Multiple Loss Mechanisms Research Articles

Rare earth doped magnetoelectric composites for enhanced electromagnetic wave absorption

Magnetoelectric electromagnetic wave absorption materials (EWAMs) with multiple loss mechanisms have shown remarkable results in solving electromagnetic (EM) interference and radar stealth. However, due to the Snoek limit, the magnetic properties are affected to some extent. Hence, based on low-cost two-dimensional graphite nanosheets and magnetic ferrite, a rare-earth doping strategy is innovatively proposed, aiming to develop a high-efficiency EWAM. Specifically, taking advantage of the significant differences in magnetic moments and dimensions between Gd and Fe ion, the modified ferrite owns unusual magnetic properties and dielectric capacity. Further, direct control of the EM parameters is achieved by finely tuning the component ratio, which in turn optimizes the response characteristics of EM wave absorption. Experimental results show a maximum reflection loss of −64.04 dB and a wide effective absorption bandwidth covering 4.88 GHz, corresponding to the absorption efficiency of −42.7 dB/mm and 3.25 GHz/mm, respectively. The outstanding performance is related to the synergistic effect of multiple loss management and impedance matching, and further confirmed by the radar cross section (RCS) reduction of 29.15 dBsm. Thus, the novel way opens a new horizon for the next magnetic-based EWAMs.

The synergistic effects on the magnetic CoNi and Fe3O4 nanoparticles co-embedded porous carbon toward enhanced microwave absorbing performance

Abstract Lightweight and environmentally friendly three-dimensional biomass-derived porous carbon (3D BPC) holds great potential as a highly effective material for microwave absorption (MA) applications. However, the high complex permittivity and lack of magnetic loss in a single 3D BPC lead to impedance mismatching and a limited absorption bandwidth. Developing 3D BPC–based absorbers with multiple loss mechanisms and excellent impedance matching remains a notable yet challenging task. In this study, inspired by a synergistic composition and microstructure design, 3D BPC co-embedded with magnetic cobalt–nickel (CoNi) and iron(III) oxide (Fe3O4) nanoparticles (3D BPC@CoNi@Fe3O4) was developed. 3D BPC@CoNi@Fe3O4 exhibited consistently low complex permittivity, primarily due to the suppression of conductive loss, whereas the introduction of magnetic phases (CoNi and Fe3O4) enhanced the magnetic loss. Optimised impedance matching, achieved through the synergistic regulation of the electromagnetic parameters, emerged as the key mechanism for improving the MA properties. The as-synthesised 3D BPC@CoNi@Fe3O4 composite, with only 20 wt.% loading demonstrated a wide effective absorption bandwidth (reflection loss [RL] < −10 dB) of 6.08 GHz and an impressive minimum RL value of −40.08 dB. These findings offer valuable insights into the development of high-performance 3D BPC–based microwave absorbers through composition and microstructure optimisation.

Electron Migratory Polarization of Interfacial Electric Fields Facilitates Efficient Microwave Absorption

AbstractHigh‐performance microwave absorption materials (MAM) are often accompanied by synergistic effects of multiple loss mechanisms, but the contribution share of various loss mechanisms has been neglected to provide a template and reference for the design of MAM. Here, a highly conductive 2D structure is designed through a functional group‐induced structure modulation strategy, composite L‐Ni@C can reach an effective absorption bandwidth of 6.45 GHz at 15% fill rate, with a maximum absorption efficiency of 99.9999%. Through the layer‐by‐layer analysis of the loss mechanism, it is found that the strong loss originates from the polarization loss at the heterogeneous interface. The movement of space charge between the two‐phase interface forms an interfacial electric field, and the in situ doping of nitrogen is cleverly achieved by the introduction of amino functional groups, which significantly enhances the rate of space charge transfer between the two‐phase interface and greatly facilitates the electron migration polarization. The space charge motion law of the interfacial electric field is also simulated using COMSOL simulation software to illustrate the electron migration polarization mechanism at heterogeneous interfaces. This work fills the gap of functional group‐induced structural modulation and presents new theories into the mechanism of space charge movement at heterogeneous interfaces.

