPs) inevitably remain in the bottom ash, potentially introducing new pollution risks during subsequent treatment processes. This study conducted an analysis of the accumulation and release potential of MPs in bottom ash samples collected from 4 municipal solid waste incineration plants in Zhejiang, China. The results showed that the abundance of MPs ranged from 20 to 118 items g−1. Remarkably, MPs were found to accumulate predominantly in smaller bottom ash particles below 4.75 mm accounted for up to 70% of the total MPs. Most MPs in the bottom ash were under 100 μm in size, with a majority exceeding 50% being less than 50 μm, typically manifesting as shafts and fibers. In scenarios of secondary crushing, the abundance of MPs increased gradually with the degree of bottom ash crushing. When bottom ash was crushed to a particle size of less than 0.6 mm, the abundance of MPs reached up to 87–901 items g−1, which is 5–10 times higher than the original bottom ash. It is estimated that the annual release of MPs may reach up to 4.05 × 1016 particles. Re-incinerating thoroughly crushed bottom ash at 600 °C successfully decomposed the MPs. Mechanical stress can significantly increase the risk of MPs releasing in bottom ash. This risk can be eliminated by using secondary incineration to achieve complete MPs decomposition.

A comparative study of wet-mix vs. dry-mix to prepare geopolymer artificial aggregates utilizing municipal solid waste incineration bottom ash (IBA) via crushing technique

The demand for sustainable alternatives to utilize incinerator bottom ash (IBA) alongside the current scarcity of natural aggregates drives the construction industry to seek innovative solutions, among which cold bonding geopolymer artificial aggregates (GPA) have tremendous leverage. This study suggests combining dry-mix and crushing techniques for producing IBA-GPA, aiming to overcome the challenges of volume instability related to metallic aluminum. The materials used as precursors include IBA, CFA, and GGBS, with anhydrous sodium metasilicate as the activator. The mixing method, water content, and IBA content are key parameters examined in this research, using characterization techniques such as XCT, TCLP, XRD, FTIR, and SEM. The results show that a proper balance between water and IBA contents is crucial for producing high-quality IBA-GPA cubes, at which the proposed technologies successfully mitigate volume instability and enhance the reliability of IBA-GPA. The dry-mix samples were less porous and more compact, with irregularly shaped pores, while the wet-mix samples had a foam-like structure with more uniformly spherical pores. Adding IBA increased pore sizes in both samples, with a more pronounced effect in the wet-mix samples. The findings provide insights into the impact of mixing methods on the properties of IBA-GPA.

Mechanical and microstructural properties of municipal solid waste incinerator bottom ash (MSWIBA) concrete exposed to salt erosion and drying-wetting cycles

In cold and saline soil areas, concretes usually experience multi-factor erosions, such as freezing-thawing cycles (FTCs), drying-wetting cycles (D-Ws), and salt erosion. To promote green and sustainable development of the construction industry, municipal solid waste incinerator bottom ash (MSWIBA) was adopted as a partial replacement for conventional fine aggregates in concretes. In this study, the coupled effects of the D-Ws and salt erosion (i.e., 5 % NaCl solution and 5 % Na2SO4 solution) were experimentally conducted to investigate the mechanical and microstructural properties of ordinary and MSWIBA concretes. The results showed that D-Ws had a negative effect on the mechanical properties of concretes. The depth and width of cracks in concretes increased with the D-Ws raised. During the D-Ws, the influence of salt solution on concretes could be divided into two stages. Initially, the filling effect of salt crystals was beneficial to the development of concrete strength. Subsequently, salt crystals accumulated in concretes caused cracks, and accelerated the deterioration of concrete specimens. Meanwhile, sodium sulphate reacted with hydration products in concretes to produce some expansive substances, the evident diffraction peaks of expansive substances (e.g., gypsum and ettringite) had been clearly observed after D-Ws. Thus, the damage effect of 5 % Na2SO4 solution (SS) to concrete structure was more serious than that of water (WT) and 5 % NaCl solution (CS). Furthermore, the total porosity of the concrete specimens generally decreased with the MSWIBA substitution rate increased. There was an optimal MSWIBA content for concretes to obtain the excellent mechanical and microstructural properties. In detail, when the substitution rate of MSWIBA was between 0 % and 33.0 %, it had an excellent effect on improving the pore structure of concretes. Specifically, the compressive strength of concretes was larger than 35.0 MPa when the substitution rate of MSWIBA with natural river sand was between 24.8 % and 57.8 %, whereas the substitution rate of MSWIBA should not exceed 33.0 % exposed to D-Ws. This study could provide a significant reference for the sustainable development of concretes in cold and saline soil areas, as well optimization and innovation usage of MSWIBA.

