Multilayer Hyperbolic Metamaterials Research Articles

Data-driven design of multilayer hyperbolic metamaterials for near-field thermal radiative modulator with high modulation contrast

The thermal modulator based on the near-field radiative heat transfer has wide applications in thermoelectric diodes, thermoelectric transistors, and thermal storage. However, the design of optimal near-field thermal radiation structure is a complex and challenging problem due to the tremendous number of degrees of freedom. In this work, we have proposed a data-driven machine learning workflow to efficiently design multilayer hyperbolic metamaterials composed of α-MoO3 for near-field thermal radiative modulator with high modulation contrast. By combining the multilayer perceptron and Bayesian optimization, the rotation angle, layer thickness and gap distance of the multilayer metamaterials are optimized to achieve a maximum thermal modulation contrast ratio of 6.29. This represents a 97 % improvement compared to previous single layer structure. The large thermal modulation contrast is mainly attributed to the alignment and misalignment of hyperbolic plasmon polaritons and hyperbolic surface phonon polaritons of each layer controlled by the rotation. The results provide a promising way for accelerating the designing and manipulating of near-field radiative heat transfer by anisotropic hyperbolic materials through the data-driven style.

Enhanced Förster resonance energy transfer on layered metal-dielectric hyperbolic metamaterials: an excellent platform for low-threshold laser action.

Förster resonance energy transfer (FRET) is a well-known physical phenomenon, which has been widely used in a variety of fields, spanning from chemistry, and physics to optoelectronic devices. In this study, giant enhanced FRET for donor-acceptor CdSe/ZnS quantum dot (QD) pairs placed on top of Au/MoO3 multilayer hyperbolic metamaterials (HMMs) has been realized. An enhanced FRET transfer efficiency as high as 93% was achieved for the energy transfer from a blue-emitting QD to a red-emitting QD, greater than that of other QD-based FRET in previous studies. Experimental results show that the random laser action of the QD pairs is greatly increased on a hyperbolic metamaterial by the enhanced FRET effect. The lasing threshold with assistance of the FRET effect can be reduced by 33% for the mixed blue- and red-emitting as QDs compared to the pure red-emitting QDs. The underlying origins can be well understood based on the combination of several significant factors, including spectral overlap of donor emission and acceptor absorption, the formation of coherent closed loops due to multiple scatterings, an appropriate design of HMMs, and the enhanced FRET assisted by HMMs.

Effect of geometry, anisotropy and composition on the third-order optical nonlinearities of multilayer hyperbolic metamaterials -INVITED

Quantum technologies require advanced optical metamaterials whose properties can be tailored and controlled as desired. Hyperbolic metamaterials have great potential for applications in nonlinear nanophoton-ics, such as all-optical switching, optical limiting, mode-locking and optical sensing. In this work, we show how to obtain strong third-order optical nonlinearities in hyperbolic multilayers exploiting the effect of bulk plas-mon polaritons. We demonstrate the tunability of these properties with angle and polarization, and we propose a model to predict them. We evidence the enhancement of the nonlinear response in low-loss metamaterials.

Deep‐Subwavelength Optical Spin Textures in Volume Plasmon Polaritons with Hyperbolic Metamaterials

AbstractHyperbolic metamaterials can support extremely high‐k wavevectors, also known as volume plasmon polaritons, with highly directional propagation and light confinement to deep‐subwavelength scales. The number of high‐k modes has an inverse relationship with the overall thickness of hyperbolic metamaterials. Here, the optical spin textures from high‐k mode polaritons on the surface of silica–silver multilayer hyperbolic metamaterials are studied. The results demonstrate that with an increase in the overall thickness, the spin texture changes from a twisted structure to a Néel‐type photonic skyrmion, due to the decrease in the number of high‐k modes. Moreover, the size of a single photonic skyrmion is less than 1/2 of the light wavelength, and the full width at half maximum of the spin angular momentum is less than 1/9 of the light wavelength. This work is expected to facilitate new applications of hyperbolic metamaterials, such as spin‐dependent excitation and detection devices at the deep‐subwavelength level.