An ultrathin ultralight electromagnetic absorber based on shortcut glass-coated amorphous magnetic Fiber/Salisbury-like screen

A structural design methodology is proposed for an ultrathin, ultralight, and absorption-adjustable electromagnetic absorber. The proposed absorber (SFSL) consists of an absorbing layer with shortcut glass-coated amorphous magnetic fiber and a substrate layer with transmitting material. This absorber features a Salisbury-like screen structure and incorporates multiple loss mechanisms. By investigating the influence of fiber distribution, length, content, and substrate layer thickness on absorption performance, it has been determined that the weight per square meter and thickness of a single-layer SFSL can be lowered within 50 g/m2 and 1.5 mm respectively. Furthermore, the absorption intensity and bandwidth can be adjusted by manipulating these parameters. The SFSL exhibits resonant behavior similar to that of a metamaterial absorber; however, SFSL with randomly distributed fibers demonstrates broader and stronger absorption characteristics in the frequency range from 2 to18 GHz. Additionally, the thicknesses of the substrate layer and surface covering affect the electromagnetic response characteristics. This work provides a simple strategy for constructing an ultrathin and ultralight composite to achieve efficient absorption of electromagnetic waves.

Defect-rich carbon nanosheets derived from p(C3O2)x for electromagnetic wave absorption applications

Defect modulation strategies have been shown to be an effective way to design efficient EMW absorbing materials, but the coexistence of multiple loss mechanisms due to the complexity of the existing models makes it difficult to elucidate the mechanism by which defect-induced dielectric losses dominate. In this work, p(C3O2)x is applied for the first time in the field of EMW absorption and the concentration of defects in the sample is controlled by changing the pyrolysis temperature. In addition, the unique molecular structure of p(C3O2)x enables the prepared samples to completely eliminate the interference of interfacial polarization and magnetic loss on EMW dissipation. The results show that the dielectric loss induced by defects significantly enhances the EMW absorption performance as the concentration of defects increases, but excessive defects lead to a sudden drop in the conductivity of the sample and reduce the EMW absorption performance. In which, the RLmin of OC-800 can reach −51.0 dB, and the EAB of OC-900 can go up to 5.6 GHz at only 1.6 mm. Finally, CST simulation verified the potential application of the prepared absorber in real scenarios. This work has improved the theoretical basis of the effect of defect-induced dielectric loss on EMW absorbing properties, and the simple synthetic raw materials and routes have made the industrialized production of highly efficient EMW absorbing materials possible.

Regulating the phase composition and microstructure of Fe3Si/SiC nanofiber composites to enhance electromagnetic wave absorption

The rational introduction of multi-components to fabricate electromagnetic wave absorbing (EMA) materials with synergistic conductive/dielectric/magnetic losses promises lightweighting and excellent EMA performance, but it remains a challenge. In this work, multicomponent Fe3Si/SiC nanofibre composites with network structure were constructed by electrostatic spinning method and in-situ carbothermal reduction strategy. Design of microstructures and multicomponent modulation by controlling the carbothermal reduction temperature. As a result, the presence of a large number of non-homogeneous interfaces, three-dimensional (3D) conductive network structures and defect structures in Fe3Si/SiC nanofibre composites induces a combination of multiple loss mechanisms that significantly improve the EMA performance. When the filling amount of Fe3Si/SiC in the paraffin transmission matrix is 20 wt%, the maximum effective absorption bandwidth (EABmax) of the fabricated material reaches 5.84 GHz with a thin thickness of 2.02 mm. Moreover, the minimum reflection loss (RLmin) value at 10.96 GHz is as low as −67.57 dB. Meanwhile, the radar cross-section (RCS) simulation verifies that the F-4 peak RCS is reduced to −30.37 dB in the range of −60°<θ < 60°. It indicates that the Fe3Si/SiC nanofiber composites have a good radar-wave dissipation capability in practical applications. In summary, the comprehensive performance of lightweight multicomponent Fe3Si/SiC nanofiber composites can meet the new application requirements and is expected to become an emerging multifunctional wave-absorbing material suitable for harsh environments.

