Multi-stage Evolution Research Articles

Multi-stage evolution characteristics and particle size effect of sandstone granules subjected to cyclic loads

Broken granules of different sizes and poor bearing capacities produced by repeated mining of coal seams contribute to natural disasters, such as rock strata movement. In this study, mechanical tests were performed on broken sandstone granules to explore their compaction and recrushing characteristics under repeated mining. The change characteristics of the relevant mechanical parameters of sandstone granules with different particle sizes and changes in energy density were examined, and compaction and recrushing mechanisms of sandstone granules under cyclic loading were identified. The results show that an increase in the initial particle size of sandstone granules has a significant effect on the increase in the strain under load. The cumulative dissipation energy corresponding to final crushing was greater for granules with larger initial sizes. The particle size of sandstone was found to be proportional to the fractal dimension after compaction and crushing. The probability of granular particles with larger initial particle sizes being broken into smaller particles is greater, resulting in the porosity attenuating most rapidly during the stress loading process of granular particles under repeated mining. Therefore, the degree of sample breakage was relatively severe. Particles were rearranged after compaction and crushing. Repeated mining results in dynamic evolution of the pore compaction, deformation, and fractur of the rock mass, as well as stable recombination. The study results provide important theoretical support for understanding of the movement mechanism of rock strata in the goaf under repeated mining.

The Middle-Late Permian Yakshawa and Late Cretaceous Daresard bauxite deposits, western Iran: Elemental deportment, parental affinities and genesis of REY minerals

The Middle-Late Permian Yakshawa bauxite deposit in the Sanandaj-Sirjan Zone and the Late Cretaceous Daresard bauxite deposit in the Zagros Fold-Thrust Belt have bauxite ores with different textures and mineralogical compositions. The presence of detrital and authigenic REY-phosphates, fluorocarbonates of the bastnasite group, and cerianite with diverse generations reflect an intricate formation process of the REY-bearing minerals in these two deposits. This clearly shows that the studied deposits have a multi-stage evolution including diagenetic and/or low-grade metamorphic, in situ fluid-assisted dissolution–reprecipitation reactions, and later bauxitization. The high abundance of monazite, textural relationships, and its LREE pattern indicate this mineral is the main LREE reservoir in the studied bauxite ores whereas xenotime, both authigenic and detrital, is the main host for HREE. The R-mode factor analyses indicates that the bauxitization process induces, at large, similar interelemental relationships in the studied deposits involving the attitude of Al oxyhydroxides, Ti oxides, and Fe oxyhydroxides to concentrate critical metals and the capability of REY-phosphate of being the main reservoir of REE + Y. As for provenance, the Eu/Eu*, Sm/Nd, and Nb/Ta proxies suggest that the bauxite ores of the Yakshawa deposit have a genetic relationship with Middle-Late Permian mafic volcanic rocks, whereas the ores of the Daresard deposit show parental affinity with the underlying fine-grained clayey limestone of the Sarvak Formation.

Hypogene Alteration of Base–Metal Mineralization at the Václav Vein (Březové Hory Deposit, Příbram, Czech Republic): The Result of Recurrent Infiltration of Oxidized Fluids

The Václav vein (Březové Hory deposit, Příbram ore area, Czech Republic) is a base–metal vein containing minor Cu-Zn-Pb-Ag-Sb sulfidic mineralization in a usually hematitized gangue. A detailed mineralogical study using an electron microprobe revealed a complicated multistage evolution of the vein. Early siderite and Fe-rich dolomite were strongly replaced by assemblages of hematite+rhodochrosite and hematite+kutnohorite/Mn-rich dolomite, respectively. In addition, siderite also experienced strong silicification. These changes were associated with the dissolution of associated sulfides (sphalerite, galena). The following portion of the vein contains low-Mn dolomite and calcite gangue with Zn-rich chlorite, wittichenite, tetrahedrite-group minerals, chalcopyrite, bornite, and djurleite, again showing common replacement textures in case of sulfides. The latest stage was characterized by the input of Ag and Hg, giving rise to Ag-Cu sulfides, native silver (partly Hg-rich), balkanite, and (meta)cinnabar. We explain the formation of hematite-bearing oxidized assemblages at the expense of pre-existing “normal” Příbram mineralization due to repeated episodic infiltration of oxygenated surface waters during the vein evolution. Episodic mixing of ore fluids with surface waters was suggested from previous stable isotope and fluid inclusion studies in the Příbram ore area. Our mineralogical study thus strengthens this genetic scenario, illustrates the dynamics of fluid movement during the evolution of a distinct ore vein structure, and shows that the low content of ore minerals cannot be necessarily a primary feature of a vein.

