Multiple Jets Research Articles

Artificial intelligence control of flow separation from a curved ramp

This work aims to control flow separation from a two-dimensional curved ramp. The Reynolds number examined is Reθ = 5700 based on the momentum thickness of the turbulent boundary layer right before the ramp. Three steady jets, blowing tangentially along the ramp from three spanwise slits, are deployed at the most likely flow separation position, upstream and downstream of this position, respectively. Three different control modes are investigated, i.e., a single jet, multiple jets, and genetic algorithm-optimized blowing rates of three jets. The single jet placed at the time-averaged flow separation position is found to be most effective and efficient in eliminating flow separation among the first and second control modes. However, it is the third control mode that may not only eliminate the separation bubble completely but also cut down the energy consumption, by up to 30%, compared to the single jet blowing at the flow separation position. The flow physics underlying the control modes is also discussed.

Calculation of Single and Multiple Low Reynolds Number Free Jets with a Lattice-Boltzmann Method

Numerical calculations of low-Reynolds-number freejets with a Lattice Boltzmann Method are presented. The calculated-time-averaged axial velocity of a round jet with Re=1030 matches experimental data, including the length of transition from laminar to turbulent flow. Special care was needed for the inlet conditions in order to reproduce the vena contracta phenomenon. The results for round jets with Re=1000/1500/2000 show good agreement with Finite Difference Method calculations from the literature. In principle, there is a strong sensitivity to the inlet conditions, suggesting a need in future experimental work to measure in detail the velocity profiles and turbulence quantities at the nozzle outlet. The application of turbulence at the inflow boundary of the calculation domain is often used to emulate sources of disturbances in experiments. The present study demonstrates the need to investigate the impact of turbulence level and length scale at inlet independent of each other. Finally, the calculation for a bundle of nine jets with a square inlet led to the finding that the velocity decay of the central jet is maximal when the spacing between the jets is ca. one jet diameter.

Jets in cross-flow as wind barrier: Best performing cases and protection mechanism

The use of multiple jets in a cross-flow as wind barriers was proven in a previous study [Franco et al. (2022)]. This study continues the analysis by expanding the wind tunnel tests on twin jets in cross-flow configurations, providing a more detailed description of the leeward flow field of the jets and explaining the mechanism responsible for the good performance of the wind barrier. Hot-wire anemometer measurements were performed on a 324-node grid for 24 combinations of velocity ratios and distances between the jets. This study focuses on two cases characterized by their good performance as wind barriers.

Measurement of differential ZZ + jets production cross sections in pp collisions at s\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$ \\sqrt{s} $$\\end{document} = 13 TeV

Diboson production in association with jets is studied in the fully leptonic final states, pp → (Z/γ*)(Z/γ*) + jets → 2ℓ2ℓ′ + jets, (ℓ, ℓ′ = e or μ) in proton-proton collisions at a center-of-mass energy of 13 TeV. The data sample corresponds to an integrated luminosity of 138 fb−1 collected with the CMS detector at the LHC. Differential distributions and normalized differential cross sections are measured as a function of jet multiplicity, transverse momentum pT, pseudorapidity η, invariant mass and ∆η of the highest-pT and second-highest-pT jets, and as a function of invariant mass of the four-lepton system for events with various jet multiplicities. These differential cross sections are compared with theoretical predictions that mostly agree with the experimental data. However, in a few regions we observe discrepancies between the predicted and measured values. Further improvement of the predictions is required to describe the ZZ+jets production in the whole phase space.

Measurements of jet cross-section ratios in 13 TeV proton-proton collisions with ATLAS