Enhanced electromagnetic wave absorption performance of Ta₄C₃Tx MXenes with optimized interlayer spacing via hydrofluoric acid etching

Ta4C3Tx MXene, a novel two-dimensional material, shows significant application potential for electromagnetic wave (EMW) absorption because of its unique layered structure and high conductivity. In this study, hydrofluoric acid etching was used to obtain Ta4C3Tx MXenes with varying interlayer spaces by adjusting the etching duration, which enhanced the EMW absorption performance. The impact of interlayer spacing on the EMW absorption performance of Ta4C3Tx MXene was systematically evaluated for the first time. The results show that the sample etched with hydrofluoric acid for 48 h (S2-48 h) exhibited the best EMW absorption performance. For S2-48 h, the optimal reflection loss (RL) value was −33.53 dB at a frequency of 9.74 GHz and a thickness of 1.4 mm. In addition, the widest effective absorption bandwidth was 2.97 GHz (10.73–13.7 GHz), which was achieved at a frequency of 11.72 GHz and a thickness of 1.2 mm. This outstanding performance is mainly attributed to good impedance matching and multiple loss mechanisms induced by the etching process, including conduction loss, dipolar polarization, interfacial polarization, and multiple RLs. Furthermore, this research expands the application potential of two-dimensional MXene materials in EMW absorption.

Heterostructure engineering of N-doped Co@ carbon nanotubes toward broadband efficient electromagnetic absorption

The synergistic effect of magnetic loss and dielectric loss, as well as the reasonable construction of microstructure, have a significant effect on improving the absorption performance of electromagnetic wave absorbers. In this paper, N-doping Co@ carbon nanotubes (NCC) composites are successfully grown in situ on cobalt particles using a cobalt source as a catalyst. The metal particle Co is encapsulated within the carbon nanotubes and N is doped in the carbon lattice. This special structure introduces a large number of heterogeneous interfaces and defects, leading to optimized impedance matching and strong electromagnetic attenuation. The results showed that the minimum reflection loss is −69.33 dB for NCC800-1 with a thickness of 1.6 mm, and NCC900-4 possesses the widest effective absorption bandwidth of 7.70 GHz at a thickness of 2.1 mm with other NCC composites. Furthermore, the radar scattering cross section simulation results confirm that the prepared absorbing coatings can well suppress radar waves in different directions. The outstanding absorption performance is attributed to the defects and heterogeneous interfaces in the cobalt-catalyzed carbon nanofibers, the conductive network formed by carbon fibers, and the synergistic effects of magnetic and dielectric losses. This work presents a novel engineering approach for synthesizing absorbers with multiple loss mechanisms and heterogeneous structures, offering a promising pathway for the development of high-performance electromagnetic wave absorbing materials.

High-performance electromagnetic wave absorption in VS2@multi-walled carbon nanotube composites

In this work, composites comprising VS2 and multi-walled carbon nanotubes (MWCNTs) were prepared using a simple hydrothermal method. The MWCNTs were dispersed among the VS2 nanosheets, which produced dipole polarization and interfacial polarization, thus enhancing the dielectric loss. Meanwhile, the electrical conductivity of the composites gradually increased with the rising content of the MWCNTs, which improved the electromagnetic wave absorption performance. By adjusting the mass ratio of VS2 to MWCNTs to 5:1, a minimum reflection loss value (RL) of −24.7 dB was achieved with a thickness of only 1.3 mm at a frequency of 14.4 GHz. Besides, when the thickness was reduced to 1.2 mm, the effective absorption bandwidth extended to 3.75 GHz. The results suggest that impedance matching and the synergistic effect of multiple loss mechanisms contribute to the excellent electromagnetic wave absorption performance of the materials. Consequently, the VS2/MWCNTs composites exhibit simple synthesis, wide absorption bandwidth, thin thickness, and high absorption capacity, rendering them a promising material for practical microwave absorption applications.

Optimizing the electromagnetic wave attenuation properties of carbon encapsulated FeCoNiCuMnx high entropy alloy nanoparticles

With the advancement of wireless technology, there is a significant need for magnetic/carbon nanocomposites capable of absorbing electromagnetic waves across a wide frequency spectrum. However, designing these absorbers with uniformly distributed magnetic nanoparticles without agglomeration, to obtain optimal magnetic loss performance remains a significant challenge. In this work, FeCoNiCuMn alloy nanoparticles encapsulated in a graphitic C-shell have been successfully synthesized using metal-organic chemical vapor deposition. The incorporation of magnetic nanoparticles boosts magnetic loss, complementing dielectric loss to optimize electromagnetic waves attenuation, while the core/shell architecture further improves impedance matching. Moreover, adjusting the Mn contents enables the regulation of absorption performance in terms of thickness and working frequency. Thanks to their optimized impedance matching and multiple loss mechanisms, the FeCoNiCuMn0.5/C nanoparticles showcased outstanding attenuation capabilities. This included achieving a reflection loss of −52.30 dB at a thickness of 2.35 mm and an effective absorbing bandwidth covers 5.52 GHz at 2.0 mm. Moreover, the coatings containing FeCoNiCuMn0.5/C nanoparticles contributed to notable reductions in radar cross-section values, with the most significant reduction reaching up to 26.04 dBm2. This study highlights the potential practical application of FeCoNiCuMn nanoparticles encapsulated within a graphitic C-shell as highly efficient electromagnetic wave absorbing materials.