Polysomatic intergrowths between amphiboles and non-classical pyriboles in magnetite: Smallest-scale features recording a protracted geological history

Abstract Non-classical pyriboles (NCPs) have tetrahedral silicate chains (Ibeam) of multiplicity higher than single (pyroxene) or double (amphibole) Ibeams and are known from amphiboles in altered mafic-ultramafic complexes. NCPs, their polysomatic sequences, and inherent chain-width disorder are petrogenetic tools for interpreting igneous and metamorphic processes. Magnetite, a refractory mineral that can trap and preserve NCPs is a major constituent of iron oxide-copper-gold (IOCG) deposits. We undertook a nanoscale study to show that NCPs and amphiboles are hosted within magnetite cores from the Jatobá Ni-bearing IOCG deposit, Carajás Mineral Province, Brazil. Monoclinic amphiboles and NCPs form polysomatic intergrowths or occur as sparse inclusions along {111}magnetite. There are two chemical populations of amphiboles: Mg-Fe- and Ca-(Al)-amphiboles, the latter including Ce-bearing Mg-hornblende and (ferro)tschermakite. The occurrence contains one of the widest ranges of chain silicates ever recorded, from simple intergrowths of single to triple Ibeam zippers, including pyroxene slabs, to longer NCP polysomes up to 15-Ibeam chains. Clinojimthompsonite (Cjim) is observed for the first time within magnetite. Although no discrete polysomes could be defined, the NCP-amphibole intergrowths have compositions between Mg-Fe amphiboles and Cjim based on Ibeam averages of 2.5–2.7. Relationships between increase in the number of C and A cations from amphibole (2-Ibeam) to n chain silicates (nIbeam) are formulated as nIbeam = T(2 + n) = C(5 + 3n) = A(1 + n), n = integer. Empirical models of crystal structures, validated by STEM simulation, are shown for 4- and 5-Ibeam chain silicates. Co-crystallization of double- and triple-chain silicate structures with rhythmic intergrowths as larger blocks along b is often accompanied by rhythmic Ca-Fe zonation along a, supporting primary NCP crystallization via self-patterning during amphibole growth within magnetite in a close-to-equilibrium system. Chain-width disorder is documented from defects including planar faults, derailments, jogs, and swells. Violations of zipper termination rules indicate primary growth rather than replacement. Amphibole-NCPs inclusions support a multi-stage evolution for Jatobá magnetite. They formed during the first cycle of magnetite overprinting within a mafic/ultramafic lithology that records syn-shearing events. Subsequent formation of calcicamphiboles, including Ce-bearing species, indicate IOCG-related fluids at the onset of mineralization. (Ferro) tschermakite formed at ~7.5 kbar during high-pressure shearing is preserved during main ore deposition. The multi-stage amphibole-NCPs generations in magnetite revealed by our nanoscale study emphasize the interpretive value of magnetite for overprinting events in terranes with protracted geological histories. Analogous NCPs are likely to be abundant in magnetite from magmatic-hydrothermal deposits hosted by greenstone belts and altered mafic/ultramafic complexes. Likewise, discovery of Ce-rich hornblende provides new avenues to understand the early, alkali-calcic alteration stages of IOCG systems and models for REE incorporation into, and subsequent release from chain silicates.

Multi-Stage Evolution of the Oceanic Lithosphere beneath Heard Island, Southern Indian Ocean