Coupling plasmon-waveguide resonance and multiple plasma modes in hyperbolic metamaterials for high-performance sensing

A sensor based on plasmon-waveguide resonance (PWR) exhibits an impressive narrow linewidth and has attracted extensive attention in plasmon label-free sensing. However, the low surface electric field intensity limits the detection ability of biomolecules, where the refractive index changes are restricted at the sensor surface. In this study, we study the coupling of PWR and multiple plasma modes in a hyperbolic metamaterial (HMM), combining narrow linewidth and electric field enhancement advantages. The PWR-HMM sensor includes a gold film, lossless dielectric layer, and metal/dielectric multilayer HMM array composed of 2-layer Au/Al2O3 stacks. The evanescent field of PWR is used to excite multiple plasma modes in the HMM. The figure of merit of the proposed structure reaches 5417/RIU owing to the existence of lossless dielectric layer, which is 11.7 times than the conventional gold film structure. The maximum bulk sensitivity of the PWR-HMM sensor was 43 000 nm/RIU. In comparison with PWR, the surface electric field intensity and the surface sensitivity of PWR-HMM increase by four and two times, respectively. Furthermore, comparing the sensing performance of the PWR-HMM sensor and PWR-nanoparticle (NP) sensor (coupling PWR and localized surface plasmon resonance), it was found that PWR-HMM has 20% higher surface sensitivity than the PWR-NP. A sensing mechanism coupling PWR and multiple plasma modes in the HMMs opens a gate to significantly improve the PWR sensors performance, which is expected to be used to resolve urgent issues in biological, medical and clinical applications.

Bulk Plasmon Polariton Modes in Hyperbolic Metamaterials for Giant Enhancement of the Transverse Magneto-Optical Kerr Effect.

We demonstrate a concept for the giant enhancement of the transverse magneto-optical Kerr effect (TMOKE) using bulk plasmon polariton (BPP) modes in non-magnetic multilayer hyperbolic metamaterials (HMMs). Since the BPP modes are excited through the attenuated total reflection (ATR) mechanism, using a Si-based prism-coupler, we considered a single dielectric magneto-optical (MO) spacer between the prism and the HMM. The working wavelength was estimated, using the effective medium approach for a semi-infinite dielectric-plasmonic multilayer, considering the region where the system exhibits type II HMM dispersion relations. Analytical results, by means of the scattering matrix method (SMM), were used to explain the physical principle behind our concept. Numerical results for giant TMOKE values (close to their maximum theoretical values, ) were obtained using the finite element method (FEM), applying the commercial software COMSOL Multiphysics. Our proposal comprises a simple and experimentally feasible structure that enables the study of MO phenomena in HMMs, which may find application in future nanostructured magnetoplasmonic metamaterials for active nanophotonic devices.

Highly Q-factor refractive index sensor based on graphene stack

The perfect absorber with high figure of merit (FOM) and sensitivity for mid-infrared application is developed in this study. The structure contains a nanoaperture as a resonator and multi-layer hyperbolic metamaterial of graphene-SiN is place under the nanoaperture to increasing the absorption. The results show how the chemical potential of graphene can improve the absorbance. Finally, a coat of SiO2 is pinpointed over the nanoaperture for enhance the absorption and protecting the surface. The proposed aperture is designed symmetrically based on crossed shape to reduce the polarization effects on sensing. The Q-factor has increased sharply to 3000 for the final device by utilizing the hyperbolic material structure. The left-hand characteristic of the hyperbolic metamaterial provides a condition for concentrating the surface Plasmon’s at the interface of the gold layer with the substrate, leading to the reflection reduction to − 46 dB. This absorber is considered as an optical sensor for various materials under test (MUT) in the optical spectrum and it is simulated by FIT method as a time-domain technique. This sensor has a sensitivity of 400 nm/RIU and the FOM of 89000 RIU−1.