Measurements of jet cross-section ratios between inclusive bins of jet multiplicity are performed in 140 fb−1 of proton-proton collisions with s=13 TeV center-of-mass energy, recorded with the ATLAS detector at CERN’s Large Hadron Collider. These ratios are constructed from double-differential cross-section measurements that are made in bins of jet multiplicity and other observables that are sensitive the energy scale and angular distribution of radiation due to the strong interaction in the final state. Additionally, the scalar sum of the two leading jets’ transverse momenta is measured triple differentially, in bins of the third jet’s transverse momentum and of jet multiplicity. These measurements are unfolded to account for acceptance and detector-related effects. The measured distributions are used to construct ratios of the inclusive jet-multiplicity bins, which have been shown to be sensitive to the strong coupling αS while being less sensitive than other observables to systematic uncertainties and parton distribution functions. The measured distributions are compared with state-of-the-art QCD calculations, including next-to-next-to-leading-order predictions for two- and three-jet events. These predictions are generally found to model the data well and perform best in bins with a modest requirement on the third jet’s transverse momentum. Significant differences between data and Monte Carlo predictions are observed in events with large rapidity gaps and invariant masses of the leading jet pair. Studies leading to reduced jet energy scale uncertainties significantly improve the precision of this work and are documented herein. © 2024 CERN, for the ATLAS Collaboration 2024 CERN

Baby’s first jets: a kinematic and hydrodynamic analysis of turning in cuttlefish hatchlings

AbstractTurning is an important aspect of life underwater, playing integral roles in predator avoidance, prey capture, and communication. While turning abilities have been explored in a diversity of adult nekton, little is currently known about turning in early ontogeny, especially for cephalopods. In this study, we investigated the turning abilities of hatchling common cuttlefish (Sepia officinalis, n = 49) and dwarf cuttlefish (Sepia bandensis, n = 30), using both kinematic and wake-based analyses. Using body tracking software and particle image velocimetry (PIV), we found that S. officinalis turned faster than S. bandensis, but both species completed equally tight turns. Orientation (arms-first or tail-first) did not have a significant effect on turning performance for either species. Cuttlefish hatchlings used multiple short jets for more controlled turning, with jet mode I (isolated vortex rings) being 3–4 times more common than jet mode II (elongated jets with leading ring structures) for both species. While both hatchlings turned more broadly than adult squid and cuttlefish, S. officinalis hatchlings turned faster than adult cuttlefish, and both hatchlings turned more tightly than other jet-propelled animals and some non-jet-propelled swimmers.

Investigating the Unsteady Dynamics of a Multi-Jet Impingement Cooling Flow Using Large Eddy Simulation

Abstract We investigate the unsteady behavior of an in-line jet impingement array of nine jets at a Reynolds number of 10,000 in a narrow channel subjected to a developing cross flow of up to 25% of the bulk jet velocity. To this end, we present an improved version of a previously published large eddy simulation (LES) now with resolved turbulence at the inflow boundaries. After a careful analysis of the transient behavior and statistical convergence of the LES, we discuss the time-averaged heat transfer characteristics of the configuration compared to numerical references of similar configurations. We then show how the large-scale unsteadiness increases from jet to jet. Both space-only and spectral proper orthogonal decompositions (POD and SPOD) are used to discuss the large-scale organization of single jets and multiple jets in combination. The latter shows a qualitative change in the unsteady behavior of the temperature footprint on the impingement wall with increasing cross flow.

Design, numerical optimisation and experimental validation of an innovative solar-powered tube heater with multiple air impingement jets

This research investigates a novel tube heater designed for the seamless integration of an innovative solar thermal system into the powder-based coating process to heat steel tube at a temperature of 240 °C. It incorporates a comprehensive numerical model developed and assessed using ANSYS FLUENT, concentrating on seven critical parameters that significantly influence the tube heater’s performance and size. These parameters include tube heater length, jets’ length, funnel height, Z/Djet, Y/Djet and X/Djet ratios, as well as jet diameter. The findings underline the critical role of tube heater length in enhancing heat transfer and maximising thermal efficiency, while reducing jet length and funnel height demonstrated negligible effects on thermal performance, promoting material economy. A lower Z/Djet ratio enhanced heat transfer uniformity, improving thermal performance, while optimal X/Djet and Y/Djet ratios were identified as 4 maintaining a balance between heat transfer rate and energy consumption. A smaller jet diameter proved beneficial since the potential core was not achieved, increasing heat transfer to the steel tubes. The experimental model, conducted to validate the novel tube heater’s performance, remarkably aligns with the numerical model, showing an R-squared value of 0.992. These results affirm the numerical setup’s accuracy and reliability in capturing the tube heater’s thermal behaviour. It is concluded that the novel tube heater stands as a highly efficient solution for the seamless integration of solar thermal systems into the powder-based coating process of steel tubes, promising significant emissions reduction.

