The relevance of the greenhouse gas N2O was investigated in two small-scale biomass combustion plants, a 30-kW fixed bed and a 70-kW moving grate furnace, both of which use double air staging. Furthermore, the 70-kW furnace was simulated with ideal reactor models, applying a detailed nitrogen chemistry mechanism to gain insights into N2O formation mechanisms that occur during double air-staged combustion.The experimental and simulated results confirm the existence of correlations between CO, NOx and N2O. For all investigated fuels, N2O reached the highest levels (increase of up to 300 %) when high CO and low NOx concentrations were present. Therefore, caution is advised when looking for minimum NOx emissions, due to the risk of having high N2O emissions, an aspect which is often overlooked.A deeper analysis of the N2O formation mechanisms revealed that N2O is mainly generated from HCN in the oxidation zone and it is thermally dissociated at high temperatures. Finally, a comparison between the results of both plants showed that the concern about high N2O emissions at minimum NOx concentrations is not a reactor-specific problem; therefore, it is necessary to ensure that CO and N2O are kept at a low level during NOx reduction with primary measures.
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