Abstract The Kerguelen Plateau is the second biggest submarine large igneous province (LIP) on Earth, however, the nature of the lithospheric mantle source underlying it remains poorly constrained. In this contribution, we provide novel insights into the oceanic lithospheric mantle underlying Heard Island (southern Indian Ocean), which represents the most recent and active phase of volcanic activity (<1 Ma) in the Kerguelen Plateau. We present petrographic and geochemical data for a suite of spinel-bearing harzburgite xenoliths hosted in basanite lavas and provide detailed constraints for distinguishing in situ mantle metasomatism from post-entrapment modification of the xenoliths following interaction with the host magma. We demonstrate that the xenolith mineral compositions and textures preserve a complex multistage history of different modal and cryptic transformations that occurred in the mantle due to: i) high degrees of partial melting that produced highly refractory whole-rock Mg# (Mg# = (Mg + Fe)/Mg × 100; 88–92), major element (FeO/MgO = 0.17) and mineral compositions (e.g. highly forsteritic olivine; Fo = (Mg + Fe)/Mg × 100; 91–92 mol %); ii) solid-state re-equilibration reactions during decompression that caused exsolution of clinopyroxene and Cr-spinel from xenolith orthopyroxene to form symplectite intergrowths; iii) cryptic metasomatism affecting the composition of xenolith clinopyroxene (i.e. enrichment in Na, Th, U and light rare earth elements, and depletion in Rb, Nb, Zr, Hf and Ti) due to interaction with carbonatitic melts in the mantle. Mantle fragments, entrapped by ascending basanite magmas as xenoliths were further modified by reactions with the host magma. This resulted in the partial dissolution of mantle orthopyroxene and replacement by newly formed and compositionally distinct assemblages of clinopyroxene (Mg# 87–91), olivine (Fo: 81–88 mol %) and Cr-spinel (i.e. ‘wehrlitisation’ of the xenoliths). This study highlights the utility of combining petrography and mineral chemistry to decipher the complex and sometimes overprinting and masking effects that different processes (e.g. melting events, metasomatism) exert on the lithospheric mantle, as well as constrain the processes that modify the xenoliths during transport towards the surface.

Multi-stage evolution of the monzonitic Larvik Plutonic Complex (Oslo Rift, Norway) and its implications for the formation of the Kodal Fe-Ti-P(−REE) deposit

The Larvik Plutonic Complex is a monzonitic complex that was emplaced early during the formation of the Permian Oslo Rift (southern Norway). It extends across its entire width (around 50 km), and is made up of a majority of larvikite (augite monzonite) and lardalite (nepheline monzogabbro to nepheline syenite) distributed in ten successive intrusive units that partially intersect each other. The Larvik Plutonic Complex also hosts occurrences of singular Fe-Ti-P-rich rocks of magmatic origin, including the Kodal deposit. These are mainly composed of titanomagnetite, ilmenite, titanaugite and apatite, the latter also featuring rare earth elements (REE) enrichment. Here, we aim to unravel the conditions that allowed the Kodal deposit to form, and determine why other mineralized bodies are not seen elsewhere in the Larvik Plutonic Complex. We compared the petrography and elemental and isotope (Sr, Nd and Hf) geochemistry of both the Kodal mineralization and the neighboring larvikite, in order to provide evidence of their petrogenetic relationship. Both lithologies share the same isotopic ratios (87Sr/86Sr(i): 0.7035–0.7043; εNd(i): +2.37 − +3.48; εHf(i): +3.39 − +9.16), which would suggest a single homogeneous source. The very low dispersion of our isotopic data also suggests that crustal contamination levels in the area were low to negligible. Normalized trace diagrams of larvikite in several localities of the Larvik Plutonic Complex also show enrichments in most incompatible elements, which becomes more prevalent towards the Kodal deposit. Elements like Sr and Eu(2+) follow an opposite trend, because of their compatibility in plagioclase. We therefore infer that the region around the Kodal deposit hosts more fractionated larvikite due to the previous crystallization of successive plagioclase cumulates. We deduce that the Kodal lobe corresponds to a more evolved intrusion, which is no part of Pluton V per se, as considered in the literature until now, but instead derives at least from a monzonitic magma at the origin of the plutons V to VIII). This also implies that the formation of Fe-Ti-P mineralization at Kodal was most likely a consequence of enrichment of the residual melt in alkaline elements and incompatible elements. These conditions support an early hypothesis of formation by silicate-liquid immiscibility, along with petrographic evidence of disequilibrium at the mineralogical scale. However, further analyses would be required to test the hypotheses of silicate-liquid immiscibility against an accumulation of the Fe-Ti-P mineralization from an evolved intermediate magma.