Efficacy, non-target impacts, and costs of mechanical control options against a bioturbator in bivalve aquaculture

Bivalve aquaculture benefits from non-chemical, operational-scale pest management tools to sustain or increase production. Mechanical methods to control a bioturbating pest (burrowing shrimp Neotrypaea californiensis) have been tested in Washington State (USA), providing a roadmap for other regions affected by native or widespread pests. These shrimp smother and bury ground-cultured oysters on tidal flats even when the shrimp are at low densities. Therefore, control methods with high efficacy are required, also considering non-target effects and costs to implement. From 2002 to 2023, 55 mechanical control trials were carried out, plus two shell-addition trials from earlier research. Methods included: 1) surface barriers, 2) shrimp removal, 3) sediment disruption, and 4) physical conditions intended to cause direct mortality (e.g. electricity, heat). Data were compiled through a meta-analysis framework, in which effect size was calculated as the log response ratio of treated relative to reference plots. Most surface barriers were not effective because they were penetrated by shrimp or insufficiently anchored; an exception was application of five inches (12.7 cm) of gravel. Shrimp removal was effective with a water-jet technique developed to collect shrimp for bait at low tide, but efforts to deploy multiple jets with a towed mechanized device were unsuccessful. Sediment disruption through surface compaction was the most common farm-scale approach but insufficiently reduced shrimp densities, whereas consolidating sediment with vibration to 1 m depth had high efficacy but has been applied only in small plots. Effect sizes were not available for any field trials of direct mortality methods, but energy required to kill shrimp was calculated from laboratory studies (1–50 kW-hr m−3 in water, and higher energy required in saturated sediment). Across all field methods, efficacy improved with effort (person-hours per area). Sediment showed reduced penetrability and increased muddiness following treatment. Non-target effects on infauna included both positive and negative effect sizes, consistent with a community change following a reduction in shrimp density. In the six studies measuring epibenthic species, no overall positive response to control of shrimp occurred, even though the reason for control is to protect surface-dwelling species from bioturbation by shrimp. This outcome illustrates the importance of pairing efficacy in terms of reduction of shrimp and improvement of farming. The vertical position of N. californiensis below nearly a meter of water-saturated sediment, along with an innate tolerance to pressure and anoxia, has placed them out of reach of most attempted mechanical methods. Although progress has been made in recent years, mechanical control options remain limited that can be carried out without permits and that economically reduce shrimp to densities compatible with benthic shellfish aquaculture at a farm scale.

Numerical study of heat transfer and entropy generation in ribbed microchannel with nanofluid and multiple jet impingement

Due to the high miniaturization of electronic devices, there is an urgent need to eliminate high heat flux in electronic devices and improve their heat transfer characteristics. This article simulated the single-phase flow to study the effects of five different arrangements of column ribs and different volume concentration (1 %–5%) of nanofluids on the convective heat transfer coefficient, pressure drop, and the irreversibility of flow heat transfer in ribbed microchannel heat sinks with multiple jets impingement (MJI) within the Re range of 200–1000. The working coolants is deionized water and water - Al2O3 nanofluid. Different important parameters, such as the characteristic of heat transfer and flow, Performance Evaluation Criterion (PEC), and entropy generation are investigated. The results indicated that MJI III can effectively improve the convective heat transfer coefficient while the increase in pressure drop is not obvious. The PEC of MJI III is 1.408 at Re = 600, which is much higher than the other MJIs. Additionally, the cooling performance and irreversibility of water-Al2O3 nanofluid are superior to those of deionized water within the research scope. With the concentration, the irreversibility of flow and heat transfer of water-Al2O3 nanofluid increasing increases. The data shows that, the overall performance is optimal when φ = 1 %, and its highest PEC is 1.75 at Re = 400.