Electromagnetic energy density in hyperbolic metamaterials

We present the theory of electromagnetic energy propagation through a dispersive and absorbing hyperbolic metamaterial (HMM). In this way, the permittivity tensor components of HMM (especially, nanowire HMM) may appear to be hopeless, but as a non-trivial step, we find that they can be cast into more transparent forms. We find under the influence of an electromagnetic wave, the responses of nanowire HMM (multilayer HMM) in the directions perpendicular to and parallel to the optical axis are similar to those of Lorentz (Drude) and Drude (Lorentz) media, respectively. We obtain simple expressions for the electromagnetic energy density formula of both typical structures of HMMs, i.e., nanowire and multilayer HMMs. Numerical examples reveal the general characteristics of the direction-dependent energy storage capacity of both nanowire and multilayer HMMs. The results of this study may shed more physical insight into the optical characteristics of HMMs.

Achieving super resolution lithography based on bulk plasmon polaritons of hyperbolic metamaterials

In this paper, we study the properties of hyperbolic dispersive metamaterial filter-transmitted bulk plasmons (BPs) composed of Al/poly 4-methyl-pentene (TPX) multilayers and analyze the interference lithography model based on this multilayer structure. With a high-order passband optical transfer function (OTF) window by optimizing the structural parameters according to rigorous coupled wave theory, the diffracted light after high-pass filtering can be used for super-resolution interference lithography. When the incident light with a wavelength of 363.8 nm is incident on the Cr mask grating with a period of 145 nm, according to the diffraction equation of the grating, it mainly transmits the diffracted wave of ±2.7k0, and then the half period of the lithography formed by the hyperbolic metamaterial (HMM) in the photoresist is 32.7 nm (∼λ/11.12). Furthermore, we investigate the effects of metal thickness, dielectric thickness, and period logarithm of the multilayer HMM on OTF and lithography performance. And it shows that after optimizing OTF, it is feasible to achieve deeper resolution to 23.4 nm (∼λ/15.5) formed by a diffracted wave of ±5k0. The research content in this paper contributes to the realization of simple and economical fabrication of nanostructures such as large-area laser interference lithography.

Plasmon mode manipulation based on multi-layer hyperbolic metamaterials.

Metamaterial with hyperbolic dispersion properties can effectively manipulate plasmonic resonances. Here, we designed a hyperbolic metamaterial (HMM) substrate with a near-zero dielectric constant in the near-infrared region to manipulate the plasmon resonance of the nano-antenna (NA). For NA arrays, tuning the equivalent permittivity of HMM substrate by modifying the thickness of Au/diamond, the wavelength range of plasmon resonance can be manipulated. When the size of the NA changes within a certain range, the spectral position of the plasmon resonance will be fixed in a narrow band close to the epsilon-near-zero (ENZ) wavelength and produce a phenomenon similar to "pinning effect." In addition, since the volume plasmon polaritons (VPP) mode is excited, it will couple with the localized surface plasmon (LSP) mode to generate a spectrum splitting. Therefore, the plasmon resonance is significantly affected and can be precisely controlled by designing the HMM substrate.

Electromagnetic forces in nanoparticles made of multilayer hyperbolic metamaterials

We theoretically study the electromagnetic forces (optical gradient force, optical torque and vacuum friction) acting on a spherical anisotropic nanoparticle, which can be characterized by multilayer hyperbolic metamaterials (mHMMs). We find three important results about these forces: (i) Firstly, we theoretically demonstrate that the optical gradient force produced on a mHMMs nanoparticle can be flexibly tuned, from pushing the particle to pulling it, just via changing incident angle of illuminating plane light wave. (ii) Secondly, we find the optical torque acting on the mHMMs nanoparticle (its filling factor is around 0.3) can be tuned between positive and negative via changing the incident angle of circularly polarized plane light. Therefore, the rotating mHMMs nanoparticle with designed filling factor can be accelerated or decelerated by the optical torque. (iii) Finally, due to the large fluctuations of dipole polarizability of mHMMs nanoparticle with appropriate filling factor, we propose a new method to obtain the large enhancement of vacuum friction torque by designing the filling factor of the rotating mHMMs nanoparticle.