SiCnws/CNTs/Cf-C/SiOC composites with multi-scale lossy phases for simultaneous electromagnetic wave absorption and thermal insulation

Carbon fiber reinforced carbon-based composites are considered to be an ideal lightweight material with exceptional high-temperature mechanical performance. Nevertheless, their high conductivity result in a strong reflection rather than absorption of electromagnetic wave (EMW) for the stealth application. To address this challenge, a novel carbon-based composite made of multi-scale lossy phases (Carbon nanotubes (CNTs), SiC nanowires (SiCnws), and Carbon fiber (Cf)) and impedance matching phase (SiOC ceramic) was fabricated by the precursor-derived method. The prepared SiCnws/CNTs/Cf-C/SiOC (SCC-CS) composites exhibit an effective absorption (EAB) of 2.4 GHz at a thickness of 1.9 mm and a minimum reflection loss (RLmin) of −58.44 dB (99% absorption) in the X band. The EMW absorption of the composite is attributed to the multiple loss mechanisms and favorable impedance matching with free space, caused by the multi-conductive phase and SiOC in the composite. In addition, the fabricated composites also have thermal insulation properties and can effectively achieve radar cross-sectional (RCS) reduction, which are promising aerospace composites with the integration of structure and function.

Magnetic poly(ionic liquid)/graphene oxide/Fe3O4 composites with multiple loss mechanisms for microwave absorbing

Microwave-absorbing materials are very important to reduce electromagnetic interference and pollution. Combining multi-component materials with multiple loss mechanisms is a practical strategy for enhancing microwave absorption performance. In this work, we synthesize a magnetic poly(ionic liquid) (PVim[FeCl4]) with crosslinkable groups and prepare PVim[FeCl4]/graphene oxide (GO)/Fe3O4 composites by incorporating GO and Fe3O4 to enhance the microwave absorption property of the composites. The synergistic effect of GO and Fe3O4 is studied at different feeding ratios, the PVim[FeCl4]/10%GO/20%Fe3O4 composite shows better microwave absorption performance, with a minimum reflection loss (RLmin) of −49.54 dB at 17.31 GHz and 7.1 mm thickness, along with an effective absorption bandwidth (EAB) of 2.52 GHz. This enhancement can be attributed to the quarter-wavelength matching model, well-matched characteristic impedance, and multiple loss mechanisms originating from PVim[FeCl4], GO, and Fe3O4. The magnetic poly(ionic liquid) composites show promising prospects in microwave absorbing materials.

MOFs-derived 3D flower-like Y2O3/C microspheres with efficient electromagnetic wave absorption properties

Y2O3 has emerged as a promising material for electromagnetic wave (EMW) absorption due to its excellent dielectric properties. However, the inherent insulating nature and single loss mechanism limit its absorption performance. Research on the microstructure modulation and component regulation of Y2O3-based absorbers remains relatively unexplored. In this work, Y2O3/C composites with flower-like architectures were synthesized for the first time via a metal-organic framework (MOFs) templating method. The effects of pyrolysis temperature on the microstructure, phase composition, and EMW absorption performance of the Y2O3/C composites were systematically investigated. At a pyrolysis temperature of 800 °C, the flower-like Y2O3/C microsphere exhibited optimal EMW absorption performance. The minimum reflection loss (RL) of pristine Y2O3 was only −4.75 dB, while the Y2O3/C composite achieved a minimum RL of −51.77 dB and a maximum effective absorption bandwidth of 4.32 GHz. Moreover, by simply adjusting the matching thickness, the optimal sample exhibited strong absorption (RL < −30 dB) over a wide frequency range of 4–18 GHz. The incorporation of carbon effectively neutralized the insulating nature of Y2O3, thereby optimizing the impedance matching. The synergistic effects of multiple loss mechanisms, including polarization loss, resistance loss, and interfacial polarization, facilitated substantial EMW attenuation. This study provides a promising strategy for the design and fabrication of high-performance rare-earth oxide EMW absorbers with tunable morphologies and properties.