Flow and heat transfer analysis of submerged multiple synthetic jet impingement in a square channel with forced-flow

This study experimentally and numerically investigated the flow and heat transfer of submerged multiple synthetic jet impingement in forced crossflow in a square-section channel with a constant heat flux on the bottom surface. In the forced channel flow, effects on heat transfer of six synthetic jets placed diagonally in the main flow have four different amplitudes and six different frequencies at various Reynolds numbers (6000 ≤ Re ≤ 40000) were examined. Jets were submerged vertically into the main flow and their effects on heat transfer in the turbulent regime of the main flow were analyzed. Temperature measurements were made using thermocouples placed at the channel entrances and exits on the target surface. The Nusselt numbers (Nu) were calculated using the measured temperatures. The results indicate that at Re = 6000, the target surface temperature decreases significantly with increasing amplitude and frequency, and the effects of amplitude and frequency on surface temperatures decreased at increasing Reynolds numbers. It was observed that the THP values increased with increasing amplitude and frequency for all Reynolds numbers tested. For a constant jet parameter (Ao = 0.88 and Wo = 27), the highest THP was determined as 2.06 at Re = 6000.

Search for pair-produced vectorlike quarks coupling to light quarks in the lepton plus jets final state using 13 TeV pp collisions with the ATLAS detector

A search is presented for the pair production of heavy vectorlike quarks (VLQs) that each decay into a W boson and a light quark. This study focuses on events where one W boson decays into leptons and the other into hadrons. The search analyzed 140 fb−1 of pp collision data with s=13 TeV, recorded by the ATLAS detector from 2015 to 2018 during run 2 of the Large Hadron Collider. The final state is characterized by a high-transverse-momentum isolated electron or muon, large missing transverse momentum, multiple small-radius jets, and a single large-radius jet identified as originating from the hadronic decay of a boosted W boson. With higher center-of-mass energy and integrated luminosity than in the run 1 search, and improved analysis tools, this analysis excludes VLQs (Q) with masses below 1530 GeV at 95% confidence level for the branching ratio B(Q→Wq)=1, an improvement of 840 GeV on the previous ATLAS limit. © 2024 CERN, for the ATLAS Collaboration 2024 CERN

Search for dark mesons decaying to top and bottom quarks in proton-proton collisions at s\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$ \\sqrt{\ extrm{s}} $$\\end{document} = 13 TeV with the ATLAS detector

A search for dark mesons originating from strongly-coupled, SU(2) dark flavor symmetry conserving models and decaying gaugephobically to pure Standard Model final states containing top and bottom quarks is presented. The search targets fully hadronic final states and final states with exactly one electron or muon and multiple jets. The analyzed data sample corresponds to an integrated luminosity of 140 fb−1 of proton-proton collisions collected at s\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$ \\sqrt{s} $$\\end{document} = 13 TeV with the ATLAS detector at the Large Hadron Collider. No significant excess over the Standard Model background expectation is observed and the results are used to set the first direct constraints on this type of model. The two-dimensional signal space of dark pion masses mπD\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$ {m}_{\\pi_D} $$\\end{document} and dark rho-meson masses mρD\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$ {m}_{\\rho_D} $$\\end{document} is scanned. For mπD/mρD\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$ {m}_{\\pi_D}/{m}_{\\rho_D} $$\\end{document} = 0.45, dark pions with masses mπD\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$ {m}_{\\pi_D} $$\\end{document}< 940 GeV are excluded at the 95% CL, while for mπD/mρD\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$ {m}_{\\pi_D}/{m}_{\\rho_D} $$\\end{document} = 0.25 masses mπD\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$ {m}_{\\pi_D} $$\\end{document}< 740 GeV are excluded.

Study of heat transfer coefficients of multiple high-pressure fan-shaped water impinging on the lower surface of high-temperature steel billets

The lack of research on the boiling heat transfer coefficient on billet surfaces during the high-pressure fan-shaped water descaling process significantly affects the cooling, quality, and rolling efficiency of the billet surface. This paper utilizes the Eulerian multiphase flow model in Fluent 19.0 software to simulate the boiling heat transfer behavior of multiple high-pressure fan-shaped water jets impinging the surface of high-temperature steel billets during descaling. The study highlights the correlation between the boiling heat transfer coefficient and three key parameters: the Reynolds number, dimensionless target distance, and dimensionless temperature. The simulation’s accuracy was validated by comparing the simulation results against experimental data. Findings indicate that the boiling heat transfer coefficients were respectively higher in the stagnation area, the lower side of the overlap zone, and at the edges of the flow strands on the billet surface, reaching up to approximately 6000 W·m−2·K−1. Additionally, the heat transfer coefficients were higher in the downstream region compared to the upstream area. The boiling heat transfer coefficient increased by 13.7 % and 9.38 % as the Reynolds number increased from 278,031 to 340,486 and as the initial temperature increased from 1373.15 K to 1573.15 K, respectively. On the other hand, the boiling heat transfer coefficient decreased by 19.0 % when reducing the target distance from 20 de to 54 de. Finally, a function was established to describe the boiling heat transfer coefficient based on the Reynolds number, dimensionless target distance, and dimensionless temperature.