Morphology evolution of supramolecular aggregates from C3-symmetric peptide amphiphiles

During the aging of supramolecular systems, new stable materials with different morphologies, molecular packing, and hierarchical organization may form from the initial assembly. Understanding the mechanisms and pathways accompanying age-related changes may allow for the controlled synthesis of multiple materials from a single molecule in a nature-inspired manner. Herein, we demonstrate the multi-stage evolution of a single solution of C3-symmetric peptide amphiphile containing diphenylalanine fragment and benzyl-1,3,5-tricarboxamide core. Transmission electron microscopy reveals the rapid formation of 20–40 nm wide nanoribbons in an aqueous solution within 60 s after preparation. The lateral edges of nanoribbons contain solvent-exposed aromatic residues that tend to merge via an unconventional edge-to-edge zipping mechanism, leading to the nanoribbon’s growth in width. After reaching a critical width and flexibility, “sticky edges” on the same nanoribbon may merge via a self-zipping mechanism, forming rigid nanotubes. Eventually, mechanical perturbations cause buckling and fracture of nanotubes into shorter nanotubes via flexural or tensile failure. This work reports new evolution pathways in soft 2D assemblies and introduces solution ageing as a promising method to control morphology of peptide amphiphiles.

Enabling multi-stage high-temperature strength evolution prediction of ceramizable composites using a novel multi-field coupled model

Strength varies significantly under high-temperature environment, due to the inherent thermomechanical behavior of the ceramizable material and its coupling with possible chemical reactions. The complexity amplifies for composite materials, considering their multi-phase and multi-scale features, and more importantly, their complicated chemical reactions under high-temperature service conditions. This study proposes an innovative multi-field coupling theory framework for predicting the multi-stage evolution behavior of high-temperature mechanical properties of a ceramizable composite, through incorporating an extended chemical kinetics method, coupled deformation, mass diffusion and heat conduction. The developed model enables direct coupling and simultaneous solving of physical, chemical and thermal variables. It captures well the degradation of mechanical properties for the initial stage and the increase of strength for the later stage, along with the increasing of temperature. The validated model also enables well prediction of time-dependent mechanical properties at high service temperature, with an average error of 8.67% against experimental measured results. The developed method can serve as a general method for the prediction of high-temperature mechanical property of thermal protection composites and structures.

Multi-omics research progress in early-onset colorectal cancer

Globally, the incidence of early-onset colorectal cancer (EOCRC) among individuals younger than 50 is escalating. Compared to late-onset colorectal cancer, EOCRC exhibits distinct clinical, pathological, and molecular features, with a higher prevalence in the left colon and rectum. However, the occurrence and development of EOCRC is a multi-factor and multi-stage evolution process, which is the result of the mutual effect of environmental, genetic and biological factors, and involves the multi-level regulation mechanism of other organisms. With the development and improvement of high-throughput sequencing technology, the application of multi-omics analysis has become an important development direction to resolve the pathogenesis of complex diseases and individualized treatment plans. This article aims to review the research progress of EOCRC at the multi-omics level, providing a theoretical foundation for earlier diagnosis and more precise treatment of this diseases.

Evolution of reservoir quality related to clay coating overgrowths in tight sandstone in the fluvial facies of the southeastern Sichuan Basin

As a result of silicate overgrowth, clay coatings influence the evolution of reservoir quality during diagenesis. Most studies indicate coatings can resist compaction and inhibit cementation, thus preserving primary porosity and serving as one of the primary controlling factors for improving reservoir quality. However, some research suggests clay coatings have insufficient hardness to resist compaction and could potentially block pore throats and prevent fluid flow within the sandstone, negatively affects reservoir quality. Therefore, to address whether coatings are positive to reservoir evolution, this study employs polarized light microscopy, scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), and porosity-permeability testing to investigate the characteristics of clay coatings within the fluvial facies sandstone of the Xiashaximiao Formation. The microscopy reveals abundant clay coatings were found, mainly in lithic-arenite with 30%–45% feldspar and rock fragments. The underlying Lianggaoshan Formation locally exhibits interbedded siltstones with volcanic rock fragments, providing material sources for the clay coatings formation. SEM and EDX analyses indicate two predominant forms of clay coatings: single-layer (primarily chlorite) and double-layer (inner smectite/illite, outer ferroan chlorite). Single-layer overgrowths primarily consist of thin layers of chlorite (5–15 μm), whereas double-layer overgrowths consist of a thin inner zone (1–5 μm) covering the grain surface and a thicker outer zone (10–20 μm) covering the inner zone, demonstrating characteristics indicative of multi-stage growth. Porosity-permeability testing results the sandstone samples have <10% porosity, which are typically tight sandstones, but those with clay coatings have higher porosity. Nevertheless, sandstones with double-layer overgrowths exhibit lower permeability relative to those with single-layer overgrowths or without overgrowths. Therefore, based on the integration of morphological and physical properties of silicate overgrowths, it is proposed the efficiency of clay coatings in resisting compaction, inhibiting cementation, and preserving primary porosity increases with the number of growth stages, layers, and thickness, which in turn depends on the abundance of source materials. Single-layer coatings facilitate fluid migration, whereas thicker double-layer overgrowths are prone to occluding narrow pore throats, thereby restricting fluid mobility. Consequently, this study establishes a model for the multi-stage evolution of clay coatings overgrowths, elucidating the varying fluid migration behaviors across different stages and providing a more detailed investigation of the implication of clay coatings on reservoir quality, thus offering new theoretical insights into diagenesis and the evolution of tight sandstone reservoirs.