Synthesis of porous carbon-encapsulated MoxC/Co based on NaCl template and ZIF-67 towards enhancing electromagnetic wave absorption

Although molybdenum carbide (MoxC) has emerged as an effective absorber of electromagnetic (EM) waves, its practical application is hindered by impedance mismatch and single loss mechanism. Herein, we developed a one-step method for creating NaCl template precursors assembled with ZIF-67 to produce porous multiple components of MoxC composites. The MoxC-Co/C composites exhibit a minimum reflection loss (RLmin) of −59.69 dB with a bandwidth of 3.12 GHz at a thickness of 1.50 mm. The RLmin reaches −71.39 dB with a bandwidth of 4.08 GHz at a thickness of 2.09 mm. The flower-like MoxC-Co/C composites are capable of improving impedance matching and offering multiple loss mechanisms such as interfacial polarization, dipolar polarization, conductive loss and magnetic loss, resulting in enhanced EM wave absorption. Thus, our work featured a simple strategy to provide a unique insight into fabricating high-performance EM wave absorbers on molybdenum carbon basis.

Lightweight, flexible, heat resistant and thermal insulating aramid nanofiber/magnetic carbon nanotube interpenetrating network aerogel for microwave absorption in complex environments

Microwave absorbing (MA) materials used in complex environments not only need efficient MA performance, but also should have comprehensive properties of being lightweight, flexible, heat-resistant and insulating. Here, we grew CoFe2O4 nanoparticles (CFO NPs) in situ on oxidized carbon nanotubes (CNTs) by a wet chemical method. Oxidized CNTs limit the aggregation of CFO NPs and form rich heterogeneous interfaces. Then CNT@CFO was mixed with aramid nanofibers (ANFs) dispersions and prepared lightweight and flexible ANF/CNT@CFO interpenetrating network aerogels through a freeze-drying process. Under the action of multiple loss mechanisms, the ANF/CNT@CFO aerogel shows −53.2 dB of minimum reflection loss, and 4.76 GHz of effective absorption bandwidth (1.59 mm). Meanwhile, the composite aerogel inherits the high heat resistance of each component, with the quality and shape remaining stable below 400 °C, and TG5% occurs at 460 °C. In addition, effective MA properties can be maintained from room temperature to 300 °C. ANF/CNT@CFO is expected to become a MA material that can be used in complex environments.

Superior microwave absorption properties of carbon-coated FeSiCr micro flakes

Carbon-coated ferromagnetic alloys can protect from microwave radiation due to their tunable electromagnetic parameters and multiple loss mechanisms. We prepared carbon-coated flaky FeSiCr (FFSC@C) powders by the encapsulation and thermal decomposition of epoxy resin. The crystallization degree and thickness of carbon coating were tuned to optimize the microwave absorption of FFSC@C. The phase composition, morphology, magnetic properties, electromagnetic parameters, and microwave absorption properties of FFSC@C were comprehensively investigated. The oriented flaky FeSiCr possessed strong attenuation capacity, the amorphous carbon improved the impedance matching of flaky FeSiCr. The sample carbonized at 500 ℃, with the epoxy addition amount of 45 wt% exhibited a broad effective absorption bandwidth of 5.60 GHz at a thickness of 2.4 mm. Compared with other absorbents, the FFSC@C exhibited stronger absorption capacity at a lower thickness and filler loading in the X-band (8−12 GHz). This work demonstrated the facile fabrication of a high-performance carbon-coated ferromagnetic microwave absorber.

Ti3C2Tx/PANI/CoNi as a ternary composite material unveiling excellent microwave absorption performance

Ti3C2Tx MXene material exhibits exceptional dielectric properties and a distinct layered structure, making it a noteworthy microwave absorbing material. However, its microwave absorption performance is limited due to poor impedance matching and a single loss mechanism. To address these issues, this work develops a solvothermal method to introduce the magnetic component CoNi alloy and generate organic polymer PANI through in-situ polymerization, resulting in the preparation of Ti3C2Tx/PANI/CoNi ternary composites that significantly improve impedance matching and microwave absorption performance. The microwave absorption properties of the binary and ternary composites are compared, and the superior performance of the ternary composites is emphasized. Among the ternary composites, M-P-CN 3:1:8 exhibited an excellent microwave absorption performance, demonstrating a minimum RL value of −55.48 dB and an effective absorption bandwidth of 5.1 GHz at a thickness of 2.0 mm. The synergistic effect of multiple loss mechanisms, multilayer structures, and multiple interfacial polarization methods further contribute to the enhanced microwave absorption performance of ternary composites. This study provides a straightforward method for synthesizing and designing multi-component composite absorbing materials based on MXene.