Reuse potential of municipal solid waste incinerator bottom ash as secondary aggregate: Material characteristics, persistent organic pollutant content and effects of pH and selected environmental lixiviants on leaching behaviour

Increasing municipal solid waste (MSW) production poses challenges for sustainable urban development. Modern energy-from-waste (EfW) facilities incinerate MSW, reducing mass and recovering energy. In the UK, MSW incineration bottom ash (MSW IBA) is primarily reused in civil engineering applications. This study characterizes UK-produced MSW IBA, examining its pH-dependent leaching behaviour and response to environmental lixiviants. Results show predominant components include a melt phase, primary glass and fine ash aggregations, and a chemical composition dominated by SiO2 (30–50 %), CaO (∼15 %), Fe2O3 (∼10 %), and Al2O3 (∼8%). X-ray absorption near edge structure (XANES) analysis shows that Zn and Cu are most likely oxygen-bound (adsorbed to oxy-hydroxides and as oxides) with some sulphur bound. Polychlorinated biphenyls (PCBs) and polychlorinated dibenzodioxins/furans (PCDD/Fs) are well below regulatory limits, and polycyclic aromatic hydrocarbons (PAHs) were undetectable. Leaching tests indicate trace elements mobilize at pHs ≤ 6. With a natural pH of 11.3 and high buffering capacity, significant acid inputs to the MSW IBA are required to reach this pH, which are improbable in the environment. Wood chip additions increase leachate’s dissolved organic carbon (DOC) and reduce pH, but had minimal impact on metal-leaching behaviour. Synthetic plant exudate solutions minimally affect metal leaching at realistic concentrations, only enhancing leaching at ≥ 1500 mg l−1 DOC. This work supports MSW IBA’s low-risk in specified civil engineering applications.

Compressed stabilised earth block synergistically valorising municipal solid waste incinerator bottom ash and sisal fiber: Strength, durability and life cycle analysis

Compressed stabilized earth blocks (CSEB) represent an eco-friendly substitute for traditional building materials, predominantly utilizing earth. Municipal Solid Waste Incineration Bottom Ash (MSWIBA) is a by-product of municipal waste treatment that can be creatively repurposed in construction projects. This research explores integrating MSWIBA as a substitute for Earth in CSEB production to conserve natural resources and repurpose waste, potentially reducing its landfill disposal. The sisal fibers (SF), often regarded as by-products of agricultural processes, offer an intriguing research material. The SF was treated with a 5 % NaOH alkaline solution to improve the CSEB bonding, increasing the flexural strength. The study aims to determine the optimal mix of stabilizers, in addition to a 10 % cement content, using various percentages of MSWIBA (10–40 % by weight of dry sand) and SF content (0.25–1 % by weight of dry soil). These blocks undergo comprehensive tests to determine their strength and durability. Wet and dry compression, flexural tests and indirect tensile tests were used to assess strength qualities, while wetting-drying cycles and acid exposure were used to determine durability. MSWIBA replaces 20 % sand in CSEB satisfying the strength. However, exceeding this amount increases void content and lowers strength, emphasizing the importance of balanced proportions for best performance. The 20 % MSWIBA and 0.75 % SF combination enhanced the compressive strength by 6.45 MPa, flexural strength by 0.92 MPa and water absorption by less than 18 %. The durability test displayed increases in compressive strength of 14.7 % and flexural strength of 93.48 % and optimized water absorption rate. Furthermore, microstructural analysis has been performed on CSEBs and the results highlight the importance of balanced cement and SF proportions for structural integrity. Life Cycle Analysis (LCA) investigation shows that construction costs using CSEB are 12.24 % higher than those with FCBs. Additionally, the study suggests that CSEB with MSWIBA and SF will be an environmentally sustainable construction material, considering factors such as energy usage, Global Warming Potential, and other environmental considerations

Impacts of advanced metals recovery on municipal solid waste incineration bottom ash: aggregate characteristics and performance in portland limestone cement concrete

The optimization of alternative materials in concrete production continues to garner considerable attention in order to meet sustainability goals and supplement natural materials. Portland limestone cement (PLC) and municipal solid waste incineration (MSWI) bottom ash (BA) have been proposed separately as green cement and coarse aggregate supplement in low-strength concrete production, creating sustainable products and alternative disposal scenario for a waste material. This study discusses the impact of advanced ash processing techniques on aggregates and presents the performance of concrete incorporating both of these products with PLC for the first time. Two sources of MSWI BA were investigated, one as-produced (TMR) and one processed with novel advanced metals recovery (AMR). The AMR process reduced total Al content in ash compared to TMR (20,500 vs 17,000 mg/kg), though not aluminum oxide content, as the AMR process targets metallic aluminum. A composition study on both aggregates supports a reduction in ferrous and non-ferrous metals following the AMR process. All control and test mixes met 28-day compressive strength requirements (17 Mpa). Both AMR and TMR MSWI BA-amended concretes yielded compressive strengths below control specimens (no ash) ranging from 17 to 23 MPa, with little to no difference observed dependent on MSWI BA processing. The life-cycle discussion supports benefits deriving from supplementing naturally mined materials and recovering ferrous and nonferrous metals with the AMR process.