Jet-assisted membrane filtration and design application: A model for fouling removal area estimation

Membrane fouling remains a significant challenge in desalination and other membrane-based filtration processes. This study presents a novel force-balance model to accurately estimate the de-fouling area in jet-assisted filtration for in-situ fouling control. The model includes various design parameters, such as initial jet velocity, nozzle diameter, impinging angle, membrane pore size, membrane resistance, and permeate flux. The validation showed a strong correlation between theoretical predictions and experimental observations, with an R2 value of 0.97, indicating high predictive accuracy. Additionally, an empirical formula and design automation tools were developed to facilitate the configuration of jet filtration modules, enabling practical application of the findings. As a demonstration, the arrangement of multiple jets in a hollow fiber membrane module was optimized using the model, significantly improving microalgae filtration performance. The optimized jet configuration enhanced permeate flux by 236 % and reduced the specific energy consumption by 67 % compared to conventional setups. This research offers a framework for extending the application of jet-based fouling mitigation and cleaning in various membrane filtration systems, providing substantial improvements in efficiency and operational sustainability.

Searching for exclusive leptoquarks with the Nambu-Jona-Lasinio composite model at the LHC and HL-LHC

We present a detailed study concerning a new physics scenario involving four fermion operators of the Nambu-Jona-Lasinio type characterized by a strong-coupling ultraviolet fixed point where composite particles are formed as bound states of elementary fermions at the scale Λ=OTeV\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$ \\Lambda =\\mathcal{O}\\left(\ extrm{TeV}\\right) $$\\end{document}. After implementing the model in the Universal FeynRules Output format, we focus on the phenomenology of the scalar leptoquarks at the LHC and the High-Luminosity option. Leptoquark particles have undergone extensive scrutiny in the literature and experimental searches, primarily relying on pair production and, more recently, incorporating single, Drell-Yan t-channel, and lepton-induced processes. This study marks, for the first time, the examination of these production modes at varying jet multiplicities. Novel mechanisms emerge, enhancing the total production cross section. A global strategy is devised to capture all final state particles produced in association with leptoquarks or originating from their decay, which we termed “exclusive”, in an analogy to the nomenclature used in nuclear reactions. The assessment of the significance in current and future LHC runs, focusing on the case of a leptoquark coupling to a muon–c quark pair, reveals greater sensitivity compared to ongoing searches. Given this heightened discovery potential, we advocate the incorporation of exclusive leptoquark searches in future investigations at the LHC.

Calibration of a soft secondary vertex tagger using proton-proton collisions at s=13 TeV with the ATLAS detector

Several processes studied by the ATLAS experiment at the Large Hadron Collider produce low-momentum b-flavored hadrons in the final state. This paper describes the calibration of a dedicated tagging algorithm that identifies b-flavored hadrons outside of hadronic jets by reconstructing the soft secondary vertices originating from their decays. The calibration is based on a proton-proton collision dataset at a center-of-mass energy of 13 TeV corresponding to an integrated luminosity of 140 fb−1. Scale factors used to correct the algorithm’s performance in simulated events are extracted for the b-tagging efficiency and the mistag rate of the algorithm using a data sample enriched in tt¯ events. Several orthogonal measurement regions are defined, binned as a function of the multiplicities of soft secondary vertices and jets containing a b-flavored hadron in the event. The mistag rate scale factors are estimated separately for events with low and high average numbers of interactions per bunch crossing. The results, which are derived from events with low missing transverse momentum, are successfully validated in a phase space characterized by high missing transverse momentum and therefore are applicable to new physics searches carried out in either phase space regime. © 2024 CERN, for the ATLAS Collaboration 2024 CERN