Multi-interfaced Ni/C@RGO/PTFE composites for electromagnetic protection applications with high environmental stability and durability

To efficiently address the growing electromagnetic pollution problem, it is urgently required to research high-performance electromagnetic materials that can effectively absorb or shield electromagnetic waves. In addition, the stability and durability of electromagnetic materials in complex practical environments is also an issue that needs to be noticed. Therefore, the starting point for our problem-solving is how to endow magnetic/dielectric multi-interfaced composite materials with excellent electromagnetic protection capability and environmental stability. In this study, magnetic/dielectric multi-interfaced Ni/carbon@reduced graphene oxide/polytetrafluoroethylene (Ni/C@RGO/PTFE) composites were developed to utilize as excellent EWA (electromagnetic wave absorption) and EMI (electromagnetic interference) shielding materials. Due to their diverse heterogeneous interfaces, rich conductive networks, and multiple loss mechanisms, the Ni/C@RGO/PTFE composite exhibits an optimal reflection loss of −61.48 dB and an effective absorption bandwidth of 7.20 GHz, with a filler loading of 5 wt%. Furthermore, Ni/C@RGO/PTFE composite films have an optimal absorption effectiveness value of 9.50 dB and an absorption coefficient of 0.49. Moreover, Ni/C@RGO/PTFE can hold high EWA performance in various corrosive media and maintain more than 90% of EMI shielding effectiveness, which can be attributed to the carbon coating and PTFE matrix acting as dual protective barriers for the susceptible metal Ni, thus obviously improving the stability and durability of composites. Overall, this work presents an effective strategy for the growth of high-performance EWA and EMI shielding materials with outstanding environmental stability and durability, which have wide application prospects in the future.

Gradient Bi-layer coating for reducing energy consumption and improving electromagnetic wave dissipation: Elucidating the role of interfaces and interfacial polarization

The implementation of smart and logical design for absorbers, along with careful selection of components, has proven to be a successful strategy in creating efficient electromagnetic wave (EMW) absorbers. By utilizing novel nanocomposite materials that integrate various loss mechanisms, including enhanced magnetic and dielectric loss, multiple scattering and reflection, and polarization loss, the fabrication of a gradient bi-layer absorber holds great promise for superior EMW absorption. By employing chemical methods, a novel dielectric-magnetic compound comprising of Co2FeAl Heusler Alloy and MWCNTs@NiSe2 was produced. Subsequently, a gradient bi-layer absorber was developed using these components to optimize impedance matching and bolster low-frequency absorption. Abundant hetero-interfaces within this ternary bi-layer nanocomposite absorber give rise to Schottky junctions and heightened interfacial polarization between its layers, components, and matrix. Notably, the utilization of Co2FeAl Heusler Alloy nanoparticles has been shown to lead to the manifestation of magnetic loss phenomena due to their inherent magnetic properties. Through the strategic utilization of the unique layer structure, in conjunction with the incorporation of multiple loss mechanisms, the ternary bi-layer nanocomposite was able to achieve an impressive reflection loss value of -29 dB, despite having a mere 1.4 mm total thickness. Our study offers a fresh framework for creating innovative bilayer gradient absorbers suitable for low frequency applications.

Molten salt-directed synthesis of carbon nanotube/C3N4/manganese carbodiimide(MnNCN): Novel microwave absorbing materials

Owing to their potential functional performance, metal-substituted carbodiimides of the form M(NCN)x have attracted the attention of scholars. However, the application of these new functional materials in microwave absorption (MA) has rarely been reported. In this study, carbon nanotube (CNT)/C3N4/MnNCN (CCM) was prepared via a facile molten salt strategy (MSS) to develop efficient microwave absorbing materials. The morphology, components, and MA properties of CCM were systematically investigated. The results show that synthesized CCM has an excellent MA performance. Specifically, the effective absorbing bandwidth (EAB) and optimal MA performance of CCM were 5.48 GHz (12.32–17.8 GHz) and −57.7 dB, respectively. The unique structure, special magnetic properties of MnNCN, and multiple loss mechanisms promote the MA properties of CCM. Therefore, this study explored the application of M(NCN)x in the field of MA for the first time and expanded the research on the MSS in the MA field.