Multistage evolution of gold mineralization in the Kibali gold district: Insights from pyrite analyses

The Kibali gold district, located on the Congo Craton, comprises a Neoarchean gold resource exceeding 28.7 Moz. The district is located within a westerly-verging stacked fold-and-thrust belt associated with a compressional tectonic regime active from ca. 2.64–2.60 Ga. Deposits are hosted by a major fault zone that consists of a complex series of smaller thrust faults, shear zones, and folds, which extend over 60 km. Gold deposits are primarily hosted in BIF and clastic sedimentary rocks. The gold and associated sulfides are in veins and disseminated in NE-to NNE-trending ore shoots within the deformed and metamorphosed volcanosedimentary rocks. Pyrite is the dominant sulfide mineral and hosts both solid solution gold and free gold. Because of its strong association with the gold mineralization, our study focusses on unravelling the metallogeny of the area by considering pyrite textural analyses, in situ trace element analyses using Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS), and S isotopic composition (δ34S) analyses using Secondary Ion Mass Spectrometry (SIMS).Eight distinct pyrite types were identified, including microcrystalline sooty (py-0a), small grains (<40 μm) (py-0b), aggregate recrystallized (py-1), core-rich inclusion (py-2), vein-like (py-3), non-zoned (py-4a), oscillatory As-bands zoned (py-4b), and cubic euhedral (py-5) pyrite. The ore-forming processes occurred over a polyphase evolution. Syn-diagenetic pyrite py-0a in volcaniclastic layers of older basin sediments served as the primary repository of Au (15.6 ppm median) with a near-zero δ34S value. Late diagenetic or early metamorphic pyrite (py-0b) was found in younger basin sediments. Py-1 resulted from solid-state recrystallization of py-0a and py-0b. During the early ore stage, porous py-2 with high Au concentrations (3.1 ppm) and various trace element enrichments precipitated due to fluid-rock interaction. Metal precipitation occurred through sulfidation and carbonation of wall rock with a relatively reduced fluid undergoing 34S-depletion. However, py-3 displayed notable trace element depletion and a complex mineral association. In a second ore stage, py-4a and zoned py-4b deposition occurred, dominated by an over-pressured fluid fracturing brittle rock. Py-4b, rich in Au (5.5 ppm) concentrated in oscillatory zoned As-rich bands, resulted from interactions during pulsed fluid flow. This process involved fluid phase separation, non-equilibrium conditions, 32S-depletion, and precipitation of py-4b with a high δ34S value (6.4 ‰ mean). Subsequently, pyrite (0–4) generations underwent deformation during a later ductile deformation event, leading to the remobilization and concentration of invisible gold into adjacent gold grains within the high-grade shoot plunging NE. This process involved shearing, boudinaging, and folding ore minerals in tightly folded structures. Late-stage py-5 formed under gold-poor fluid conditions or inefficient gold depositional conditions. Brittle fracturing of these grains later provided local sites for remobilized gold. The study contributes insights into the origin and evolution of gold mineralization in the Kibali gold district, supporting a multistage ore-forming fluid system.