Nanostructured multilayer hyperbolic metamaterials for high efficiency and selective solar absorption.

Highly efficient solar-to-thermal conversion is desired for the renewable energy technologies, such as solar thermo-photovoltaics and solar thermo-electric systems. In order to maximize the energy conversion efficiency, solar-selective absorbers are essential with its absorption characteristics specially tailored for solar applications. Here, we propose a wideband spectral-selective absorber based on three-dimensional (3D) nanostructured hyperbolic metamaterial (HMM), which can realize near-unity absorption across the UV and NIR spectral ranges. Moreover, the optical topological transition (OTT) of iso-frequency surface (IFS) is manipulated to selectively enhance light absorption in the entire solar spectrum, crucial for improved energy utilization. Impressive solar-to-thermal conversion efficiency of 95.5% has been achieved. Particularly, such superior properties can be retained well even over a wide range of incident angles. These findings open new avenues for designing high-performance solar thermal devices, especially in the fields related to solar energy harvesting.

Highly efficient SERS substrates with different Ag interparticle nanogaps based on hyperbolic metamaterials

Surface-enhanced Raman scattering (SERS) substrates based on Hyperbolic metamaterials (HMM) have received tremendous attention due to the presence of confined optical modes, i.e., the surface plasmon polaritons (SPP) and bulk plasmon polaritons (BPP). In the present study, a multilayer HMM SERS substrate was fabricated, comprising a monolayer of silver nanoparticles (Ag NPs) and Au-Al2O3 films. Our study demonstrates that the Ag NPs layer excited SPP and BPP, and the localized surface plasmon (LSP) resonance of the Ag NPs layer coupled with BPP, creating a strong electromagnetic field at the interparticle gaps of the Ag NPs. Interestingly, increasing the multilayer stacking of HMM will strengthen the SERS activity until a certain threshold. On the top of HMM, the interparticle gaps of the Ag NPs were adjusted to enhance the SERS characteristics and the maximum EF appeared at the gap of 10 nm. Performing theoretical simulations as well as experiments, the ultra-sensitivity, good reproducibility, reusability, and high enhancement factor of the proposed SERS substrate were assessed. Lastly, the ultralow limits of detection for melamine in milk were 10−7 M, satisfying the needs for successful implementation in the food safety field.

Design and Research of Enhanced LED Performance Based on Graphical Substrate with Multilayer Hyperbolic Metamaterials

This paper mainly studies the influence of multilayer hyperbolic metamaterials (HMMs) with different structural parameters on the intensity of spontaneous radiation of quantum wells, thereby improving the coupling efficiency of incident electromagnetic waves and free electrons on metal nano-surfaces. In this paper, numerical simulations of visible light bands of 450–700 nm of Ag, Au, and Cu thin films are performed. The local field enhancements of multilayer HMMs with different shapes are compared, and it is found that circle Ag/Si multilayer HMMs have stronger field enhancement effects than other structures. At the same time, Purcell analysis was performed by changing various parameters of multilayer HMMs. It is found that the thickness of the metal/dielectric layer, the distance between the dipole and the HMMs, and the length of the multilayer HMMs change the intensity of the plasmon resonance radiation and have a great impact on the position of the resonance wavelength.

Composite Structure Based on Gold-Nanoparticle Layer and HMM for Surface-Enhanced Raman Spectroscopy Analysis.

Hyperbolic metamaterials (HMMs), supporting surface plasmon polaritons (SPPs), and highly confined bulk plasmon polaritons (BPPs) possess promising potential for application as surface-enhanced Raman scattering (SERS) substrates. In the present study, a composite SERS substrate based on a multilayer HMM and gold-nanoparticle (Au-NP) layer was fabricated. A strong electromagnetic field was generated at the nanogaps of the Au NPs under the coupling between localized surface plasmon resonance (LSPR) and a BPP. Additionally, a simulation of the composite structure was assessed using COMSOL; the results complied with those achieved through experiments: the SERS performance was enhanced, while the enhancing rate was downregulated, with the extension of the HMM periods. Furthermore, this structure exhibited high detection performance. During the experiments, rhodamine 6G (R6G) and malachite green (MG) acted as the probe molecules, and the limits of detection of the SERS substrate reached 10−10 and 10−8 M for R6G and MG, respectively. Moreover, the composite structure demonstrated prominent reproducibility and stability. The mentioned promising results reveal that the composite structure could have extensive applications, such as in biosensors and food safety inspection.

