In this paper, the phase composition of steel alloyed additionally with aluminum, nitrogen, titanium after deformation and heat treatment of steel is analyzed. The purpose of this work is to determine the phase composition of steel alloyed additionally with aluminum, nitrogen, titanium, the phase forming sequence during crystallization, morphology of multilayer inclusions. Research methods: Microstructural, X-ray microanalysis and X-ray diffraction analyses are used to determine the structural state of alloys. Research results: It is shown that during additional doping after crystallization the formation of multilayer inclusions, oxides, nitrides and carbonitrides occurs. It is testified that during the crystallization of steel the multiphase inclusions, in the center of which there is a metastable oxide (Al, Ti)2(O, N)3 surrounded by nitride (Ti, Fe) N, are formed from the melt. After further heating of the steel to a temperature of (1 533±10) K and hot plastic deformation with a degree of 50 % (HPD), the oxide (Al, Ti)2(O, N)3 is not revealed in the steel as a structural component. In the center of the multilayer inclusions the phase (Ti, Al) N surrounded by titanium nitride (Ti, Fe) N is observed. After heating and exposure at (1 123±10) K, individual inclusions of titanium nitride TiN, (Ti, Fe) N are observed.