Investigating rock mutation characteristics and damage state warning model based on energy conversion

AbstractRock engineering achieves the secondary stress balance through rock mass structure adjustment, where energy conversion is throughout and associated closely with rock deformation and damage. In this study, a series of triaxial compression tests were conducted on red sandstone to investigate these features. The results showed that the damage state of red sandstone specimens presented five stages under different confining pressure, corresponding to the multistage evolution characteristic of the energy conversion. In the case of the dissipation energy conversion ratio (η), it showed five stages: a gradual increase, decreasing gradually and reaching a minimum value, increasing gradually, increasing with growth rate, and accelerated growth, therein the strong nonlinearity reflected the stability and instability of the internal structure of the rock and had the basic characteristics of the mutation theory, therefore the damage state warning model was established on just that. The relation between the η and time fitted by a four‐rank potential function had a fitting parameter (R2) larger than 0.9, and the bifurcation set of the η calculated by the damage state warning model had twice stages less than 0. The second stage, which occurred near the minimum value of the η and run through the plastic deformation stage, could be used to predict rock damage and fracture, and it was proven feasible by acoustic emission (AE) precursor and better than AE warning. This research can enrich the methods for identifying rock damage state and provide reference for revealing the occurrence and development mechanism of various rock instability disasters.

Reconstruction of palaeo‐oil reservoirs in the ultra‐deep and over‐mature Sinian Dengying Formation of the Central Sichuan Basin: Insights from basin and petroleum system modelling

Ultra‐deep Sinian carbonate rocks are rich in natural gas, and the Deng‐4 Member of the Central Sichuan Basin has been shown to have an extremely high degree of thermal evolution. They are characterized by dry gas produced due to the thermal cracking of palaeo‐oil reservoirs (PORs). The distribution of PORs as materials for the formation of cracked gas reservoirs remains unclear. The complex multistage evolution process and limited drilling data make it challenging to precisely and systematically recover a range of PORs. Based on basin and petroleum system modelling (BPSM), the bottom‐up migration and accumulation method was used to investigate the distribution of PORs. Research shows that the PORs in the Sinian Deng‐4 Member were mainly formed in the Early–Middle Triassic under the mixed contribution of Cambrian and Sinian source rocks, and the coupling of palaeostructural and trap settings controlled its accumulation. Generally, the distribution of PORs can be divided into two categories: one is located at the core of the uplift zone and is controlled by structural‐stratigraphic composite traps, whereas the other is controlled by a series of lithologic traps formed in the slope area. Sensitivity analysis showed that the distribution patterns of the PORs were mostly related to the facies conditions (physical characteristics) of the reservoirs. The widely distributed PORs provide necessary and sufficient material conditions for the formation of cracked Sinian gas reservoirs in the Central Sichuan Basin, and the North Slope area has great potential for natural gas exploration in the future.

Photon-triggered jets as probes of multi-stage jet modification

Prompt photons are created in the early stages of heavy ion collisions and traverse the QGP medium without any interaction. Therefore, photontriggered jets can be used to study the jet quenching in the QGP medium. In this work, photon-triggered jets are studied through different jet and jet substructure observables for different collision systems and energies using the JETSCAPE framework. Since the multistage evolution used in the JETSCAPE framework is adequate to describe a wide range of experimental observables simultaneously using the same parameter tune, we use the same parameters tuned for jet and leading hadron studies. The same isolation criteria used in the experimental analysis are used to identify prompt photons for better comparison. For the first time, high-accuracy JETSCAPE results are compared with multi-energy LHC and RHIC measurements to better understand the deviations observed in prior studies. This study highlights the importance of multistage evolution for the simultaneous description of experimental observables through different collision systems and energies using a single parameter tune.

Multistage evolution of the Aladağ mantle peridotites (S-Türkiye): Processes of partial melting and melt-peridotite interaction in Mid-Ocean Ridge and Subduction Zones