Analyze the influence of nozzle shape and orientation on inline arrangement of multiple jets impingement on a concave surface

ABSTRACT The present study reports the thermal behavior of multiple jets on a hot concave surface with different nozzle geometries such as circular and elliptical and different orientation. Tests are performed with five different nozzles at different values of nondimensional nozzle to surface distance (z/d = 2–10) and Reynolds number (5000–28,000). Here, the parameter coefficient of variation (COV) is used to estimate the non-uniformity in the local Nu variation. For N-2, the value of CO V y , non − dim is found to be 50–60% higher compared to N-3 at z/d = 2; while at z/d ≥ 8, for N-3, the value of CO V y , non − dim is found to be 10–15% higher compared to N-2. The higher temperature uniformity ( CO V x , non − dim ) is noted in the fountain region compared to impingement region for the circular and elliptical nozzles. The thermal performance of elliptical jets is found to be sensitive toward the jet orientation at lower z/d values. The magnitude of temperature non-uniformity decreases with the increase in the z/d values. Among the tested nozzles, Nozzle N-2 consistently demonstrates superior performance across all nozzle-to-plate distances and with an increase in the z/d value improvement with nozzle N-2 reduces.

Pileup density estimate independent on jet multiplicity

The hard-scatter processes in hadronic collisions are often largely contaminated with soft background coming from pileup in proton-proton collisions, or underlying event in heavy-ion collisions. There are multiple methods to remove the effect of pileup for jets. Two such methods, Area Subtraction and Constituent Subtraction, use the pileup density as the main ingredient to estimate the magnitude of pileup contribution on an event-by-event basis. The state-of-the-art approaches to estimating pileup density are sensitive to the number of hard-scatter jets in the event. This paper presents a new pileup-density estimation method that minimizes the sensitivity on the presence of hard-scatter jets in the event. Using a detector-level simulation, we provide a comparison of the new method with the state-of-the-art estimation methods. We observe a significantly lower bias for the estimated pileup density when using the new method. We conclude that the new method has the potential to significantly improve pileup mitigation in proton-proton collisions or the underlying event subtraction in heavy-ion collisions.

Integrated Experiment-Theory Framework for Studying Mass Transport Effects in Electrochemical CO2 Reduction on Copper

Electrochemical carbon dioxide reduction (eCO2R) has emerged as a promising approach to produce high-value fuels and chemicals using renewable energy sources. In particular, Cu catalysts can convert CO2 to a wide range of hydrocarbon and oxygenate products, including CO, formate, ethanol and ethylene. However, the activity and selectivity of eCO2R is highly dependent on mass transport and the corresponding reaction microenvironment present under operating conditions. In this talk, we present an integrated framework that combines experiments with computational fluid dynamics (CFD) and density functional theory (DFT) based microkinetic modeling to predict the effect of varying mass transport on eCO2R in a custom-designed flow cell. The flow cell is designed with multiple electrolyte jets impinging onto the electrocatalyst surface for rapid and homogeneous reactant transport. We first demonstrate the effect of mass transport in a flow cell architecture by controlling the flow rate of CO2-saturated 0.1 M KHCO3 to a Cu electrocatalyst. Significant increases in the production rates of formate and CO are observed with increasing flow rate, as well as an enhancement in multi-carbon products at high overpotentials. Increasing flow rate promotes hydrogen evolution at low overpotentials but has little effect at large overpotentials, suggesting a transition from HCO3 - to water as the dominant proton donor with increasing overpotential. CFD simulations are employed to model the distribution of boundary layer thicknesses within the flow cell, which subsequently set the boundary conditions for the coupled 1D transport-microkinetic model. The calculated boundary layer thickness values are corroborated by experimentally measured transport-limited currents. Our model successfully predicts experimentally observed trends in selectivity with mass transport, such as an increase in the production of ethylene and ethanol at high flow rates due to enhanced CO2 transport. The slight suppression of hydrogen reduction at higher flow rates due to an increase in *CO coverage is also predicted and supported by experimental results. This work demonstrates the importance of incorporating transport processes in the CFD-DFT coupled modeling of device performance for electrochemical CO2 reduction.This work was performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344. LLNL release number: LLNL-ABS-857566.