Converting municipal solid waste incineration bottom ash into the value-added artificial lightweight aggregates through cold-bonded granulation technology

To effective recycle the Municipal solid waste incineration bottom ash (MSWIBA), this study adopts cold consolidation granulation technology to develop eco-friendly artificial lightweight aggregates (ALCBAs), and the materials are over 50 % dosage of MSWIBA, less 50 % fly ash (FA) or ground granulated blast furnace slag (GGBFS), and 10 % ordinary Portland cement (OPC). This study investigated the effects of different binder types and dosages on the properties of ALCBAs, including compressive strength, water absorption rate, bulk density, microstructures, pore development, heavy metal leaching behavior, and sustainability. The feasibility of ALCBAs to design green concrete was also explored. The results show that with higher content of MSWIBA and binders of FA, GGBFS and OPC, the ALCBAs with compressive strength greater than 2.5 MPa, bulk density of about 1000 kg/m3 and water absorption rate greater than 12 % was successfully developed. Increasing the content of FA/GGBFS is beneficial to improve the compressive strength and reduce the water absorption rate and the total porosity and lower the air bubbles percentage of ALCBAs. More importantly, both FA and GGBFS are mixed into ALCBAs, the compressive strength is at 2.5 MPa-3.0 MPa, the water absorption rate is significantly reduced, and the energy consumption, carbon footprint and cost are also significantly reduced. As the content of ALCBAs increases, although the compressive strength and splitting tensile strength are not as good as concrete with natural aggregates, the density of low-carbon concrete with ALCBAs gradually decreases, and the interface transition zone is gradually improved. Overall, ALCBAs can be beneficial to the conservation of natural resources (natural aggregates) and effectively solve the shortage of natural aggregates, and can be used to deal with the accumulation of solid waste in a green way, and it also can open up new channel for solid waste recycling.

NaAlO2 activated slag and MSWI bottom ash: Phase assemblages and thermodynamic assessment of long-term leaching behavior

Long-term leaching (heavy metal ions) behavior of municipal solid waste incineration bottom ash (MSWI BA) is one of the issues limiting its application in alkali activated materials (AAMs). This study investigates NaAlO2 activated slag (partially replaced by MSWI BA) in terms of the reaction process and leaching behavior. A combined approach of experimental observation and thermodynamic modeling is utilized. The hardened pastes were evaluated by reaction kinetics, mineralogy, microstructure, strength, and leaching. The thermodynamic modeling included consideration of the raw materials chemistry and activator types. Results show that the modeled C(N)−A−S−H is in line with quantitative results. Specifically, modeled hydrotalcite content (3g/100g binder) is slightly higher than the experimental results (2g/100g binder) at 28 days. Furthermore, the uptake of Cu dramatically increases at 20 days by the generated C(N)−A−S−H gels, while the binding capacity of Sb, sulfates, and chlorides increases with the formation of hydrotalcite formation over time.

Insights into the usage of biobased organic acids for treating municipal solid waste incineration bottom ash towards metal removal and material recycling

The recycling of incineration bottom ash (IBA) is crucial for sustainable municipal solid waste (MSW) management and alleviating landfill burdens. However, limited environmentally friendly methods exist to effectively treat IBA for safe recycling. This study systematically examined the performance of biobased organic acids, namely citric acid (CA), oxalic acid (OA), lactic acid (LA), and levulinic acid (LEA), for IBA treatment. CA shows high extraction efficiency for most trace metals (e.g., Mn > 65 %, Pb > 50 %, Co approx.100 %, Cd > 85 %, Zn > 80 %, Ni > 80 %), while OA performs better for certain trace metals (e.g., Sn approx.99 %, Sb > 70 %, Mo > 70 %, Cr > 50 %). Multivariate statistical analysis and instrumental techniques were used to gain deeper insights into the critical mechanisms, including proton promoted dissolution, ligand related dissolution and precipitation/co-precipitation. The latter two mechanisms are distinctive metal extraction behaviours by organic acids compared to their inorganic counterparts. Both CA- and OA-treated alkaline-washed IBA residues demonstrate high leaching reduction efficiency (>99.9 %) of the critical heavy metals, making the treated IBA residues suitable for safe recycling as construction materials. This study highlights the potential of environmentally friendly organic acids which can be derived from bio-wastes for treating and repurposing IBA as resources for construction materials, promoting sustainable waste management for MSW incineration ash.