The Aladağ ophiolite is located in the eastern Taurides, north of the city of Adana, southern Türkiye and, from bottom to top, is composed of mantle peridotites, ultramafic-mafic cumulates, isotropic (massive) gabbro and diabase dykes. Mantle peridotites are represented by varying degrees of serpentinized dunite, harzburgite and lherzolite. We studied 100 lherzolite, harzburgite and dunite samples representing the entire Aladağ ophiolite mantle. Whole rock major and trace element analysis were performed for all samples, and mineral chemistry analysis were carried out on selected mineral phases.According to geochemical characteristics, mantle peridotites are divided into two sub-groups: abyssal (Group-1) and suprasubduction zone peridotites (Group-2). Group-1 mantle peridotites are represented by high clinopyroxene modal abundances, whole-rock and clinopyroxene heavy Rare Earth Element (REE) contents and low spinel Cr# values (13–47). Whole-rock heavy REE patterns indicate that these rocks are 5–18 % unhydrous partial melting residues. In contrast, Group-2 mantle peridotites are represented by lower clinopyroxene modal abundances, whole-rock and clinopyroxene heavy REE contents, and higher spinel Cr# values (44–74) than Group-1 samples, reflecting higher partial melting degrees of up to 33 %. Light REE and LILE enriched whole-rock and clinopyroxene contents of Group-2 samples reflect that, in addition to depletion, they were enriched with fluids/melts and underwent both cryptic and modal metasomatism in the subduction zone.Aladağ peridotites have formed originally by low degree partial melting at mid-ocean spreading ridge (MOR) and later re-melted and metasomatized/refertilized in a suprasubduction zone (SSZ) environment.

Silurian–Devonian construction of active continental margin in the southwestern Paleo-Asian Ocean witnesses the modification of fluvial system by early land plants

In accretionary orogeny, the intra-oceanic subduction-accretion could generate juvenile continental crustal materials and form new continental blocks by their lateral tectonic accretion, and the juvenile continental crust would provide a sialic basement for continental margin arc during the subsequent oceanic-continental subduction-accretion. These two distinct subduction-accretion processes occurred successively in the southwestern part of the Paleo-Asian Ocean during the Neoproterozoic–Late Paleozoic and created a multi-stage evolution of continental crusts in West Junggar. In this study, a Late Silurian landmass in West Junggar is revealed by the detailed geological mapping and comparison of the Late Silurian–Early Devonian angular unconformity in southern and northern West Junggar. This crucial unconformity confines the Middle Silurian termination of Early Paleozoic intra-oceanic subduction-accretion, as evidenced by the pre-Late Silurian emplacement of Cambrian–Ordovician ophiolitic mélanges, the Middle Silurian cessation of Early Paleozoic arc magmatism and the Late Silurian–Early Devonian sedimentary hiatus. The Late Silurian landmass was consequently constructed by amalgamations of island arcs, accretionary complexes and seamounts, and its break-up was marked by the Middle Devonian opening of the Karamay back-arc Ocean in central West Junggar. In contrast with the Early Paleozoic intra-oceanic arc systems, continental margin arcs on the sialic basement of rifted landmass emerged since the Middle Devonian, as suggested by our new chronological data and field observations. We further unravel that the increase in mudstone of Devonian successions on the active continental margin is contemporaneous with the emergence and boom of lycopsid forest in West Junggar, which is in agreement with a global trend in alteration of fluvial systems due to evolution of early land plants. In summary, this paper presents a typical record for two distinguished styles of subduction-accretion systems that developed successively in an accretionary orogeny, and sedimentary successions of the later active continental margin documented the interaction between terrestrial sedimentation and early land plants.

Multistage evolution of the Angara orogenic belt (SW Siberian craton) from granulite to ultrahigh-temperature metamorphism

An exotic block of andalusite-bearing garnet-cordierite-sillimanite gneisses was identified in the area of ultrahigh-temperature metamorphic complex of Angara-Kan block (southwestern Siberian Craton). Study of PT-conditions of these rocks indicate that peak PT-parameters correspond to granulite facies at moderate pressure (T = 820 °C, P = 6 kbar) and was followed by clockwise retrograde PT-path with changing direction from near isothermal decompression to near isobaric cooling at pressure about 3 kbar. The new U-Pb SHRIMP and LA-ICP-MS data on zircons and monazite indicate the time of granulite metamorphism at 1865 ± 5 Ma. The age data, metamorphic mineral assemblages and micro-textures indicate that garnet-cordierite-sillimanite gneisses were not affected by later ultrahigh-temperature metamorphism (1.78–1.76 Ga) widespread in the Angara-Kan block. Thus, the block of garnet-cordierite-sillimanite gneisses can be considered as a fragment of the early granulite metamorphic complex, which was tectonically combined with UHT metamorphic block of the Angara-Kan terrane. The observations prove multistage metamorphic history of the Angara-Kan block and indicate collisional event at ca. 1.86 Ga typical for Siberian craton amalgamation. This metamorphic episode caused melting out of a large volume of post-collisional granitoids and probably played a key role in pre-conditioning of the crust for achieving of UHT conditions during the following metamorphism.

