Prefabricated steel structures are being promoted in China as an important measure to reduce building carbon emissions (CEs). Currently, high-quality carbon emission factors and calculation methods that identify the sources of CEs from construction process are lacking. This study proposed a process-based method for calculating on-site construction CEs and empirically demonstrated its feasibility using a case of a multistory steel structure with typical column-beam systems. Six construction processes comprising 38 subprocesses were first categorized, then the energy and materials consumed for each subprocess were determined to obtain the first-hand CE parameters. The CEs from hoisting the first- and second-section columns were 10.52 kgCO2/column and 14.41 kgCO2/column, respectively, and the CEs from their installation were in the range 38.16–69.18 kgCO2/column. The CEs from hoisting the primary and secondary beams using a car crane were 7.73 kgCO2/beam and 4.52 kgCO2/beam, respectively, with lower CEs of 2.40 kgCO2/beam and 2.22 kgCO2/beam, respectively when a tower crane was used for hoisting. The 14 connection types used to install the primary beams and the 11 connection types used to install the secondary beams had CEs of 13.84–125.96 kgCO2/beam and 10.39–43.49 kgCO2/beam, respectively. The total on-site construction CE was subsequently calculated by summing the CEs from each process. This method was able to track the CE sources for each construction process and their contributions to identify those with high CE intensities. In addition, the case study was evaluated to provide specific feedback on the current national standard for calculating CEs from building construction.
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