Few-layer metamaterials for a spontaneous emission enhancement.

Multilayer hyperbolic metamaterials consisting of alternating metal and dielectric layers have important applications in spontaneous emission enhancement. In contrast to the conventional choice of at least dozens of layers in multilayer structures to achieve tunable Purcell effect on quantum emitters, our numerical calculations reveal that multilayers with fewer layers and thinner layers would outperform in the Purcell effect. These discoveries are attributed to the negative contributions by an increasing layer number to the imaginary part of the reflection coefficient and the stronger coupling between surface plasmon polariton modes on a thinner metal layer. This work could provide fundamental insights and a practical guide for optimizing the local density of optical states enhancement functionality of layered metamaterials.

Influence of Nonlocality on Transmittance and Reflectance of Hyperbolic Metamaterials

In this paper we investigate transmittance and reflectance spectra of multilayer hyperbolic metamaterials in the presence of strong spatial dispersion. Our analysis revealed a number of intriguing optical phenomena, which cannot be predicted with the local response approximation, such as total reflectance for small angles of incidence or multiple transmittance peaks of resonant character (instead of the respective local counterparts, where almost complete transparency is predicted for small angles of incidence and the broad-angle transparency can be observed within a range of larger angles of incidence). We believe that the observed effects may serve as a working principle in a number of new potential applications, such as spatial filtering, biosensing, or beam steering.

Correction to: Perfect Narrowband Absorber Based on Patterned Graphene-Silica Multilayer Hyperbolic Metamaterials

Correction to: Perfect Narrowband Absorber Based on Patterned Graphene-Silica Multilayer Hyperbolic Metamaterials

Perfect Narrowband Absorber Based on Patterned Graphene-Silica Multilayer Hyperbolic Metamaterials

Graphene-based hyperbolic metamaterials are well known for their optical anisotropy, high absorption of electromagnetic radiation, and low energy loss. We proposed a novel multilayer graphene-silica hyperbolic metamaterial designed as a grating structure providing narrowband near-perfect absorption of radiation in a mid-infrared band. The absorber is designed for insensitivity of the absorptance peak positioning on the angle of the incident radiation and distinct polarization selectivity of absorption for the TM mode only. A new way of handling the absorption is achieved by varying the thickness of its combined graphene-silica layers. Possibly, the type of absorber will be applicable in the fields of optical sensing, photoelectric detection, and other potential fields.

Magnetically Tunable Near-Field Radiative Heat Transfer in Hyperbolic Metamaterials

Active control of radiative heat transfer still remains open due to its exciting application potential. In view of this, we present a theoretical demonstration of dynamically tunable near-field radiative heat transfer (NFRHT) between two multilayer hyperbolic metamaterials (consisting of alternating layers of a magneto-optical (MO) material and a dielectric) using an external magnetic field. We show that magnetization-induced hyperbolic modes play a significant role in radiative heat transfer and allow a highly tunable heat flux. Moreover, the hybridization of intrinsic and magnetization-induced hyperbolic modes significantly enhances the radiative heat transfer. In particular, we find that polarization conversion due to nonzero off-diagonal elements enables the spectral heat transfer coefficient for the TE polarization to be as large as that for the TM polarization, which is vastly different from the case of two closely spaced bulk MO plates. In addition, to quantitatively characterize the thermal modulation, we show a negative thermal magnetoresistance effect in this system, which approaches $\ensuremath{-}59.6\mathrm{%}$ when the magnetic field intensity reaches 10 T. Our findings may be beneficial for active noncontact thermal management at the nanoscale, and facilitate a deeper understanding of the mechanisms of MO hyperbolic metamaterials in terms of NFRHT.