Structural attributes, evolution and petroleum geological significances of the Tongnan negative structure in the central Sichuan Basin, SW China

The Tongnan secondary negative structure in central Sichuan Basin has controls and influences on the structural framework and petroleum geological conditions in the Gaoshiti-Moxi area. To clarify the controls and influences, the deformation characteristics, structural attributes and evolution process of the Tongnan negative structure were investigated through a series of qualitative and quantitative methods such as balanced profile restoration, area-depth-strain (ADS) analysis, and structural geometric forward numerical simulation, after comprehensive structural interpretation of high-precision 3D seismic data. The results are obtained in three aspects. First, above and below the P/AnP (Permian/pre-Permian) unconformity, the Tongnan negative structure demonstrates vertical differential structural deformation. It experiences two stages of structural stacking and reworking: extensional depression (from the Sinian Dengying Formation to the Permian), and compressional syncline deformation (after the Jurassic). The multi-phase trishear deformation of the preexisting deep normal faults dominated the extensional depression. The primary depression episodes occurred in the periods from the end of Late Proterozoic to the deposition of the 1st–2nd members of the Dengying Formation, and from the deposition of Lower Cambrian Longwangmiao Formation–Middle–Upper Cambrian until the Ordovician. Second, the multi-stage evolution process of the Tongnan negative structure controlled the oil and gas migration and adjustment and present-day differential gas and water distribution between the Tongnan negative structure and the Gaoshiti and Moxi-Longnüsi structural highs. Third, the Ordovician, which is limitedly distributed in the Tongnan negative structure and is truncated by the P/AnP unconformity on the top, has basic geological conditions for the formation of weathering karst carbonate reservoirs. It is a new petroleum target deserving attention.

Evolution of lasR mutants in polymorphic Pseudomonas aeruginosa populations facilitates chronic infection of the lung

Chronic infection with the bacterial pathogen Pseudomonas aeruginosa often leads to coexistence of heterogeneous populations carrying diverse mutations. In particular, loss-of-function mutations affecting the quorum-sensing regulator LasR are often found in bacteria isolated from patients with lung chronic infection and cystic fibrosis. Here, we study the evolutionary dynamics of polymorphic P. aeruginosa populations using isolates longitudinally collected from patients with chronic obstructive pulmonary disease (COPD). We find that isolates deficient in production of different sharable extracellular products are sequentially selected in COPD airways, and lasR mutants appear to be selected first due to their quorum-sensing defects. Polymorphic populations including lasR mutants display survival advantages in animal models of infection and modulate immune responses. Our study sheds light on the multistage evolution of P. aeruginosa populations during their adaptation to host lungs.

Abundance and Genetic Significance of Lithium in Karst-Type Bauxite Deposits: A Comparative Review

Palaeo weathering during the Cretaceous–Eocene interval is most favorable for bauxitization, i.e., transport and deposition in traps on the karstified surfaces of the Mediterranean karst bauxite belt, including the Parnassos–Ghiona bauxite deposit. Resources of lithium (Li), a critical metal of strategic significance in karst-type bauxite deposits, have attracted significant attention in recent years. Due to the discovery of the Li enrichment in certain karstic bauxite deposits in Europe and particularly in China, this review study is focused on the unexplored Li content in the Parnassos–Ghiona (Greece) bauxite deposit, aiming to improve the understanding of the major controlling factors for their origin and enrichment of critical metals. The presence of thin (up to 50 cm) pyrite-bearing coal seams and carbonaceous facies on top of the Parnassos–Ghiona bauxite deposit, at the transition between B3 (the youngest) bauxite horizon and the occurrence of multicolor bauxite ores reflecting a multistage evolution and changes in the mineralogy and geochemistry, is a common feature with other bauxite deposits in Europe and elsewhere. The organic matter, such as microorganisms in coal layers and carbonaceous layers (derived from plants and algae growing in paleo-mires after a regression of the sea), contains Li, which is derived from seawater, as suggested by a positive correlation with B (a seawater component as well). The available geological, mineralogical, and geochemical data highlight the particular significance of coal layers and carbonaceous layers overlying bauxite bodies as a driving force for redox reactions and as a source of Li in the exploration of karst-type bauxite deposits.